framework
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Data and Competition: a General Framework with Applications to Mergers, Market Structure, and Privacy Policy [electronic journal].
framework
Costly Concessions: An Empirical Framework for Matching with Imperfectly Transferable Utility [electronic journal].
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Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols
Inorg. Chem. Front., 2024, 11,1998-2006
DOI: 10.1039/D4QI00113C, Research Article
DOI: 10.1039/D4QI00113C, Research Article
Mengna Li, Benlai Wu, Maochun Hong
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
The content of this RSS Feed (c) The Royal Society of Chemistry
Highly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02190D, Research Article
DOI: 10.1039/D3QI02190D, Research Article
Semi Kim, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Yeeun Seong, Song Li, Juyeong Kim
Precise carving of ZIF nanocrystals generates heterogeneous internal mesoporosity, providing effective mass transport and uncoordinated active sites for enhanced heterogeneous catalysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Precise carving of ZIF nanocrystals generates heterogeneous internal mesoporosity, providing effective mass transport and uncoordinated active sites for enhanced heterogeneous catalysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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The content of this RSS Feed (c) The Royal Society of Chemistry
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands
Inorg. Chem. Front., 2024, 11,2281-2289
DOI: 10.1039/D4QI00314D, Research Article
DOI: 10.1039/D4QI00314D, Research Article
Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
The content of this RSS Feed (c) The Royal Society of Chemistry
High catalytic performance of porphyrin-based MOFs has been achieved by introducing multiple functionality into their ligands and modulating their conformation.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan
Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article
DOI: 10.1039/D3QI02662K, Research Article
Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
The content of this RSS Feed (c) The Royal Society of Chemistry
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Stable Calcium Ellagate Metal-Organic Framework as High Performance Green Memorizer Bearing High Working Temperature
Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00038B, Research Article
DOI: 10.1039/D4QI00038B, Research Article
Ting-Bo Liu, Jing-Wen Deng, Li Yi, Hai-Ying Fu, Liang-Wen Shi, Shi-Ying Lin, Yue Liu, Hao-Hong Li, Jing-Bo Liu, Jian-Zhi Liu
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
The content of this RSS Feed (c) The Royal Society of Chemistry
The development of green memorizers with distinct mechanism is significant. In this work, renewable polyphenol ellagic acid (EA) and environmentally friendly calcium were used to construct a unique 3D interpenetrated...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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The content of this RSS Feed (c) The Royal Society of Chemistry
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Trifluoroacetic acid molecules confined into/onto metal–organic frameworks using H2btzip for efficiently improving proton conductivity using a synergistic effect
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00605D, Research Article
DOI: 10.1039/D4QI00605D, Research Article
Xiaoxue Ma, Xin Li, Xueke Han, Lu Zhang, Ronghua Liu, Hongguo Hao, Hui Yan, Xin Zhao, Xiangjin Kong, Huawei Zhou, Xia Li, Hongjie Zhu, Suna Wang, Yunwu Li, Dichang Zhong, Fangna Dai
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Two outstanding proton conducting materials have been obtained by loading TFA molecules onto/into the surface or pores of MOFs. After post-treatment, their proton conductivity values are greatly increased under the same conditions.
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The content of this RSS Feed (c) The Royal Society of Chemistry
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When microplastics/plastics meet metal–organic frameworks: turning threats into opportunities
Chem. Sci., 2024, 15,17781-17798
DOI: 10.1039/D4SC05205F, Review Article
DOI: 10.1039/D4SC05205F, Review Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Pengfei Wu, Mengting Guo, Ran-Wei Zhang, Qing Huang, Guibin Wang, Ya-Qian Lan
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
The content of this RSS Feed (c) The Royal Society of Chemistry
The study discussed how MOFs treat microplastics, how to make plastic-based MOFs, and how MOF@plastic composites can be used. It aids in understanding how to convert plastic/microplastic concerns into opportunities for high-valued products.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Probing water adsorption and stability under steam flow of Zr-based metal-organic frameworks using 91Zr solid-state NMR spectroscopy
Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04589K, Edge Article
DOI: 10.1039/D4SC04589K, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Athulya Nadol, Florian Venel, Raynald Giovine, Maeva Leloire, Christophe Volkringer, Thierry Loiseau, Christel Gervais, Caroline Mellot-Draznieks, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Frédérique Pourpoint
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
The content of this RSS Feed (c) The Royal Society of Chemistry
The stability of metal-organic frameworks (MOFs) in the presence of water is crucial for a wide range of applications, including the production of freshwater, desiccation, humidity control, heat pumps/chillers and...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Dual-functional porphyrinic zirconium-based metal–organic framework for the fluorescent sensing of histidine enantiomers and Hg2+
Anal. Methods, 2024, 16,2386-2399
DOI: 10.1039/D3AY02241B, Paper
DOI: 10.1039/D3AY02241B, Paper
Shili Qin, Fanshu Meng, Fenglong Jin, Xidi Xu, Ming Zhao, Hongtao Chu, Lidi Gao, Shuren Liu
L-Cys/PCN-222 as a novel and dual-functional fluorescent sensor was developed. It not only showed a higher chiral fluorescent recognition of L-histidine but also performed as a visual sensor for Hg2+ in actual surface water.
The content of this RSS Feed (c) The Royal Society of Chemistry
L-Cys/PCN-222 as a novel and dual-functional fluorescent sensor was developed. It not only showed a higher chiral fluorescent recognition of L-histidine but also performed as a visual sensor for Hg2+ in actual surface water.
The content of this RSS Feed (c) The Royal Society of Chemistry
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552: Do You Want to Build a JS Framework? ☃️ CSS Wishlist for 2023
Austin power updates, what do you need if you want to build a new JavaScript framework, and what do we hope CSS brings in 2023?
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T.N. govt. sanctions funds to implement framework for flood protection work
The funds are to be utilised for the implementation and monitoring of an environmental and social management framework for flood protection work in Chennai, Tiruvallur, Chengalpattu, and Kancheepuram districts
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A multi-scale framework for predicting α-cyclodextrin assembly on polyethylene glycol axles
Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01048E, Paper
DOI: 10.1039/D4SM01048E, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Cameron D. Smith, Chenfeng Ke, Wenlin Zhang
We predict the assembly and time-dependent distribution of cyclodextrin along PEG axles by combining atomistic molecular dynamics with an analytical treatment of bulk diffusion. Our kinetic Monte Carlo can aid in the design of polypseudorotaxanes.
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We predict the assembly and time-dependent distribution of cyclodextrin along PEG axles by combining atomistic molecular dynamics with an analytical treatment of bulk diffusion. Our kinetic Monte Carlo can aid in the design of polypseudorotaxanes.
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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides
RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
DOI: 10.1039/D4RA06622G, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
The content of this RSS Feed (c) The Royal Society of Chemistry
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Harnessing the UiO-67 metal–organic framework for advanced detection of cadmium ions in water bodies
RSC Adv., 2024, 14,35618-35627
DOI: 10.1039/D4RA06811D, Paper
DOI: 10.1039/D4RA06811D, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Bhuvaneswari Selvaraj, Lakshmi Priya G., Selva Balasubramanian
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
The content of this RSS Feed (c) The Royal Society of Chemistry
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes
RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
DOI: 10.1039/D4RA06537A, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
The content of this RSS Feed (c) The Royal Society of Chemistry
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
The content of this RSS Feed (c) The Royal Society of Chemistry
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AI Ethical Framework: Three Things We Agree On
If not all AI is bad, then how do we decide whether a particular use of AI is ethical or not? How do we design and build AI features that are consistent with our values?
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AI Ethical Framework: AI Model Questions
When people evaluate services, they often consider factors like cost, features, reliability, and performance. For AI, we want to extend those factors by asking questions about how the AI model is built and its impact.
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AI Ethical Framework: AI Usage Questions
How we deploy AI in our work and product development may hold as much weight in shaping the risks and ethics as the specific models we choose.
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Achieving isopropenyl-enriched polyisoprene: unraveling the role of bidentate vs. tridentate iron precatalysts through ligand framework design
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02659D, Paper
DOI: 10.1039/D4DT02659D, Paper
Sunny Sohail, Yanping Ma, Qaiser Mahmood, Zexu Hu, Yizhou Wang, Tongling Liang, Wen-Hua Sun
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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The content of this RSS Feed (c) The Royal Society of Chemistry
The coordination sphere and steric variations in iron catalysts present a fascinating strategy for adjusting monomer regio- and stereoselective enchainment, leading to the development of novel polymer structures in isoprene polymerization.
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A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02734E, Paper
DOI: 10.1039/D4DT02734E, Paper
Hui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang Tang
A biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.
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A biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.
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Solvatomorphic Phase Transitions and Tunable Luminescence Emission in Lanthanide Metal-Organic Frameworks
Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02613F, Paper
DOI: 10.1039/D4DT02613F, Paper
Alena A. Vasileva, Pavel A. Demakov, Tatiana Y. Guselnikova, Alexey A. Ryadun, Vladimir P Fedin, Danil N. Dybtsev
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
The content of this RSS Feed (c) The Royal Society of Chemistry
Four new metal-organic frameworks with the formulae [Sm2(phen)2(NO3)2(chdc)2]·2Solv, where Solv = N,N-dimethylformamide (DMF; 1), N,N-dimethylacetamide (DMA; 2), N,N-diethylformamide (DEF; 3), N-formylpiperidine (NFP; 4), phen = 1,10-phenanthroline and chdc2– = trans-1,4-cyclohexanedicarboxylate...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Rational fabrication of an anionic zinc carboxylate framework as a fluorescent probe for 2,6-pyridinedicarboxylic acid
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02529F, Paper
DOI: 10.1039/D4DT02529F, Paper
Hui-Hui Xie, Hao Yu, Xiuling Xu, Si-Fu Tang
An anionic zinc carboxylate framework has been fabricated as a fluorescent sensor for the detection of 2,6-pyridinedicarboxylic acid (DPA).
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The content of this RSS Feed (c) The Royal Society of Chemistry
An anionic zinc carboxylate framework has been fabricated as a fluorescent sensor for the detection of 2,6-pyridinedicarboxylic acid (DPA).
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Multifunctional chiral metal hydrogen-bonded organic frameworks constructed from lanthanide ions with a trigonal prismatic coordination environment
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02131B, Paper
DOI: 10.1039/D4DT02131B, Paper
Guo Peng, Guo-Xing Zhou, Xiang-Tao Dong, Yong-Bo Peng, Rong-Yan Zhang, Ying-Zhao Ma, Xiao-Ming Ren
Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Four multifunctional chiral lanthanide hydrogen-bonded organic frameworks with second harmonic generation, single molecule magnet behavior and proton conductive ability are reported herein.
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Two amino-functionalized metal–organic frameworks with different topologies for C2H2/C2H4 separation
Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02592J, Communication
DOI: 10.1039/D4DT02592J, Communication
Yue Li, Mingming Xu, Hongyan Liu, Xiaokang Wang, Yutong Wang, Meng Sun, Weidong Fan, Daofeng Sun
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Two amino-functionalized metal–organic frameworks (UPC-121 and UPC-122) with different topologies were obtained by regulating metal ions. Among them, UPC-122 exhibit the potential to separate C2H2/C2H4 at room temperature.
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framework
Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction
Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
The content of this RSS Feed (c) The Royal Society of Chemistry
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective
Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
The content of this RSS Feed (c) The Royal Society of Chemistry
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting
Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
The content of this RSS Feed (c) The Royal Society of Chemistry
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Construction of oxygen-rich vacancies and heterojunctions coupled with different morphologies of CeO2/mesoporous TiO2 framework structures for efficient photocatalytic CO2 reduction performance
Dalton Trans., 2024, 53,17963-17975
DOI: 10.1039/D4DT02014F, Paper
DOI: 10.1039/D4DT02014F, Paper
Morigejile Liu, Guangmei Jiang, Zaiwang Zhao, Ying Shi, Siqin Zhao
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
Construction of oxygen-rich vacancies and heterojunction-coupled CeO2/mesoporous TiO2 framework structures with different morphologies and efficient photocatalytic CO2 reduction performance.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Imine bond-directed assembly of polyoxometalate-based metal–organic frameworks
Dalton Trans., 2024, 53,17902-17908
DOI: 10.1039/D4DT02609H, Paper
DOI: 10.1039/D4DT02609H, Paper
Xiang Yu, Xinyu Xu, Lei Gao, Rengan Luo, Yi-Fan Liu, Yu-Hao Gu, Shuai Yuan
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry
A series of isostructural polyoxometalate-based MOFs were constructed by linking polyoxometalates and metal clusters with imine bonds under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro
Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Customized structures of hydrogen-bonded organic frameworks towards photocatalysis
Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03766A, Review Article
DOI: 10.1039/D4EE03766A, Review Article
Chengdi Ma, Liyang Qin, Tianhua Zhou, Jian Zhang
This review provides a comprehensive analysis of the unique structural characteristics of HOFs and their diverse functional properties, while further exploring the potential of HOFs in the field of photocatalysis.
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This review provides a comprehensive analysis of the unique structural characteristics of HOFs and their diverse functional properties, while further exploring the potential of HOFs in the field of photocatalysis.
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framework
XRDMatch: a semi-supervised learning framework to efficiently discover room temperature lithium superionic conductors
Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02970D, Paper
DOI: 10.1039/D4EE02970D, Paper
Zheng Wan, Zhenying Chen, Hao Chen, Yizhi Jiang, Jinhuan Zhang, Yidong Wang, Jindong Wang, Hao Sun, Zhongjie Zhu, Jinhui Zhu, Linyi Yang, Wei Ye, Shikun Zhang, Xing Xie, Yue Zhang, Xiaodong Zhuang, Xiao He, Jinrong Yang
We propose XRDMatch, a semi-supervised learning framework that integrates consistency regularization and pseudo-labeling. Using X-ray diffraction patterns as descriptors, it effectively addresses data scarcity by leveraging abundant unlabeled data.
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We propose XRDMatch, a semi-supervised learning framework that integrates consistency regularization and pseudo-labeling. Using X-ray diffraction patterns as descriptors, it effectively addresses data scarcity by leveraging abundant unlabeled data.
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framework
Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage
Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
The content of this RSS Feed (c) The Royal Society of Chemistry
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
Advancing high-temperature electrostatic energy storage via linker engineering of metal–organic frameworks in polymer nanocomposites
Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04085F, Paper
DOI: 10.1039/D4EE04085F, Paper
Zongliang Xie, Zhiyuan Huang, He Li, Tianlei Xu, Haoyu Zhao, Yunfei Wang, Pang Xi, Zhiqiang Cao, Virginia Altoe, Liana M Klivansky, Zaiyu Wang, Steven Shelton, Shiqi Lai, Peng Liu, Chenhui Zhu, Michael D. Connolly, Corie Y. Ralston, Xiaodan Gu, Zongren Peng, Jian Zhang, Yi Liu
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
The content of this RSS Feed (c) The Royal Society of Chemistry
High-performance, thermally resilient polymer dielectrics are essential for film capacitors used in advanced electronic devices and renewable energy systems, particularly at elevated temperatures where conventional polymers fail to perform. Compositing...
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
Strengthening the India link in the Indo-Pacific Economic Framework for Prosperity
framework
Palladium particle-catalyzed selective butadiene hydrogenation: effect of covalent organic framework modification
React. Chem. Eng., 2024, 9,950-958
DOI: 10.1039/D3RE00606A, Paper
DOI: 10.1039/D3RE00606A, Paper
Xianming Li, Yi Wang, Qiao Yuan, Xintai Chen, Xiaoling Mou, Xiangen Song, Li Yan, Ronghe Lin, Yunjie Ding
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
The content of this RSS Feed (c) The Royal Society of Chemistry
Deposition of a covalent organic framework on palladium nanoparticles induces geometric and electronic effects on the metal species and improves their selective performance in 1,3-butadiene hydrogenation.
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
All-in-one Rh(III)-covalent organic framework for sustainable and regioselective C(sp2)–H bond functionalization
Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01098A, Paper
DOI: 10.1039/D4CY01098A, Paper
Luohe Wang, Junnan E, Xiubin Bu, Jing Zeng, Xiaobo Yang, Hua Fu, Zhen Zhao
RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
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RhCOF-SYNU-1 serves as a transition-metal catalyst, photocatalyst, and metal ligand, enabling regioselective C(sp2)–H bond functionalization and offering a sustainable approach for Rh(III) catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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framework
Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst
Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
The content of this RSS Feed (c) The Royal Society of Chemistry
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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framework
Phenol Hydroxyl-Modified Imine-Based Covalent organic framework for enhanced solar-driven generation of H2O2 via Hydrogen Bonds
Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01096E, Paper
DOI: 10.1039/D4CY01096E, Paper
Lang Chen, Song Qin, Jiahui Hang, Bo Chen, Jinyang Kang, yang zhao, Shan-Yong Chen, Yongdong Jin, Hongjian Yan, Yuanhua Wang, Xia Chuanqin
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
The content of this RSS Feed (c) The Royal Society of Chemistry
Photosynthesis of H2O2 have been considered an eco-friendly strategy. However, the concentration of H2O2 in reported studies is far from industrial requirement. Herein, we present a strategy by employing phenolic...
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
Anthracene-based covalent organic framework supported palladium nanoparticles for visible-light-mediated Suzuki-Miyaura cross-coupling
Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01083C, Paper
DOI: 10.1039/D4CY01083C, Paper
Lei Li, Qiujie Shan, Jiyuan Zang, Lei Yu, David James Young, Zhi-Gang Ren, Hong-Xi Li
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
The content of this RSS Feed (c) The Royal Society of Chemistry
An anthracene-based covalent organic framework (COF) anchoring Pd(0) nanoparticles (Pd/AntCOF) photocatalyzed Suzuki-Miyaura cross-coupling of arylbromides and arylboronic acids in water under blue LED irradiation at ambient temperature. The AntCOF both...
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
Dual metal centers within a water-stable Co/Ni bimetallic metal-triazolate framework contribute to durable photocatalysis for water treatment
Nanoscale, 2024, 16,20082-20088
DOI: 10.1039/D4NR03940H, Communication
DOI: 10.1039/D4NR03940H, Communication
Minling Zheng, Yubo Liu, Qifu Zhang, Wenjing Li, Yong Zhang, Guangxue Feng, Yating Hu, Shaoming Huang
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
The content of this RSS Feed (c) The Royal Society of Chemistry
A bimetallic CoNi-MET with fixed metal occupancy combines the strong water resistance of Co-MET with the high porosity of a Ni-MET.
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
Liquid exfoliation of a series of expanded layered Cu(II)-paddlewheel metal–organic frameworks to form nanosheets
Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02663B, Paper
DOI: 10.1039/D4NR02663B, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joshua Nicks, Thomas M. Roseveare, Michael S. Harris, David J. Ashworth, George Danczuk, Lee Brammer, Jonathan A. Foster
The effects of linker length on nanosheet dimensions and properties are investigated through the ultrasonic liquid exfoliation of an isoreticular series of layered metal–organic frameworks.
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The effects of linker length on nanosheet dimensions and properties are investigated through the ultrasonic liquid exfoliation of an isoreticular series of layered metal–organic frameworks.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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framework
Copper(II)-based metal–organic framework delivery of calcium ascorbate for enhanced chemodynamic therapy via H2O2 self-supply and glutathione depletion
Biomater. Sci., 2024, 12,1871-1882
DOI: 10.1039/D3BM01922E, Paper
DOI: 10.1039/D3BM01922E, Paper
Meng Zhang, Hongjin Xue, Jiaxin Yang, Xin Zhao, Mei Xue, Wei Sun, Jianfeng Qiu, Zhihong Zhu
A Cu/ZIF-8/Vc-Ca/HA nanosystem synchronously releases Fenton catalytic Cu2+ and Vc-Ca to achieve improved chemodynamic therapy via H2O2 self-supply and GSH depletion.
The content of this RSS Feed (c) The Royal Society of Chemistry
A Cu/ZIF-8/Vc-Ca/HA nanosystem synchronously releases Fenton catalytic Cu2+ and Vc-Ca to achieve improved chemodynamic therapy via H2O2 self-supply and GSH depletion.
The content of this RSS Feed (c) The Royal Society of Chemistry
framework
PET image-guided kidney injury theranostics enabled by a bipyramidal DNA framework
Biomater. Sci., 2024, 12,2086-2095
DOI: 10.1039/D3BM01575K, Paper
DOI: 10.1039/D3BM01575K, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Pinghui Li, Zhidie Huang, Xiaoyan Duan, Tao Wang, Shaowen Yang, Dawei Jiang, Jianbo Li
We constructed 68Ga-BDF and employed PET imaging to establish its pharmacokinetic model. BDF was eliminated from the body via the urinary system. We observed distinct imaging indicators in UUO and AKI mouse models. Furthermore, we observed the therapeutic effect of BDF on AKI.
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We constructed 68Ga-BDF and employed PET imaging to establish its pharmacokinetic model. BDF was eliminated from the body via the urinary system. We observed distinct imaging indicators in UUO and AKI mouse models. Furthermore, we observed the therapeutic effect of BDF on AKI.
The content of this RSS Feed (c) The Royal Society of Chemistry