framework

Porphyrin-Based Covalent Organic Frameworks from Design, Synthesis to Biological Applications

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4BM00214H, Review Article
Open Access
Xin-Gui Li, Junjian Li, Jinfeng Chen, Liangmei Rao, Libin Zheng, Fei Yu, Yijing Tang, Jie Zheng, Jie Ma
Covalent organic frameworks (COFs) constitute a class of highly functional porous materials characterized by ordered structures, high crystallinity, and a substantial specific surface area, primarily composed of light atoms such...
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framework

Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
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framework

RBI's framework for reclassification of FPI to FDI

The Reserve Bank of India on Monday issued an operational framework for reclassification of investment made by a foreign portfolio investor to foreign direct investment (FDI) if the entity breaches the prescribed limit. Markets regulator Sebi too has issued a circular on procedure for reclassification of FPI investment to FDI.




framework

The Policy Framework for Investment in Agriculture

The Policy Framework for Investment in Agriculture is a flexible tool which helps governments evaluate their investment policies in the ten areas essential to creating an attractive environment for investors and in enhancing the development benefits of agricultural investment.




framework

Public consultation on updating the Policy Framework for Investment

This public consultation was held to gather interested stakeholders' comments on the draft chapters of the Policy Framework for Investment currently being updated. The consultation ran until 31 December 2014.




framework

2nd Online public consultation on updating the Policy Framework for Investment

This online public consultation was held to gather interested stakeholders' comments on the draft Policy Framework for Investment currently being updated. The consultation ran until 25 February 2015.




framework

OECD Ministers launch new framework to boost sustainable investment

OECD Ministers have endorsed updated guidelines to help national governments and regional groups create the right conditions to attract domestic and foreign investment.




framework

Policy Framework for Investment - Pocket Edition 2015

The Policy Framework for Investment (PFI) is a comprehensive and systematic tool for improving investment conditions. The pocket edition of the PFI contains the full text of the 2015 update minus the supplemental questions and reference lists. Find the integral text and other tools online at www.oecd.org/investment/pfi.htm




framework

The Policy Framework for Investment (PFI)

The Policy Framework for Investment (PFI) is a non-prescriptive tool for improving investment policy for development. It helps governments to design and implement policy reforms to create a truly attractive, robust and competitive environment for domestic and foreign investment.




framework

Towards an international framework for investment facilitation

Many governments seek to promote and facilitate inward investments that they expect will benefit their economy. This paper looks at the merits of an international framework to facilitate investment in support of sustainable and inclusive growth.




framework

G20 ministers welcome OECD disaster risk assessment and financing framework

G20 Finance Ministers have welcomed a new OECD/G20 framework designed to help governments develop financial strategies for disaster risk management.




framework

Colombia: Assessment of the Regulatory Framework of Private Pensions

This review of Colombia by the OECD Working Party on Private Pensions examines Colombia’s position with respect to core principles related to pension systems.




framework

Peer Review Report of Luxembourg - Phase 1: Legal and Regulatory Framework

This report summarises the legal and regulatory framework for transparency and exchange of information for tax purposes in Luxembourg.




framework

A Framework for Financing Water Resources Management

This report provides a framework for policy discussions around financing water resources management that are taking place at local, basin, national, or transboundary levels.




framework

Integrated Assessment of Climate Change Impacts: Conceptual Frameworks, Modelling Approaches and Research Needs - Environment Working Paper No. 66

This paper presents a framework to include feedbacks from climate impacts on the economy in integrated assessment models. The proposed framework uses a production function approach, which links climate impacts to key variables and parameters used in the specification of economic activity. The paper pays particular attention to the challenges of distinguishing between damages and the costs of adapting to climate change.




framework

Korea : A framework for growth and social cohesion

This report was prepared to help Korea identify and address main social policy challenges. It suggests specific policy options and a strategy to “go social”, based on the practices and reforms that have worked well in other countries.




framework

G20: Remarks for Session 2 - Framework for Strong, Sustainable and Balanced Growth

We therefore need a “copernician” change in our approach to the growth – inequality nexus: let’s not think growth first, and inequality thereafter but let’s consider both of them, together, in their circularity. In other words, let’s think “Inclusive Growth”, right from the start, and let’s make it another touchstone of our efforts and complement the Pittsburgh tryptic of strong, sustainable and balanced growth!




framework

The quantification of structural reforms in OECD countries: a new framework

This document describes and discusses a new supply side framework that quantifies the impact of structural reforms on per capita income in OECD countries.




framework

OECD Framework for Regulatory Policy Evaluation

The OECD Framework for Regulatory Policy Evaluation assists countries in systematically evaluating the design and implementation of regulatory policy, against the achievement of strategic regulatory objectives.




framework

The quantification of structural reforms in OECD countries: a new framework

This document describes and discusses a new supply side framework that quantifies the impact of structural reforms on per capita income in OECD countries.




framework

OECD Global Conference on Governance Innovation: Towards Agile Regulatory Frameworks in the Fourth Industrial Revolution

Conference to exchange information on the need for and experience with governance innovation in the context of different sectors and different countries, both within and outside of the OECD, and to inform future OECD work.




framework

Hungary has improved legal framework for fighting foreign bribery, but must do more to detect and prosecute

Hungary’s law banning bribery of foreign public officials is relatively good on paper but lacks effective application, according to a new OECD report. Hungary must strengthen detection and prosecution of individuals and companies involved in foreign bribery.




framework

Despite progress made and improved legal framework, OECD seriously concerned about Turkey’s level of detection and investigation of foreign bribery

Turkey is a significant and geopolitically critical economy. Its companies, like those from many other countries, operate in corruption-prone sectors and countries. In spite of this, only 10 allegations have come to the attention of Turkish authorities since foreign bribery became an offence in Turkey in 2003.




framework

Chile must conclude its current legislative reforms of the criminal sanctions regime and clarify its corporate liability framework to better combat foreign bribery

Chile must make further progress on key recommendations of the OECD Working Group on Bribery in International Business Transactions, more than three years after its Phase 3 evaluation in March 2014.




framework

Czech Republic should further develop its framework programme for preschool education, says OECD

The Czech Republic should build on the strengths of its preschool education framework to further enhance the quality of its early childhood education and care services, according to a new OECD report.




framework

The quantification of structural reforms in OECD countries: a new framework

This document describes and discusses a new supply side framework that quantifies the impact of structural reforms on per capita income in OECD countries.




framework

Reports to support efforts in the framework of the Strategic Approach to International Chemicals Management

The OECD/UNEP Global PFC group has published two new reports to support efforts in the framework of the Strategic Approach to International Chemicals Management (SAICM) to improve information sharing at a global level on perfluorinated chemistries.




framework

Quantification of the mixed-valence and intervalence charge transfer properties of a cofacial metal–organic framework via single crystal electronic absorption spectroscopy

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01521K, Edge Article
Open Access
Patrick W. Doheny, Jack K. Clegg, Floriana Tuna, David Collison, Cameron J. Kepert, Deanna M. D'Alessandro
Gaining a fundamental understanding of charge transfer mechanisms in three-dimensional Metal–Organic Frameworks (MOFs) is crucial to the development of electroactive and conductive porous materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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framework

Write Libraries, Not Frameworks

When a programmer thinks "I've got some code that will make others' lives easier", there are two forms that can take: a library, or a framework.




framework

The crystal structure of (RS)-7-chloro-2-(2,5-di­meth­oxy­phen­yl)-2,3-di­hydro­quinazolin-4(1H)-one: two hydrogen bonds generate an elegant three-dimensional framework structure

In the title compound, C61H15ClN2O3, the heterocyclic ring adopts an envelope conformation, folded across the N⋯N line, with the 2,5-di­meth­oxy­phenyl unit occupying a quasi-axial site. There are two N—H⋯O hydrogen bonds in the structure: one hydrogen bond links mol­ecules related by a 41 screw axis to form a C(6) chain, and the other links inversion-related pairs of mol­ecules to form an R22(8) ring. The ring motif links all of the chains into a continuous three-dimensional framework structure. Comparisons are made with the structures of some related compounds.




framework

In situ deca­rbonylation of N,N-di­methyl­formamide to form di­methyl­ammonium cations in the hybrid framework compound {[(CH3)2NH2]2[Zn{O3PC6H2(OH)2PO3}]}n

The title phospho­nate-based organic–inorganic hybrid framework, poly[bis(dimethylammonium) [(μ4-2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C2H8N)2[Zn(C6H4O8P2)]}n, was formed unexpectedly when di­methyl­ammonium cations were formed from the in situ deca­rbonylation of the N,N-di­methyl­formamide solvent. The framework is built up from ZnO4 tetra­hedra and bridging di­phospho­nate tetra-anions to generate a three-dimensional network comprising [100] channels occupied by the (CH3)2NH2+ cations. Within the channels, an array of N—H⋯O hydrogen bonds help to establish the structure. In addition, intra­molecular O—H⋯O hydrogen bonds between the appended –OH groups of the phenyl ring and adjacent PO32− groups are observed.




framework

Crystal structure, DFT calculation, Hirshfeld surface analysis and energy framework study of 6-bromo-2-(4-bromo­phen­yl)imidazo[1,2-a]pyridine

The title imidazo[1,2-a] pyridine derivative, C13H8Br2N2, was synthesized via a single-step reaction method. The title mol­ecule is planar, showing a dihedral angle of 0.62 (17)° between the phenyl and the imidazo[1,2-a] pyridine rings. An intra­molecular C—H⋯N hydrogen bond with an S(5) ring motif is present. In the crystal, a short H⋯H contact links adjacent mol­ecules into inversion-related dimers. The dimers are linked in turn by weak C—H⋯π and slipped π–π stacking inter­actions, forming layers parallel to (110). The layers are connected into a three-dimensional network by short Br⋯H contacts. Two-dimensional fingerprint plots and three-dimensional Hirshfeld surface analysis of the inter­molecular contacts reveal that the most important contributions for the crystal packing are from H⋯Br/Br⋯H (26.1%), H⋯H (21.7%), H⋯C/C⋯H (21.3%) and C⋯C (6.5%) inter­actions. Energy framework calculations suggest that the contacts formed between mol­ecules are largely dispersive in nature. Analysis of HOMO–LUMO energies from a DFT calculation reveals the pure π character of the aromatic rings with the highest electron density on the phenyl ring, and σ character of the electron density on the Br atoms. The HOMO–LUMO gap was found to be 4.343 eV.




framework

Organically pillared layer framework of [Eu(NH2–BDC)(ox)(H3O)]

The non-porous three-dimensional structure of poly[(μ5-2-amino­benzene-1,4-di­carboxyl­ato)(μ6-oxalato)(oxomium)europium(III)], [Eu(C8H5NO4)(C2O4)(H3O)]n or [EuIII(NH2–BDC)(ox)(H3O)]n (NH2–BDC2− = 2-amino­terephthalate and ox2− = oxalate) is constructed from two-dimensional layers of EuIII–carboxyl­ate–oxalate, which are connected by NH2–BDC2− pillars. The basic structural unit of the layer is an edge-sharing dimer of TPRS-{EuIIIO9}, which is assembled through the ox2− moiety. The intra­layer void is partially occupied by TPR-{EuIIIO6} motifs. Weak C—H⋯O and strong, classical intra­molecular N—H⋯O and inter­molecular O—H⋯O hydrogen-bonding inter­actions, as well as weak π–π stacking inter­actions, affix the organic pillars within the framework. The two-dimensional layer can be simplified to a uninodal 4-connected sql/Shubnikov tetra­gonal plane net with point symbol {44.62}.




framework

Crystal structure of a two-dimensional metal–organic framework assembled from lithium(I) and γ-cyclo­dextrin

The crystal structure of the polymeric title compound, catena-poly[[[di­aqua­lithium]-μ-γ-cyclo­dextrin(1−)-[aqua­lithium]-μ-γ-cyclo­dextrin(1−)] pentadecahydrate], {[Li2(C48H79O40)2(H2O)3]·15H2O}n, consists of deprotonated γ-cyclo­dextrin (CD) mol­ecules assembled by lithium ions into metal–organic ribbons that are cross-linked by multiple O—H⋯O hydrogen bonds into sheets extending parallel to (0overline11). Within a ribbon, one Li+ ion is coordinated by one deprotonated hydroxyl group of the first γ-CD torus and by one hydroxyl group of the second γ-CD torus as well as by two water mol­ecules. The other Li+ ion is coordinated by one deprotonated hydroxyl and by one hydroxyl group of the second γ-CD torus, by one hydroxyl group of the first γ-CD torus as well as by one water mol­ecule. The coordination spheres of both Li+ cations are distorted tetra­hedral. The packing of the structure constitute channels along the a axis. Parts of the hy­droxy­methyl groups in cyclo­dextrin molecules as well as water mol­ecules show two-component disorder. Electron density associated with additional disordered solvent mol­ecules inside the cavities was removed with the SQUEEZE [Spek (2015). Acta Cryst. C71, 9–18] routine in PLATON. These solvent mol­ecules are not considered in the given chemical formula and other crystal data. Five out of the sixteen hy­droxy­methyl groups and one water mol­ecule are disordered over two sets of sites.




framework

Ni3Te2O2(PO4)2(OH)4, an open-framework structure isotypic with Co3Te2O2(PO4)2(OH)4

Single crystals of Ni3(TeO(OH)2)2(PO4)2, trinickel(II) bis[(oxidodihydoxidotellurate(IV)] bis(phosphate),were obtained by hydro­thermal synthesis at 483 K, starting from NiCO3·2Ni(OH)2, TeO2 and H3PO4 in a molar ratio of 1:2:2. The crystal structure of Ni3Te2O2(PO4)2(OH)4 is isotypic with that of Co3Te2O2(PO4)2(OH)4 [Zimmermann et al. (2011). J. Solid State Chem. 184, 3080–3084]. The asymmetric unit comprises two Ni (site symmetries overline{1}, 2/m) one Te (m), one P (m), five O (three m, two 1) and one H (1) sites. The tellurium(IV) atom shows a coordination number of five, with the corresponding [TeO3(OH)2] polyhedron having a distorted square-pyramidal shape. The two NiII atoms are both octa­hedrally coordinated but form different structural elements: one constitutes chains made up from edge-sharing [NiO6] octa­hedra extending parallel to [010], and the other isolated [NiO2(OH)4] octa­hedra. The two kinds of nickel/oxygen octa­hedra are connected by the [TeO3(OH)2] pyramids and the [PO4] tetra­hedra through edge- and corner-sharing into a three-dimensional framework structure with channels extending parallel to [010]. Hydrogen bonds of medium strength between the hy­droxy groups and one of the phosphate O atoms consolidate the packing. A qu­anti­tative structure comparison between Ni3Te2O2(PO4)2(OH)4 and Co3Te2O2(PO4)2(OH)4 is made.




framework

Competitive formation between 2D and 3D metal-organic frameworks: insights into the selective formation and lamination of a 2D MOF

The structural dimension of metal–organic frameworks (MOFs) is of great importance in defining their properties and thus applications. In particular, 2D layered MOFs are of considerable interest because of their useful applications, which are facilitated by unique structural features of 2D materials, such as a large number of open active sites and high surface areas. Herein, this work demonstrates a methodology for the selective synthesis of a 2D layered MOF in the presence of the competitive formation of a 3D MOF. The ratio of the reactants, metal ions and organic building blocks used during the reaction is found to be critical for the selective formation of a 2D MOF, and is associated with its chemical composition. In addition, the well defined and uniform micro-sized 2D MOF particles are successfully synthesized in the presence of an ultrasonic dispersion. Moreover, the laminated 2D MOF layers are directly synthesized via a modified bottom-up lamination method, a combination of chemical and physical stimuli, in the presence of surfactant and ultrasonication.




framework

Extraordinary structural complexity of ilmajokite: a multilevel hierarchical framework structure of natural origin

The crystal structure of ilmajokite, a rare Na-K-Ba-Ce-titanosilicate from the Khibiny mountains, Kola peninsula, Russia, has been solved using single-crystal X-ray diffraction data. The crystal structure is based on a 3D titanosilicate framework consisting of trigonal prismatic titanosilicate (TPTS) clusters centered by Ce3+ in [9]-coordination. Four adjacent TPTS clusters are linked into four-membered rings within the (010) plane and connected via ribbons parallel to 101. The ribbons are organized into layers parallel to (010) and modulated along the a axis with a modulation wavelength of csinβ = 32.91 Å and an amplitude of ∼b/2 = 13.89 Å. The layers are linked by additional silicate tetrahedra. Na+, K+, Ba2+ and H2O groups occur in the framework cavities and have different occupancies and coordination environments. The crystal structure of ilmajokite can be separated into eight hierarchical levels: atoms, coordination polyhedra, TPTS clusters, rings, ribbons, layers, the framework and the whole structure. The information-based analysis allows estimation of the complexity of the structure as 8.468 bits per atom and 11990.129 bits per cell. According to this analysis, ilmajokite is the third-most complex mineral known to date after ewingite and morrisonite, and is the most complex mineral framework structure, comparable in complexity to paulingite-(Ca) (11 590.532 bits per cell).




framework

PtychoShelves, a versatile high-level framework for high-performance analysis of ptychographic data

Over the past decade, ptychography has been proven to be a robust tool for non-destructive high-resolution quantitative electron, X-ray and optical microscopy. It allows for quantitative reconstruction of the specimen's transmissivity, as well as recovery of the illuminating wavefront. Additionally, various algorithms have been developed to account for systematic errors and improved convergence. With fast ptychographic microscopes and more advanced algorithms, both the complexity of the reconstruction task and the data volume increase significantly. PtychoShelves is a software package which combines high-level modularity for easy and fast changes to the data-processing pipeline, and high-performance computing on CPUs and GPUs.




framework

New Report Proposes Framework To Encourage Fluency With Information Technology

The explosive growth of information technology is having a profound impact on our lives.




framework

Report Offers New Framework to Guide K-12 Science Education, Calls for Shift in the Way Science Is Taught in U.S.

A report released today by the National Research Council presents a new framework for K-12 science education that identifies the key scientific ideas and practices all students should learn by the end of high school.




framework

Report Recommends New Framework for Estimating the Social Cost of Carbon

To estimate the social cost of carbon dioxide for use in regulatory impact analyses, the federal government should use a new framework that would strengthen the scientific basis, provide greater transparency, and improve characterization of the uncertainties of the estimates, says a new report by the National Academies of Sciences, Engineering, and Medicine.




framework

New Report Proposes Framework to Identify Vulnerabilities Posed by Synthetic Biology

Given the possible security vulnerabilities related to developments in synthetic biology – a field that uses technologies to modify or create organisms or biological components – a new report by the National Academies of Sciences, Engineering, and Medicine proposes a framework to identify and prioritize potential areas of concern associated with the field.




framework

Substantial Gap Exists Between Demand for Organ Transplants in U.S. and Number of Transplants Performed - New Report Offers Ethical, Regulatory, and Policy Framework for Research to Increase Quantity & Quality of Organs For Transplantation, Save Lives

The number of patients in the U.S. awaiting organ transplantation outpaces the amount of transplants performed in the U.S., and many donated organs are not transplanted each year due to several factors, such as poor organ function, says a new report from the National Academies of Sciences, Engineering, and Medicine.




framework

Report Offers Framework to Guide Decisions About Spirit Lake and Toutle River System at Mount St. Helens - Inclusive Decision-Making Process Is Needed

A new report from the National Academies of Sciences, Engineering, and Medicine offers a framework to guide federal, tribal, state and local agencies, community groups, and other interested and affected parties in making decisions about the Spirit Lake and Toutle River system, near Mount St. Helens in southwest Washington state.




framework

New Report Proposes Framework for Policymakers to Address Debate Over Encryption

A new report by the National Academies of Sciences, Engineering, and Medicine proposes a framework for evaluating proposals to provide authorized government agencies with access to unencrypted versions of encrypted communications and other data.




framework

New Report Says Individual Research Results Should Be Shared With Participants More Often - Recommends Framework for Decision-Making

When conducting research involving the testing of human biospecimens, investigators and their institutions should routinely consider whether and how to return individual research results on a study-specific basis through an informed decision-making process, says a new report from the National Academies of Sciences, Engineering, and Medicine.




framework

Report Proposes Recommendations and New Framework to Speed Progress Toward Open Science

While significant progress has been made in providing open access to scientific research, a range of challenges -- including the economics of scientific publication and cultural barriers in the research enterprise -- must be overcome to further advance the openness of science, says a new report from the National Academies of Sciences, Engineering, and Medicine.




framework

Statement on Call for Moratorium on and International Governance Framework for Clinical Uses of Heritable Genome Editing

A commentary published in Nature calls for a moratorium on clinical uses of heritable human genome editing and the establishment of an international governance framework.




framework

New Report Offers Framework for Developing Evidence-Based Opioid Prescribing Guidelines for Common Medical Conditions, Surgical Procedures

For severe acute pain due to surgeries and medical conditions, there is a lack of guidance on the appropriate type, strength, and amount of opioid medication that clinicians should prescribe to patients, says a new report from the National Academies of Sciences, Engineering, and Medicine.




framework

Sustainable urban mobility: a new urban grouping framework can help inform city planners

While cities worldwide are expanding so is the significant carbon dioxide footprint of urban transport. Consequently, there is an urgent need for sustainable urban mobility solutions. A thorough analysis of the variables and dynamics of urban mobility in cities can aid in planning sustainable mobility policy. This study used a new system of classification by type (typologisation) relevant to urban mobility in global cities, with data from 331 cities in 124 countries covering 40% of the global urban population (as of 2016).