chemical

GHS chemical labels

Avery UltraDuty GHS Chemical Labels are designed for pigment-based desktop inkjet printers.




chemical

Countertop cabinet for chemical storage

This durable, compact countertop cabinet safely stores up to two 4-liter bottles of acids or bases near your workspace.




chemical

App for in-the-field chemical management

By combining its popular eBinder app and Chemical Inventory Scanning app functionality into a singular SDS/Chemical Management mobile app, VelocityEHS provides users with easier online and offline access to Safety Data Sheets, as well as the ability to quickly scan chemical container barcodes and manage inventory information.




chemical

Hazardous chemical storage cabinets

Stak-a-Cab Safety Storage Cabinets are constructed of 1-inch-thick, multi-ply plywood and finished with chemical-resistant paint.




chemical

Storage cabinet for flammable chemicals

This cabinet is specifically designed for the storage of flammable chemicals. Standard size is 35 inches high and 22 inches deep, with available 30-, 36- and 48-inch widths and a removable shelf for larger container storage.




chemical

Asbestos among first 10 chemicals EPA to analyze under updated TSCA

Washington – Asbestos is one of the first 10 chemicals to be evaluated for potential health and environmental risks under the Frank R. Lautenberg Chemical Safety for the 21st Century Act, the Environmental Protection Agency announced on Nov. 29.




chemical

EPA releases annual report on chemical risk evaluations

Washington – The Environmental Protection Agency has published a report on risk evaluations as part of requirements established by the Frank R. Lautenberg Chemical Safety for the 21st Century Act.




chemical

EPA requests input on documents for TSCA chemical evaluations, proposes asbestos rule

Washington — The Environmental Protection Agency is seeking comment on problem formulation documents for the first 10 chemicals slated for evaluation for potential health and environmental risks under the Frank R. Lautenberg Chemical Safety for the 21st Century Act, as well as a systematic review approach document and a proposed significant new use rule for asbestos.




chemical

Treating chemical burns

Are chemicals used in your workplace? Mayo Clinic notes that chemical burns can be caused by a variety of substances, including strong acids, drain cleaners, paint thinners and gasoline.




chemical

Chemical safety 101: flammable liquids

Did you know? Flammable liquids are required to be stored in approved glass, plastic or metal containers.




chemical

Chemical Safety Board calls for stronger standards on reactive chemicals

Washington — “It is past time for regulators to fully recognize the hazards presented by reactive chemicals,” Katherine Lemos, chair and CEO of the Chemical Safety Board, says in a new video in which the agency calls on OSHA and the Environmental Protection Agency to strengthen their standards on these substances.




chemical

Chemical Safety Board vows to increase transparency amid leadership changes

Washington — The Chemical Safety Board says it will resume providing updates on incident investigations to “provide important initial information” on agency developments.




chemical

Chemical Safety Board calls on OSHA to provide guidance on process hazard analysis

Washington — OSHA should develop guidance on the process hazard analysis element of its standard on process safety management of highly hazardous chemicals (1910.119), the Chemical Safety Board recommends in a final report on an April 2018 explosion and fire at a Wisconsin refinery.




chemical

Chemical Safety Board warns of emergency discharges from pressure release valves

Washington — A look at four incidents – some deadly – involving emergency discharges from pressure release valves has prompted the Chemical Safety Board to issue a safety alert.




chemical

Handling hazardous chemicals

What are the requirements for labeling secondary chemical containers?




chemical

Chemical Safety 101

What should a beginner know about chemical safety on Day 1 of a new job?




chemical

Safe storage of chemicals

What’s the correct ventilation system for my chemical storage space?




chemical

EPA proposal would ‘strengthen’ chemical risk evaluations

Washington — The Environmental Protection Agency wants to expand the scope of chemical risk evaluation policies under the Toxic Substances Control Act of 1976.




chemical

EPA seeks to increase protections for two toxic chemicals

Washington — The Environmental Protection Agency wants to strengthen restrictions on two persistent, bioaccumulative and toxic chemicals already regulated under the Toxic Substances Control Act of 1976.




chemical

‘Extraordinary effort’: Chemical Safety Board eliminates investigation backlog

Washington — A long-standing Chemical Safety Board concern is no more: The agency has cleared its backlog of open investigations and incident reports.




chemical

EPA to review five more toxic chemicals for risk evaluation

Washington — The Environmental Protection Agency has initiated its 12-month review process to prioritize five toxic chemicals for risk evaluation under the Toxic Substances Control Act.




chemical

Exposure to common ‘forever’ chemicals linked to risk factor for heart disease: study

Nanjing, China — A recent study highlighting the expected ties between exposure to cancer-causing per- and polyfluoroalkyl substances, or PFAS, and a risk factor for heart disease could impact workers.




chemical

EPA says new rule will protect chemical facilities and communities

Washington — The Environmental Protection Agency is aiming to “improve safety at facilities that use and distribute hazardous chemicals,” as well as protect nearby communities, via a final rule.




chemical

EPA proposal eyes additional reporting of chemical data

Washington — Chemical manufacturers and importers of 16 different chemicals would be required to submit data from unpublished health and safety studies, under a recently announced Environmental Protection Agency proposed rule.




chemical

EPA rule will mandate response plans for weather-related chemical discharges

Washington — More than 5,300 industrial facilities must submit plans for responding to “worst case” chemical discharges into waterways during adverse weather events, under a new Environmental Protection Agency final rule.




chemical

EPA aims to strengthen chemical risk evaluation process

Washington — The Environmental Protection Agency says a new rule “charts the path for our risk evaluations to ensure we meet the core objective to protect public health under our nation’s premier chemical safety law.”




chemical

Chemical Safety Board praises NFPA standard on hazardous waste

Washington — The National Fire Protection Association’s voluntary standard on preventing fires and uncontrolled chemical reactions at hazardous waste facilities carries significant influence from the Chemical Safety Board – and CSB officials appreciate it.




chemical

EPA urges chemical facilities to prepare for Gulf Coast hurricane season

Dallas — During inclement weather, facility operators are obligated to maintain safety, minimize any chemical/oil releases and discharges, and report them in a timely manner.




chemical

EPA classifying two ‘forever chemicals’ as hazardous

Washington — The Environmental Protection Agency will designate as hazardous two cancer-causing per- and polyfluoroalkyl substances, or PFAS, with wide industrial and consumer use, under a new final rule.




chemical

Fatal chemical release prompts safety board’s call for ‘preventive safeguards’

Washington — Establishing and implementing engineering controls as “preventive safeguards” during a process hazard analysis can help prevent liquid overflow and a possible chemical disaster, the Chemical Safety Board says.




chemical

Safety board to chemical facilities: Hurricane Beryl is an ‘early warning’

Washington — The Chemical Safety Board is urging chemical facilities to prepare for a season of “potentially more frequent and more powerful hurricanes and other extreme weather events.”




chemical

EPA says chemical review updates prioritize worker safety

Washington — Updates to Environmental Protection Agency reviews of new chemicals under the Toxic Substances Control Act will strengthen worker protections, an agency official says.




chemical

Chemical Safety Board pushes for expanded use of remote isolation equipment

Washington — Many chemical facilities “have not fully recognized that the effective remote isolation of equipment is critical to quickly stopping releases of hazardous materials” and protecting workers, the Chemical Safety Board says.




chemical

EPA delays data submission date for ‘forever chemicals’ reporting rule

Washington — The Environmental Protection Agency is delaying the data submission period for a final rule requiring manufacturers and importers of per- and polyfluoroalkyl substances to report information on PFAS use, exposures and hazards.




chemical

Chemical Safety Board video highlights lessons from deadly chemical release

Washington — Chemical facility owners and operators should take into account how simultaneous operations can affect work and ensure they have written, easy-to-understand procedures in place, the Chemical Safety Board says in a new video.




chemical

‘And then there was one’: Kulinowski about to be sole member of Chemical Safety Board

Washington — Chemical Safety Board interim Executive Authority Kristen Kulinowski said she will “do everything in my power to maintain as many of the functions of the CSB as are permissible by law” as the agency comes closer to operating with just one of its five board seats filled – hers.




chemical

EPA requests input on proposed significant new use rules for six chemicals, issues final rule for others

Washington — The Environmental Protection Agency, in accordance with the Frank R. Lautenberg Chemical Safety for the 21st Century Act, is seeking comment on proposed significant new use rules for six chemical substances that are subject to agency premanufacture notices.




chemical

FDA Proposes to Ban Food Additive, Continues Assessments of Additional Chemicals

The US Food and Drug Administration proposed to revoke the regulation authorizing the use of brominated vegetable oil (BVO) in food. The agency concluded that the intended use of BVO in food is no longer considered safe after the results of studies conducted in collaboration with the National Institutes of Health (NIH) found the potential for adverse health effects in humans.




chemical

Sun Chemical: Natural Colors

Sun Chemical introduces SUNFOODS™Natural Colorants, a product line available in the Americas, Europe, Middle East, and Africa. SUNFOODS natural colors can match a wide array of industry standard and custom colors that can be applied to a variety of food and beverage products.




chemical

Chemical splash goggle

The 750AFR (Advanced Fog Resistance) Chemical Splash Goggle is designed for maximum anti-fog protection, featuring one of the most advanced protective coatings in the industry.




chemical

Sherwin-Williams' New Coating Technology Offers Rapid Curing, Extended Workability, Easy Application and Chemical Resistance 

Sherwin-Williams High Performance Flooring launched Accelera One is an advanced coating technology designed for decorative flake and quartz flooring systems that meet the rigorous demands of commercial and institutional environments, delivering a high level of performance, ease of application and chemical resistance.




chemical

FDA Offers Update on Post-market Assessment of Chemicals in the Food Supply

The updated list includes select food ingredients (including food and color additives), food contact substances and contaminants under FDA review.




chemical

FDA Issues Import Alert for Food Products with Chemical Contaminants Including PFAS

The alert gives the FDA the ability to help prevent entry of human food products into the U.S. if they are found to be contaminated with a broad range of human-made chemicals.




chemical

The Solution to Death From a Fentanyl Overdose Could Lie in Its Chemical Structure

Scientists have identified a molecule that appears to restore normal breathing in mice following a large dose of fentanyl.




chemical

Structural and biochemical characterization of the M405S variant of Desulfovibrio vulgaris formate dehydrogenase

Molybdenum- or tungsten-dependent formate dehydrogenases have emerged as significant catalysts for the chemical reduction of CO2 to formate, with biotechnological applications envisaged in climate-change mitigation. The role of Met405 in the active site of Desulfovibrio vulgaris formate dehydrogenase AB (DvFdhAB) has remained elusive. However, its proximity to the metal site and the conformational change that it undergoes between the resting and active forms suggests a functional role. In this work, the M405S variant was engineered, which allowed the active-site geometry in the absence of methionine Sδ interactions with the metal site to be revealed and the role of Met405 in catalysis to be probed. This variant displayed reduced activity in both formate oxidation and CO2 reduction, together with an increased sensitivity to oxygen inactivation.




chemical

Open-source electrochemical cell for in situ X-ray absorption spectroscopy in transmission and fluorescence modes

X-ray spectroscopy is a valuable technique for the study of many materials systems. Characterizing reactions in situ and operando can reveal complex reaction kinetics, which is crucial to understanding active site composition and reaction mechanisms. In this project, the design, fabrication and testing of an open-source and easy-to-fabricate electrochemical cell for in situ electrochemistry compatible with X-ray absorption spectroscopy in both transmission and fluorescence modes are accomplished via windows with large opening angles on both the upstream and downstream sides of the cell. Using a hobbyist computer numerical control machine and free 3D CAD software, anyone can make a reliable electrochemical cell using this design. Onion-like carbon nanoparticles, with a 1:3 iron-to-cobalt ratio, were drop-coated onto carbon paper for testing in situ X-ray absorption spectroscopy. Cyclic voltammetry of the carbon paper showed the expected behavior, with no increased ohmic drop, even in sandwiched cells. Chronoamperometry was used to apply 0.4 V versus reversible hydrogen electrode, with and without 15 min of oxygen purging to ensure that the electrochemical cell does not provide any artefacts due to gas purging. The XANES and EXAFS spectra showed no differences with and without oxygen, as expected at 0.4 V, without any artefacts due to gas purging. The development of this open-source electrochemical cell design allows for improved collection of in situ X-ray absorption spectroscopy data and enables researchers to perform both transmission and fluorescence simultaneously. It additionally addresses key practical considerations including gas purging, reduced ionic resistance and leak prevention.




chemical

Electrochemical cell for synchrotron nuclear resonance techniques

Developing new materials for Li-ion and Na-ion batteries is a high priority in materials science. Such development always includes performance tests and scientific research. Synchrotron radiation techniques provide unique abilities to study batteries. Electrochemical cell design should be optimized for synchrotron studies without losing electrochemical performance. Such design should also be compatible with operando measurement, which is the most appropriate approach to study batteries and provides the most reliable results. The more experimental setups a cell can be adjusted for, the easier and faster the experiments are to carry out and the more reliable the results will be. This requires optimization of window materials and sizes, cell topology, pressure distribution on electrodes etc. to reach a higher efficiency of measurement without losing stability and reproducibility in electrochemical cycling. Here, we present a cell design optimized for nuclear resonance techniques, tested using nuclear forward scattering, synchrotron Mössbauer source and nuclear inelastic scattering.




chemical

New copper carboxyl­ate pyrene dimers: synthesis, crystal structure, Hirshfeld surface analysis and electrochemical characterization

Two new copper dimers, namely, bis­(dimethyl sulfoxide)­tetra­kis­(μ-pyrene-1-carboxyl­ato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C2H6OS)2] or [Cu2(pyr-COO−)4(DMSO)2] (1), and bis­(di­methyl­formamide)­tetra­kis­(μ-pyrene-1-carboxyl­ato)dicopper(Cu—Cu), [Cu2(C17H9O2)4(C3H7NO)2] or [Cu2(pyr-COO−)4(DMF)2] (2) (pyr = pyrene), were synthesized from the reaction of pyrene-1-carb­oxy­lic acid, copper(II) nitrate and tri­ethyl­amine from solvents DMSO and DMF, respectively. While 1 crystallized in the space group Poverline{1}, the crystal structure of 2 is in space group P21/n. The Cu atoms have octa­hedral geometries, with four oxygen atoms from carboxyl­ate pyrene ligands occupying the equatorial positions, a solvent mol­ecule coordinating at one of the axial positions, and a Cu⋯Cu contact in the opposite position. The packing in the crystal structures exhibits π–π stacking inter­actions and short contacts through the solvent mol­ecules. The Hirshfeld surfaces and two-dimensional fingerprint plots were generated for both compounds to better understand the inter­molecular inter­actions and the contribution of heteroatoms from the solvent ligands to the crystal packing. In addition, a Cu2+/Cu1+ quasi-reversible redox process was identified for compound 2 using cyclic voltammetry that accounts for a diffusion-controlled electron-donation process to the Cu dimer.




chemical

2-Cyano-2-iso­nitro­soacetamide–3,4-di­methylpyrazole (1/1): a co-crystal of two mol­ecules with agrochemical activities

In the structure of the title co-crystal, C3H3N3O2·C5H8N2, the components are linked by a set of directional O—H⋯N, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds to yield a two-dimensional mono-periodic arrangement. The structure propagates in the third dimension by extensive π–π stacking inter­actions of nearly parallel mol­ecules of the two components, following an alternating sequence. The primary structure-defining inter­action is very strong oxime-OH donor to pyrazole-N acceptor hydrogen bond [O⋯N = 2.587 (2) Å], while the significance of weaker hydrogen bonds and π–π stacking inter­actions is comparable. The distinct structural roles of different kinds of inter­actions agree with the results of a Hirshfeld surface analysis and calculated inter­action energies. The title compound provides insights into co-crystals of active agrochemical mol­ecules and features the rational integration in one structure of a fungicide, C3H3N3O2, and a second active component, C5H8N2, known for alleviation the toxic effects of fungicides on plants. The material appears to be well suited for practical uses, being non-volatile, air-stable, water-soluble, but neither hygroscopic nor efflorescent.




chemical

The AUREX cell: a versatile operando electrochemical cell for studying catalytic materials using X-ray diffraction, total scattering and X-ray absorption spectroscopy under working conditions

Understanding the structure–property relationship in electrocatalysts under working conditions is crucial for the rational design of novel and improved catalytic materials. This paper presents the Aarhus University reactor for electrochemical studies using X-rays (AUREX) operando electrocatalytic flow cell, designed as an easy-to-use versatile setup with a minimal background contribution and a uniform flow field to limit concentration polarization and handle gas formation. The cell has been employed to measure operando total scattering, diffraction and absorption spectroscopy as well as simultaneous combinations thereof on a commercial silver electrocatalyst for proof of concept. This combination of operando techniques allows for monitoring of the short-, medium- and long-range structure under working conditions, including an applied potential, liquid electrolyte and local reaction environment. The structural transformations of the Ag electrocatalyst are monitored with non-negative matrix factorization, linear combination analysis, the Pearson correlation coefficient matrix, and refinements in both real and reciprocal space. Upon application of an oxidative potential in an Ar-saturated aqueous 0.1 M KHCO3/K2CO3 electrolyte, the face-centered cubic (f.c.c.) Ag gradually transforms first to a trigonal Ag2CO3 phase, followed by the formation of a monoclinic Ag2CO3 phase. A reducing potential immediately reverts the structure to the Ag (f.c.c.) phase. Following the electrochemical-reaction-induced phase transitions is of fundamental interest and necessary for understanding and improving the stability of electrocatalysts, and the operando cell proves a versatile setup for probing this. In addition, it is demonstrated that, when studying electrochemical reactions, a high energy or short exposure time is needed to circumvent beam-induced effects.