framework

Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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framework

Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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framework

Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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framework

A liquid-infiltrated Al2O3 framework electrolyte enables aqueous zinc batteries

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04928D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rongyu Deng, Yi Yuan, Zixuan Li, Feixiang Wu, Alex W Robertson
Aqueous zinc-ion battery anodes face the twin challenges of dendrite growth and severe side reactions. Here a liquid-infiltrated Al2O3 framework electrolyte (LIAFE) is developed to address these issues and enables...
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framework

Catalytic Ethynylation of Formaldehyde for Selective Propargyl Alcohol Production Using the Copper Metal Organic Framework HKUST-1

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ06001B, Paper
Wanxi Yang, Wencai Peng, Han Li, Jin Mao, Liqiang Qian, Qingyu Zhang
HKUST-1 with high crystallinity has been successfully synthesized by solvothermal method using Cu(NO3)2·3H2O as a copper source, 1,3,5-benzenetricarboxylic acid as organic ligand, and N,N-dimethylformamide as solvent. HKUST-1 exhibited a typical...
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framework

Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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framework

Metal–organic framework-derived mesoporous Co3O4 with high specific surface area for enhanced xylene sensing

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01096E, Paper
Liwen Wang, Guanghui Zhang, Ruishu Zhang, Siqi Yang, Wenjuan Huang, Xiangbai Chen
Co3O4 hollow polyhedra have a high specific surface area and mesoporous structure. The Co3O4 gas sensor has excellent sensing performance and selectivity for xylene.
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framework

Adsorption isotherms of enantiomers on a chiral open-framework copper borophosphate LiCu2[BP2O8(OH)2]

New J. Chem., 2024, 48,7189-7196
DOI: 10.1039/D4NJ00314D, Paper
Zhanna D. Uteeva, Raul U. Sadykov, Diana O. Bagdanova, Marat R. Agliullin, Vladimir Yu. Guskov
The chiral recognition during adsorption in pores with only supramolecular (not molecular) chirality was shown for the first time on zeotype material copper borophosphate LiCu2[BP2O8(OH)2].
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framework

Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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framework

Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper
Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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framework

Hydrogen-bonded organic frameworks with extended conjugate systems for boosted photocatalytic degradation

New J. Chem., 2024, 48,7213-7224
DOI: 10.1039/D4NJ00610K, Paper
Xiaojuan Bai, YiLin Xin, Tianqi Jia, Linlong Guo, Wei Song, Derek Hao
A schematic mechanism of the photocatalytic degradation process of SMX by solvothermal synthesis of hydrogen-bonded organic framework materials.
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framework

Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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framework

Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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framework

Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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framework

Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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framework

Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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framework

A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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framework

Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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framework

A highly stable hydrogen-bonded organic framework for hydrogen storage

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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framework

A framework for detection, measurement, and welfare analysis of platform bias [electronic resource] / Imke Reimers, Joel Waldfogel

Cambridge, Mass. : National Bureau of Economic Research 2023




framework

Hong Kong unveils responsible AI framework for financial sector

Hong Kong’s responsible AI framework comes amid increasing international competition and tensions affecting access to AI technology




framework

A review on metal–organic frameworks (MOFs) and MOF–textile composites for personal protection

Mater. Chem. Front., 2024, 8,3509-3527
DOI: 10.1039/D4QM00358F, Review Article
Junmei Li, Yinan Fan, Ruigan Zhang, Demao Ban, Zhixuan Duan, Xiaoyuan Liu, Lifang Liu
Metal–organic frameworks (MOFs) have become a research hotspot for effective adsorption and degradation of chemical warfare agents (CWAs) and toxic industrial chemicals (TICs).
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framework

Tailoring the adsorption properties of imidazole-based halogen bonded organic frameworks for anionic dye removal

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article
Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]+ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
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framework

Sweet MOFs: Exploring the Potential and Restraints of Integrating Carbohydrates with Metal-Organic Frameworks for Biomedical Applications

Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00525B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessio Zuliani, Victor Ramos, Alberto Escudero, Noureddine Khiar
The unique features of metal-organic frameworks (MOFs) such as biodegradability, reduced toxicity and high surface area offer the possibility of developing smart nanosystems for biomedical applications through the simultaneous functionalization...
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framework

Ordered crown-ether 2D framework based loose nanofiltration membranes for improved separation and stability

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06349J, Communication
Jae Jun Kim, Hui-Ran Seo, Jinseok Kim, Mun Hyeon Kim, Jinwook Park, Hyunkee Hong, Hee Joong Kim, Jong-Chan Lee
Loose nanofiltration (LNF) membranes, known for high water permeability and dye/salt selectivity, have been widely used. However, LNF membranes fabricated through layer-by-layer (LbL) assembly lack structural stability and uniformity. Herein,...
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framework

Modulating the band gap of a pyrazinoquinoxaline-based metal–organic framework through orbital hybridization for enhanced visible light-driven CN bond construction

J. Mater. Chem. A, 2024, 12,30582-30590
DOI: 10.1039/D4TA06282E, Paper
Zitong Chen, Linghui Cao, Aogang Liu, Pengda Liu, Yuan Chen, Juntao Yan, Bao Li
An indium-based metal–organic framework bearing a pyrazinoquinoxaline derivative is synthesized to facilitate two methods for the construction of CN bonds, and their mechanisms are investigated through detailed theoretical calculations.
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framework

Unsaturated coordination modulation and enlarged pore size in nanoflower-like metal organic frameworks for enhanced lithium–oxygen battery performance

J. Mater. Chem. A, 2024, 12,30591-30600
DOI: 10.1039/D4TA06346E, Paper
Lingwen Zhao, Juanjuan Feng, Adeel Abbas, Hao Sun, Chunlei Wang, Hongchao Wang
Unsaturated coordination modulation alters the discharge path and increased pore size accelerates ion exchange and oxygen transport, synergistically improving the electrochemical performance of LOBs.
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framework

An azo-receptor immobilized mesoporous honeycomb silica framework as a solid-state chromogenic sensor for capturing ultra-trace cadmium ions from environmental/industrial samples

J. Mater. Chem. A, 2024, 12,30567-30581
DOI: 10.1039/D4TA04574B, Paper
Anju P. Veedu, Balasurendran Jeyakumar, Akhila Maheswari Mohan, Satheesh Kuppusamy, Pitchaiah K. Chinaraga, Manjula Muthurathinam, C. V. S. Brahmananda Rao, Sivaraman Nagarajan, Prabhakaran Deivasigamani
A solid-state naked-eye sensor composed of a mesoporous honeycomb structured silica monolith impregnated with a DMTHBD receptor offers a simple, rapid and eco-benign approach for the selective sensing of trace Cd2+, with brilliant color transitions.
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framework

One-pot spatial engineering of multi-enzymes in metal–organic frameworks for enhanced cascade activity

J. Mater. Chem. A, 2024, 12,30318-30328
DOI: 10.1039/D4TA06211F, Paper
Wenqing Fan, Kang Liang, Jieying Liang
A one-pot strategy was developed for the first time to achieve the precise spatial arrangement of multiple enzymes in MOFs, improving multi-enzyme cascade efficiency.
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Design and construction of porphyrin box-based metal–organic frameworks with hierarchical superstructures for efficient energy transfer and photooxidation

J. Mater. Chem. A, 2024, 12,30685-30691
DOI: 10.1039/D4TA05576D, Paper
Qian Xu, Peng Zhang, Yuanyuan Sun, Jishi Chen, Chuantao Hou, Zonghua Wang
A porphyrin box-based MOF with hierarchical superstructures was synthesized, exhibiting enhanced performance in singlet oxygen-mediated photooxidation.
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framework

A sustainable redox-mediated pathway for improved transition metal organic framework activation and CO2 uptake performance

J. Mater. Chem. A, 2024, 12,30454-30464
DOI: 10.1039/D4TA02526A, Paper
Taylor Jade Self, Jiabin Niu, Wen Liu, Chaobin He, Mei Chee Tan
Sustainable substitutions in MOF fabrication and processing can confidently be made by employing redox engineering for synergistic valency and defect constitution, based on application, without sacrificing active site functionality.
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Metal–organic framework derived low-crystallinity cobalt–nitrogen–carbon electrocatalysts for nitrate reduction to ammonia

J. Mater. Chem. A, 2024, 12,30409-30419
DOI: 10.1039/D4TA05443A, Paper
Yue Cao, Shengbo Yuan, Wenbo Zhou, Yan Hai, Xiaoman Li, Min Luo
NO3 and H2O molecules adsorbed on the surface of Co–N–C-500 are activated and dissociated. The generated active hydrogen species (*H) can promote the hydrogenation of the intermediates and thus increase the NH3 yield.
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Ir nanoparticles decorated NiFe metal–organic framework as a highly efficient and stable heterostructure electrocatalyst for overall seawater splitting

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06515H, Communication
Hefeng Wang, Zixiao Li, Zhengwei Cai, Chaoxin Yang, Shengjun Sun, Xiaoyan Wang, Min Zhang, Meng Yue, Dongdong Zheng, Asmaa Farouk, Mohamed S. Hamdy, Xuping Sun, Bo Tang
Ir nanoparticle decorated NiFe metal–organic framework on Ni foam (Ir@NiFe-MOF/NF) acts as a bifunctional catalyst for the oxygen evolution reaction and the hydrogen evolution reaction in alkaline seawater with excellent performance and stability.
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framework

A doubly interpenetrated perylene diimide-based zirconium metal–organic framework for selective oxidation of sulfides powered by blue light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06294A, Paper
Chao Wei, Ming Lu, Jing-Jing Li, Ze-Jiu Diao, Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun
A doubly interpenetrated perylene diimide-based zirconium metal–organic framework is developed as a heterogeneous photocatalyst for selective photocatalytic oxidation of organic sulfides powered by blue light.
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A π–d conjugated metal–organic framework decorated on a MXene-carbon nanofiber as a self-standing electrode for flexible supercapacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06232A, Paper
Zahir Abbas, Shaikh M. Mobin
A c-MOF is grown on MX-CNF, which was prepared via electrospining method. Furthermore, it utilized for flexible supercapcitors with different flexibility angles.
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framework

Silver-incorporated NiCo metal–organic frameworks with controlled morphology for enhanced cycling in flexible supercapacitor applications

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC02970D, Paper
Chu Chu, Wenjing Zhang, Xuehua Yan, Yingnan Yan, Jianmei Pan, Zohreh Shahnavaz, Jamile Mohammadi Moradian
The specific capacitance of NCA15-MOF/NF was 1317 F g−1, which was significantly higher compared to the NCA0-MOF/NF. After 15 000 charge–discharge cycles, the NCA15-MOF/NF retained 89% of its initial specific capacitance.
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Application of metal organic frameworks (MOFs) and their derivatives in the cathode materials of aqueous zinc-ion batteries

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03273J, Review Article
Pingchun Guo, Shisong Ouyang, Hedong Jiang, Jiake Li, Hua Zhu, Yanxiang Wang
Metal–organic frameworks (MOFs) are regarded as potential candidate materials for the cathodes of aqueous zinc-ion batteries. This review presents the applications of MOFs and their derivatives in the cathodes of aqueous zinc-ion batteries.
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framework

A metal–organic framework enhanced single network organohydrogel with superior low-temperature adaptability and UV-blocking capability towards human-motion sensing

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper
Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH2 nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00521J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu, Jianchun Jiang
Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement.
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Personalization Pyramid: A Framework for Designing with User Data

As a UX professional in today’s data-driven landscape, it’s increasingly likely that you’ve been asked to design a personalized digital experience, whether it’s a public website, user portal, or native application. Yet while there continues to be no shortage of marketing hype around personalization platforms, we still have very few standardized approaches for implementing personalized UX.

That’s where we come in. After completing dozens of personalization projects over the past few years, we gave ourselves a goal: could you create a holistic personalization framework specifically for UX practitioners? The Personalization Pyramid is a designer-centric model for standing up human-centered personalization programs, spanning data, segmentation, content delivery, and overall goals. By using this approach, you will be able to understand the core components of a contemporary, UX-driven personalization program (or at the very least know enough to get started). 

Growing tools for personalization: According to a Dynamic Yield survey, 39% of respondents felt support is available on-demand when a business case is made for it (up 15% from 2020).

Source: “The State of Personalization Maturity – Q4 2021” Dynamic Yield conducted its annual maturity survey across roles and sectors in the Americas (AMER), Europe and the Middle East (EMEA), and the Asia-Pacific (APAC) regions. This marks the fourth consecutive year publishing our research, which includes more than 450 responses from individuals in the C-Suite, Marketing, Merchandising, CX, Product, and IT.

Getting Started

For the sake of this article, we’ll assume you’re already familiar with the basics of digital personalization. A good overview can be found here: Website Personalization Planning. While UX projects in this area can take on many different forms, they often stem from similar starting points.      

Common scenarios for starting a personalization project:

  • Your organization or client purchased a content management system (CMS) or marketing automation platform (MAP) or related technology that supports personalization
  • The CMO, CDO, or CIO has identified personalization as a goal
  • Customer data is disjointed or ambiguous
  • You are running some isolated targeting campaigns or A/B testing
  • Stakeholders disagree on personalization approach
  • Mandate of customer privacy rules (e.g. GDPR) requires revisiting existing user targeting practices
Workshopping personalization at a conference.

Regardless of where you begin, a successful personalization program will require the same core building blocks. We’ve captured these as the “levels” on the pyramid. Whether you are a UX designer, researcher, or strategist, understanding the core components can help make your contribution successful.  

From the ground up: Soup-to-nuts personalization, without going nuts.

From top to bottom, the levels include:

  1. North Star: What larger strategic objective is driving the personalization program? 
  2. Goals: What are the specific, measurable outcomes of the program? 
  3. Touchpoints: Where will the personalized experience be served?
  4. Contexts and Campaigns: What personalization content will the user see?
  5. User Segments: What constitutes a unique, usable audience? 
  6. Actionable Data: What reliable and authoritative data is captured by our technical platform to drive personalization?  
  7. Raw Data: What wider set of data is conceivably available (already in our setting) allowing you to personalize?

We’ll go through each of these levels in turn. To help make this actionable, we created an accompanying deck of cards to illustrate specific examples from each level. We’ve found them helpful in personalization brainstorming sessions, and will include examples for you here.

Personalization pack: Deck of cards to help kickstart your personalization brainstorming.

Starting at the Top

The components of the pyramid are as follows:

North Star

A north star is what you are aiming for overall with your personalization program (big or small). The North Star defines the (one) overall mission of the personalization program. What do you wish to accomplish? North Stars cast a shadow. The bigger the star, the bigger the shadow. Example of North Starts might include: 

  1. Function: Personalize based on basic user inputs. Examples: “Raw” notifications, basic search results, system user settings and configuration options, general customization, basic optimizations
  2. Feature: Self-contained personalization componentry. Examples: “Cooked” notifications, advanced optimizations (geolocation), basic dynamic messaging, customized modules, automations, recommenders
  3. Experience: Personalized user experiences across multiple interactions and user flows. Examples: Email campaigns, landing pages, advanced messaging (i.e. C2C chat) or conversational interfaces, larger user flows and content-intensive optimizations (localization).
  4. Product: Highly differentiating personalized product experiences. Examples: Standalone, branded experiences with personalization at their core, like the “algotorial” playlists by Spotify such as Discover Weekly.

Goals

As in any good UX design, personalization can help accelerate designing with customer intentions. Goals are the tactical and measurable metrics that will prove the overall program is successful. A good place to start is with your current analytics and measurement program and metrics you can benchmark against. In some cases, new goals may be appropriate. The key thing to remember is that personalization itself is not a goal, rather it is a means to an end. Common goals include:

  • Conversion
  • Time on task
  • Net promoter score (NPS)
  • Customer satisfaction 

Touchpoints

Touchpoints are where the personalization happens. As a UX designer, this will be one of your largest areas of responsibility. The touchpoints available to you will depend on how your personalization and associated technology capabilities are instrumented, and should be rooted in improving a user’s experience at a particular point in the journey. Touchpoints can be multi-device (mobile, in-store, website) but also more granular (web banner, web pop-up etc.). Here are some examples:

Channel-level Touchpoints

  • Email: Role
  • Email: Time of open
  • In-store display (JSON endpoint)
  • Native app
  • Search

Wireframe-level Touchpoints

  • Web overlay
  • Web alert bar
  • Web banner
  • Web content block
  • Web menu

If you’re designing for web interfaces, for example, you will likely need to include personalized “zones” in your wireframes. The content for these can be presented programmatically in touchpoints based on our next step, contexts and campaigns.

Contexts and Campaigns

Once you’ve outlined some touchpoints, you can consider the actual personalized content a user will receive. Many personalization tools will refer to these as “campaigns” (so, for example, a campaign on a web banner for new visitors to the website). These will programmatically be shown at certain touchpoints to certain user segments, as defined by user data. At this stage, we find it helpful to consider two separate models: a context model and a content model. The context helps you consider the level of engagement of the user at the personalization moment, for example a user casually browsing information vs. doing a deep-dive. Think of it in terms of information retrieval behaviors. The content model can then help you determine what type of personalization to serve based on the context (for example, an “Enrich” campaign that shows related articles may be a suitable supplement to extant content).

Personalization Context Model:

  1. Browse
  2. Skim
  3. Nudge
  4. Feast

Personalization Content Model:

  1. Alert
  2. Make Easier
  3. Cross-Sell
  4. Enrich

We’ve written extensively about each of these models elsewhere, so if you’d like to read more you can check out Colin’s Personalization Content Model and Jeff’s Personalization Context Model

User Segments

User segments can be created prescriptively or adaptively, based on user research (e.g. via rules and logic tied to set user behaviors or via A/B testing). At a minimum you will likely need to consider how to treat the unknown or first-time visitor, the guest or returning visitor for whom you may have a stateful cookie (or equivalent post-cookie identifier), or the authenticated visitor who is logged in. Here are some examples from the personalization pyramid:

  • Unknown
  • Guest
  • Authenticated
  • Default
  • Referred
  • Role
  • Cohort
  • Unique ID

Actionable Data

Every organization with any digital presence has data. It’s a matter of asking what data you can ethically collect on users, its inherent reliability and value, as to how can you use it (sometimes known as “data activation.”) Fortunately, the tide is turning to first-party data: a recent study by Twilio estimates some 80% of businesses are using at least some type of first-party data to personalize the customer experience. 

Source: “The State of Personalization 2021” by Twilio. Survey respondents were n=2,700 adult consumers who have purchased something online in the past 6 months, and n=300 adult manager+ decision-makers at consumer-facing companies that provide goods and/or services online. Respondents were from the United States, United Kingdom, Australia, and New Zealand.Data was collected from April 8 to April 20, 2021.

First-party data represents multiple advantages on the UX front, including being relatively simple to collect, more likely to be accurate, and less susceptible to the “creep factor” of third-party data. So a key part of your UX strategy should be to determine what the best form of data collection is on your audiences. Here are some examples:

Figure 1.1.2: Example of a personalization maturity curve, showing progression from basic recommendations functionality to true individualization. Credit: https://kibocommerce.com/blog/kibos-personalization-maturity-chart/

There is a progression of profiling when it comes to recognizing and making decisioning about different audiences and their signals. It tends to move towards more granular constructs about smaller and smaller cohorts of users as time and confidence and data volume grow.

While some combination of implicit / explicit data is generally a prerequisite for any implementation (more commonly referred to as first party and third-party data) ML efforts are typically not cost-effective directly out of the box. This is because a strong data backbone and content repository is a prerequisite for optimization. But these approaches should be considered as part of the larger roadmap and may indeed help accelerate the organization’s overall progress. Typically at this point you will partner with key stakeholders and product owners to design a profiling model. The profiling model includes defining approach to configuring profiles, profile keys, profile cards and pattern cards. A multi-faceted approach to profiling which makes it scalable.

Pulling it Together

While the cards comprise the starting point to an inventory of sorts (we provide blanks for you to tailor your own), a set of potential levers and motivations for the style of personalization activities you aspire to deliver, they are more valuable when thought of in a grouping. 

In assembling a card “hand”, one can begin to trace the entire trajectory from leadership focus down through a strategic and tactical execution. It is also at the heart of the way both co-authors have conducted workshops in assembling a program backlog—which is a fine subject for another article.

In the meantime, what is important to note is that each colored class of card is helpful to survey in understanding the range of choices potentially at your disposal, it is threading through and making concrete decisions about for whom this decisioning will be made: where, when, and how.

Scenario A: We want to use personalization to improve customer satisfaction on the website. For unknown users, we will create a short quiz to better identify what the user has come to do. This is sometimes referred to as “badging” a user in onboarding contexts, to better characterize their present intent and context.

Lay Down Your Cards

Any sustainable personalization strategy must consider near, mid and long-term goals. Even with the leading CMS platforms like Sitecore and Adobe or the most exciting composable CMS DXP out there, there is simply no “easy button” wherein a personalization program can be stood up and immediately view meaningful results. That said, there is a common grammar to all personalization activities, just like every sentence has nouns and verbs. These cards attempt to map that territory.




framework

Baku Climate Talks: G77, China Reject Framework For Draft Text On New Climate Finance Goal

G77 and China rejected the substantive framework for a draft negotiating text prepared by the co-chairs of the Ad-Hoc Work Programme on the New Collective Quantified Goal (NCQG), arguing that it does not accurately reflect the concerns raised by developing countries. 




framework

A systematic review of green and sustainable chemistry training research with pedagogical content knowledge framework: current trends and future directions

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00166D, Review Article
Sevgi Aydin Gunbatar, Betul Ekiz Kiran, Yezdan Boz, Elif Selcan Oztay
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framework

Enhanced photocatalysis of metal/covalent organic frameworks by plasmonic nanoparticles and homo/hetero-junctions

Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article
Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
The content of this RSS Feed (c) The Royal Society of Chemistry




framework

A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

Mater. Horiz., 2024, 11,1704-1709
DOI: 10.1039/D3MH01790G, Communication
Peng-Fei Li, Chun-Li Hu, Jiang-Gao Mao, Fang Kong
NCS NaLu(SeO3)2 was designed by framework-optimized structural transformation from CS NaGa(SeO3)2. NaLu(SeO3)2 exhibits large SHG responses, a wide band gap, a short UV cut-off edge, high LIDT, sufficient birefringence and high thermal stability.
The content of this RSS Feed (c) The Royal Society of Chemistry




framework

Exploring negative thermal expansion materials with bulk framework structures and their relevant scaling relationships through multi-step machine learning

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D3MH01509B, Communication
Yu Cai, Chunyan Wang, Huanli Yuan, Yuan Guo, Jun-Hyung Cho, Xianran Xing, Yu Jia
We uses the multi-step ML method to mine 1000 potential NTE materials from ICSD, MPD and COD databases, and the presented phase diagram can serve as a preliminary criterion for judging and designing new NTE materials.
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The content of this RSS Feed (c) The Royal Society of Chemistry




framework

Heterointerface regulation of covalent organic framework-anchored graphene via a solvent-free strategy for high-performance supercapacitor and hybrid capacitive deionization electrodes

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication
Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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framework

Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
The content of this RSS Feed (c) The Royal Society of Chemistry




framework

Biphenyl Tetracarboxylic Acid based Metal-Organic Frameworks: A Case of Topology-Dependent Thermal Expansion

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02185H, Communication
Zhanning Liu, Chengyong Xing, Shaowen Wu, Min Ma, Jian Tian
The large inherent flexibility and highly modular nature of metal-organic frameworks (MOFs) made them ideal candidates for the study of negative thermal expansion (NTE). Among the diverse organic ligands, the...
The content of this RSS Feed (c) The Royal Society of Chemistry




framework

Monetary Policy and Heterogeneity: An Analytical Framework [electronic journal].




framework

Markets and Markup: A New Empirical Framework and Evidence on Exporters from China [electronic journal].