Like most paddlers I have a tendency to shoot pictures in a horizontal (landscape) format. It is more tricky to shoot in a vertical format from my tippy kayaks, especially, when I have to use a paddle to stabilize my camera.

Interaction Designer’s 2020 portfolio

There is much I take for granted in my life, and the normal functioning of American government is one of those things. In my 46 years, I've lived under nine different presidents. The first I remember is Carter. I've voted in every presidential election since 1992, but I do not

It's been a while since I wrote a blog post, I guess in general, but also a blog post about video games. Video games are probably the single thing most attributable to my career as a programmer, and everything else I've done professionally after that. I still feel video games

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Ryan Holiday is described by the New York Times as popularizing stoicism, a philosophy of personal ethics which has been practiced by Kings, presidents, artists, writers, and entrepreneurs. His career started at 19 when he dropped out of college at 19 to work with author Robert Greene. Today, he’s a NYT Bestselling author, with 9 books under his belt, including his latest book: Stillness Is the Key which hit #1 on its first week. In this episode: Stillness isn’t a monk-like existence only reserved for the enlightened. Stillness is the idea of being still in a chaotic world and where our best work will come from. Ryan’s personal habits and process during the creation process to find stillness and it doesn’t include meditation. How to say no and build a practice around managing your time. Enjoy! FOLLOW RYAN: instagram | twitter | website Listen to the Podcast Subscribe   Watch the Episode  This podcast is brought to you by CreativeLive. CreativeLive is the world’s largest hub for online creative education in photo/video, art/design, music/audio, craft/maker, money/life and the ability to make a living in any of those disciplines. They are high quality, highly curated classes taught by the world’s top […]

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Cheri has been a student and teacher of Zen for over 35 years. She is the author of over 20 books on Zen, and founded the Mountain View Zen Center and the Zen Monastery Peace Center. Cheri also founded a non-profit dedicated to transforming lives and ending suffering, Living Compassion, whose primary work is the Africa Vulnerable Children Project in Zambia. Ashwini co-facilitates and creates workshops with Cheri. She runs the operations of the two nonprofits that Cheri founded. Her eclectic background includes degrees in physics, business, and computer science to working in advertising, an investment bank, a social enterprise, and several technology startups in the Silicon Valley. Cheri and Ashwini have co-written multiple books, including their latest Don’t Suffer, Communicate. Today’s episode isn’t just about awareness practice, it’s about a framework for navigating life. A few highlights: Zen isn’t just the practice of keeping things nicely organized, it’s also a spiritual practice largely focused on awareness and where you direct attention. Self-improvement is an endless diss. The very nature of saying we need improvement implies we’re not enough. Cheri and Ashwini share some useful tools to redirect the attention, such as using a recorder to access the wisdom, love, and compassion that is […]

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So many of us are going along on the path that we think we want, only to realize that something is missing. The same was true for today’s guest, Chelsea Yamase (@chelseakauai) who found herself heading into a potential career that was slowly killing her soul. Through a winding path of architecture, graphic design, journalism, and a myriad of side hustles, she found herself faced with the big question: pursue the unconventional life of your dreams or stick to a “real job”. She lept. Today, Chelsea is a sought after model, photographer, influencer and movement enthusiast from Hawaii with a focus on mindful living. She’s been featured in Travel and Leisure, Cosmopolitan, Condé Nast Traveler, to name a few, and and worked with numerous brands such as Canon USA, Adidas, Google, Athleta, GoPro, DJI Global and The National Parks Foundation. In this episode: How to give yourself structure that can help you take a leap into an unconventional lifestyle What can you make with what’s around you? Constraints are a path to creativity and a key gaining new perspectives As money and opportunities come in, how do you stay in alignment with your values and the work you really want […]

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Connections between set theoretic Yang-Baxter and reflection equations and quantum integrable systems are investigated. We show that set theoretic $R$-matrices are expressed as twists of known solutions. We then focus on reflection and twisted algebras and we derive the associated defining algebra relations for $R$-matrices being Baxterized solutions of the $A$-type Hecke algebra ${cal H}_N(q=1)$. We show in the case of the reflection algebra that there exists a "boundary" finite sub-algebra for some special choice of "boundary" elements of the $B$-type Hecke algebra ${cal B}_N(q=1, Q)$. We also show the key proposition that the associated double row transfer matrix is essentially expressed in terms of the elements of the $B$-type Hecke algebra. This is one of the fundamental results of this investigation together with the proof of the duality between the boundary finite subalgebra and the $B$-type Hecke algebra. These are universal statements that largely generalize previous relevant findings, and also allow the investigation of the symmetries of the double row transfer matrix.

Yang-Mills gauge theory on Minkowski space supports a Batalin-Vilkovisky-infinity algebra structure, all whose operations are local. To make this work, the axioms for a BV-infinity algebra are deformed by a quadratic element, here the Minkowski wave operator. This homotopy structure implies BCJ/color-kinematics duality; a cobar construction yields a strict algebraic structure whose Feynman expansion for Yang-Mills tree amplitudes complies with the duality. It comes with a `syntactic kinematic algebra'.

We first give a sufficient condition, issued from pluripotential theory, for an unbounded domain in the complex Euclidean space $mathbb C^n$ to be Kobayashi hyperbolic. Then, we construct an example of a rigid pseudoconvex domain in $mathbb C^3$ that is Kobayashi hyperbolic and has a nonempty core. In particular, this domain is not biholomorphic to a bounded domain in $mathbb C^3$ and the mentioned above sufficient condition for Kobayashi hyperbolicity is not necessary.

In a multitype branching process, it is assumed that immigrants arrive according to a nonhomogeneous Poisson or a generalized Polya process (both processes are formulated as a nonhomogeneous birth process with an appropriate choice of transition intensities). We show that the renormalized numbers of objects of the various types alive at time $t$ for supercritical, critical, and subcritical cases jointly converge in distribution under those two different arrival processes. Furthermore, some transient moment analysis when there are only two types of particles is provided. AMS 2000 subject classifications: Primary 60J80, 60J85; secondary 60K10, 60K25, 90B15.

The aim of this paper is to obtain a generalized CK-extension theorem in superspace for the bi-axial Dirac operator. In the classical commuting case, this result can be written as a power series of Bessel type of certain differential operators acting on a single initial function. In the superspace setting, novel structures appear in the cases of negative even superdimensions. In these cases, the CK-extension depends on two initial functions on which two power series of differential operators act. These series are not only of Bessel type but they give rise to an additional structure in terms of Appell polynomials. This pattern also is present in the structure of the Pizzetti formula, which describes integration over the supersphere in terms of differential operators. We make this relation explicit by studying the decomposition of the generalized CK-extension into plane waves integrated over the supersphere. Moreover, these results are applied to obtain a decomposition of the Cauchy kernel in superspace into monogenic plane waves, which shall be useful for inverting the super Radon transform.

Software Defined Networking is currently revolutionizing computer networking by decoupling the network control (control plane) from the forwarding functions (data plane) enabling the network control to become directly programmable and the underlying infrastructure to be abstracted for applications and network services. Next to the well-known OpenFlow protocol, the XML-based NETCONF protocol is also an important means for exchanging configuration information from a management platform and is nowadays even part of OpenFlow. In combination with NETCONF, YANG is the corresponding protocol that defines the associated data structures supporting virtually all network configuration protocols. YANG itself is a semantically rich language, which -- in order to facilitate familiarization with the relevant subject -- is often visualized to involve other experts or developers and to support them by their daily work (writing applications which make use of YANG). In order to support this process, this paper presents an novel approach to optimize and simplify YANG data models to assist further discussions with the management and implementations (especially of interfaces) to reduce complexity. Therefore, we have defined a bidirectional mapping of YANG to UML and developed a tool that renders the created UML diagrams. This combines the benefits to use the formal language YANG with automatically maintained UML diagrams to involve other experts or developers, closing the gap between technically improved data models and their human readability.

A process for reductive amination of aliphatic cyanoaldehydes to aliphatic diamines comprising (1) providing a mixture of 1,3-cyanocyclohexane carboxaldehyde and/or 1,4-cyanocyclohexane carboxaldehyde; (2) contacting said mixture with a metal carbonate based solid bed or a weak base anion exchange resin bed at a temperature from 15 to 40 ° C. for a period of at least 1 minute; (3) thereby treating said mixture, wherein said treated mixture has a pH in the range of 6 to 9; (4) feeding said treated mixture, hydrogen, and ammonia into a continuous reductive amination reactor system; (6) contacting said treated mixture, hydrogen, and ammonia with each other in the presence of one or more heterogeneous metal based catalyst systems at a temperature from 80 ° C. to 160 ° C. and a pressure from 700 to 3500 psig; (7) thereby producing one or more cycloaliphatic diamines is provided.

A branched hetero polyfunctional polyoxyalkylene compound represented by the following formula (1): wherein Z represents a hydroxyl group-removed residue of pentaerythritol or dipentaerythritol, OA1 and OA2 represent an oxyalkylene group having 2 to 4 carbon atoms, L1, L2 and L3 represent an alkylene group or an alkylene group that contains an ester bond, a urethane bond, an amide bond, an ether bond, a carbonate bond, a secondary amino group or a urea bond, X and Y are different from each other and represent a functional group capable of a chemical reaction; m and n are an average number of moles of the oxyalkylene group added, m represents 5 to 1,000, n represents 0 to 1,000, and p, q and r represent 0 or 1; and s1 is an integer of 2 or more and s1+s2=4 or 6.

Disclosed is a process for preparing an aryloxyalkylene amine compound via an aminoethylation reaction comprising: a) reacting an aromatic hydroxyl compound in the presence of a basic catalyst with a 2-oxazolidinone compound of the formula II to form an intermediate reaction product; wherein R3 is selected from the group consisting of hydrogen or lower alkyl having 1 to 6 carbon atoms, R4 is selected from the group consisting of hydrogen, straight or branched chain alkyl having from one to six carbon atoms, phenyl, alkaryl, or arylalkyl; and b) reacting the intermediate product of step a) with a polyalkylene polyamine.

Polyamide molding materials for transparent molding parts. The materials comprise transparent copolyamides that contain: (A) 40 to 100 wt % of at least one transparent copolyamide with a glass transition temperature (Tg) of at least 80° C. and not more than 150° C., composed of at least two diamines that are different from each other, wherein the at least two diamines are a mixture of (a) 50 to 90 mol % bis-(4-amino-3-methylcyclohexyl)methane (MACM) and/or bis-(4-amino-3-ethylcyclohexyl)methane (EACM) and/or bis-(4-amino-3,5-dimethylcyclohexyl)methane (TMACM) and b) 10 to 50 mol % aliphatic diamine having 9 to 14 carbon atoms, in particular decandiamine, particularly preferably at least 20 mol % decandiamine, each relative to the total amount of diamines, and of one or more aliphatic dicarboxylic acids, having 6 to 36 carbon atoms, (B) 0 to 60 wt % of at least one further polymer, (C) 0 to 10 wt % of additives, the sum of the components (A), (B) and (C) totaling 100% by weight.

The method for detection of cyanide in water is a method for the detection of a highly toxic pollutant, cyanide, in water using ZnO2 nanoparticles synthesized locally by an elegant Pulsed Laser Ablation technique. ZnO2 nanoparticles having a median size of 4 nm are synthesized from pure zinc metal target under UV laser irradiation in a 1-10% H2O2 environment in deionized water. The synthesized ZnO2 nanoparticles are suspended in dimethyl formamide in the presence of Nafion, and then ultrasonicated to create a homogenous suspension, which is used to prepare a thin film of ZnO2 nanoparticles on a metal electrode. The electrode is used for cyanide detection.

A composite material and method of making and using the same is described. In particular a dental (and preferably photocurable) composite material, and the use of a composite material according to the invention as a dental material and a method for preparation of a composite material according to the invention. Also disclosed are novel radically polymerizable monomers comprising at least one polyalicyclic structure element and certain ethylenic structure elements, which are particularly suitable for use in a composite material according to the invention.

The invention provides a method for the manufacture of a catheter comprising a hydrophilic gel. The method comprising the steps of combining a polymeric photoinitiator of the general formula (I): R1(A1)r-(R2(A2)m-O)o—(R3(A3)n-O)p—R4(A4)s (I) with one or more gel-forming polymers and/or gel-forming monomers to form a matrix composition, curing the matrix composition by exposing it to UV radiation, exposing the matrix composition to a swelling medium and incorporating the hydrophilic gel into a catheter. The invention also provides autocuring of the polymeric photoinitiator (I) to provide a gel precursor, a hydrophilic gel and a catheter comprising or coated with the hydrophilic gel of the invention.

The present invention relates to novel isocyanate and isothiocyanate compounds, to pharmaceutical compositions comprising them, and to the use thereof in the treatment of cancer diseases in humans and animals. The novel isocyanate and isothiocyanate compounds are distinguished, as compared with the known isocyanate and isothiocyanate compounds, by improved therapeutical breadth, i.e. fewer side effects while having high anti-tumor activity.

The present invention relates to a process for the synthesis of 2-cyanophenylboronic acid and the esters and salts thereof of formula (II), which are intermediates of the synthesis of active pharmaceutical ingredients such as Perampanel or E2040. formula (II): (II).

Organophosphorus compounds, catalytic systems comprising a metallic element forming a complex with the organophosphorus compounds and methods of hydrocyanation and of hydroformylation employed in the presence of the catalytic systems are described.

A production method of a cationized cellulose or a cationized hydroxyalkylcellulose, including step 1 for adding a cationizing agent to cellulose and mechanically decrystallizing the cellulose and step 2 for adding a basic compound to the mixture obtained in step 1 and mechanically decrystallizing the cellulose, or a production method of a cationized cellulose or a cationized hydroxyalkylcellulose, including a step 3 for adding a basic compound to cellulose and mechanically decrystallizing the cellulose and step 4 for adding a cationizing agent to the mixture obtained in step 3 and mechanically decrystallizing the cellulose. The cellulose and the cationizing agent are allowed to react with each other in step 2 or step 4.

A coating agent containing a hydroxyalkyl cellulose in which a content of hydroxyalkoxy groups within the hydroxyalkyl cellulose is within a range of 40 to 50% by mass, preferably a coating agent containing a hydroxyalkyl cellulose in which the content of hydroxyalkoxy groups is within a range of 40 to 50% by mass and also a viscosity of 2% aqueous solution at 20° C. is within a range of 3.0 to 5.9 mPa·s; and a solid preparation coated with the coating agent.

Aromatic isocyanates are produced by reacting one or more aromatic primary amines with phosgene in the gas phase. The phosgene and primary aromatic amine(s) are reacted at a temperature above the boiling temperature of the amine(s) in a reactor having a reaction space which is essentially rotationally symmetric to the direction of flow. The flow fate, averaged over the cross-section, of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is between 4 and 80% is not more than 8 m/sec. The flow rate averaged over the cross-section of the reaction mixture along the axis of the essentially rotationally symmetric reaction space in the section of the reaction space in which the conversion of the amine groups into isocyanate groups is 4 to 80% is always below the flow rate averaged over the cross-section at the start of this section.

Isocyanates are produced in the gas phase and by-products such as ammonium halides are selectively separated from the gas phase by desublimation.

The present invention relates to a method for working up distillation, residues from isocyanate production in which monomeric isocyanate present in distillation residues is recovered by means of a spray-dry method and the overall yield of monomeric isocyanate is thus significantly increased.

A method for producing a polyisocyanate includes a purification step of purifying an unpurified polyisocyanate, the purification step including a tar ingredient removal step of removing tar ingredients from an unpurified polyisocyanate, and a distillation step of distilling the unpurified polyisocyanate from which tar ingredients have been removed through a dividing wall distillation column.

An object of the present invention is to improve the stability of an ethylenically unsaturated compound having an isocyanate group in the molecule by preventing a polymerization of the ethylenically unsaturated compound. The present invention relates to a stabilizing composition for an isocyanate group-containing ethylenically unsaturated compound, comprising: an isocyanate group-containing ethylenically unsaturated compound (A) which comprises one or more isocyanate groups and one or more ethylenically unsaturated groups in the molecule; and a stabilizing agent (B) which is a compound in which at least one of the ethylenically unsaturated groups in the compound (A) is replaced with an alkyl group which may have a substituent.

The present invention features monocyclic cyanoenone compositions and methods for using the same in the treatment of diseases such as cancer, inflammatory diseases and neurodegenerative diseases.

A substituted phenoxyethyl(isopropyl)acyloxyalkyl phosphonate having phosphorusheterocyclic ring and having herbicidal activity, with a general formula of I, wherein R represents 5,5-dimethyl-1,3,2-dioxaphosphorinan-2-one-2-yl, or 1-oxo-1-phospha-2,6,7-trioxabicyclo[2,2,2]octan-4-yl, or 1-sulfo-1-phospha-2,6,7-trioxabicyclo 2,6,7-trioxabicyclo[2,2,2]octan-4-yl; R1 represents H, C1-C4 alkyl, phenyl, furyl, pyridyl, or phenyl substituted with methyl, methoxyl, nitro or chloro; R2 represents H, methyl, and methyl only if R in the general formula I is 1-sulfo-1-phospha-2,6,7-trioxabicyclo[2,2,2]octan-4-yl as phosphorusheterocyclic ring; X and Y represent H, halogen, C1-C4 alkyl or trifluoromethyl, and X and Y are the same or different. The compounds according to the present invention may be used as active component of dicotyledonous broadleaf weed herbicides.

Penoxsulam, 2-(2,2-difluoroethoxy)-N-(5,8-dimethoxy[1,2,4]-triazolo[1,5-c]pyrimidin-2-yl)-6-(trifluoromethyl)benzenesulfonamide, is useful in controlling broadleaf weeds and sedges in turfgrass and in vine and orchard floors.

Provided is a method of producing an electrophotographic photosensitive member having improved sensitivity and capable of outputting an image having less image defects due to a ghost phenomenon not only under a normal-temperature, normal-humidity environment but also under a low-temperature, low-humidity environment as a particularly severe condition. The method of producing a gallium phthalocyanine crystal includes subjecting a gallium phthalocyanine and a specific amine compound, which are added to a solvent, to a milling treatment to perform crystal transformation of the gallium phthalocyanine. In addition, the gallium phthalocyanine crystal is used in the photosensitive layer of the electrophotographic photosensitive member.

A solution of a gallium phthalocyanine contains a compound of formula (1) and a gallium phthalocyanine of formula (2), H2N—CH2—R1—CH2—NH2 (1) wherein R1 represents a single bond, or a substituted or unsubstituted alkylene group having 1 to 10 main-chain carbon atoms, a substituent of the substituted alkylene group is an alkyl group having 1 to 3 carbon atoms, an alkyl group having 1 to 3 carbon atoms and being substituted with an amino group, or a hydroxy group, one of the carbon atoms in the main chain of the alkylene group may be replaced with an oxygen atom, a sulfur atom, or a bivalent group represented by the formula —NR2—, and R2 represents a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or an alkyl group having 1 to 3 carbon atoms and being substituted with an amino group, and wherein X1 represents a chlorine atom or hydroxy group.

Provided is a method of producing an electrophotographic photosensitive member having improved sensitivity and capable of outputting an image having less image defects due to a ghost phenomenon not only under a normal-temperature, normal-humidity environment but also under a low-temperature, low-humidity environment as a particularly severe condition. The method of producing a gallium phthalocyanine crystal includes subjecting a gallium phthalocyanine and a specific amine compound, which are added to a solvent, to a milling treatment to perform crystal transformation of the gallium phthalocyanine. In addition, the gallium phthalocyanine crystal is used in the photosensitive layer of the electrophotographic photosensitive member.

Cyanine dye compounds having a substituted methine moiety that are nucleic acid stains, particularly for fluorescent staining of RNA, including compounds having the formula where R1 is a C1-C6 alkyl, sulfoalkyl, carboxyalkyl or C1-C6 alkoxy; each R2 is independently selected from the group consisting of H, C1-C6 alkyl, C1-C6 alkoxy, fused benzo, trifluoromethyl, amino, sulfo, carboxy and halogen, that is optionally further substituted; at least one of R3, R4, and R5 is an alkyl, aryl, heteroaryl, cyclic, or heterocyclic moiety that is optionally substituted by alkyl, amino, aminoalkyl, carboxy, nitro, or halogen; and the remaining R3, R4 or R5 are hydrogen; X is S, O, or Se; and D is a substituted or unsubstituted pyridinium, quinolinium or benzazolium moiety.

Hyaluronic acid (HA) conjugates or crosslinked HAs compositions for coating an implantable device are provided. The implantable device can be used for treating a disorder such as atherosclerosis, thrombosis, restenosis, high cholesterol, hemorrhage, vascular dissection or perforation, vascular aneurysm, vulnerable plaque, chronic total occlusion, claudication, anastomotic proliferation for vein and artificial grafts, bile duct obstruction, ureter obstruction, tumor obstruction, and combinations thereof.

Hyaluronic acid (HA) conjugates or crosslinked HAs compositions for coating an implantable device are provided. The implantable device can be used for treating a disorder such as atherosclerosis, thrombosis, restenosis, high cholesterol, hemorrhage, vascular dissection or perforation, vascular aneurysm, vulnerable plaque, chronic total occlusion, claudication, anastomotic proliferation for vein and artificial grafts, bile duct obstruction, ureter obstruction, tumor obstruction, and combinations thereof.

The present disclosure relates to a novel benzindocyanine compound for labeling biomolecules and a method for preparing the same.

A composition having proanthocyanidin compounds having an average degree of polymerization of at least about 6. A method of administering to an immunosuppressed patient or a patient diagnosed with sepsis or septic shock a composition having a proanthocyanidin. A method of administering to a patient diagnosed with a gram negative bacterial infection a composition having proanthocyanidin compounds having an average degree of polymerization of at least about 6.

Disclosed is a drug effective in the treatment of fibromyalgia. Basically, the disclosed therapeutic agent was created on the basis of experiments showing improvement in symptoms when etanercept was administered to patients suffering from fibromyalgia. Etanercept is known as a therapeutic agent for rheumatoid arthritis, and the JFIQ score of patients not suffering from fibromyalgia improved considerably in the preferred embodiment. In other words, a therapeutic agent for fibromyalgia is disclosed that contains etanercept as an active ingredient in an effective amount.

The present invention provides processes for the manufacturing of polypeptide conjugates. In particular, the invention provides methods for the purification of polypeptide conjugates, which include at least one polymeric modifying groups, such as a poly(alkylene oxide) moiety. Exemplary poly(alkylene oxide) moieties include poly(ethylene glycol) (PEG) and poly(propylene glycol). In an exemplary process, hydrophobic interaction chromatography (HIC) is used to resolve different glycoforms of glycoPEGylated polypeptides.

This disclosure relates to a method of preparing polyamide particles. The method include spray drying a solution containing a polyamide to form polyamide particles having an average diameter of between about 0.5 μm and about 10 μm and at least about 85% of the polyamide particles having a diameter distribution of no more than about 1.5 μm.

According to an aspect of the present invention, in a medium conveyance apparatus which securely supports and conveys a medium, by providing a function for applying a back tension to the medium, in a guide section which forms a guide for supporting the medium in a medium conveyance unit, it is possible to apply a back tension to the medium of which at least a portion is securely supported by the medium conveyance unit, thereby restricting the occurrence of creasing and floating when the medium is securely supported by the medium conveyance unit and maintaining the flatness of the medium which is securely supported by the medium conveyance unit.

A vehicle yaw stability control method and a vehicle yaw stability control apparatus are provided. The yaw rate {dot over (ψ)} of the vehicle is measured. A first reference yaw rate {dot over (ψ)}ref is set. A difference yaw rate Δ{dot over (ψ)} is set. Stabilizing braking intervention is triggered when a value of the difference yaw rate Δ{dot over (ψ)} exceeds limits defined by difference yaw rate threshold values Δ{dot over (ψ)}min, Δ{dot over (ψ)}max. Information regarding the shape of the road ahead of the vehicle is acquired. The reliability of the driver steering input δ is evaluated upon stabilizing braking intervention being triggered. In case the driver steering input δ is deemed unreliable a replacement reference yaw rate {dot over (ψ)}refroad is set based on the acquired road shape and a replacement difference yaw rate Δ{dot over (ψ)}road is set whereupon stabilizing braking intervention is performed based on the replacement difference yaw rate Δ{dot over (ψ)}road.

The disclosure relates to a novel use of a food composition for human use, having fewer than 1600 picomoles of polyamines, for the production of a medical food which is intended to combat a syndrome or pathology involving N-methyl-D-aspartate receptor subunit NR2-B.

The present patent application concerns an enzyme capable of catalysing the conversion of a α-hydroxyglycine to an α-amide and the use of such enzymes for producing a C-terminal α-amidated peptide.