with Diverse quantum interference regimes in intramolecular singlet fission chromophores with thiophene-based linkers By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17823-17830DOI: 10.1039/D4SC03546A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jonghwan Lee, Sungsik Eom, Hyungjun KimThis work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Automated electrosynthesis reaction mining with multimodal large language models (MLLMs) By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17881-17891DOI: 10.1039/D4SC04630G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shi Xuan Leong, Sergio Pablo-García, Zijian Zhang, Alán Aspuru-GuzikLeveraging multimodal large language models (MLLMs) to process multimodal data inputs and complex inter-modality data dependencies for automated (electro)chemical data mining from scientific literature.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Quadrupolar dinuclear hypervalent tin(IV) compounds with near-infrared emission consisting of Schiff bases based on π-conjugated scaffolds By pubs.rsc.org Published On :: Chem. Sci., 2024, 15,17950-17961DOI: 10.1039/D4SC05006A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kazuya Tanimura, Kento Tanaka, Masayuki Gon, Kazuo TanakaThe study focuses on dinuclear hypervalent tin(IV) compounds with near-infrared (NIR) emission and unique quadrupolar orientations, showing potential for constructing electronic structures with narrow energy gaps.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06334A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun FengWe present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Cyclo[4]pyrrole with α–β direct linkages By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06670G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuhua Sun, Riku Kitahara, Tomoya Ichino, Yuki Ide, Hisanori Senboku, Soji Shimizu, Takayuki Tanaka, Yasuhide InokumaA cyclo[4]pyrrole bearing pyrrole(α)–pyrrole(β) direct linkages was synthesized from an oligoketone precursor. Cyclo[4]pyrrole exhibited a non-planar macrocyclic structure whose global π-conjugation was altered depending on the dihedral angles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04629C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo PoliThe catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06537A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Álvaro Valdés-Maqueda, Manuel Plaza, Carlos ValdésThe photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Mechanism of action and evaluation of ratiometric probes for uric acid using lanthanide complexes with tetraazatriphenylene sensitisers By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC05743K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David ParkerSix Eu(III) and Tb(III) complexes are evaluated for the rapid ratiometric analysis of urate in diluted serum, together with mechanistic studies probing the intermediate exciplex and the excited state dynamics by transient absorption spectroscopy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials By pubs.rsc.org Published On :: Chem. Sci., 2024, Accepted ManuscriptDOI: 10.1039/D4SC04957H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele CascellaThe preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Shape-shifting with dance By www.thehindu.com Published On :: Thu, 10 Nov 2016 00:00:00 +0530 Sanjukta Sinha dwells on belonging and relationships in Kin , her new contemporary Kathak production Full Article Mumbai
with Entertainment with a finesse By www.thehindu.com Published On :: Thu, 10 Nov 2016 00:00:00 +0530 Filmmaker Mansoor Khanon the cinema of his illustrious father and his comeback plans Full Article Mumbai
with Burning with desire By www.thehindu.com Published On :: Fri, 11 Nov 2016 00:00:00 +0530 Using the text of an existing play, Jyoti Dogra’s devised piece Toye examines the actors’body through performance Full Article Mumbai
with Want to work with directors who enrich my acting: Ranveer By www.thehindu.com Published On :: Thu, 17 Nov 2016 00:00:00 +0530 The 31-year-old actor said after megastar Amitabh Bachchan and superstar Shah Rukh Khan, he is the only actor to be directed by Bhansali and Chopra. Full Article Mumbai
with Dear Zindagi music: Déjà vu with a hint of new By www.thehindu.com Published On :: Thu, 17 Nov 2016 00:00:00 +0530 Amit Trivedi returns as a composer for the new Gauri Shinde film with a bunch of feel-good tracks Full Article Mumbai
with From text to speech : the MITalk system / Jonathan Allen, M. Sharon Hunnicutt, Dennis Klatt, with Robert C. Armstrong and David Pisoni By darius.uleth.ca Published On :: Cambridge [Cambridgeshire] ; New York : Cambridge University Press, 1987 Full Article
with Markets correlate with economic performance, not political dispensation: Ashish Somaiyaa, CEO, WhiteOak Capital AMC By www.thehindubusinessline.com Published On :: Sat, 01 Jun 2024 18:55:45 +0530 Ashish Somaiyaa, CEO, WhiteOak Capital AMC, on the impact of elections on the market and more Full Article Portfolio
with Leveraging equity taxation with arbitrage funds By www.thehindubusinessline.com Published On :: Sat, 05 Oct 2024 16:26:50 +0530 Arbitrage funds come with both – safety of capital as a debt fund and taxation of an equity fund. Full Article Mutual Funds
with PM Modi a 'demanding' boss, have to be 'fully prepared' to hold discussions with him: EAM Jaishankar By www.newkerala.com Published On :: Mon, 11 Nov 2024 12:46:02 +0530 Full Article
with Rapid miRNA detection in skin interstitial fluid using a hydrogel microneedle patch integrated with DNA probes and graphene oxide By pubs.rsc.org Published On :: Lab Chip, 2024, 24,4989-4997DOI: 10.1039/D4LC00715H, PaperHanjia Zheng, Fatemeh Keyvani, Sadegh Sadeghzadeh, Dragos F. Mantaila, Fasih A. Rahman, Joe Quadrilatero, Mahla PoudinehA simple and rapid fluorescence-based sensor sensors using DNA functionalized graphene oxide for miRNA detection from skin interstitial fluid.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Inertial co-focusing of heterogeneous particles in hybrid microfluidic channels with constantly variable cross-sections By pubs.rsc.org Published On :: Lab Chip, 2024, 24,5032-5042DOI: 10.1039/D4LC00479E, PaperTianwei Zhao, Peng Zeng, Yuanting Zhang, Jinxia Li, Hui Sun, Imrich Gablech, Honglong Chang, Xichen Yuan, Pavel Neužil, Jianguo FengInertial focusing chips based on hybrid microfluidic channels were presented for high-efficiency heterogeneous particle co-focusing, offering significant applications in microfluidic flow cytometry and single-cell analysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Rapid low-cost assembly of modular microvessel-on-a-chip with benchtop xurography By pubs.rsc.org Published On :: Lab Chip, 2024, 24,5065-5076DOI: 10.1039/D4LC00565A, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shashwat S. Agarwal, Marcos Cortes-Medina, Jacob C. Holter, Alex Avendano, Joseph W. Tinapple, Joseph M. Barlage, Miles M. Menyhert, Lotanna M. Onua, Jonathan W. SongOur study is a novel implementation of xurography for multi-layer microfluidic device fabrication. We demonstrate the versatility of this approach by presenting several modular 3D vessel-matrix arrangements.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Real-time monitoring of a 3D blood–brain barrier model maturation and integrity with a sensorized microfluidic device By pubs.rsc.org Published On :: Lab Chip, 2024, 24,5085-5100DOI: 10.1039/D4LC00633J, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Maria Cristina Ceccarelli, Marie Celine Lefevre, Attilio Marino, Francesca Pignatelli, Katarzyna Krukiewicz, Matteo Battaglini, Gianni CiofaniA new in vitro sensorized model of the blood–brain barrier has been developed and characterized.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Optical tweezer-assisted cell pairing and fusion for somatic cell nuclear transfer within an open microchannel By pubs.rsc.org Published On :: Lab Chip, 2024, Advance ArticleDOI: 10.1039/D4LC00561A, PaperYidi Zhang, Han Zhao, Zhenlin Chen, Zhen Liu, Hanjin Huang, Yun Qu, Yaowei Liu, Mingzhu Sun, Dong Sun, Xin ZhaoWe developed a somatic cell nuclear transfer-electrofusion system for pairing and fusing oocytes and somatic cells with a thousand-fold volume difference. The system showed a 90.56% pairing efficiency, potentially boosting batch cloning efficiency.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
with Man armed with machete creates tension in Aluva By www.thehindu.com Published On :: Tue, 05 Nov 2024 00:48:17 +0530 Full Article Kerala
with Kerala State school sports meet off to a vibrant start with grand inaugural ceremony By www.thehindu.com Published On :: Tue, 05 Nov 2024 01:10:23 +0530 The inaugural ceremony featured a march past with student athletes from 14 districts and the United Arab Emirates (UAE) parading from Durbar Hall Ground to the college ground Full Article Kerala
with Allow only dolly workers with police verification certificate to carry pilgrims to Sabarimala: Kerala HC By www.thehindu.com Published On :: Thu, 07 Nov 2024 11:44:35 +0530 Full Article Kochi
with A man’s love affair with a sport that gave him a life By www.thehindu.com Published On :: Thu, 07 Nov 2024 20:05:29 +0530 Full Article Kochi
with Syro-Malabar Church affirms solidarity with Munambam protesters By www.thehindu.com Published On :: Thu, 07 Nov 2024 21:33:51 +0530 State government must urgently intervene in the issue, since hundreds of families are facing threat of displacement from the land they had purchased and had been staying in for decades, says Church spokesperson Full Article Kerala
with Kerala man arrested with nitrazepam tablets By www.thehindu.com Published On :: Fri, 08 Nov 2024 10:09:01 +0530 Full Article Kerala
with IBM’s new GenAI Innovation Centre to open doors to all looking to experiment with its AI platform By www.thehindu.com Published On :: Tue, 12 Nov 2024 18:47:37 +0530 Full Article Kerala
with Government partners with MicroSave to optimise Community Investment Support Fund By www.thehindubusinessline.com Published On :: Thu, 22 Aug 2024 20:52:38 +0530 MicroSave has signed MoU with Rural Development Ministry on July 29 Full Article Policy
with Govt proposes new window in NRS auctions for buying coal without end use requirement By www.thehindubusinessline.com Published On :: Thu, 29 Aug 2024 19:02:13 +0530 Coal Ministry proposes new window in NRS Linkage Auction Policy for long-term coal linkages without end use restrictions Full Article Commodities
with Most powers of controversial patents chief Pandit withdrawn By www.thehindubusinessline.com Published On :: Wed, 04 Sep 2024 22:08:31 +0530 businessline was the first to report administrative head of intellectual property rights in the country, Prof Unnat P Pandit, has been indicted in a computer purchase case Full Article Policy
with FDI policy: Instead of overall review, govt may continue with tweaks By www.thehindubusinessline.com Published On :: Wed, 09 Oct 2024 20:07:22 +0530 Focus will be on liberalising sector specific policy as and when required; improving processes Full Article Economy
with India to continue supporting Global South with strong forex reserves, says FM Sitharaman By www.thehindubusinessline.com Published On :: Wed, 23 Oct 2024 21:57:57 +0530 At a Centre for Global Development event, Sitharaman highlighted India’s use of foreign reserves to aid distressed nations without conditions. Full Article Policy
with Govt proposes 15-year PPA for FDRE projects with battery storage By www.thehindubusinessline.com Published On :: Tue, 29 Oct 2024 18:47:57 +0530 The Power Ministry seeks stakeholder feedback on amendments Full Article Policy
with Govt may bring flex fuel vehicles on a par with EVs By www.thehindubusinessline.com Published On :: Tue, 05 Nov 2024 22:15:00 +0530 Mulls reducing GST, offering support to crops to boost ethanol output Full Article Policy
with Force Gurkha with five doors incoming By www.thehindubusinessline.com Published On :: Fri, 29 Mar 2024 22:01:00 +0530 With the latest model, Force readies itself to take on the Jimny and the upcoming five-door derivative of the Mahindra Full Article Auto focus
with TN Health Dept to launch 25 bike ambulances with Rs 1.60 crore allocation By www.newkerala.com Published On :: Fri, 08 Nov 2024 00:30:02 +0530 Full Article
with Karwa Chauth 2024: 5 fasting tips for women with diabetes By www.dnaindia.com Published On :: Sat, 19 Oct 2024 10:07:00 GMT Here are five fasting tips to help them manage diabetes effectively during Karwa Chauth 2024. Full Article Health
with 'I have not worked out': This is how Vidya Balan achieved drastic weight loss without exercising By www.dnaindia.com Published On :: Wed, 30 Oct 2024 13:08:00 GMT Despite numerous diets and rigorous workouts, she frequently found that the weight would return. Full Article Health
with Shah Rukh Khan feels breathless after quitting smoking: Know withdrawal symptoms, how to manage them By www.dnaindia.com Published On :: Mon, 04 Nov 2024 13:42:00 GMT Quitting smoking is a major accomplishment, but it can come with withdrawal symptoms that vary in intensity and duration based on the individual and how long they smoked. Full Article Health
with 'I gain weight as body...' Arjun Kapoor reveals being diagnosed with Hashimoto's disease By www.dnaindia.com Published On :: Thu, 07 Nov 2024 13:18:00 GMT Hashimoto's disease can lead to hypothyroidism, or an underactive thyroid, causing symptoms like fatigue, weight gain, dry skin, and slowed heart rate. Full Article Health
with Combination targeted treatment produces lasting remissions in people with resistant aggressive B-cell lymphoma By www.cancer.gov Published On :: Wed, 19 Jun 2024 12:00:00 +0000 More than half of clinical trial participants treated with venetoclax, ibrutinib, prednisone, obinutuzumab, and lenalidomide (ViPOR) had substantial tumor shrinkage. Of those, 38% had tumors that disappeared completely. Full Article
with For healthy adults, taking multivitamins daily is not associated with a lower risk of death By www.cancer.gov Published On :: Wed, 26 Jun 2024 12:00:00 +0000 A large analysis of data from nearly 400,000 healthy U.S. adults followed for more than 20 years has found no association between regular multivitamin use and lower risk of death. Full Article
with Immunotherapy approach shows potential in some people with metastatic solid tumors By www.cancer.gov Published On :: Thu, 11 Jul 2024 12:00:00 +0000 A new cellular immunotherapy approach shrank tumors in 3 of 7 patients with metastatic colon cancer, in a small NCI clinical trial. Normal white blood cells from each patient were genetically engineered to produce receptors that recognize and attack their specific cancer cells. Full Article
with NIH study links neighborhood environment to prostate cancer risk in men with West African genetic ancestry By www.cancer.gov Published On :: Mon, 16 Sep 2024 12:00:00 +0000 A new study suggests, for men with West African genetic ancestry, living in a disadvantaged neighborhood was associated with a higher risk of prostate cancer. The researchers posit that chronic stress—such as from racial profiling, housing discrimination, and exposure to violence—may be a possible driver. Full Article
with Immunotherapy after surgery helps people with high-risk bladder cancer live cancer-free longer By www.cancer.gov Published On :: Mon, 16 Sep 2024 12:00:00 +0000 An NCI trial shows that giving patients pembrolizumab after surgery for high-risk muscle invasive bladder cancer doubles the median length of time that they remain cancer free, compared with observation alone after surgery. Full Article
with Sabalenka opens WTA Finals with sweep By www.rediff.com Published On :: No. 1 seed Aryna Sabalenka of Belarus had little trouble getting past China's Qinwen Zheng in a group-stage match at the WTA Finals on Saturday, prevailing 6-3, 6-4 in Riyadh, Saudi Arabia. Full Article
with Defiant BRS MLA Mynampalli Hanumantha Rao to decide future course of action after talks with supporters By www.thehindu.com Published On :: Tue, 22 Aug 2023 14:08:14 +0530 “I had not made any personal accusation against the Chief Minister K. Chandrashekhar Rao or the party. My grouse is against Mr. Harish Rao only,” he said. Full Article Telangana