chemical

[ASAP] Photochemically Mediated Nickel-Catalyzed Synthesis of <italic toggle="yes">N</italic>-(Hetero)aryl Sulfamides

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Published On :: Mon, 04 May 2020 04:00:00 GMT

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00139


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chemical

[ASAP] The Synthesis of Functionalized 3-Aryl- and 3-Heteroaryloxazolidin-2-ones and Tetrahydro-3-aryl-1,3-oxazin-2-ones via the Iodocyclocarbamation Reaction: Access to Privileged Chemical Structures and Scope and Limitations of the Method

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Published On :: Tue, 05 May 2020 04:00:00 GMT

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.9b03400


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chemical

Electrochemical biosensing platforms on the basis of reduced graphene oxide and its composites with Au nanodots

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Analyst, 2020, Advance Article
DOI: 10.1039/C9AN02592H, Paper
Liang Mei, Qingyong Zhang, Min Du, Zhiyuan Zeng
rGO and AuNDs-rGO, synthesized by a simple photochemical reduction method, are used for electrochemical biosensors and show good glucose detection.
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chemical

Target triggered ultrasensitive electrochemical polychlorinated biphenyl aptasensor based on DNA microcapsules and nonlinear hybridization chain reaction

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Analyst, 2020, Advance Article
DOI: 10.1039/D0AN00065E, Paper
Ting Han, Shaozhen Wang, Feifan Sheng, Sicheng Wang, Tianyue Dai, Xiaojun Zhang, Guangfeng Wang
In this work, we demonstrated an ultrasensitive detection platform for polychlorinated biphenyls (PCBs) based on DNA microcapsules and a nonlinear hybridization chain reaction (NHCR).
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chemical

A signal cascade amplification strategy based on RT-PCR triggering of G-quadruplex DNAzyme for a novel electrochemical detection of viable Cronobacter sakazakii

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Analyst, 2020, Accepted Manuscript
DOI: 10.1039/D0AN00270D, Paper
Yuanyuan Yuan, Xianyong Wu, Zhanmin Liu, QIqi Ning, Liqiang Fu, Sujuan Wu
Cronobacter sakazakii is an important opportunistic food-borne pathogen, and it can cause severe diseases with main symptoms including neonatal meningitis, necrotizing enterocolitis, and sepsis. For the achievement of practical and...
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chemical

A disposable molecularly imprinted electrochemical sensor for the ultra-trace detection of the organophosphorus insecticide phosalone employing monodisperse Pt-doped UiO-66 for signal amplification

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Analyst, 2020, 145,3245-3256
DOI: 10.1039/D0AN00278J, Paper
Liping Xu, Jiebin Li, Jiajia Zhang, Junyong Sun, Tian Gan, Yanming Liu
A disposable electrochemical sensor was fabricated based on monodisperse Pt-doped UiO-66 and a mesoporous molecularly imprinted polymer to specifically detect phosalone.
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chemical

An electrochemical sensor based on enzyme-free recycling amplification for sensitive and specific detection of miRNAs from cancer cells

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Analyst, 2020, 145,3353-3358
DOI: 10.1039/D0AN00275E, Paper
Lili Jiang, Yuling Yang, Yuhong Lin, Ziyi Chen, Chao Xing, Chunhua Lu, Huanghao Yang, Shusheng Zhang
A catalyzed hairpin assembly and binding-induced formation of the DNA three-way junction for ultrasensitive electrochemical detection of diverse miRNAs is reported.
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chemical

Trace manganese detection via differential pulse cathodic stripping voltammetry using disposable electrodes: additively manufactured nanographite electrochemical sensing platforms

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Analyst, 2020, 145,3424-3430
DOI: 10.1039/D0AN00018C, Paper
Open Access
Diego P. Rocha, Christopher W. Foster, Rodrigo A. A. Munoz, Gary A. Buller, Edmund M. Keefe, Craig E. Banks
Additive manufacturing is a promising technology for the rapid and economical fabrication of portable electroanalytical devices.
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chemical

Novel ratiometric electrochemical sensor for no-wash detection of fluorene-9-bisphenol based on combining CoN nanoarrays with molecularly imprinted polymers

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Analyst, 2020, 145,3320-3328
DOI: 10.1039/D0AN00345J, Paper
Zhaoyi Liu, Yong Zhang, Bing Li, Xiang Ren, Hongmin Ma, Qin Wei
A ratiometric molecularly imprinted polymers electrochemical sensor was fabricated based on the direct electrochemical oxidation of BHPF on CoN nanoarray electrode.
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chemical

Synthesis of a manganese dioxide nanorod-anchored graphene oxide composite for highly sensitive electrochemical sensing of dopamine

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Analyst, 2020, 145,3283-3288
DOI: 10.1039/D0AN00348D, Paper
Juan Li, Huifang Shen, Suhua Yu, Geshan Zhang, Chuanli Ren, Xiaoya Hu, Zhanjun Yang
A novel manganese dioxide nanorod-anchored graphene oxide (MnO2 NRs/GO) composite was synthesized by a simple hydrothermal method for the development of a highly sensitive electrochemical sensor for dopamine.
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chemical

A highly efficient preconcentration route for rapid and sensitive detection of endotoxin based on an electrochemical biosensor

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Analyst, 2020, Accepted Manuscript
DOI: 10.1039/D0AN00315H, Paper
Wenrui Ma, Lulu Liu, Yi Xu, Li Wang, Li Chen, Sheng Yan, Lingling Shui, Zhijun Wang, Shunbo Li
An impedimetric aptasensor for detection of endotoxin in a microfluidic chip was proposed, in which the Apt/AuNPs/SPCE sensing surface was fabricated in screen-printed electrode with good biological activity and stability....
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chemical

Laser-induced graphene hybrid photoelectrode for enhanced photoelectrochemical detection of glucose

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Analyst, 2020, Advance Article
DOI: 10.1039/D0AN00252F, Paper
Hui Li, Chengxiang Guo, Changchun Liu, Lei Ge, Feng Li
The in situ and synchronous fabrication of Ni0/NiO–CdS–graphene hybrid photoelectrodes is developed using a facile and scalable direct-laser-writing method for photoelectrochemical detection of glucose.
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chemical

An electrochemical biosensor based on methylene blue-loaded nanocomposites as signal-amplifying tags to detect pathogenic bacteria

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Analyst, 2020, Advance Article
DOI: 10.1039/D0AN00470G, Paper
Shengjun Bu, Kuiyu Wang, Zhongyi Li, Chengyu Wang, Zhuo Hao, Wensen Liu, Jiayu Wan
Synthesis of new methylene blue–magainin I organic–inorganic nanocomposites as electrochemical signal labels for the detection of bacteria.
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chemical

A homogeneous photoelectrochemical hydrogen sulfide sensor based on the electronic transfer mediated by tetrasulfophthalocyanine

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Analyst, 2020, Advance Article
DOI: 10.1039/D0AN00302F, Paper
Xinyang Wang, Huanan Zhao, Zhonghui Chen, Fang Luo, Longhua Guo, Bin Qiu, Zhenyu Lin, Jian Wang
A homogeneous photoelectrochemical sensor for H2S detection based on the electronic transfer mediated by [Fe(III)PcS4]+ was developed with an un-modified photoelectrode.
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chemical

Tetrahedral DNA Nanostructure-decorated Electrochemical Platform for Simple and Ultrasensitive EGFR Genotyping of Plasma ctDNA

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Analyst, 2020, Accepted Manuscript
DOI: 10.1039/D0AN00591F, Paper
Xuyao Wang, Jianping Wu, Weilin Mao, Xia He, Liming Ruan, Junlan Zhu, Peng Shu, Zhenqi Zhang, Bitao Jiang, Xingguo Zhang
Genotyping of the epidermal growth factor receptor (EGFR) mutation status is of great importance in the screening of appropriate advanced non-small cell lung carcinoma (NSCLC) patients to receive superior tyrosine...
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chemical

[ASAP] A Coculture Based Tyrosine-Tyrosinase Electrochemical Gene Circuit for Connecting Cellular Communication with Electronic Networks

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Published On :: Thu, 02 Apr 2020 04:00:00 GMT

ACS Synthetic Biology
DOI: 10.1021/acssynbio.9b00469


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chemical

[ASAP] A Chemical Switch System to Modulate Chimeric Antigen Receptor T Cell Activity through Proteolysis-Targeting Chimaera Technology

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Published On :: Thu, 30 Apr 2020 04:00:00 GMT

ACS Synthetic Biology
DOI: 10.1021/acssynbio.9b00476


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chemical

[ASAP] A Chemical Switch for Transforming a Purine Agonist for Toll-like Receptor 7 to a Clinically Relevant Antagonist

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Published On :: Mon, 04 May 2020 04:00:00 GMT

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00011


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chemical

[ASAP] Scaffold Repurposing of in-House Chemical Library toward the Identification of New Casein Kinase 1 d Inhibitors

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Published On :: Mon, 04 May 2020 04:00:00 GMT

ACS Medicinal Chemistry Letters
DOI: 10.1021/acsmedchemlett.0c00028


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chemical

Painting with fire: Sir Joshua Reynolds, photography, and the temporally evolving chemical object / Matthew C. Hunter

By library.mit.edu
Published On :: Sun, 19 Apr 2020 06:00:02 EDT

Online Resource


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chemical

Photochemical α-carboxyalkylation of tryptophols and tryptamines via C–H functionalization

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Chem. Commun., 2020, 56,4930-4933
DOI: 10.1039/D0CC00847H, Communication
Zhiqiang Pan, Yuchang Liu, Fengchi Hu, Qinglong Liu, Wenbin Shang, Chengfeng Xia
A process for the α-carboxyalkylation of tryptophols and tryptamines by the functionalization of C–H bonds under visible light irradiation has been developed.
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chemical

New insight derived from a two-compartment cell: electrochemical behavior of FeF3 positive electrode

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Chem. Commun., 2020, 56,4878-4881
DOI: 10.1039/D0CC01162B, Communication
Kazuki Yoshii, Noboru Taguchi, Takeshi Miyazaki, Masahiro Shikano, Hikari Sakaebe
A designed two-compartment cell revealed the degradation mechanism and an essentially effective additive for the FeF3 composite electrode.
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chemical

Chemically synthesized circular RNAs with phosphoramidate linkages enable rolling circle translation

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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC02140G, Communication
Kosuke Nakamoto, Naoko Abe, Genichiro Tsuji, Yasuaki Kimura, Fumiaki Tomoike, Yoshihiro Shimizu, Hiroshi Abe
Circular RNA without a stop codon enables rolling circle translation. we carried out one-pot chemical synthesis of circular RNA from RNA fragments. The synthesized circular RNAs acted as translation templates, despite the presence of unnatural phosphoramidate linkages.
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chemical

Ultrasensitive DNA Electrochemical Biosensor Based on MnTBAP Biomimetic Catalyzed AGET ATRP Signal Amplification Reaction

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Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC02176H, Communication
Haobo Sun, Yunliang Qiu, Yajie Lu, Jinming Kong, Xueji Zhang
In this paper, an ultrasensitive, highly selective and green electrochemical biosensor for quantifying DNA sequences (aM DNA) based on MnTBAP catalyst for AGET ATRP reaction is proposed. For the first...
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chemical

Harnessing chemical exchange: 19F magnetic resonance OFF/ON zinc sensing with a Tm(III) complex

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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01876G, Communication
Meng Yu, Da Xie, Rahul T. Kadakia, Weiran Wang, Emily L. Que
A Tm(III) complex displays an “off–on” 19F NMR/MRI response to Zn(II) upon tuning the chemical exchange rate.
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chemical

An ultrasensitive electrochemical biosensor for Pseudomonas aeruginosa assay based on a rolling circle amplification-assisted multipedal DNA walker

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Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01619E, Communication
Huang Zhou, Shaoyun Duan, Ji Huang, Fengjiao He
An ultrasensitive electrochemical biosensor was developed based on RCA and multipedal DNA walking strategy for the assay of 16S rRNA gene, and it has great application potential in food safety, environmental monitoring, and disease diagnosis.
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chemical

Electrochemically generated N-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

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Chem. Commun., 2020, 56,5010-5013
DOI: 10.1039/C9CC09869K, Communication
Binbin Huang, Chao Yang, Jia Zhou, Wujiong Xia
This study presents a straightforward protocol for approaching N-sulphonylamidines via an electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines.
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chemical

Synthetic method, growth mechanism and electrochemical properties of PbSnS2 nanosheets for supercapacitors

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Chem. Commun., 2020, 56,5062-5065
DOI: 10.1039/D0CC01011A, Communication
Yuhan Zeng, Hehe Huang, Shenhu Huang, Tongtong Jiang, Zekai Fang, Lin Li, Yuming Dai
Facile hydrothermally synthesized PbSnS2 nanosheets with various morphologies were developed to obtain high performance electrode materials for supercapacitors.
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chemical

Modified cation-exchange membrane for phosphate recovery in an electrochemically assisted adsorption–desorption process

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Chem. Commun., 2020, 56,5046-5049
DOI: 10.1039/C9CC09563B, Communication
Kostadin V. Petrov, Laura Paltrinieri, Lukasz Poltorak, Louis C. P. M. de Smet, Ernst J. R. Sudhölter
A novel ion separation methodology using a cation-exchange membrane modified with iron oxide nanoparticles (Fe3O4 NPs) coated with polyhexamethylene guanidine (PHMG) is proposed.
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chemical

Effects of oxidation treatment by KClO3/H2SO4 systems on the chemical, crystal and microscopic structures of polyacrylonitrile fibers

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00442A, Paper
Cheng Zhang, Shijie Xiao, Zhigang Shen, Runping Li, Jianhua Liu, Shenghui Guo, Lei Xu
Oxidation treatment of PAN fibers (PFs) in a KClO3/H2SO4 system as a new pretreatment method for carbon fiber oxidation stabilization.
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chemical

Novel 2-naphthyl substituted zinc naphthalocyanine: synthesis, optical, electrochemical and spectroelectrochemical properties

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00987C, Paper
T. V. Dubinina, E. O. Moiseeva, D. A. Astvatsaturov, N. E. Borisova, P. A. Tarakanov, S. A. Trashin, K. De Wael, L. G. Tomilova
New zinc naphthalocyanine with bulky 2-naphthyl groups was obtained. Aggregation drastically influences its optical and electrochemical behavior. Spectroelectrochemistry helps to establish the oxidation potential and reveals unusual color change.
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chemical

Detection of 3,4-diaminotoluene based on Sr0.3Pb0.7TiO3/CoFe2O4 core/shell nanocomposite via an electrochemical approach

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01074J, Paper
Ali B. Abou Hammad, Amir Elzwawy, A. M. Mansour, M. M. Alam, Abdullah M. Asiri, Mohammad Razaul Karim, Mohammed M. Rahman, Amany M. El Nahrawy
We reported a scalable sol–gel method for the preparation of Sr0.3Pb0.7TiO3/CoFe2O4 core–shell magnetic nanocomposite with a finely controlled shell and evaluated its efficiency as an electrochemical sensor for the selective detection of 3,4-diaminotoluene.
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chemical

Physicochemical properties of a urea/zinc chloride eutectic mixture and its improved effect on the fast and high yield synthesis of indeno[2,1-c]quinolines

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01342K, Paper
Diana Peña-Solórzano, Vladimir V. Kouznetsov, Cristian Ochoa-Puentes
An environmentally friendly and efficient method for the synthesis of indeno[2,1-c]quinolines is developed using a urea/zinc chloride eutectic mixture as a green mildly acidic medium.
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chemical

Effect of the graphene sheets incorporation on physicochemical properties of nano-alumina

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9NJ06317J, Paper
Elena A. Trusova, Dmitry D Titov, Alex N Kirichenko, Michael Y Zorin
The colloidal processing method was suggested for obtaining of chemically homogeneous composite powder based on graphene and nano-alumina. The method allows integrating a hybrid structure by mixing components at nanoscale...
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chemical

Synthesis and herbicidal application of turpentine derivative p-menthene type secondary amines as sustainable agrochemicals

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New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00583E, Paper
Huanhuan Dong, Shichao Xu, Jing Wang, Hongmei Zhang, Yuxiang Chen, Liangwu Bi, Zhendong Zhao
Compound 3a showed excellent herbicidal activity against barnyard grass with IC50 = 7.0 mg L−1, and exhibited good selection for rice, wheat, and radish at 100 mg L−1.
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chemical

A non-enzymatic electrochemical approach for L-Lactic acid sensor development based on CuO.MWCNT nanocomposites modified with a nafion matrix

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New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01715A, Paper
Mohammad M. Hussain, Abdullah M. Asiri, Mohammed M. Rahman
Copper oxide ornamented multi-walled carbon nanotube nanocomposites (CuO.MWCNT NCs) were prepared using an unsophisticated wet-chemical technique in basic medium. CuO.MWCNT NCs was examined by using various analytical techniques for example...
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chemical

[ASAP] A Chemically Stable Fluorescent Mimic of Dihydroartemisinin, Artemether, and Arteether with Conserved Bioactivity and Specificity Shows High Pharmacological Relevance to the Antimalarial Drugs

By dx.doi.org
Published On :: Mon, 20 Apr 2020 04:00:00 GMT

ACS Infectious Diseases
DOI: 10.1021/acsinfecdis.9b00430


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chemical

Agricultural and Veterinary Chemicals Legislation Amendment (Streamlining Regulation) Bill 2018 [Provisions] / The Senate, Rural and Regional Affairs and Transport Legislation Committee

By prospero.murdoch.edu.au
Published On ::

Australia. Parliament. Senate. Rural and Regional Affairs and Transport Legislation Committee, author, issuing body


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chemical

Agricultural and Veterinary Chemicals Legislation Amendment (Australian Pesticides and Veterinary Medicines Authority Board and Other Improvements) Bill 2019 [Provisions] / The Senate, Rural and Regional Affairs and Transport Legislation Committee

By prospero.murdoch.edu.au
Published On ::

Australia. Parliament. Senate. Rural and Regional Affairs and Transport Legislation Committee, author, issuing body


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chemical

Synthesis, Structural Characterization, Physicochemical Properties and Transformations of Dehydroevodiamine and Its Hydrochloride Salts

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CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00136H, Paper
Guoshun Zhang, xiaoqing shang, wei han, lifeng zhang, guolian ren, Shuqiu Zhang
As a quinazolinocarboline alkaloid, dehydroevodiamine (DHED) derived from Evodia rutaecarpa has recently gained attention because it improves memory failure in Alzheimer's mice. However, its solid forms, which have not yet...
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chemical

Commerce ministry recommends continuation of anti-dumping duty on Chinese chemical

By economictimes.indiatimes.com
Published On :: 2020-05-05T12:00:58+05:30

In a notification, the ministry's investigation arm Directorate General of Trade Remedies (DGTR) has said there is a "positive" evidence of likelihood of dumping of Sodium Citrate and injury to the domestic industry if the existing anti-dumping duty would be removed.


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chemical

Introduction to chemical engineering thermodynamics / J.M. Smith, Late Professor of Chemical Engineering (University of California, Davis), H.C. Van Ness (Late Professor of Chemical Engineering, Rensselaer Polytechnic Institute), M.M. Abbott (Late Profess

By prospero.murdoch.edu.au
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Smith, J. M. (Joseph Mauk), 1916- author


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chemical

Photochemical rearrangement of diarylethenes: synthesis of functionalized phenanthrenes

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Org. Biomol. Chem., 2020, 18,3098-3103
DOI: 10.1039/D0OB00296H, Paper
A. V. Zakharov, A. V. Yadykov, A. G. Lvov, E. A. Mitina, V. Z. Shirinian
The photocyclization of diarylethenes bearing naphthalene units was explored and a convenient protocol for the synthesis of functionalized phenanthrenes was proposed.
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chemical

Biochemical characterisation of an α1,4 galactosyltransferase from Neisseria weaveri for the synthesis of α1,4-linked galactosides

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Org. Biomol. Chem., 2020, 18,3142-3148
DOI: 10.1039/D0OB00407C, Paper
Kun Huang, Andrea Marchesi, Kristian Hollingsworth, Peter Both, Ashley P. Mattey, Edward Pallister, Helene Ledru, Simon J. Charnock, M. Carmen Galan, W. Bruce Turnbull, Fabio Parmeggiani, Sabine L. Flitsch
A new α1,4 galactosyltransferase has been characterised and used for the synthesis of natural and non-natural cell surface trisaccharide antigens.
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chemical

Electrochemical synthesis of selenyl-dihydrofurans via anodic selenofunctionalization of allyl-naphthol/phenol derivatives and their anti-Alzheimer activity

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Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00629G, Communication
Marcos R. Scheide, Alex R. Schneider, Guilherme A. M. Jardim, Guilherme M. Martins, Daniele C. Durigon, Sumbal Saba, Jamal Rafique, Antonio L. Braga
Herein, we report an eco-friendly, electrosynthetic approach for the intramolecular oxyselenylation of allyl-naphthol/phenol derivatives.
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Electrochemically enabled functionalization of indoles or anilines to synthesis of hexafluoroisopropoxy indole and anilinederivatives

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Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00157K, Communication
Zu-yu Mo, Xin-Yu Wang, Yu-zhen Zhang, Li Yang, Hai-Tao Tang, Ying-Ming Pan
An environmentally benign electrochemically enabled site-selective functionalization of indole or aniline derivatives with hexafluoroisopropanol in the presence of tetrabutyl ammonium hexafluorophosphate as redox catalyst and electrolyte was demonstrated in this...
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chemical

Controlling the liberation rate of the in situ release of a chemical fuel for the operationally autonomous motions of molecular machines

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Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00669F, Paper
Chiara Biagini, Giorgio Capocasa, Daniele Del Giudice, Valerio Cataldi, Luigi Mandolini, Stefano Di Stefano
Aminolysis of the anhydride of 2-cyano-2-phenylpropanoic acid can be employed to conveniently regulate the liberation rate of the related acid which, in turn, can be used as a fuel for acid–base operated molecular machines.
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chemical

[ASAP] Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries

By dx.doi.org
Published On :: Fri, 01 May 2020 04:00:00 GMT

ACS Energy Letters
DOI: 10.1021/acsenergylett.0c00700


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chemical

Soft probes for bio-electrochemical imaging Tzu-En Lin

By library.mit.edu
Published On :: Sun, 20 Jan 2019 12:54:47 EST

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chemical

The Origin of a New Progenitor Stem Cell Group in Human Development: An Immunohistochemical-, Light- and Electronmicroscopical Analysis / Hubert Wartenberg, Andreas Miething, Kjeld Møllgård

By library.mit.edu
Published On :: Sun, 20 Jan 2019 12:54:47 EST

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