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Defect-engineered WSxSe2−x nanocrystals anchored on selenized polyacrylonitrile fibers toward high-performance sodium/potassium-ion batteries with a wide working temperature range

Inorg. Chem. Front., 2024, 11,2164-2177
DOI: 10.1039/D3QI02640J, Research Article
Fuyu Xiao, Jingran Zhang, Weiming Zhou, Yixing Fang, Xiaotong He, Wenbin Lai, Chuyuan Lin, Mingyang Ge, Haosen Fan, Qingrong Qian, Mingdeng Wei, Qinghua Chen, Lingxing Zeng
WSSe-Se@PAN was fabricated by the electrospinning route combined with selenization treatment. It exhibited a wide working temperature range for SIB/PIB applications.
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Te doped 1T/2H-MoSe2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries

Inorg. Chem. Front., 2024, 11,2017-2028
DOI: 10.1039/D4QI00259H, Research Article
Zhiqi Li, Jiawen Yan, Qiming Li, Ao Xu, Jianchao Sun, Yijing Wang, Xiaoyu Zhang, Xueqin Sun, Fuyi Jiang, Yanli Zhou
MoSe2 with a two-dimensional layer-like structure has been considered a promising anode material for sodium-ion batteries (SIBs) on account of its high capacity and rich reserves on Earth.
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Gelation-induced controlled synthesis of TiO2 with tunable phase transition for efficient photocatalytic hydrogen evolution

Inorg. Chem. Front., 2024, 11,2178-2186
DOI: 10.1039/D4QI00193A, Research Article
Wenwei Lei, Ying Wang, Hongji Wang, Norihiro Suzuki, Chiaki Terashima, Akira Fujishima
A facile gelation-assisted coordination self-assembly method for mediated fabrication of TiO2 photocatalysts with controlled phase structures and morphologies is presented, showing excellent photocatalytic hydrogen production performance.
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Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00171K, Research Article
Mariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng Ma
The levels of Nd3+ in CsPbCl3 lie below the top of the host's VB. Consequently, Nd3+ luminescence is not observed.
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Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00334A, Research Article
Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang Tong
Two magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.
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Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00225C, Research Article
Zehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen Li
Photocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen.
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NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00182F, Research Article
Bing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua Yang
The formation of intrinsic carbon defects and phase engineered FeP nanoparticles regulated by NH3 plasma etching significantly enhanced the oxygen reduction reaction performance of N-doped carbon nanotubes.
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00429A, Research Article
Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
A comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.
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Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00462K, Research Article
Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
The long-neglected stereochemically active lone pair groups ClO3 and BrO3 are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00511B, Research Article
Open Access
Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
A cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.
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Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00500G, Research Article
Qingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang Tao
Recently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Deciphering the active species and reaction mechanism in water oxidation catalyzed by a copper complex with redox-active ligands

Inorg. Chem. Front., 2024, 11,2365-2372
DOI: 10.1039/D4QI00163J, Research Article
Qing Fan, Cong Yang, Mengdi Li, Chen Wang, Guixia Wang, Xiangfei Kong, Qiping Zhu
This theoretical study unveils active species and the reaction mechanism in electrochemical water oxidation catalyzed by a copper complex with redox-active ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan

Inorg. Chem. Front., 2024, 11,2402-2412
DOI: 10.1039/D3QI02662K, Research Article
Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
Two isostructural homochiral MOFs exhibit significantly different enantioselective recognition performances closely associated with the different coordination habits of the metal centers in the MOFs.
The content of this RSS Feed (c) The Royal Society of Chemistry




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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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New Ultraviolet Transparent Rare-Earth Borates with Enhanced Birefringence Induced by Cation Chemical Substitution

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00840E, Research Article
Guanglian Sun, xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu
Birefringence determined by optical anisotropy is one of the most pivotal and fundamental performance of optical materials. However, optimizing the birefringence remains a significant challenge. Herein, a simple and effective...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00490F, Research Article
Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
β-Ga2O3 photodetectors achieve ultrahigh responsivity under low supply voltage and ultralow light intensity conditions via band engineering with polar Hf0.5Zr0.5O2 as an insert layer.
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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
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A wheel-like polyoxometalate for haloperoxidase inspired antibiofouling with H2O2 in-situ provided by electrocatalysis

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00482E, Research Article
Yumeng Bian, Runze Wang, xinxin xu, Jin Chen, Qiang Wang
Biofouling is adhering of micro-organisms on submerged surfaces, which is a common phenomenon presents serious hazard to industry and public health. Nanozymes with haloperoxidase mimic activity are promising options to...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00771A, Research Article
Xuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong Guo
X-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reservoirs with less than 50% storage down to single digit

Key dams’ water level unchanged at 87% of capacity this week




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Down the AI rabbit hole, strewn with health benefits and ethical pitfalls 

Regulatory frameworks covering AI need fine-tuning to harness its potential without halting growth 




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COPing with cascading health concerns that climate change brings to our doorstep

Climate and Health: A global challenge needs a local solution to build resilient health systems




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Tennis, yoga and unwinding with a book

Ritesh Kumar’s daily routine includes yoga, a plant-based diet, contemplation, tennis, and unwinding with a good book.




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Walks, conscious nutrition and switching off with Buzo

Akshay Chaturvedi, Founder CEO of Leverage.biz, shares tips on health, fitness and his beloved German shepherd




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Breaking down ‘patent thickets’ without smothering innovation

With recent patent-linked rejections, governments push back on big pharma’s strategy




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Syngenta signs MoUs with CSSRI and HAU on crop productivity, sustainable agriculture

MoUs aim to implement projects related to capacity building of rural youth in agriculture and allied sciences, safe use of crop protection chemicals and adoption of new technologies, among other things




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India-US farm trade to get a boost with Trump’s comeback

Experts predict an increase in India’s exports, including tea, coffee, and spices, while imports of American farm products like tree nuts and fresh fruits are also likely to rise




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Govt withdraws sugar stock disclosure order citing comfortable domestic availability

Food Ministry says sufficient quantity of sugar is available in the country to meet the domestic demand throughout the year after reviewing prices and availability of the sweetener




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Skye Air intensifies quick-commerce partnerships, targets expansion to six cities within two years

The firm focuses on delivering consignments within 10 minutes for quick-commerce clients and within four hours for e-commerce clients




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Cochin International Airport announces winter schedule with 1,576 weekly operations 

As per the new winter schedule, the total number of weekly services to UAE alone will be 134




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Gujarat HC orders release of SW South Wind I after pact with exporting firm

Two more arrest orders are pending against the vessel




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MHI to consult with Ministry of Health again for guidelines on e-ambulances

Ministry says companies like Force Motors, Maruti Suzuki, Tata Motors and Toyota ready to manufacture e-ambulances under the Scheme




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Kandla Port plans new container terminal and multipurpose berth with ₹27,000 crore investment

Positioned strategically between Tuna Tekra and the entry point of Kandla, the proposed site could help vessels avoid an 11-kilometer trek through the creek, providing cost advantages




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Cyient DLM signs pact with Honeywell Aerospace Technologies

Cyient DLM The company signs a 16-year programme forecast to develop liquid cooling loops that will be used in select applications of Micro VCS




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Chennai now directly connected by air with Brunei

Brunei’s national airline will fly3three times a week between Brunei and Chennai on Tuesdays, Thursdays and Saturdays




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Air India sets up war room for a smooth merger with Vistara

Vistara chief commercial officer Deepak Rajawat named AI Express CFO in a management rejig, Vistara CEO Vinod Kannan will continue to hold the role of chief integration officer




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Faced with revenue headwinds, airlines go extra mile to win customers

These initiatives come amid increased capacity and intensified competition in the Indian skies




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Vistara bids adieu with last flight to Singapore; integrated Air India takes to the skies

UK115 flight from Delhi to Singapore was the last flight of Vistara with the code 'UK' while UK986 from Mumbai to Delhi was the carrier's last domestic flight




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Wipro inks $700-million takeover deal with Metro AG




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Fino Payments Bank goes live with enhanced deposit limit of ₹2 lakh

Move in line with the revised guidelines announced by RBI




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Tech Mahindra partners with OxygenForIndia to deploy 3,000 oxygen concentrators and 40,000 oxygen cylinders

The OxygenForIndia campaign is aimed at providing oxygen cylinders to those in need




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PayPoint partners with Digit General Insurance for health insurance to rural areas

The insurance covers pre-hospitalisation and post-hospitalization expenses along with road ambulance charges




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IPO: Sresta Natural Bioproducts files draft papers with SEBI

The IPO comprises a fresh issue of equity shares aggregating up to ₹50 crore and an offer sale of up to 70.3 lakh equity shares




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Brimming with devotion

Young musicians made waves at the annual Navarathri Sangeetholsavam at Sree Erinjeri Karthyayani temple, Thrissur.




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Dance from within

Performances by Kathak prodigy Protyasha and Manipuri by Sudip Ghosh impressed, writes Gudipoodi Srihari.




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A band with the right mix

Indian Ocean on surviving two decades and rising above their lows




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On August 15, Carnegie Hall echoed with Eastern and Western musical notes

Festival of India@75 brought together stalwart musicians to celebrate the freedom of musical expression




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Donor-modified asymmetric N/B/O multi-resonance TADF emitters for high-performance deep-blue OLEDs with the BT.2020 color gamut

Chem. Sci., 2024, 15,18135-18145
DOI: 10.1039/D4SC04896B, Edge Article
Open Access
Jing Jin, Zhaolong He, Di Liu, Yongqiang Mei, Jiahui Wang, Huihui Wan, Jiuyan Li
Spiro-acridine modified N/B/O type MR-TADF emitters realized deep blue fluorescence with an EQEmax of 20.5% and CIE (0.147, 0.048), which is state-of-the-art efficiency for N/B/O type deep-blue MR emitters with CIEy approaching the BT.2020 standard.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemoenzymatic multistep retrosynthesis with transformer loops

Chem. Sci., 2024, 15,18031-18047
DOI: 10.1039/D4SC02408G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Kreutter, Jean-Louis Reymond
Integrating enzymatic reactions into computer-aided synthesis planning (CASP) should help devise more selective, economical, and greener synthetic routes.
The content of this RSS Feed (c) The Royal Society of Chemistry