Mazda Motor Corp has sought loans totalling about 300 billion yen ($2.8 billion) from Japan's three megabanks and other lenders to ride out the coronavirus epidemic, a source with direct knowledge of...

Mazda Motor Corp has sought loans totalling about 300 billion yen ($2.8 billion) from Japan's three megabanks and other lenders to ride out the coronavirus epidemic, a source with direct knowledge of...

Mazda Motor Corp has sought loans totalling about 300 billion yen ($2.8 billion) from Japan's three megabanks and other lenders to ride out the coronavirus epidemic, a source with direct knowledge of...

Harley-Davidson recently launched the Low Rider in the country. The Low Rider S differentiates itself from the standard version with its all-black theme, however, it still uses chrome at some areas like the exhaust tips.

It has been well over three weeks our motorcycles have been parked and there are now nearly three more weeks to go before the coronavirus lockdown hopefully lifts. When you do finally get back on the road, remember to check these six things.

The Platina 110 H-Gear is the latest addition to Bajaj's best-selling commuter's line up. We were in Pune recently to find out what exactly the new Platina is all about and what all improvements it brings to the table over an already super hit model.

Ather 450 is the brand’s flagship scooter that is currently seen as the benchmark among all-electric scooters currently on sale. How practical is it to ride? Can it match a conventional scooter in terms of comfort and other attributes?

Yes, Indian FTR 1200 series is based on the FTR 750 race bike. Unlike the race machine, of course, the FTR 1200 is fitted with brakes upfront and it has a proper seat. So, what is a flat track-bred street bike like to ride?

There is a new retro cruiser in town and this one has landed straight from Italy. The Benelli Imperiale 400 directly eyes the Classic 350 from Royal Enfield that has been enjoying its monopoly in India for a long time now. So, is the Imperiale 400 good enough to change that?

Launched a few days back, the 2020 TVS Apache RTR 200 4V BS6 stills comes across as a worthy contender in its newest avatar. After having ridden it at TVS' Hosur racetrack, here is what we think about it!

The new 2020 TVS Apache RTR 160 4V is now BS6 compliant. The bike now gains some features and it also loses a handful in the process. We have ridden it at the company's racetrack in Hosur and here is what we think about it.

BS-VI Honda SP125 Review: Honda's second BS6 compliant two-wheeler not only is now more fuel-efficient and cleaner for the environment, but it also offers several new features. We rode it around the streets of Mumbai to find out more.

2020 TVS Apache RR 310 Track Ride Review: The RR 310 has undoubtedly always been a performance machine with great looks, but it now it reaffirms its position with better handling and features.

Honda Activa 6G gains multiple new features and now has a more environmental-friendlier engine. So, what all it packs in, how it is to ride and most importantly, does it justify the Rs 8,000 premium in pricing? All these questions answered below.

During its second innings in the EV space, TVS is quite confident with the iQube and why not! In this review, we tell you is TVS' latest offering has got what it takes to be a worthy all-rounder.

BS-VI Royal Enfield Himalayan Review | To be honest, we couldn't take the new Himalayan out on, for example, a jungle trail. But we'll try to answer the only pressing question on our minds – is this the best Himalayan yet?

Under the scheme, Strides shareholders will get 1 share of SSL for every 6 shares of Strides while Sequent shareholders will get 1 share of SSL for 25 shares of Sequent.

Article By: Enoch Kaulaity

The Haskell  Women's indoor track and field season got off with a visit up the road earlier this month and competed in the Cavalier Relays on January 16, 2015. A repeat return for the Cavalier Night Relays took place this past Friday the 30th on the Johnson County Community College campus.

Ride-along and interview Nokia's Aaron Dannenbring

Sidewalk Labs officially pulled out of Toronto after years of controversy, hacker bribed a Roblox worker to reveal user account data, Telus’ revenue falls by nearly 20 per cent year over year.   Sidewalk Labs pulls the plug on smart city project The tug-of-war for Toronto’s infamous Sidewalk Labs’ smart city project ended yesterday when…

An Edmonton family is expressing frustration because their 12-year-old daughter, who has a rare disorder, cannot access the horse therapy she needs.

The FIA has clarified the rules on adjusting ride heights between qualifying and the race, after paddock rumours suggested Red Bull was running a self-altering system

Neighbours of Tamsin Calidas, who moved to Scotland from London, are keen to put their side as her book I am an Island looks set for success

Tamsin Calidas’s memoir about swapping Notting Hill for a croft on a small Hebridean island luxuriates in its landscape. The heather and the Munros, the raw skies and the wild tides of the Atlantic are lavishly described. The islanders, by contrast, are largely anonymous, thoughtless and cruel.

Delays follow COVID-19 diagnosis for Kiramager star Rio Komiya in March

In the fight against COVID-19, Uber has extended support by offering free rides to frontline BMC healthcare workers and non-COVID patients in Mumbai through its recently launched UberMedic service.

All UberMedic cars are fitted with a roof-to-floor plastic sheeting enclosing the driver. Additionally, all drivers are being trained in safety procedures and provided with personal protective equipment such as masks, gloves, sanitisers and disinfectants to sanitise the cars between rides.

The agreement is part of Uber’s recent offer to provide free rides worth Rs 1 crore to the Maharashtra government. Prabhjeet Singh, Director, Operations and Head of Cities, Uber India & South Asia, said, “The BMC has been working tirelessly to contain the spread of COVID-19. We feel privileged to be supporting them in these challenging times and will help move what matters by leveraging our global experience, technology and network of drivers.”

Uber’s recently launched UberMedic service has been transporting frontline medical workers in 35+ hospitals across 23 Indian cities.

Catch up on all the latest Crime, National, International and Hatke news here. Also download the new mid-day Android and iOS apps to get latest updates.

Mid-Day is now on Telegram. Click here to join our channel (@middayinfomedialtd) and stay updated with the latest news

Whether it's off-screen or on-screen mothers don't have it easy. It's taken Bollywood a long time to get their idea of a mom right, so on this mother's day let's look at some of the actresses who gave 'mother' a whole new dimension.

Shared to Facebook group That's It, I'm Wedding Shaming by a Canadian member, the photograph showed the cousin sporting a curve-hugging frock as she stood with the bride.

A fiive-year-old boy who drove off in his parents' car ended up being given a ride in a Lamborghini thanks to a friendly Utah resident who was encouraged by the Adrian Zamarripa's story.

Danielle Young, based in Brisbane, Australia, said she originally considered purchasing Shona Joy dresses for $240, but wanted to keep costs down as much as possible.

While Mayawati's projects to build parks and statues have drawn derision in the drawing rooms of the stately homes in the country, the people at her rallies are in awe of her. Her work is Dalit power, they feel and will make her immortal. Kulsum Mustafa has more.

A glimpse into the lives of women waste-pickers in Pune by Suchismita Pai.

Desperate times call for desperate measures goes the adage. Ten migrant workers in the city just did that.

சென்னை: நடிகர் தனுஷ் சினிமாத்துறைக்கு வந்து 18 ஆண்டுகள் ஆனதை முன்னிட்டு அவரது அண்ணனும் இயருக்குநருமான செல்வராகவன் காமன் டிபியை ரிலீஸ் செய்துள்ளார். நடிகர் தனுஷ் செல்வராகவன் இயக்கத்தில் வெளியான துள்ளுவதோ இளமை என்ற படத்தில் முதன் முதலாக நடித்தார். தனுஷ் பள்ளி மாணவராக நடித்த அந்தப் படம் பெரும் வெற்றி பெற்றது. துள்ளுவதோ இளமைப் படத்தில்

Mazda Motor Corp has sought loans totalling about 300 billion yen ($2.8 billion) from Japan's three megabanks and other lenders to ride out the coronavirus epidemic, a source with direct knowledge of the matter said on Saturday.

Mazda Motor seeks $2.8 billion in loans to ride out pandemic: Source

The molecular salt, C23H26N2O2+·Cl−, was obtained from 1-isobutyl-8,9-dimeth­oxy-3-phenyl-5,6-di­hydro­imidazo[5,1-a]iso­quinoline, which was synthesized by cyclo­condensation of α-benzoyl­amino-γ-methyl-N-[2-(3,4-di­meth­oxy­phen­yl)eth­yl]valeramide in the presence of phosphoryl chloride. The tetra­hydro­pyridine ring adopts a twist–boat conformation. In the crystal structure, centrosymmetric dimers are formed by N—H⋯Cl and C—H⋯Cl hydrogen bonds.

This study is an investigation into the crystal structure of the biologically active drug mol­ecule riluzole [RZ, 6-(tri­fluoro­meth­oxy)-1,3-benzo­thia­zol-2-amine], C8H5F3N2OS, and its derivative, the riluzolium chloride salt [RZHCl, 2-amino-6-(tri­fluoro­meth­oxy)-1,3-benzo­thia­zol-3-ium chloride], C8H6F3N2OS+·Cl−. In spite of repeated efforts to crystallize the drug, its crystal structure has not been reported to date, hence the current study provides a method for obtaining crystals of both riluzole and its corresponding salt, riluzolium hydro­chloride. The salt was obtained by grinding HCl with the drug and crystallizing the obtained solid from di­chloro­methane. The crystals of riluzole were obtained in the presence of l-glutamic acid and d-glutamic acid in separate experiments. In the crystal structure of RZHCl, the –OCF3 moiety is perpendicular to the mol­ecular plane containing the riluzolium ion, as can be seen by the torsion angle of 107.4 (3)°. In the case of riluzole, the torsion angles of the four different mol­ecules in the asymmetric unit show that in three cases the tri­fluoro­meth­oxy group is perpendicular to the riluzole mol­ecular plane and only in one mol­ecule does the –OCF3 group lie in the same mol­ecular plane. The crystal structure of riluzole primarily consists of strong N—H⋯N hydrogen bonds along with weak C—H⋯F, C—H⋯S, F⋯F, C⋯C and C⋯S inter­actions, while that of its salt is stabilized by strong [N—H]+⋯Cl− and weak C—H⋯Cl−, N—H⋯S, C—H⋯F, C⋯C, S⋯N and S⋯Cl− inter­actions.

Imidazolium salts are common building blocks for functional materials and in the synthesis of N-heterocyclic carbene (NHC) as σ-donor ligands for stable metal complexes. The title salt, 1,3-bis­(4-hy­droxy­phen­yl)-1H-imidazol-3-ium chloride (IOH·Cl), C15H13N2O2+·Cl−, is a new imidazolium salt with a hy­droxy functionality. The synthesis of IOH·Cl was achieved in high yield via a two-step procedure involving a di­aza­butadiene precursor followed by ring closure using tri­methylchloro­silane and paraformaldehyde. The structure of IOH·Cl consists of a central planar imidazolium ring (r.m.s. deviation = 0.0015 Å), with out-of-plane phenolic side arms. The dihedral angles between the 4-hy­droxy­phenyl substituents and the imidazole ring are 55.27 (7) and 48.85 (11)°. In the crystal, O—H⋯Cl hydrogen bonds connect the distal hy­droxy groups and Cl− anions in adjacent asymmetric units, one related by inversion (−x + 1, −y + 1, −z + 1) and one by the n-glide (x − {1over 2}, −y + {1over 2}, z − {1over 2}), with donor–acceptor distances of 2.977 (2) and 3.0130 (18) Å, respectively. The phenolic rings are each π–π stacked with their respective inversion-related [(−x + 1, −y + 1, −z + 1) and (−x, −y + 1, −z + 1)] counterparts, with inter­planar distances of 3.560 (3) and 3.778 (3) Å. The only other noteworthy inter­molecular inter­action is an O⋯O (not hydrogen bonded) close contact of 2.999 (3) Å between crystallographically different hy­droxy O atoms on translationally adjacent mol­ecules (x + 1, y, x + 1).

Charge-assisted hydrogen bonding plays a significant role in the crystal structures of solvates of ionic com­pounds, especially when the cation or cations are primary ammonium salts. We report the crystal structures of four ammonium salts of molybdenum halide cluster solvates where we observe significant hydrogen bonding between the solvent molecules and cations. The crystal structures of bis­(anilinium) octa-μ3-chlorido-hexa­chlorido-octa­hedro-hexa­molybdate N,N-di­­methyl­formamide tetra­solvate, (C6H8N)2[Mo6Cl8Cl6]·4C3H7NO, (I), p-phenyl­enedi­ammonium octa-μ3-chlorido-hexa­chlorido-octa­hedro-hexa­mol­yb­date N,N-di­methyl­formamide hexa­solvate, (C6H10N2)[Mo6Cl8Cl6]·6C3H7NO, (II), N,N'-(1,4-phenyl­ene)bis­(propan-2-iminium) octa-μ3-chlorido-hexa­chlo­rido-octa­hedro-hexa­molybdate acetone tris­olvate, (C12H18N2)[Mo6Cl8Cl6]·3C3H6O, (III), and 1,1'-dimethyl-4,4'-bipyridinium octa-μ3-chlo­rido-hexa­chlorido-octa­hedro-hexa­molybdate N,N-di­methyl­formamide tetra­solvate, (C12H14N2)[Mo6Cl8Cl6]·4C3H7NO, (IV), are reported and described. In (I), the anilinium cations and N,N-di­methyl­formamide (DMF) solvent mol­ecules form a cyclic R42(8) hydrogen-bonded motif centered on a crystallographic inversion center with an additional DMF mol­ecule forming a D(2) inter­action. The p-phenyl­enedi­ammonium cation in (II) forms three D(2) inter­actions between the three N—H bonds and three independent N,N-di­methyl­formamide mol­ecules. The dication in (III) is a protonated Schiff base solvated by acetone mol­ecules. Compound (IV) contains a methyl viologen dication with N,N-di­methyl­formamide mol­ecules forming close contacts with both aromatic and methyl H atoms.

The title compound [systematic name: (1R*, 8S)-2-acetamidoocta­hydro­pyrrol­izin-4-ium chloride–N-[(1R, 8S)-hexa­hydro-1H-pyrrolizin-2-yl)acetamide (1/1)], 2(C9H16N2O)·HCl or C9H17N2O+·Cl−·C9H16N2O, arose as an unexpected product when 1-exo-acetamido­pyrrolizidine (AcAP; C9H16N2O) was dissolved in CHCl3. Within the AcAP pyrrolizidine group, the unsubstituted five-membered ring is disordered over two orientations in a 0.897 (5):0.103 (5) ratio. Two AcAP mol­ecules related by a crystallographic twofold axis link to H+ and Cl− ions lying on the rotation axis, thereby forming N—H⋯N and N—H⋯Cl⋯H—N hydrogen bonds. The first of these has an unusually short N⋯N separation of 2.616 (2) Å: refinement of different models against the present data set could not distinguish between a symmetrical hydrogen bond (H atom lying on the twofold axis and equidistant from the N atoms) or static or dynamic disorder models (i.e. N—H⋯N + N⋯H—N). Computational studies suggest that the disorder model is slightly more stable, but the energy difference is very small.

In 2,2,5-trimethyl-1,3-dioxane-5-carb­oxy­lic acid, C8H14O4, the carboxyl group occupies an equatorial position on the 1,3-dioxane ring. In the crystal, O—H⋯O hydrogen bonds form chains of mol­ecules, which are linked into a three-dimensional network by C—H⋯O hydrogen bonds. The asymmetric unit of 2,2,5-trimethyl-1,3-dioxane-5-carb­oxy­lic anhydride, C16H26O7, consists of two independent mol­ecules, which are linked by C—H⋯O hydrogen bonds. In the crystal, these units are connected into corrugated layers two mol­ecules thick and parallel to the ab plane by additional C—H⋯O hydrogen bonds.

The crystal structure of title salt, C14H36N44+·2ClO4−·2Cl−, has been determined using synchrotron radiation at 220 K. The structure determination reveals that protonation has occurred at all four amine N atoms. The asymmetric unit contains one half-cation (completed by crystallographic inversion symmetry), one perchlorate anion and one chloride anion. A distortion of the perchlorate anion is due to its involvement in hydrogen-bonding inter­actions with the cations. The crystal structure is consolidated by inter­molecular hydrogen bonds involving the 1,4,8,11-tetra­methyl-1,4,8,11-tetra­azonia­cyclo­tetra­decane N—H and C—H groups as donor groups, and the O atoms of the perchlorate and chloride anion as acceptor groups, giving rise to a three-dimensional network.

In the title hydrated complex, [Co(C15H10ClN3)2]Cl2·4H2O, the complete dication is generated by overline{4} symmetry. The CoN6 moiety shows distortion from regular octa­hedral geometry with the trans bond angles of two N—Co—N units being 160.62 (9)°. In the crystal, O—H⋯Cl and C—H⋯O inter­actions link the components into (001) sheets. The title compound exhibits blue-light emission, as indicated by photoluminescence data, and a HOMO–LUMO energy separation of 2.23 eV was obtained from its diffuse reflectance spectrum.

The crystal structure of title compound, (C14H36N4)[CrO3Cl]2Cl2, has been determined by synchrotron radiation X-ray crystallography at 220 K. The macrocyclic cation lies across a crystallographic inversion center and hence the asymmetric unit contains one half of the organic cation, one chloro­chromate anion and one chloride anion. Both the Cl− anion and chloro­chromate Cl atom are involved in hydrogen bonding. In the crystal, hydrogen bonds involving the 1,4,8,11-tetra­methyl-1,4,8,11-tetra­azonia­cyclo­tetra­decane (TMC) N—H groups and C—H groups as donor groups and three O atoms of the chloro­chromate and the chloride anion as acceptor groups link the components, giving rise to a three-dimensional network.

Terbium oxychloride, TbOCl, was synthesized via the simple heat-treatment of TbCl3·6H2O and its structure was determined by refinement against X-ray powder diffraction data. TbOCl crystallizes with the matlockite (PbFCl) structure in the tetra­gonal space group P4/nmm and is composed of alternating (001) layers of (TbO)n and n Cl−. The unit-cell parameters, unit-cell volume, and density were compared to the literature data of other isostructural rare-earth oxychlorides in the same space group and showed good agreement when compared to the calculated trendlines.

The new copper(II) complex [CuLCl2]2, where L is a product of Schiff base condensation between methyl­amine and 2-pyridine­carbaldehyde, is built of discrete centrosymmetric dimers.

The new copper(II) complex, namely, di-μ-chlorido-bis{chlorido[methyl(pyridin-2-ylmethylidene)amine-κ2N,N']copper(II)}, [Cu2Cl4(C7H8N2)2], (I), with the ligand 2-pyridylmethyl-N-methylimine (L, a product of Schiff base condensation between methylamine and 2-pyridinecarbaldehyde) is built of discrete centrosymmetric dimers. The coordination about the CuII ion can be described as distorted square pyramidal. The base of the pyramid consists of two nitrogen atoms from the bidentate chelate L [Cu—N = 2.0241 (9), 2.0374 (8) Å] and two chlorine atoms [Cu—Cl = 2.2500 (3), 2.2835 (3) Å]. The apical position is occupied by another Cl atom with the apical bond being significantly elongated at 2.6112 (3) Å. The trans angles of the base are 155.16 (3) and 173.79 (2)°. The Cu...Cu separation in the dimer is 3.4346 (3) Å. In the crystal structure, the loosely packed dimers are arranged in stacks propagating along the a axis. The X-band polycrystalline 77 K EPR spectrum of (I) demonstrates a typical axial pattern characteristic of mononuclear CuII complexes. Compound (I) is redox active and shows a cyclic voltammetric response with E1/2 = −0.037 V versus silver–silver chloride electrode (SSCE) assignable to the reduction peak of CuII/CuI in methanol as solvent.

Crystals of the rare earth metal polytelluride LaTe1.82(1), namely, lanthanum telluride (1/1.8), have been grown by molten alkali halide flux reactions and vapour-assisted crystallization with iodine. The two-dimensionally incommensurately modulated crystal structure has been investigated by X-ray diffraction experiments. In contrast to the tetra­gonal average structure with unit-cell dimensions of a = 4.4996 (5) and c = 9.179 (1) Å at 296 (1) K, which was solved and refined in the space group P4/nmm (No. 129), the satellite reflections are not compatible with a tetra­gonal symmetry but enforce a symmetry reduction. Possible space groups have been derived by group–subgroup relationships and by consideration of previous reports on similar rare earth metal polychalcogenide structures. Two structural models in the ortho­rhom­bic superspace group, i.e. Pmmn(α,β,1 over 2)000(−α,β,1 over 2)000 (No. 59.2.51.39) and Pm21n(α,β,1 over 2)000(−α,β,1 over 2)000 (No. 31.2.51.35), with modulation wave vectors q1 = αa* + βb* + 1 over 2c* and q2 = −αa* + βb* + 1 over 2c* [α = 0.272 (1) and β = 0.314 (1)], have been established and evaluated against each other. The modulation describes the distribution of defects in the planar [Te] layer, coupled to a displacive modulation due to the formation of different Te anions. The bonding situation in the planar [Te] layer and the different Te anion species have been investigated by density functional theory (DFT) methods and an electron localizability indicator (ELI-D)-based bonding analysis on three different approximants. The temperature-dependent electrical resistance revealed a semiconducting behaviour with an estimated band gap of 0.17 eV.