chemical

Black titanium oxide: synthesis, modification, characterization, physiochemical properties, and emerging applications for energy conversion and storage, and environmental sustainability

Chem. Soc. Rev., 2024, 53,10660-10708
DOI: 10.1039/D4CS00420E, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xuelan Hou, Yiyang Li, Hang Zhang, Peter D. Lund, James Kwan, Shik Chi Edman Tsang
The current synthesis methods, modifications, and characterizations of black titanium oxide (B-TiOx) as well as a nuanced understanding of its physicochemical properties and applications in green energy and environment are reviewed.
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chemical

Enhancing electrochemical reactions in organic synthesis: the impact of flow chemistry

Chem. Soc. Rev., 2024, 53,10741-10760
DOI: 10.1039/D4CS00539B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Morgan Regnier, Clara Vega, Dimitris I. Ioannou, Timothy Noël
Utilizing electrons directly offers significant potential for advancing organic synthesis by facilitating novel reactivity and enhancing selectivity under mild conditions.
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chemical

Sapiential battery systems: beyond traditional electrochemical energy

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00832D, Review Article
Tongrui Zhang, Jiangtao Yu, Haoyang Guo, Jianing Qi, Meihong Che, Machuan Hou, Peixin Jiao, Ziheng Zhang, Zhenhua Yan, Limin Zhou, Kai Zhang, Jun Chen
This review delves into the study of sapiential battery systems, providing an overview of their pivotal features of high-throughput material screening, self-diagnosis, self-healing, self-charging, temperature adaptation, and degradability.
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chemical

Exploring chemical concepts through theory and computation [electronic resource] / edited by Shubin Liu.

Weinheim, Germany : Wiley-VCH, [2024]




chemical

Contribution of an instructional module, incorporating PhET simulations, to Rwanda students’ knowledge of chemical reactions and acids and bases through Social Interaction.

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00105B, Paper
Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode MUKAMA, Olivier Habimana, Paulin Manirakiza , Jean Claude Dushimimana , Jean Pierre Alpha Munyaruhengeri , Samia Khan, Elizabeth Lakin
The current study ascertained the influence an instructional module had on enhancing students’ understanding of chemical reactions and acid-base topics. The sample size for this study consisted of 197 students,...
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chemical

Chemical bonding in Swedish upper secondary school education: a force-based teaching model for enhanced understanding

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00258J, Paper
Catalin Koro Arvidsson
This study investigates if a force-based teaching approach, based on quantum mechanical principles and developed in a lesson study, would enhance the understanding of chemical bonding among upper secondary school...
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chemical

A high-performance and self-powered polarization-sensitive photoelectrochemical-type Bi2O2Te photodetector based on a quasi-solid-state gel electrolyte

Mater. Horiz., 2024, 11,1710-1718
DOI: 10.1039/D3MH01882B, Communication
Song Yang, Shujie Jiao, Yiyin Nie, Yue Zhao, Shiyong Gao, Dongbo Wang, Jinzhong Wang
A quasi-solid-state photoelectrochemical-type Bi2O2Te photodetector exhibits excellent linear polarized light detection capability.
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chemical

In situ self-reconstructed hierarchical bimetallic oxyhydroxide nanosheets of metallic sulfides for high-efficiency electrochemical water splitting

Mater. Horiz., 2024, 11,1797-1807
DOI: 10.1039/D3MH02090H, Communication
Yaning Fan, Junjun Zhang, Jie Han, Mengyuan Zhang, Weiwei Bao, Hui Su, Nailiang Wang, Pengfei Zhang, Zhenghong Luo
The obtained bimetallic sulfide catalyst can be reconstituted as FeCoOOH, which has high efficacy for water splitting. The activation energy barrier of key reaction steps can be effectively reduced by dual-metal cooperation.
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chemical

Heterostructured grafting of NiFe-layered double hydroxide@TiO2 for boosting photoelectrochemical cathodic protection

Mater. Horiz., 2024, 11,1808-1816
DOI: 10.1039/D3MH02134C, Communication
Zhi-Jun Wang, Hui Xie, Seong Chan Jun, Jiang Li, Li Cheng Wei, Yu Chen Fang, Shude Liu, Ming Ma, Zheng Xing
Grafting NiFe-LDH nanosheets onto TiO2 nanorod arrays largely improves the photoexcited charge separation and accelerates the surface oxidation reaction, leading to stable & self-enhancing photoelectrochemical cathodic protection performance.
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chemical

N-Type polymeric mixed conductors for all-in-one aqueous electrolyte gated photoelectrochemical transistors

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00267A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Latifah Almulla, Victor Druet, Christopher E. Petoukhoff, Wentao Shan, Nisreen Alshehri, Sophie Griggs, Yazhou Wang, Maryam Alsufyani, Wan Yue, Iain McCulloch, Frédéric Laquai, Sahika Inal
An n-type organic photoelectrochemical transistor produces large and reversible current changes in response to light-intensity variations in aqueous electrolytes. A long exciton lifetime of the n-type gate ensures a high photovoltage response.
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chemical

A mechanochemical process to capture and separate carbon dioxide from natural gas using boron nitride nanosheets

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00188E, Communication
Srikanth Mateti, Ying (Ian) Chen, Gautham Sathikumar, Qi Han, Shiva Prasad, Reza Ghandehari Ferdowsi, Amrito Battacharjee
A mechanochemical process to store and separate CO2 gas using boron nitride nanosheets.
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chemical

Photochemical engineering unsaturated Pt islands on supported Pd nanocrystals for a robust pH-universal hydrogen evolution reaction

Mater. Horiz., 2024, 11,1964-1974
DOI: 10.1039/D3MH02041J, Communication
Yidan Liu, Nuttapon Yodsin, Ting Li, Haocheng Wu, Rongrong Jia, Liyi Shi, Zhuangchai Lai, Supawadee Namuangruk, Lei Huang
Novel core–shell Pd7@Ptx heterostructured nanocrystals with Pt-islands shell of unsaturated coordination edges could be directly photodeposited on a reduced graphene oxide support as a highly efficient HER electrocatalyst in a wide pH range.
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chemical

Electrochemical modulation of mechanical properties of glycolated polythiophenes

Mater. Horiz., 2024, 11,2021-2031
DOI: 10.1039/D3MH01827J, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ilaria Abdel Aziz, Johannes Gladisch, Chiara Musumeci, Maximilian Moser, Sophie Griggs, Christina J. Kousseff, Magnus Berggren, Iain McCulloch, Eleni Stavrinidou
This work investigates the changes in the mechanical properties of glycolated polythiophenes induced by electrochemical addressing and by electrolyte concentration, due to its ability to stabilize water.
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chemical

Chemically Fueled Dynamic Switching Between Assembly-Encoded Emissions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00251B, Communication
Manirul Islam, Malay Kumar Baroi, Basab Kanti Das, Aanchal Kumari, Krishnendu Das, Sahnawaz Ahmed
Self-assembly provides access to non-covalently synthesized supramolecular materials with distinct properties from a single building block. However, dynamic switching between functional states still remains challenging but holds enormous potential in...
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chemical

Frontiers in Chemical Engineering [electronic journal].

Frontiers Media S.A




chemical

Chemical Review and Letters [electronic journal].




chemical

Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3 and BrO3 are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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chemical

High-efficiency ammonia synthesis via electrochemical nitrate reduction over Co3O4 nanoarrays by B doping

Inorg. Chem. Front., 2024, 11,2339-2345
DOI: 10.1039/D4QI00310A, Research Article
Zhiqin Deng, Heng Liu, Huiyong Wang, Chaoqun Ma, Juan Du, Baozhan Zheng
B acts as an effective dopant to boost the catalytic activity of Co3O4 for the nitrate reduction reaction towards NH3 synthesis. Such B-Co3O4/TM achieves a high faradaic efficiency of 94.7% and a large NH3 yield rate of 407.3 μmol h−1 cm−2.
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chemical

Understanding the synthesis mechanism, chemical structures and optical properties of aromatic carbon nitride

Inorg. Chem. Front., 2024, 11,2346-2354
DOI: 10.1039/D4QI00355A, Research Article
Yunhu Wang, Fangxu Dai, Yafei Tao, Kai Zhang, Bingjie Li, Mingming Zhang, Kang Liu, Jixiang Xu, Lei Wang, Jun Xing
The chemical structures and optical properties of aromatic carbon nitride and intermediates have been systematically studied; hereby the detailed synthesis mechanism of aromatic carbon nitride is explicitly proposed.
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chemical

Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan

Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article
Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
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chemical

Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites

Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
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chemical

Electrochemical frontiers in the nitrogen cycle

Inorg. Chem. Front., 2024, 11,2202-2204
DOI: 10.1039/D4QI90016B, Editorial
Xuping Sun, Jieshan Qiu, Chenghua Sun
Xuping Sun, Jieshan Qiu and Chenghua Sun introduce this Inorganic Chemistry Frontiers themed collection on nitrogen cycle electrocatalysis.
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chemical

New Ultraviolet Transparent Rare-Earth Borates with Enhanced Birefringence Induced by Cation Chemical Substitution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00840E, Research Article
Guanglian Sun, xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu
Birefringence determined by optical anisotropy is one of the most pivotal and fundamental performance of optical materials. However, optimizing the birefringence remains a significant challenge. Herein, a simple and effective...
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chemical

Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00519H, Research Article
Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
By doping transition metals into CoOx, we can regulate the deintercalation capacity of OH. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH, and accelerated the kinetics of HMFOR.
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chemical

Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02335D, Research Article
Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
Density functional theory calculations show that Tan+1Cn and Tan+1CnO2 MXenes have excellent open circuit voltages and maximum storage capacities for use in alkali metal-ion batteries.
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chemical

UPL recognised as top patent applicant in agro-chemical research

This recognition comes from the Global Innovation Index (GII) 2024, which annually ranks the world’s economies based on their innovation capabilities




chemical

Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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chemical

Deep Learning Enabled Ultra-high Quality NMR Chemical Shift Resolved Spectra

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04742G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhengxian Yang, Weigang Cai, Wen Zhu, Xiaoxu Zheng, Xiaoqi Shi, Mengjie Qiu, Zhong Chen, Maili Liu, Yanqin Lin
High quality chemical shift resolved spectra have long been pursued in nuclear magnetic resonance (NMR). In order to obtain chemical shift information with high resolution and sensitivity, a neural network...
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chemical

Electrochemical reconstruction of metal–organic gels into crystalline oxy-hydroxide heterostructures for efficient oxygen evolution electrocatalysis

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05799F, Edge Article
Open Access
Kang Liu, Haikuo Lan, Yuting Chen, Weicheng Tang, Zhenyu Xiao, Yunmei Du, Jun Xing, Zexing Wu, Lei Wang
An amorphous MOG electrochemically reconstitutes to a crystalline NiOOH/FeOOH heterostructure with the morphology changed from nanofibers to nanosheets as a high-performance OER electrocatalyst.
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chemical

Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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chemical

Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05977H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei Li
Ischemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...
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chemical

Rapid, Potent, and Persistent Covalent Chemical Probes to Deconvolute PI3Kα Signaling

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05459H, Edge Article
Open Access
Lukas Bissegger, Theodora Alexandra Alexandra Constantin, Erhan Keles, Luka Raguž, Isobel Barlow-Busch, Clara Orbegozo, Thorsten Schaefer, Valentina Borlandelli, Thomas Bohnacker, Rohitha SriRamaratnam, Alexander Schäfer, Matthias Gstaiger, John E. Burke, Chiara Borsari, Matthias Wymann
Chemical probes have gained importance in the elucidation of signal transduction in biology. Insufficient selectivity and potency, lack of cellular activity and inappropriate use of chemical probes has major consequences...
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chemical

Discovery of penicillic acid as a chemical probe against tau aggregation in Alzheimer’s Disease

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05469E, Edge Article
Open Access
Jennifer Shyong, Jinliang Wang, Tran Quoc Dung Huynh, Marina Fayzullina, Bo Yuan, Ching-Kuo Lee, Thomas Minehan, Paul M. Seidler, Clay Wang
Alzheimer’s Disease (AD) is a neurodegenerative disorder proven to be caused by the aggregation of protein tau into fibrils, resulting in neuronal death. The irreparable neuronal damage leads to irreversible...
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chemical

Surface modification of paper-based microfluidic devices via initiated chemical vapor deposition

Lab Chip, 2024, 24,4940-4947
DOI: 10.1039/D4LC00414K, Tutorial Review
Stacey Bacheller, Malancha Gupta
Paper-based microfluidic devices offer a low-cost platform for biological and environmental detection. This tutorial review shows that initiated chemical vapor deposition can be used to modify these devices with functional polymers.
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chemical

P3MOT-decorated metal-porphyrin-based zirconium-MOF for the efficient electrochemical detection of 4-nitrobenzaldehyde

Anal. Methods, 2024, 16,2093-2100
DOI: 10.1039/D4AY00152D, Paper
Wen-yi Chen, Xin-yu Huang, Qian Sun, En-qing Gao
Developed a novel hybrid P3MOT@PCN-222(Fe) via in situ polymerization for 4-NBA detection. Showcased broad detection range, high sensitivity, selectivity and stability, laying groundwork for environmental monitoring.
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chemical

Surface charge-induced electrospray for high-throughput analysis of complex samples and electrochemical reaction intermediates using mass spectrometry

Anal. Methods, 2024, 16,2002-2008
DOI: 10.1039/D4AY00276H, Communication
Yajie Huang, Yajun Zheng, Qianqian Zuo, Zhiming Zhang, Lixuan Zhu, Yun Li, Zhiping Zhang
A novel surface charge induced electrospray ionization is proposed due to its features of no contact between sample solution and metal electrode, fast analytical process (less than 40 s), and high analytical sensitivity.
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chemical

Electrochemical aptasensor based on silver-thiolated graphene for high-sensitive detection of Pb2+

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00322E, Paper
Jie Zhou, Changchun Hu, Shuo Li, Chuanxiang Zhang, Yuan Liu, Zhu Chen, Song Li, Hui Chen, Yan Deng
The presence of lead ions (Pb2+) not only leads to environmental contamination but also poses a significant risk to public health through their migration into food and drinking water. Therefore,...
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chemical

An efficient electrochemical sensor based on the Ce-MOF/g-C3N5 composite for the detection of nitrofurazone

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D3AY02221H, Paper
Jianxia Gu, Yiqiong Jia, Zhanbin Jin, Tingting Wei, Yongxia Li
The Ce-MOF/g-C3N5 composite was first constructed using a simple reflux method in an oil bath, and the electrochemical sensor fabricated based on this composite shows excellent detection performance in nitrofurazone detection in practical samples.
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chemical

Converging optical and electrochemical detection strategies for multimodal hydrazine sensing: insights into substituent-driven diverse response

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00063C, Paper
Rikitha S. Fernandes, Sahil Deepak Vasistha, Ritesh Kumar Singh, Sanket Goel, Nilanjan Dey
A pair of pyrene-based chalcogen derivatives have been developed, which demonstrate multimodal ratiometric response towards hydrazine.
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chemical

LAMP-based hydrogen ion selective electrochemical sensor for highly sensitive detection of Mycoplasma pneumoniae

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00341A, Paper
Huiqing Wang, Yang Li, Lin Tian, Xinyi Li, Qian Gao, Yaru Liu, Cuiping Ma, Qing Wang, Chao Shi
An urgent need for a concise and rapid detection method for Mycoplasma pneumoniae is required due to its severe impact on human’s health. To meet such a need, this study...
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chemical

Heparin-stabilized gold nanoparticles embedded in graphene for the electrochemical determination of esculetin

Anal. Methods, 2024, 16,2256-2266
DOI: 10.1039/D4AY00229F, Paper
Vinicius José da Silva, Luan Gabriel Baumgarten, Juliana Priscila Dreyer, Edson Roberto Santana, Almir Spinelli, João Paulo Winiarski, Iolanda Cruz Vieira
A conductive nanocomposite consisting of heparin-stabilized gold nanoparticles embedded in graphene was prepared for esculetin determination in tea and jam samples.
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chemical

Direct solid sample analysis of low-cost jewelry using spectroanalytical techniques: exploratory chemical data evaluation and metal migration with synthetic sweat

Anal. Methods, 2024, 16,2286-2291
DOI: 10.1039/D4AY00325J, Paper
Thaila Lorena de Araújo, Fabiola Manhas Verbi Pereira, Edenir Rodrigues Pereira-Filho
Jewelry samples were directly analyzed using LIBS and XRF.
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chemical

An overview of electrochemical biosensors used for COVID-19 detection

Anal. Methods, 2024, 16,2164-2176
DOI: 10.1039/D3AY02042H, Minireview
Tatiana Lima Valerio, Raquel Anastácio, Stella Schuster da Silva, Carolina Camargo de Oliveira, Marcio Vidotti
This short review presents the latest advances in the field of electrochemical biosensors, focusing particularly on impedimetric biosensors for the direct measurement of analytes.
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chemical

Design and fabrication of La-based perovskites incorporated with functionalized carbon nanofibers for the electrochemical detection of roxarsone in water and food samples

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00264D, Paper
Mariya Antony John Felix, Santhiyagu Sahayaraj Rex Shanlee, Shen-Ming Chen, Sundaresan Ruspika, Ramachandran Balaji, Narendhar Chandrasekar, Periyanayagam Arockia Doss
Fabrication of potent electrocatalyst, La-based perovskites coupled with functionalized carbon nanofibers (LMO/f-CNF) for ultrasensitive electrochemical detection of roxarsone in edible and water samples.
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chemical

Semisynthetic phytochemicals in cancer treatment: a medicinal chemistry perspective

RSC Med. Chem., 2024, 15,3345-3370
DOI: 10.1039/D4MD00317A, Review Article
Meghna Arora, Ankit Kumar Singh, Adarsh Kumar, Harshwardhan Singh, Prateek Pathak, Maria Grishina, Jagat Pal Yadav, Amita Verma, Pradeep Kumar
Semisynthetic phytochemicals in cancer treatment.
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chemical

The chemical treasury in garlic




chemical

Thickness-dependent response of aerosol-jet-printed ultrathin high-aspect-ratio electrochemical microactuators

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00886C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ji Zhang, Jeremy J. Baumberg, Sohini Kar-Narayan
Trilayer electrochemical actuators comprising an electrolyte layer sandwiched between two electrode layers have been shown to exhibit large deformations at low actuation voltages. Here we report aerosol-jet printing (AJP) of...
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chemical

Synergy of prediction rule and total synthesis in solving the stereochemical puzzle of eucalactam B

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01777C, Research Article
Chenqi Wang, Junyang Liu, Tao Ye
The absolute configurations of the fungal-derived reduced polyketide eucalactam B were initially predicted using the “Biochemistry-based rule” and later confirmed through its first successful total synthesis.
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chemical

Electrochemical approach for upgrading the pollutant CS2: three-component N–H thiocarbamylation of sulfoximines

Org. Chem. Front., 2024, 11,6477-6482
DOI: 10.1039/D4QO01310G, Research Article
Peng Qian, Wenjing Xiong, Qian Meng, Jinxiu Liu, Xiyuan Li, Liangquan Sheng
We report an electrochemical approach for upgrading the pollutant CS2via the thiocarbamylation of sulfoximines, in which CS2 and amines are incorporated as a readily available source of dithiocarbamate.
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chemical

Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01827C, Research Article
Open Access
Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu Chen
Mechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...
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