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P3MOT-decorated metal-porphyrin-based zirconium-MOF for the efficient electrochemical detection of 4-nitrobenzaldehyde

Anal. Methods, 2024, 16,2093-2100
DOI: 10.1039/D4AY00152D, Paper
Wen-yi Chen, Xin-yu Huang, Qian Sun, En-qing Gao
Developed a novel hybrid P3MOT@PCN-222(Fe) via in situ polymerization for 4-NBA detection. Showcased broad detection range, high sensitivity, selectivity and stability, laying groundwork for environmental monitoring.
The content of this RSS Feed (c) The Royal Society of Chemistry




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578: Customer Support, P3 Color, Dave on Productivity, and Mobile vs Desktop

Is Apple's Numbers amazing or the worst? Customer support at various levels of software, Figma and P3 color, imagining a colorspace property in CSS, what's Dave doing for productivity, how has offloading CSS Tricks affected Chris, and should we build different websites for mobile vs desktop?




p3

Montblanc and Ferrari’s new pen is inspired by the carmaker’s iconic Daytona SP3

Montblanc has reimagined the limited edition fountain pen Montblanc Ferrari Stilema SP3 LE 599’s ink-filling mechanism behind a semi-translucent red blade



  • Life & Style

p3

Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes

Org. Chem. Front., 2024, 11,6385-6392
DOI: 10.1039/D4QO01243G, Research Article
Jinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian Chen
A cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Theoretical insights into Pd-catalyzed dual γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids: mechanistic pathways, substituent influence on product selectivity, diastereoselectivity, and additive effects

Org. Chem. Front., 2024, 11,6393-6410
DOI: 10.1039/D4QO01451K, Research Article
Jiaoyang Liu, Li-juan Huang, Zeang Sun, Juan Li
DFT calculations were employed to explore the detailed reaction mechanism and the origins of the experimentally observed product, regio-, and diastereoselectivities in the Pd-catalyzed dual-γ-1,1-C(sp3)–H activation of aliphatic carboxylic acids.
The content of this RSS Feed (c) The Royal Society of Chemistry




p3

Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
The content of this RSS Feed (c) The Royal Society of Chemistry




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IBzH (IBenzhydryl): Sterically-Flexible N-Aliphatic N-Heterocyclic Carbenes (NHC) for Iron-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Unactivated Haloalkanes

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01315H, Communication
Marlena Kardela, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
Iron-catalyzed cross-coupling has emerged as a pivotal concept for the synthesis of valuable products across various facets of chemical research, including pharmaceuticals, organic materials and biological probes. In this respect,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Vintage meets modern in this solar powered radio and MP3 player




p3

Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Iron/photoredox dual-catalyzed redox-neutral double decarboxylative C(sp3)–C(sp3) cross-coupling

Green Chem., 2024, 26,11334-11339
DOI: 10.1039/D4GC04523H, Paper
Qi Zhang, Shanghui Wu, Xuesong Wu
An efficient iron porphyrin/photoredox dual catalytic system for the double decarboxylative radical C(sp3)–C(sp3) cross-coupling under redox-neutral and mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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EtOH-mediated cascade C(sp3)–H alkylation via aromatization-driven [1,6]-hydride transfer: green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indoles

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04534C, Paper
Yao-Bin Shen, Qian-Hao Zhuang, Xiao-Lin Wang, Xiao-De An, Bin Qiu, Tiesheng Shi, Jian Xiao
Unprecedented EtOH-mediated cascade C(sp3)–H alkylation reactions of 4-dialkylamino-indole-3-carbaldehydes have been realized for the green and divergent synthesis of spirocyclic azepino[4,3,2-cd]indole derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




p3

112 Bytes Win32/PerfectXp-pc1/sp3 Add Admin Shellcode

112 bytes small Win32/PerfectXp-pc1/sp3 (Tr) add administrator shellcode.




p3

Microsoft IIS ISAPI FrontPage fp30reg.dll Chunked Overflow

This is an exploit for the chunked encoding buffer overflow described in MS03-051 and originally reported by Brett Moore. This particular modules works against versions of Windows 2000 between SP0 and SP3. Service Pack 4 fixes the issue.




p3

Microsoft IIS ISAPI FrontPage fp30reg.dll Chunked Overflow

This is an exploit for the chunked encoding buffer overflow described in MS03-051 and originally reported by Brett Moore. This particular modules works against versions of Windows 2000 between SP0 and SP3. Service Pack 4 fixes the issue.




p3

Call for case studies – Call for participation: Entrepreneurship360

The OECD and the EC are inviting individual teachers and schools to submit case studies about their strategies, practices and achievements in promoting entrepreneurship in schools and VET. Participation in the Call requires a submission of an abstract of 1-2 pages by email to Joseph.Tixier@oecd.org indicating in the subject line "Entrepreneurship360- Call for case studies". Deadline for submission is 30 April 2014.




p3

Call for case studies – Call for participation: Entrepreneurship360

The OECD and the EC are inviting individual teachers and schools to submit case studies about their strategies, practices and achievements in promoting entrepreneurship in schools and VET. Participation in the Call requires a submission of an abstract of 1-2 pages by email to Joseph.Tixier@oecd.org indicating in the subject line "Entrepreneurship360- Call for case studies". Deadline for submission is 30 April 2014.




p3

The crystal structures of Fe-bearing MgCO3 sp2- and sp3-carbonates at 98 GPa from single-crystal X-ray diffraction using synchrotron radiation

The crystal structure of MgCO3-II has long been discussed in the literature where DFT-based model calculations predict a pressure-induced transition of the carbon atom from the sp2 to the sp3 type of bonding. We have now determined the crystal structure of iron-bearing MgCO3-II based on single-crystal X-ray diffraction measurements using synchrotron radiation. We laser-heated a synthetic (Mg0.85Fe0.15)CO3 single crystal at 2500 K and 98 GPa and observed the formation of a monoclinic phase with composition (Mg2.53Fe0.47)C3O9 in the space group C2/m that contains tetra­hedrally coordinated carbon, where CO44− tetra­hedra are linked by corner-sharing oxygen atoms to form three-membered C3O96− ring anions. The crystal structure of (Mg0.85Fe0.15)CO3 (magnesium iron carbonate) at 98 GPa and 300 K is reported here as well. In comparison with previous structure-prediction calculations and powder X-ray diffraction data, our structural data provide reliable information from experiments regarding atomic positions, bond lengths, and bond angles.




p3

Saturation and self-absorption effects in the angle-dependent 2p3d resonant inelastic X-ray scattering spectra of Co3+

It is shown that the 2p3d resonant inelastic X-ray scattering intensity is distorted by saturation and self-absorption effects, i.e. by incident-energy-dependent saturation and by emission-energy-dependent self-absorption.




p3

MP3 Player That Does Not Make Unwanted Noise




p3

Controling New mp3 player.




p3

Why do smartphones always get better features than MP3 players?




p3

MP123PAK MP3-Player: Charging and Playing




p3

Coby mp3 player bugs




p3

How to make a custom USB cable for a Finis Neptune MP3 player?




p3

Recommendations for a good MP3 player in 2019?




p3

MP3 players and Playlist




p3

Find Real China Wholesale Distributors for MP3 Players

Chinese firms are producing and exporting popular electronics such as MP3 players that are high in quality and affordable.




p3

Ipod Most Popular Mp3 Mp4 player

This article describes the many iPods generations and features that made this product one of the most popular mp3 mp4 players of all times.




p3

How to Make Your Own Free MP3 Ringtones

Learn how to make your own mp3 ringtone and never buy ringtones again. I will teach you how to make free mp3 ringtones from your own music database. The price for a ringtone range between $2.5 to $3.5, so why spend when you can get them 100% free.




p3

MP3 Player Download

Today, MP3 players are highly versatile. They can be hooked into car stereos, CD players, computer hard drives, and simply as a standalone player with its own music collection. There are many sites that offer software-based MP3 player downloads.




p3

Choosing an MP3 Player

Selecting an MP3 Player that is exactly what you want is simple with a buying guide to get you headed in the right direction.




p3

A Guide to Buying an mp3 Multimedia Player

With digital music coming, the mp3 player has taken the high ground in digital music and video entertainment. There are a number of important issues to consider when choosing the type of player that will suit your requirements best...




p3

Mp3 Player Purchase Tips

This article explains the features of mp3 players which will help one to make the best of this next purchase. Internal memory size, battery life, connectivity to pc and other features are explained as well.




p3

UkeySoft Apple Music Converter for Mac v. 6.8.6 Now Supports Convert Apple Music to MP3 on macOS Catalina 10.15

UkeySoft Software Inc. a multimedia and encryption software development company has developed and released Apple Music Converter for users to convert Apple Music to MP3, M4A, WAV, FLAC, etc. on the latest macOS system Catalina.




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UkeySoft Apple Music Converter & Spotify Music Converter to Convert Streaming Music to MP3 for Listening on Any MP3 Player

UkeySoft has overcome streaming music various DRM technical problems and offers UkeySoft Apple Music Converter and UkeySoft Spotify Music Converter which can convert Apple Music and Spotify songs to MP3, M4A, WAV for listening on any MP3 players.




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UkeySoft Has Released Spotify Music Converter for Spotify Free & Premium Users to Download MP3s Songs

Spotify Free users cannot download songs to offline listening. Good news: UkeySoft Software Inc. offers its Spotify Music Converter to helps all users download Spotify songs to MP3 for freely listening.




p3

P365's Just Got Better!

True Precision Produces First Ever P365 Match Grade Barrels




p3

Small molecule antagonists of phosphatidylinositol-3,4,5-triphosphate (PIP3) and uses thereof

Disclosed are new members of a class of non-lipid small molecule inhibitors which interfere with the interaction between phosphoinositol-3,4,5-triphosphate (PIP3) and pleckstrin homology (PH) domains. These molecules target a broad range of PIP3-dependent signaling events in vitro and exert significant anti-tumor activity in vivo, with improved activity and selectivity toward particular PH domains. The small molecule inhibitors of the invention can be used alone or together with tumor necrosis factor (TNF)-related apoptosis-inducing ligand (TRAIL) or other cancer medicament to treat cancer. Small molecule inhibitors of the invention act synergistically in combination with TRAIL and with other Akt inhibitors in treating cancer. Pharmaceutical compositions and methods for treating cancer are provided.




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What Does It Take to Make Your Podcast Better? – TAP318

If your podcast isn't improving, it might be stagnating. This can hurt your growth and your potential. Here's what you need to improve!










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How to Support Your Podcast Audience on Android – TAP325

Apple gets a lot of attention in podcasting, but Android is actually more popular than iOS. Here's how to not forget your Android podcast fans!




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How YOU Can Help Podcasting Grow – TAP326

Podcasting is unlike any other media. You, as a podcast-fan or a podcaster, are the most powerful influence to bring more people to podcasts.




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Podcasting Lessons from a Binge-Listener – TAP327

Podcasting is a time-shifted media. Some fans will binge on all your content, which can reveal some areas to improve your podcast. Here are 12 lessons.