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Woman arrested for killing elderly father with an ice axe after he refused to switch off the lights




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Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
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Concise synthesis of succinimide-fused densely 1,3-cyclohexadienes via Co-catalyzed [2+2+2] cycloaddition of 1,6-diynes and maleimides

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00435C, Research Article
Jinhui Cai, Kaili Cen, Ziyi Zhai, Yuan Liu, Jiahao Wei, Mixia Ouyang, Guojun He, Shuyu Huang, Feng Zhao
Herein, we report a new route towards succinimide-fused densely 1,3-cyclohexadienes through the reaction of 1,6-diynes with electron-deficient alkenes under cobalt catalysis. This method shown high efficiency, wide substrate scope, good...
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Synthesis of oxindole fused 1,3-oxazepanes via hydride transfer initiated ring expansion of pyrrolidine

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00474D, Research Article
Peng He, Zongkang Wang, Qiongwen Kang, Nana Fei, Chengyu Wang, Yanzhong Li
An efficient B(C6F5)3 catalyzed protocol for the synthesis of oxindole fused 1,3-oxazepanes from pyrrolidine substituted aryl alkynones has been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Shah Rukh Khan, Aamir Khan refused to work with Aishwarya Rai in this film, it became blockbuster, won 4 National Awards

Before signing Ajay Devgn as the third lead along with Salman Khan and Aishwarya Rai in Hum Dil De Chuke Sanam, Sanjay Leela Bhansali had offered the film to Aamir Khan and Shah Rukh Khan.




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Confused about my spouses resentment

I�m honestly lost and struggling to maintain my sobriety since my space left me two months ago, six months after my rehab Originally, I think we both had such a bright outlook She�s always had...



  • Newcomers to Recovery

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Fireline Fused Cristal 0,06 mm nu voor maar € 10,00

Fireline Fused Cristal Merk: Berkley Lengte: 110 meter De nummer 1 transparante superlijn ter wereld. Kenmerken van de Fireline Fused Cristal: - 3x sterker dan een mono lijn - Ultiem gevoelig. - Schuurbestendig - Extreem sterk - Ook geschikt voor op de molen De lijnen zijn in drie verschillende diameters te verkrijgen. Iedere diameter heeft weer een andere draagkracht.




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At Chennai’s new rooftop bar, catch sunsets and sip on innovative cocktails like shiitake-infused whisky

Located on the 10th floor in Egmore, and spread across 4,500 square feet, Irida Skky Lounge focusses on technique-driven dishes and cocktails




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Watch: Hyderabad’s Chika Cafe serves coffee-infused gulab jamun 




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Grumpy Priest Has Good News for Goose, Gander, and Gender Confused

Sometimes you can judge a podcast by its title!




fused

Spirit-suffused matter




fused

Forest of Dean new homes plan is refused

Councillors reject the plans saying they have concerns over a lack of public transport.




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Merging Jinnah hospital and SMC: Confused Sindh Medical College students call off protest for now

Say they want ‘hard facts’ on the matter.




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Fable’s THC-Infused Botanical Cocktails

Available in three varieties — Into the Woods, Best Zest and Night Flight — each can of Fable contains a 5mg micro dose of Delta-9 THC and 3mg CBD.




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PSILLI Mushroom Infused Functional Sparkling Waters

PSILLI™ will use a variety of mushroom types to create five distinct formulations: Brain Boost to support cognitive and immune function; Study Buddy, a Nootropic supplement; Energizer, a natural energy enhancer; Good Mood a mood optimizer and appetite moderator; and Bedtime, for relaxing.




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Korean Red Ginseng-Infused Sparkling Herbal Drink

Korea Ginseng Corp. US announced the introduction of the six-year-old Korean Red Ginseng-infused sparkling herbal drink HSW to the health-conscious consumers of WaBa Grill, a healthy rice bowl chain.




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Four Sigmatic Organic Instant Teas Infused With Functional Mushrooms

Functional mushroom coffee brand, Four Sigmatic announced that it will debut a new line of organic instant teas. Each tea is infused with functional mushrooms and adaptogens for focus, calm, positive mood, and immune and gut support.




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Confused re presentation of passport no. on booking site

Hi, I don't know which forum to use for this but perhaps I can be sent in the right direction. I am trying to complete my booking of the second of two flights for a relative on Ryanair (Dublin to Manchester UK and back). Each flight was booked...




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Art Hounds: Globally infused banjo tunes on 'Intermodal Blues'

Plus, Art Hounds recommend an ice-skating performance inspired by black social dances and an Earth Day singalong with Dan Chouinard.




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Top Court Rules against Socialist Who Refused Military Duty

[Politics] :
The Supreme Court has ruled against a man who cited his socialist beliefs as grounds for objecting to military service.  In upholding a lower court decision to dismiss the man’s case against the state conscription agency, the top court said Oct. 25 that there had been no error in interpreting the legal ...

[more...]




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Ensuring Human Control over AI-Infused Systems

Human control over technology was a concern thousands of years ago when early humans sought to ensure safe use of fire. Later, control over horse-drawn wagons and eventually steam engines led to debates about how to make the most of their benefits while limiting dangers. Now questions of control are central in the design of AI-infused technologies, for which some advocates envision full machine autonomy while others promote human autonomy.




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Fable’s THC-Infused Botanical Cocktails

Fable announced the nationwide launch of its signature line of premium THC/CBD-infused botanical cocktails.




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ON breakfast-inspired flavors, tropical-infused flavors

Optimum Nutrition (ON), part of Glanbia Performance Nutrition, introduced four new, limited-edition flavors across the brand’s Gold Standard 100% Whey and AMIN.O. ENERGY product lines.




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Hardy Beverage’s hydrogen-infused waters refresh consumers, pets

When Carolyn Chism Hardy, founder and CEO of Hardy Beverage, learned about the benefits of hydrogen-infused water she used her wealth of knowledge in the beverage market and as an entrepreneur to create health-focused hydration for consumers.




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No Disability Pension for Police Officer Who Refused Surgery

The Illinois Appellate Court upheld the denial of a disability pension to a police officer who refused surgery to address his injury. Case: Shirley v. Village of Clarendon Hills Police Pension…




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British Columbia, Canada: Arbitrator Decides Employer Could Terminate Employee Who Refused Government-Ordered Vaccination

On April 4, 2022, in Fraser Health Authority v British Columbia General Employees’ Union, 2022 CanLII 25560, Arbitrator Koml Kandola of the British Columbia Labour Relations Board dismissed the union’s grievance respecting the dismissal of the grievor because she was ineligible to work under the order issued b




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Defiance, Defused: A Roadmap to Radical Behavior Change

Hard-to-meet goals can frustrate children with ADHD. Deploy these approaches to prevent meltdowns and transform relationships.





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Cannabis-Infused Fruit Strips Are Fruit Roll-Ups for Adults

Fruit Slabs start as a cannabis-infused fruit blend with no added sugar that is then dried into a bite-sized square. 




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Cannabis-Infused Edibles Market to Climb

According to a report from Zion Market Research, the global cannabis edibles market was valued at approximately USD 2,376 million in 2018 and is expected to generate around USD 11,564 million by 2025, at a CAGR of around 25.4% between 2019 and 2025.




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Navy appeals court decision barring punishment for SEALs who refused vaccine

Government attorneys appealed a Texas judge's finding that the Navy's strict religious accommodation process violates the religious freedoms of 35 sailors who refused the vaccine.

The post Navy appeals court decision barring punishment for SEALs who refused vaccine first appeared on Federal News Network.




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Rs 325 or Rs 470? Swiggy share price targets leave investors confused after listing

On its listing day, brokerage firms - Macquarie and JM Financial - became the first ones to initiate coverage on the debutant but came out with polar opposite views. Macquarie's initiating coverage report gave it an underperform rating with a target price of Rs 325, which indicates downside potential of 17% from IPO issue price of Rs 390.




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RECORDING: Acclaimed Singer Songwriter Laura Baron Returns With Poignant Jazz Infused Album 'Beauty In The Broken'

With a distinguished career spanning folk, jazz, and world music, award-winning singer songwriter Laura Baron has recently released her latest album, Beauty in the Broken, a stirring collection that sees her embracing her jazz roots in a new light. Featuring eight original songs along with an inspired jazz-infused take on the classic song "Dream a Little Dream," Baron’s latest work captures a journey of healing and transformation....




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Confused Reporter Interviewing Trump Is Inspiring Some Top-Tier Memeage

On July 28th, Axios reporter Jonathan Swan interviewed President Donald Trump on HBO about several topics including the staggering number of COVID-19 cases in the United States. His reactions to some of Trump's remarks are priceless, and needless to say, the memes have been top-tier. You can watch the interview here and garner your own reactions. Now on with the memes!




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Amy Adams Refused Sexually Explicit ‘SNL’ Song to Protect Young ‘Enchanted’ Fans

By Matt Solomon Published: November 11th, 2024




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'My farm was destroyed by drought then floods - I am confused'

Climate change is wreaking havoc on farmers in Nigeria.






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'I refused to get out of the car unless they took me home'

South Korean orphan Milton dreamed of making it to America, the land of his father. One day he seized his chance.




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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Catalytic asymmetric Michael and Nef-type sequential reaction of nitroolefin with azlactone to construct oxazole-fused succinimide

Chem. Commun., 2024, 60,13384-13387
DOI: 10.1039/D4CC04858J, Communication
Rui Weng, Yuqiao Zhou, Yaqin Zhang, Xiaoming Feng, Xiaohua Liu
A series of oxazole-fused succinimides bearing vicinal quaternary carbon centers were synthesized via catalytic asymmetric Michael addition and Nef-type sequential reactions of nitroolefins with azlactones.
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A heat-resistant explosive featuring an N,N'-ethylene bridged 1,2,4-1H-triazole fused ring

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00898G, Communication
Shaoqing Wang, Congcong Li, Shaojia Li, Hongquan Yin, Qing Ma, Fu-Xue Chen
A high thermal stability explosive with a fused-ring structure was formed by N,N'-ethylene bridging, exhibiting decomposition temperatures comparable to traditional HNS.
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A rhodium-catalyzed cascade C–H activation/annulation strategy for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00193A, Paper
Yinsong Wu, Guanghao Shi, Yanan Liu, Yangzilin Kong, Mengdi Wu, Demao Wang, Xiaobing Wu, Yongjia Shang, Xinwei He
We have developed a cascade annulation strategy triggered by rhodium(III)-catalyzed C–H activation for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines from free NH-sulfoximines with maleimides under mild conditions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Chemical analysis of Chang’e-5 lunar soil using LA–ICP–MS in highly diluted fused glass discs

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00329B, Technical Note
Shi-Tou Wu, Ding-Shuai Xue, Yue-Heng Yang, Hao Wang, Chunlai Li, Fu-Yuan Wu
The bulk chemical compositions of extraterrestrial material can provide critical information on the evolution and magmatism of planetary bodies. However, accurate measurements are challenging, because these samples, particularly returned samples,...
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Efficient organic solar cells based on low-cost pentacyclic fused-ring small molecule acceptors with a fill factor over 80%

J. Mater. Chem. A, 2024, 12,30558-30566
DOI: 10.1039/D4TA06146B, Paper
Qingya Wei, Yuanyuan Li, Weikun Chen, Qinhao Shi, Shaofeng Zhu, Wensheng Yan, Yingping Zou
A low-cost pentacyclic fused-ring SMA, BZ4F-ch1, was designed with a cyclohexyl side-chain, which achieved a high device efficiency over 16% with an FF over 80%. Besides, the highest PCE/MOC value of 3.56 revealed remarkable cost-effectiveness.
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Design, Synthesis, and Optoelectronic Properties of Benzothiadiazole-fused Sulfur and Nitrogen-containing Polycyclic Heteroaromatics

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04250F, Paper
Yuxin Yin, Rui Shi, Zhongwei Liu, Yanru Li, Ting Jiang, Lingxu Zhao, Jie Li, Deyang Ji, Liqiang Li, Zhuping Fei
The optoelectronic property of sulfur and nitrogen-containing polycyclic heteroaromatics is still low and structure-property relationships remain unclear as compared with that of acenes and sulfur-heterocyclic aromatic hydrocarbons, which is mainly...
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Why Kajol REFUSED To Do Salaam Venky

Revathy's new film Salaam Venky tells an emotional story of a caring mother looking after her terminally-ill son.But as much as the trailer is a tear-jerker, the trailer launch was full of laughs.




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Recent synthetic strategies for the functionalization of fused bicyclic heteroaromatics using organo-Li, -Mg and -Zn reagents

Chem. Soc. Rev., 2024, 53,11045-11099
DOI: 10.1039/D4CS00369A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Vasudevan Dhayalan, Vishal S. Dodke, Marappan Pradeep Kumar, Hatice Seher Korkmaz, Anja Hoffmann-Röder, Pitchamuthu Amaladass, Rambabu Dandela, Ragupathy Dhanusuraman, Paul Knochel
This review presents various new strategies for the functionalization of 5 and 6-membered fused heteroaromatics. These synthetic strategies enable rapid access to complex heterocyclic compounds.
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Mumbai | An artistic space in Khotachiwadi village has infused new life into the heritage neighbourhood

The initiative has kickstarted conversations around preservation and could serve as inspiration for other such locales in the country




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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article
Open Access
Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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