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GUBIO, Nigeria — Unrelenting price rises and a brutal insurgency had already made it hard for Nigerians in northeastern Borno State to feed their families. When a dam collapsed in September, flooding the state capital and surrounding farmland, many people ran out of options. Now they queue for handouts in camps for those displaced by fighting between extremist Boko Haram rebels and the military. When those run out, they seek work on local farms where they risk being killed or raped by local bandits. "I can't even cry anymore. I'm too tired," said Indo Usman, who tried to start again in the state capital Maiduguri, rearing animals for the two annual Muslim holy days, after years of repeatedly fleeing rebel attacks in rural Borno. The flood washed that all away, driving her, her husband and their six children to a bare room at Gubio, an unfinished housing project about 96 km northwest of Maiduguri that has become a displacement camp. Torrential rains and floods in 29 of Nigeria's 36 states this year have destroyed more than 1.5 million hectares of cropland, affecting more than 9 million people, according to the Food and Agriculture Organization of the United Nations. Climate change is a factor, as is Nigeria's poorly maintained or non-existent infrastructure as well as vulnerabilities caused by the weakening Naira currency and the scrapping of a government fuel subsidy. The cost of staples like rice and beans has doubled, tripled or even quadrupled in a year, depending on location — an unmanageable shock for millions of poor families. Mass kidnappings for ransom in the northwest and conflict between farmers and pastoralists in the central belt, traditionally the nation's bread basket, have also disrupted agriculture and squeezed food supplies. 'Hungriest of the hungry' Roughly 40% of Nigeria's more than 200 million people live below the international poverty line of $2.15 per person per day, the World Bank estimates. Already, 25 million people live in acute food and nutrition insecurity - putting their lives or livelihoods in immediate danger, according to a joint analysis by the government and U.N. agencies. That number is expected to rise to 33 million by next June-August. "The food crisis in Nigeria is immense because what we are seeing is a crisis within a crisis within a crisis," said Trust Mlambo, head of program for the northeast at the World Food Program, in an interview with Reuters in Maiduguri. With international donors focused on emergencies in Gaza, Ukraine and Sudan, Mlambo said there was not enough funding to fully meet Nigeria's growing need for food aid. "We are really prioritizing the hungriest of the hungry," he said. In Borno, the Alau dam, upriver from Maiduguri, gave way on Sept. 9, four days after state officials had told the public it was secure. Local residents and engineers had been warning that it was under strain. Hundreds of people were killed in the resulting flood, according to aid workers who did not wish to be identified for fear of offending the state government. A spokesperson for the state government did not respond to requests for comment. Zainab Abubakar, a self-employed tailor in the city who lived in relative comfort with her husband and six children in a house with a refrigerator, was awoken at midnight by water rushing into her bedroom. They ran for their lives while the flood destroyed their house and carried everything away, including her sewing machine. Now, they are sheltering at Gubio and collecting rice from aid agencies in a plastic bucket. "There is no alternative," she said. In Banki, on Nigeria's border with Cameroon about 133 km southeast of Maiduguri, Mariam Hassan lost crops of maize, pepper and then okra in repeated flooding of her subsistence farm this year, leaving her with nothing to eat or sell. "I beg the neighbors or relatives to give me food, not even for me but for my children, for us to survive," said Hassan, who has eight children. "The situation has turned me into a beggar."
Until now, β-hydroxybutyrate (BHB) has been known as a compound produced by the liver to be used as fuel.
The post Metabolic Compound Found to Regulate Appetite and Body Weight appeared first on Sci.News: Breaking Science News.
Torrential rains and floods in 29 of Nigeria's 36 states this year have destroyed more than 1.5 million hectares of cropland, affecting more than nine million people
At least 104 people have been sickened, with 34 hospitalized, in an outbreak of E. coli food poisoning tied to onions served on McDonald's Quarter Pounder hamburgers, federal health officials said Wednesday.
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This paper puts forward a verification method for compound purposes and compound reasons to be used during purpose limitation.
When it is absolutely necessary to collect privacy related information, it is essential that privacy enhancing technologies (PETs) protect access to data - in general accomplished by using the concept of purposes bound to data. Compound purposes and reasons are an enhancement of purposes used during purpose limitation and binding and are more expressive than purposes in their general form. Data users specify their access needs by making use of compound reasons which are defined in terms of (compound) purposes. Purposes are organised in a lattice with purposes near the greatest lower bound (GLB) considered weak (less specific) and purposes near the least upper bound (LUB) considered strong (most specific).
Access is granted based on the verification of the statement of intent (from the data user) against the compound purpose bound to the data; however, because purposes are in a lattice, the data user is not limited to a statement of intent that matches the purposes bound to the data exactly - the statement can be a true reflection of their intent with the data. Hence, the verification of compound reasons against compound purposes cannot be accomplished by current published verification algorithms.
Before presenting the verification method, compound purposes and reasons, as well as the structures used to represent them, and the operators that are used to define compounds is presented. Finally, some thoughts on implementation are provided.
Chempound is a new generation repository architecture based on RDF, semantic dictionaries and linked data. It has been developed to hold any type of chemical object expressible in CML and is exemplified by crystallographic experiments and computational chemistry calculations. In both examples, the repository can hold >50k entries which can be searched by SPARQL endpoints and pre-indexing of key fields. The Chempound architecture is general and adaptable to other fields of data-rich science.
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The post Deadly E. coli outbreak linked to McDonald’s Quarter Pounders sickens 49 people in 10 states appeared first on Boston.com.
A trooper from the Michigan State Police recently rescued a construction worker who was stuck under 700 pounds of drywall while working alone on a job site in Sault Ste. Marie, Michigan, reported George Hunter of The Detroit News.
The Tiger XT line of volatile organic compound detectors includes the Tiger XTL Portable VOC Gas Detector; the Tiger XT Handheld VOC Detector; and the Tiger XT Select Benzene Gas Detector, which incorporates a 10.0 eV lamp within its sensor that can detect total aromatic compounds down to concentrations of 1 ppb.
A white paper from Lehigh explains the Compound Effect Solution to Plantar Fasciitis – how to give your employees the 1-2-3 punch, providing the best-fitting approved footwear, along with custom orthotics and medical-grade compression socks.
Product launches with more than 30% fat content—such as high-fat dairy—are up, and butter sales have jumped, outpacing the growth of margarines and spreads by 360%.
These meat and poultry products were shipped to other establishments and distributors nationwide, then distributed to restaurants, schools and institutions.
This study presents the first theoretical predictions of the phase transitions, elastic properties, and thermal behavior of AuMTe2 (M = Ga, In) chalcopyrite compounds. Using density functional theory and the quasi-harmonic Debye model, key mechanical and thermodynamic properties are analyzed, offering insights valuable for future experimental validation.
L3-edge high-energy-resolution fluorescence-detection X-ray absorption near-edge structure (XANES) spectra for palladium and rhodium compounds are presented, with focus on their electronic structures. The data are compared with transmission XANES spectra recorded at the K-edge. A correlation between the absorption edge energy and the metal ion oxidation state is not observed. Despite the different filling of the 4d orbitals and different local coordination, the Rh and Pd compounds show remarkably similar spectral shapes. Calculation of the density of states and of the L3-XANES data reproduce the experimental results.
The Swiss Light Source facilitates fragment-based drug-discovery campaigns for academic and industrial users through the Fast Fragment and Compound Screening (FFCS) software suite. This framework is further enriched by the option to utilize the Smart Digital User (SDU) software for automated data collection across the PXI, PXII and PXIII beamlines. In this work, the newly developed HEIDI webpage (https://heidi.psi.ch) is introduced: a platform crafted using state-of-the-art software architecture and web technologies for sample management of rotational data experiments. The HEIDI webpage features a data-review tab for enhanced result visualization and provides programmatic access through a representational state transfer application programming interface (REST API). The migration of the local FFCS MongoDB instance to the cloud is highlighted and detailed. This transition ensures secure, encrypted and consistently accessible data through a robust and reliable REST API tailored for the FFCS software suite. Collectively, these advancements not only significantly elevate the user experience, but also pave the way for future expansions and improvements in the capabilities of the system.
A pressure-induced triclinic-to-monoclinic phase transition has been caught `in the act' over a wider series of high-pressure synchrotron diffraction experiments conducted on a large, photoluminescent organo-gold(I) compound. Here, we describe the mechanism of this single-crystal-to-single-crystal phase transition, the onset of which occurs at ∼0.6 GPa, and we report a high-quality structure of the new monoclinic phase, refined using aspherical atomic scattering factors. Our case illustrates how conducting a fast series of diffraction experiments, enabled by modern equipment at synchrotron facilities, can lead to overestimation of the actual pressure of a phase transition due to slow transformation kinetics.
The title compound, C20H16N2O2, is composed of two monosubstituted benzene rings and one benzimidazole unit. The benzimidazole moiety subtends dihedral angles of 46.16 (7) and 77.45 (8)° with the benzene rings, which themselves form a dihedral angle of 54.34 (9)°. The crystal structure features O—H⋯N and O—H⋯O hydrogen-bonding interactions, which together lead to the formation of two-dimensional hydrogen-bonded layers parallel to the (101) plane. In addition, π–π interactions also contribute to the crystal cohesion. Hirshfeld surface analysis indicates that the most significant contacts in the crystal packing are: H⋯H (47.5%), O⋯H/H⋯O (12.4%), N⋯H/H⋯N (6.1%), C⋯H/H⋯C (27.6%) and C⋯C (4.6%).
In the title compound, bis[aqua(2,2'-bipyridine)fluoridotin(II)] hexafluoridotin(IV), [SnF(C10H8N2)(H2O)]2[SnF6], an ionic mixed-valent tin(II)–tin(IV) compound, the bivalent tin atom is the center atom of the cation and the tetravalent tin atom is the center atom of the anion. With respect to the first coordination sphere, the cation is monomeric, with the tin(II) atom having a fourfold seesaw coordination with a fluorine atom in an equatorial position, a water molecule in an axial position and the two nitrogen atoms of the chelating 2,2'-bipyridine ligand in the remaining axial and equatorial positions. The bond lengths and angles of this hypervalent first coordination sphere are described by 2c–2e and 3c–4e bonds, respectively, all of which are based on the orthogonal 5p orbitals of the tin atom. In the second coordination sphere, which is based on an additional, very long tin–fluorine bond that leads to dimerization of the cation, the tin atom is trapezoidal–pyramidally coordinated. The tetravalent tin atom of the centrosymmetric anion has an octahedral coordination. The differences in its tin–fluorine bond lengths are attributed to hydrogen bonding, as the two of the four fluorine atoms are each involved in two hydrogen bonds, linking anions and cations together to form strands.
The molecular structure of the tripodal carbamoylmethylphosphine oxide compound diethyl {[(5-[2-(diethoxyphosphoryl)acetamido]-3-{2-[2-(diethoxyphosphoryl)acetamido]ethyl}pentyl)carbamoyl]methyl}phosphonate, C25H52N3O12P3, features six intramolecular hydrogen-bonding interactions. The phosphonate groups have key bond lengths ranging from 1.4696 (12) to 1.4729 (12) Å (P=O), 1.5681 (11) to 1.5811 (12) Å (P—O) and 1.7881 (16) to 1.7936 (16) Å (P—C). Each amide group adopts a nearly perfect trans geometry, and the geometry around each phophorus atom resembles a slightly distorted tetrahedron.
During our studies of the oxidation of gold(I) complexes of trialkylphosphane chalcogenides, general formula R1R2R3PEAuX, (R = tert-butyl or isopropyl, E = S or Se, X = Cl or Br) with PhICl2 or elemental bromine, we have isolated a set of seven mixed-valence by-products, the bis(trialkylphosphane chalcogenido)gold(I) tetrahalogenidoaurates(III) [(R1R2R3PE)2Au]+[AuX4]−. These correspond to the addition of one halogen atom per gold atom of the AuI precursor. Compound 1, bis(triisopropylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C9H21PS)2][AuCl4] or [(iPr3PS)2Au][AuCl4], crystallizes in space group P21/n with Z = 4; the gold(I) atoms of the two cations lie on twofold rotation axes, and the gold(III) atoms of the two anions lie on inversion centres. Compound 2, bis(tert-butyldiisopropylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C10H23PS)2][AuCl4] or [(tBuiPr2PS)2Au][AuCl4], crystallizes in space group P1 with Z = 4; the asymmetric unit contains two cations and two anions with no imposed symmetry. A least-squares fit of the two cations gave an r.m.s. deviation of 0.19 Å. Compound 3, bis(tri-tert-butylphosphane sulfide)gold(I) tetrachloridoaurate(III), [Au(C12H27PS)2][AuCl4] or [(tBu3PS)2Au][AuCl4], crystallizes in space group P1 with Z = 1; both gold atoms lie on inversion centres. Compound 4a, bis(tert-butyldiisopropylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C10H23PS)2][AuBr4] or [(tBuiPr2PS)2Au][AuBr4], crystallizes in space group P21/c with Z = 4; the cation lies on a general position, whereas the gold(III) atoms of the two anions lie on inversion centres. Compound 4b, bis(tert-butyldiisopropylphosphane selenide)gold(I) tetrabromidoaurate(III), [Au(C10H23PSe)2][AuBr4] or [(tBuiPr2PSe)2Au][AuBr4], is isotypic with 4a. Compound 5a, bis(tri-tert-butylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C12H27PS)2][AuBr4] or [(tBu3PS)2Au][AuBr4], is isotypic with compound 4a. Compound 5a, bis(tri-tert-butylphosphane sulfide)gold(I) tetrabromidoaurate(III), [Au(C12H27PS)2][AuBr4] or [(tBu3PS)2Au][AuBr4], crystallizes in space group P1 with Z = 1; both gold atoms lie on inversion centres. Compound 5b, bis(tri-tert-butylphosphane selenide)gold(I) tetrabromidoaurate(III), [Au(C12H27PSe)2][AuBr4] or [(tBu3PSe)2Au][AuBr4], is isotypic with 5a. All AuI atoms are linearly coordinated and all AuIII atoms exhibit a square-planar coordination environment. The ligands at the AuI atoms are antiperiplanar to each other across the S⋯S vectors. There are several short intramolecular H⋯Au and H⋯E contacts. Average bond lengths (Å) are: P—S = 2.0322, P—Se = 2.1933, S—Au = 2.2915, and Se—Au = 2.4037. The complex three-dimensional packing of 1 involves two short C—Hmethine⋯Cl contacts (and some slightly longer contacts). For 2, four C—Hmethine⋯Cl interactions combine to produce zigzag chains of residues parallel to the c axis. Additionally, an S⋯Cl contact is observed that might qualify as a ‘chalcogen bond’. The packing of 3 is three-dimensional, but can be broken down into two layer structures, each involving an S⋯Cl and an H⋯Cl contact. For the bromido derivatives 4a/b and 5a/b, loose associations of the anions form part of the packing patterns. For all four compounds, these combine with an E⋯Br contact to form layers parallel to the ab plane.
While compounded topical pain creams have become an increasingly popular alternative to oral pain medications and opioids, there is a lack of scientific evidence to support their safety or effectiveness, says a new report from the National Academies of Sciences, Engineering, and Medicine.
The use of compounded bioidentical hormone therapies (cBHTs) — an increasingly popular approach to relieve symptoms of menopause and male hypogonadism — should be limited to the small number of patients who cannot benefit from an FDA-approved hormone therapy product, says a new report from the National Academies of Sciences, Engineering, and Medicine.
Lack of representation in research is compounding disparities in health outcomes, with serious consequences for underrepresented groups and the nation as a whole. Urgent actions are needed by NIH, FDA, and others to boost representation of racial and ethnic minority groups and other underrepresented populations in clinical trials and research.
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The U.S. Department of Justice announced that a company that supplies ingredients for compound drugs agreed to pay $21.75 million to resolve allegations that it falsely inflated average wholesale prices. The…
Lignans are plant-based compounds that, once ingested, are converted into enterolignans by gut bacteria. These enterolignans, particularly enterolactone, a
Chemical appears to have highest global-warming impact of any compound to dateTORONTO, ON - Scientists from U of T’s Department of Chemistry have discovered a novel chemical lurking in the atmosphere that appears to be a long-lived greenhouse gas (LLGHG). The chemical – perfluorotributylamine (PFTBA) – is the most radiatively efficient chemical found to date, […]
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