chemical

[ASAP] Physicochemical Data of Carbonic-Anhydrase-Blended Aqueous Potassium Lysinate Solutions as New Absorbents

Journal of Chemical & Engineering Data
DOI: 10.1021/acs.jced.9b00963




chemical

[ASAP] Re-examining Dust Chemical Aging and Its Impacts on Earth’s Climate

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00102




chemical

[ASAP] Reactive VOC Production from Photochemical and Heterogeneous Reactions Occurring at the Air–Ocean Interface

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00095




chemical

Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00554A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chi Y. Cheng, Josh E. Campbell, Graeme M. Day
Evolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.
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chemical

Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue

Chem. Sci., 2020, 11,4488-4498
DOI: 10.1039/D0SC00544D, Edge Article
Open Access
Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-Tejada
A fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Metal-free carbon monoxide-releasing micelles undergo tandem photochemical reactions for cutaneous wound healing

Chem. Sci., 2020, 11,4499-4507
DOI: 10.1039/D0SC00135J, Edge Article
Open Access
Jian Cheng, Bin Zheng, Sheng Cheng, Guoying Zhang, Jinming Hu
Metal-free carbon monoxide-releasing polymers (CORPs) are synthesized via a direct polymerization approach, exhibiting not only improved stability but also accelerated wound healing performance as compared to CORM-3.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers

Chem. Sci., 2020, 11,4360-4373
DOI: 10.1039/C9SC06272F, Edge Article
Open Access
Kristjan Kunnus, Lin Li, Charles J. Titus, Sang Jun Lee, Marco E. Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, William B. Doriese, Galen C. O'Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, Kent Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. Gaffney
Photoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Selective electrochemical reduction of carbon dioxide to ethanol via a relay catalytic platform

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01133A, Edge Article
Open Access
Juan Du, Shaopeng Li, Shulin Liu, Yu Xin, Bingfeng Chen, Huizhen Liu, Buxing Han
The relay catalytic platform is very efficient and selective for CO2 electroreduction to ethanol.
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chemical

Electrochemical Radical Reactions of Alkyl Iodides: A Highly Efficient, Clean, Green Alternative to Tin Reagents

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01694B, Edge Article
Open Access
diyuan Li, Tsz-Kan Ma, Reuben J Scott, Jonathan David Wilden
An electrochemical ‘redox-relay’ system has been developed which allows the generation of C-centered radicals. Intermolecular ‘tin-like’ radical reactions can subsequently be conducted under the most benign of conditions. The yields...
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

End-to-end Data Analytics for Product Development: A Practical Guide for Fast Consumer Goods Companies, Chemical Industry and Processing Tools Manufacturers


 

An interactive guide to the statistical tools used to solve problems during product and process innovation

End to End Data Analytics for Product Development is an accessible guide designed for practitioners in the industrial field. It offers an introduction to data analytics and the design of experiments (DoE) whilst covering the basic statistical concepts useful to an understanding of DoE. The text supports product innovation and development across



Read More...




chemical

Too many chemicals, so little time

On June 4, Carolina Science Cafe discusses how the Environmental Protection Agency evaluates chemicals.




chemical

Microfabricated electrochemical sensing devices

Lab Chip, 2020, 20,1358-1389
DOI: 10.1039/C9LC01112A, Critical Review
Fumihiro Sassa, Gokul Chandra Biswas, Hiroaki Suzuki
Electrochemistry provides possibilities to realize smart microdevices of the next generation with high functionalities.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Advanced 96-microtiter plate based bioelectrochemical platform reveals molecular short cut of electron flow in cytochrome P450 enzyme

Lab Chip, 2020, 20,1449-1460
DOI: 10.1039/C9LC01220F, Paper
Ronny Frank, Christoph Prönnecke, Ronny Azendorf, Heinz-Georg Jahnke, Annette G. Beck-Sickinger, Andrea A. Robitzki
We developed a novel 96-well microtiter plate based bioelectrochemical platform with a vertical divided cell three-electrode architecture and a 96-multipotentiostat to perform fully parallelised bioelectrocatalytic screenings on redox enzymes.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

An implantable multifunctional neural microprobe for simultaneous multi-analyte sensing and chemical delivery

Lab Chip, 2020, 20,1390-1397
DOI: 10.1039/D0LC00021C, Communication
Bo Wang, Ximiao Wen, Yan Cao, Shan Huang, Hoa A. Lam, Tingyi “Leo” Liu, Pei-Shan Chung, Harold G. Monbouquette, Pei-Yu Chiou, Nigel T. Maidment
PDMS thin-film transfer and enzyme microstamping enabled 3-in-1 Si/PDMS hybrid chemtrode for multi-analyte sensing and chemical delivery in vivo.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Hybrid paper and 3D-printed microfluidic device for electrochemical detection of Ag nanoparticle labels

Lab Chip, 2020, 20,1648-1657
DOI: 10.1039/D0LC00276C, Paper
Charuksha Walgama, Michael P. Nguyen, Lisa M. Boatner, Ian Richards, Richard M. Crooks
A hybrid paper/plastic microfluidic device for detection of Ag nanoparticle labels at concentrations as low as 12 pM.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Chemical signals in vertebrates. editor, Christina D. Buesching

Online Resource




chemical

The first copper(II) complex with 1,10-phenanthroline and salubrinal with interesting biochemical properties

Metallomics, 2020, Advance Article
DOI: 10.1039/D0MT00006J, Paper
Sebastiano Masuri, Enzo Cadoni, Maria Grazia Cabiddu, Francesco Isaia, Maria Giovanna Demuru, Lukáš Moráň, David Buček, Petr Vaňhara, Josef Havel, Tiziana Pivetta
The novel complex Cu(phen)2(salubrinal)(ClO4)2 shows high free radical scavenging activity and good cytotoxic activity and induces cell death through ER-stress.
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The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Distribution and chemical form of selenium in Neptunia amplexicaulis from Central Queensland, Australia

Metallomics, 2020, 12,514-527
DOI: 10.1039/C9MT00244H, Paper
Maggie-Anne Harvey, Peter D. Erskine, Hugh H. Harris, Gillian K. Brown, Elizabeth A. H. Pilon-Smits, Lachlan W. Casey, Guillaume Echevarria, Antony van der Ent
Elemental mapping of selenium in the hyperaccumulator Neptunia amplexicaulis determined whole plant and tissue level selenium distribution. The total concentrations and chemical forms of selenium are also reported for this species.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

[ASAP] Kinetic Analysis of Electrochemical Lactonization of Ketones Using Water as the Oxygen Atom Source

ACS Catalysis
DOI: 10.1021/acscatal.0c00931




chemical

[ASAP] Isolated Pd Sites as Selective Catalysts for Electrochemical and Direct Hydrogen Peroxide Synthesis

ACS Catalysis
DOI: 10.1021/acscatal.0c01305




chemical

[ASAP] Enhancing the Electrocatalytic Activity of Pd/M (M = Ni, Mn) Nanoparticles for the Oxygen Reduction Reaction in Alkaline Media through Electrochemical Dealloying

ACS Catalysis
DOI: 10.1021/acscatal.9b05499




chemical

Nonstick chemicals that stick around and detecting ear infections with smartphones

The groundwater of Rockford, Michigan, is contaminated by per- and polyfluoroalkyl substances, chemicals found in everything from nonstick pans to dental floss to—in the case of Rockford—waterproofing agents from a shoe factory that shut down in 2009. Science journalist Sara Talpos talks with host Meagan Cantwell about how locals found the potentially health-harming chemicals in their water, and how contamination from nonstick chemicals isn’t limited to Michigan. Also this week, host Sarah Crespi talks with Shyamnath Gollakota of the University of Washington in Seattle about his work diagnosing ear infections with smartphones. With the right app and a small paper cone, it turns out that your phone can listen for excess fluid in the ear by bouncing quiet clicks from the speaker off the eardrum. Clinical testing shows the setup is simple to use and can help parents and doctors check children for this common infection. This week’s episode was edited by Podigy. Ads on this show: Science Rules! podcast with Bill Nye Download the transcript (PDF)  Listen to previous podcasts. About the Science Podcast [Image: Dennis Wise/University of Washington; Music: Jeffrey Cook]




chemical

Getting bisphenol A out of food containers, and tracing minute chemical mixtures in the environment

As part of a special issue on chemicals for tomorrow’s Earth, we’ve got two green chemistry stories. First, host Sarah Crespi talks with contributing correspondent Warren Cornwell about how a company came up with a replacement for the popular can lining material bisphenol A and then recruited knowledgeable critics to test its safety. Sarah is also joined by Beate Escher of the Helmholtz Centre for Environmental Research and the University of Tübingen to discuss ways to trace complex mixtures of humanmade chemicals in the environment. They talk about how new technologies can help detect these mixtures, understand their toxicity, and eventually connect their effects on the environment, wildlife, and people. Read more in the special issue on chemicals for tomorrow’s Earth. This week’s episode was edited by Podigy. Listen to previous podcasts. About the Science Podcast Download a transcript (PDF)




chemical

Why some diseases come and go with the seasons, and how to develop smarter, safer chemicals

On this week’s show, host Joel Goldberg gets an update on the coronavirus pandemic from Senior Correspondent Jon Cohen. In addition, Cohen gives a rundown of his latest feature, which highlights the relationship between diseases and changing seasons—and how this relationship relates to a potential coronavirus vaccine. Also this week, from a recording made at this year’s AAAS annual meeting in Seattle, host Meagan Cantwell speaks with Alexandra Maertens, director of the Green Toxicology initiative at Johns Hopkins University, Baltimore, about the importance of incorporating nonanimal testing methods to study the adverse effects of chemicals. This week’s episode was produced with help from Podigy. Download a transcript (PDF) Listen to previous podcasts. About the Science Podcast [Image: Let Ideas Compete/Flickr; Music: Jeffrey Cook] 




chemical

Derivatization and rapid GC—MS screening of chlorides relevant to the Chemical Weapons Convention in organic liquid samples

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00263A, Paper
Open Access
Marja-Leena Kuitunen, Jorgelina Cecilia Altamirano, Peter Siegenthaler, Terhi Hannele Taure, Vesa Mauri Antero Häkkinen, Paula Vanninen
A simple derivatization technique was developed for the analysis of seven Schedule 3 chemicals and one Schedule 2 chemical listed in the Chemical Weapons Conventions (CWC). Phosgene, phosphorus oxychloride, phosphorus...
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Elemental chemical composition and As speciation in rice varieties selected for biofortification

Anal. Methods, 2020, 12,2102-2113
DOI: 10.1039/D0AY00294A, Paper
Bruna Moreira Freire, Vivian da Silva Santos, Pericles de Carvalho Ferreira Neves, Juliana Maria Oliveira Souza Reis, Samuel Simião de Souza, Fernando Barbosa, Bruno Lemos Batista
Toxic elements, essential elements and other elements were determined in Brazilian rice by inductively coupled plasma-mass spectrometry (ICP-MS). A method for As speciation using hydride generation was developed and applied in rice samples.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Discrimination between fresh, chilled, and frozen/thawed chicken based on its skin's spectrochemical and optical properties

Anal. Methods, 2020, 12,2093-2101
DOI: 10.1039/D0AY00324G, Paper
Omnia Hamdy, Zienab Abdel-Salam, Mohamed Abdel-Harith
Monitoring of the spectrochemical and optical properties of biomaterials has been widely utilized in many biomedical applications for both diagnosis and therapy.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Electrochemical determination of paracetamol in a pharmaceutical dose by adsorptive voltammetry with a carbon paste/La2O3 microcomposite

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00442A, Paper
Edgar Nagles, Mario Ceroni, John Hurtado-Murillo, John Hurtado Belalcazar
This paper presents a new application for microcomposites based on carbon paste (CP) and La2O3 (LaOX). This simple and versatile microcomposite (LaOX/CPE) was applied toward the determination of paracetamol (PCM)...
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Development and validation of a real-time microelectrochemical sensor for clinical monitoring of tissue oxygenation/perfusion

Anal. Methods, 2020, Advance Article
DOI: 10.1039/D0AY00206B, Paper
Gama Theophile Gnahoré, Jack L. Kelly, Saidhbhe L. O'Riordan, Fiachra B. Bolger, Michelle M. Doran, Michelle Sands, John P. Lowry
Oxygen is critically important to tissue viability and there is increasing demand for its reliable real-time clinical monitoring in order to prevent, diagnose and treat several pathological disorders, including hypoxia, stroke and reperfusion injury.
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chemical

Fabrication of an electrochemical sensor based on metal-organic framework ZIF-8 for quantitation of silver ion: optimizing experimental conditions by central composite design (CCD)

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00843E, Paper
Farzaneh Hashemi , Ali Reza Zanganeh, Farid Naeimi , Maryam Tayebani
The ZIF-8 was synthesized and carbon paste electrode (CPE) modified with this metal-organic framework utilized for quantitation of silver(Ι) by differential pulse anodic stripping voltammetry (DPASV) technique. The prepared ZIF-8...
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

[ASAP] Isothermal Chemical Denaturation: Data Analysis, Error Detection, and Correction by PARAFAC2

Analytical Chemistry
DOI: 10.1021/acs.analchem.9b05748




chemical

[ASAP] In Vivo Chemical Analysis of Plant Sap from the Xylem and Single Parenchymal Cells by Capillary Microsampling Electrospray Ionization Mass Spectrometry

Analytical Chemistry
DOI: 10.1021/acs.analchem.0c00939




chemical

[ASAP] Predicting Deprotonation Sites Using Alchemical Derivatives

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.9b09472




chemical

[ASAP] The Conformational Landscape, Internal Rotation, and Structure of 1,3,5-Trisilapentane using Broadband Rotational Spectroscopy and Quantum Chemical Calculations

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.0c01100




chemical

[ASAP] Mercury Magnetic Isotope Effect: A Plausible Photochemical Mechanism

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.0c00661




chemical

[ASAP] Photochemical Generation of Benzoazetinone by UV Excitation of Matrix-Isolated Precursors: Isatin or Isatoic Anhydride

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.0c02562




chemical

Bioactive scaffolds based on collagen filaments with tunable physico-chemical and biological features

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00233J, Paper
Ting Lu, Hong Hu, Yuanqi Li, Qingsong Jiang, Jinlei Su, Hai Lin, Yun Xiao, Xiangdong Zhu, Xingdong Zhang
Native tissues such as nerve bundles, blood vessels and tendons have extracellular matrices with a characteristic linear orientation, which cannot be fully achieved with the current technology for the development of regenerative biomaterials.
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The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Effect of network homogeneity on mechanical, thermal and electrochemical properties of solid polymer electrolytes prepared by homogeneous 4-arm poly(ethylene glycols)

Soft Matter, 2020, 16,4290-4298
DOI: 10.1039/D0SM00289E, Paper
Monami Tosa, Kei Hashimoto, Hisashi Kokubo, Kazuhide Ueno, Masayoshi Watanabe
The effect of network inhomogeneity in solid polymer electrolytes on its electrolyte properties was investigated by employing a model polymer network composed of a homogeneous 4-arm poly(ethylene glycol) (tetra-PEG) network and Li salt.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Inspect chemical factories before reopening: Tamil Nadu Consumer Protection Organisation

The Tamil Nadu Consumer Protection Organisation has asked the Tamil Nadu government to form a committee of officials from the environment, industries




chemical

Odor thresholds for chemicals with established health standards / edited by Sharon S. Murnane, Alex H. Lehocky, Patrick D. Owens




chemical

An electrochemical study of oxidative dissolution of synthetic nickel-iron-sulphide minerals in aqueous media [electronic resource] / by Terence Edwin Warner

Warner, Terence E., 1960-




chemical

Mining chemicals handbook




chemical

Heterogeneous electrochemical reactions taking place on metallic iron in ammoniacal-carbonate solutions containing dissolved nickel, cobalt, copper and thiosulfate ions / Anna d'Aloya de Pinilla

D'Aloya de Pinilla, Anna, author




chemical

Chemical and electrochemical leaching studies of synthetic and natural ilmenite in hydrochloric acid solutions / by Nurul Ain Jabit

Jabit, Nurul Ain, author




chemical

Your chemical science thesis [electronic resource] : an introductory guide to writing up your research project / [written and edited by Natalie Mansfield]

Mansfield, Natalie




chemical

[ASAP] In Liquid Infrared Scattering Scanning Near-Field Optical Microscopy for Chemical and Biological Nanoimaging

Nano Letters
DOI: 10.1021/acs.nanolett.0c01291




chemical

Palladium-catalyzed synthesis of [60]fullerene-fused furochromenones and further electrochemical functionalization

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00264J, Research Article
Majid Hussain, Chuang Niu, Guan-Wu Wang
The palladium-catalyzed heteroannulation of [60]fullerene with 4-hydroxycoumarins affords [60]fullerene-fused furochromenones, which can be further derivatized via an electrochemical method to synthesize 1,2,3,4-adducts.
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The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Access to SCN-containing thiazolines via electrochemical regioselective thiocyanothiocyclization of N-allylthioamides

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00300J, Research Article
Yan-An Zhang, Zhong Ding, Peng Liu, Wei-Si Guo, Li-Rong Wen, Ming Li
An electrochemical thiocyclization of N-allylthioamides has been developed for the synthesis of SCN-containing 2-thiazolines and NCS-containing thiazines.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




chemical

Handbook for Chemical Society authors / [Chemical Society]

Chemical Society (Great Britain)




chemical

Nanochemistry : a chemical approach to nanomaterials / Geoffrey A. Ozin and André C. Arsenault

Ozin, Geoffrey A., 1943-