radical Turkey Needs Radical New Direction to Save the Economy By www.chathamhouse.org Published On :: Mon, 23 Nov 2020 15:45:06 +0000 Turkey Needs Radical New Direction to Save the Economy Expert comment NCapeling 23 November 2020 Turkey should emulate the reformist approach it adopted after the 2001 crisis to prevent an economic and financial breakdown - but this looks highly unlikely. Although Ankara has witnessed what appears to be an abrupt change of its top economic team with two fresh appointments to key positions – Naci Ağbal as governor of the central bank and Lütfi Elvan as finance and treasury minister – a cardinal rule of thumb in Turkish politics is that the more drama one sees, the less policy change there will actually be. Financial markets reacted positively to the moves in the expectation they will signal a change of Turkey’s overall economic approach, but the reality is Turkish president Recep Tayyip Erdoğan is simply putting loyalists into key bureaucratic positions to help ensure the primary role of these functions becomes ‘selling’ his policies more effectively, rather than altering them. The hope from the markets – which saw the beleaguered Turkish lira appreciate against the US dollar at the news – is that Turkey adopts substantial interest rate increases as well as measures to repress liquidity expansion in order to temper its controversial so-called ‘Triple C’ approach of using cheap credit to stimulate growth with an unsustainable consumption and construction boom. But instead, Erdoğan’s declaration after the appointments were made indicates the new restrictions in which they will now operate, saying ‘we are in a historic struggle against those who want to force Turkey into modern capitulations through the shackles of interest rates, foreign exchange rates and inflation’. Learn from past successes To resolve its current underlying economic problems, Turkey should actually be looking to its recent past and aiming to emulate the approach pursued by former prime minister Bülent Ecevit during the 2001 financial crisis when he recruited Kemal Derviş, a senior World Bank official with extensive experience and international contacts in economic, financial, and monetary affairs. As economy minister with a broad mandate to spearhead a durable economic recovery plan, Dervis established independent market regulatory agencies covering banking, telecommunications, energy, and other key sectors, and strengthened the competition authority. He also either liquidated or merged insolvent banks, granted central bank autonomy to guarantee price stability, and ensured recruitment was based on competence, expertise, and meritocracy. Crucially, his productivity-enhancing restructuring blueprint was designed in Turkey rather than being imposed by the International Monetary Fund (IMF) or another external agency. Ecevit also turbocharged reforms motivated in part by a desire to join the EU with constitutional, political and legal modernization which widened personal freedom, significantly curtailed capital punishment, liberalized the cultural environment for Kurds, and fortified the rule of law. And one of his coalition partners in that work, the right-wing pro-Turkish National Action Party (MHP), is now allied with the current ruling Justice and Development Party (AKP). His foreign minister Ismail Cem also enhanced Turkey’s relations with both Europe and the US, initiated the so-called ‘earthquake diplomacy’ with his Greek counterpart George Papandreou after twin tragedies struck both nations in 1999, and largely avoided entanglement in Middle Eastern conflicts. The net result of all these actions was that Turkey emerged from the crisis with greater resilience, a more robust regulatory framework, upgraded political and economic institutions, rapidly decreasing inflation, a credible central bank, a stronger financial system, closer relations with the EU and US, and heightened domestic and foreign investor confidence. But now that similar woes are engulfing Turkey anew, is Erdogan and the AKP/MHP alliance able – and willing – to repeat the Ecevit recipe? Present signs indicate they are highly unlikely to as they are too committed to entrenching the Triple C model. Although this model will likely further consolidate their power, it will also empty the civil service of qualified professionals, restrict civil liberties and freedoms, and create more ideological politics, affecting Turkey’s foreign policy. Such a stubborn refusal to shift direction is increasing the inevitability of a deep economic and financial breakdown and so, unless Turkey undertakes a serious policy departure instead of continuing to resort to the quick fix approach, there is real likelihood it will simply accelerate towards disaster. Full Article
radical Association of Free-to-Total PSA Ratio and 18F-DCFPyL Prostate-Specific Membrane Antigen PET/CT Findings in Patients with Biochemical Recurrence After Radical Prostatectomy: A Prospective Single-Center Study By jnm.snmjournals.org Published On :: 2024-11-01T04:25:31-07:00 In Canada and across the globe, access to PSMA PET/CT is limited and expensive. For patients with biochemical recurrence (BCR) after treatment for prostate cancer, novel strategies are needed to better stratify patients who may or may not benefit from a PSMA PET scan. The role of the free-to-total prostate-specific antigen (PSA) ratio (FPSAR) in posttreatment prostate cancer, specifically in the PSMA PET/CT era, remains unknown. Our aim in this study was to determine the association of FPSAR in patients referred for 18F-DCFPyL PSMA PET/CT in the BCR setting and assess the correlation between FPSAR and 18F-DCFPyL PSMA PET/CT positivity (local recurrence or distant metastases). Methods: This prospective study included 137 patients who were referred for 18F-DCFPyL PSMA PET/CT and had BCR with a total PSA of less than 1 ng/mL after radical prostatectomy (RP) (including adjuvant or salvage radiotherapy). Blood samples were collected on the day of 18F-DCFPyL PSMA PET/CT. FPSAR was categorized as less than 0.10 or as 0.10 or more. A positive 18F-DCFPyL PSMA PET/CT scan was defined by a PROMISE classification lesion score of 2 or 3, irrespective of the site of increased tracer uptake (e.g., prostate, pelvic nodes, bone, or viscera). Results: Overall, 137 blood samples of patients with BCR after RP were analyzed to calculate FPSAR. The median age at 18F-DCFPyL PSMA PET/CT was 68.6 y (interquartile range, 63.0–72.4 y), and the median PSA at 18F-DCFPyL PSMA PET/CT was 0.3 ng/mL (interquartile range, 0.3–0.6 ng/mL). Eighty-six patients (62.8%) had an FPSAR of less than 0.10, whereas 51 patients (37.2%) had an FPSAR of 0.10 or more. An FPSAR of 0.10 or more was identified as an independent predictor of a positive 18F-DCFPyL PSMA PET/CT scan, with an odds ratio of 6.99 (95% CI, 2.96–16.51; P < 0.001). Conclusion: An FPSAR of 0.10 or more after RP independently correlated with increased odds of a positive 18F-DCFPyL PSMA PET/CT scan among BCR post-RP patients. These findings may offer an inexpensive method by which to triage access to 18F-DCFPyL PSMA PET/CT in jurisdictions where availability is not replete. Full Article
radical ‘War Games’ on Trump Return Reveal Radical Left’s Plans to Counter ‘Autocratic Threats’ By www.breitbart.com Published On :: Wed, 13 Nov 2024 01:21:01 +0000 Recent simulations conducted by left-leaning anti-Trump experts envision the U.S. facing an unprecedented erosion of democratic norms under a second Trump administration, according to Transition Integrity Project co-founder Rosa Brooks, who suggested the recent “war games” demonstrated the need for “creative” resistance and “harm reduction” tactics to counter what she describes as “autocratic” maneuvers President Donald Trump would employ. The post ‘War Games’ on Trump Return Reveal Radical Left’s Plans to Counter ‘Autocratic Threats’ appeared first on Breitbart. Full Article 2024 Election Media Politics 2024 Presidential Election autocracy Brennan Center for Justice Civil Liberties democracy Donald Trump Protests resistance Rosa Brooks The New Republic Transition Integrity Project Trump Administration war games
radical Qu'est-ce que «4B», le mouvement radical féministe sud-coréen devenu viral aux États-Unis depuis la victoire de Donald Trump? By www.journaldemontreal.com Published On :: Tue, 12 Nov 2024 19:49:48 EST Non aux rencontres amoureuses, au sexe, au mariage ou à élever des enfants avec un homme. Full Article
radical Classification and quantitative characterisation of the excited states of π-conjugated diradicals By pubs.rsc.org Published On :: Faraday Discuss., 2024, 254,107-129DOI: 10.1039/D4FD00055B, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lujo Matasović, Hugo Bronstein, Richard H. Friend, Felix PlasserA detailed classification scheme for the excited states of diradicals is presented highlighting the connections between the states of closed-shell and open-shell molecules.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Radical Play : Revolutionizing Children's Toys in 1960s and 1970s America [Electronic book] / Rob Goldberg. By encore.st-andrews.ac.uk Published On :: Durham : Duke University Press, [2023] Full Article
radical Figures of Radical Absence : Blanks and Voids in Theory, Literature, and the Arts [Electronic book] / Alexandra-Ecaterina Irimia. By encore.st-andrews.ac.uk Published On :: Berlin ; Boston : De Gruyter, [2023] Full Article
radical Strategic pathway selection for photocatalytic degradation: roles of holes and radicals By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI01635A, Review ArticleYixuan Li, Xu Gao, Yuxin LiAs global resources become scarce and environmental issues become increasingly severe, developing photocatalytic technology for efficiently and cleanly degrading pollutants has become a research trend.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI02072C, Research ArticleXin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li ZhangA new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Transesterification or polymerization? Reaction mechanism and kinetics of 2-(diethylamino)ethyl methacrylate with methanol and the competitive effect on free-radical polymerization By pubs.rsc.org Published On :: React. Chem. Eng., 2024, Advance ArticleDOI: 10.1039/D4RE00406J, PaperJudith Cabello-Romero, Román Torres-Lubián, Javier Francisco Enríquez-Medrano, Adrián Ochoa-Terán, Jesús Jara-Cortés, Iván Zapata-GonzálezTransesterification of 2-(diethylamino)ethyl methacrylate (DEAEMA) with methanol leads to the formation of methyl methacrylate (MMA) and amino alcohol. This reaction significantly affects DEAEMA polymerization giving rise to poly(DEAEMA-co-MMA).To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Kinetic and reactivity of gas-phase reaction of acyclic dienes with hydroxyl radical in the 273–318 K temperature range By pubs.rsc.org Published On :: RSC Adv., 2024, 14,12303-12312DOI: 10.1039/D3RA08750F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng YangThe relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines By pubs.rsc.org Published On :: RSC Adv., 2024, 14,12556-12560DOI: 10.1039/D4RA01914H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling LuAn electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Rational design of a lysosome-targeted fluorescent probe for monitoring the generation of hydroxyl radicals in ferroptosis pathways By pubs.rsc.org Published On :: RSC Adv., 2024, 14,12864-12872DOI: 10.1039/D4RA00562G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lili Zhong, Datian Fu, Jin Xu, Linyan Tan, Haimei Wu, Min WangA novel hydrocyanine-based turn-on fluorescence probe HCy-Lyso, with excellent lysosome-targeting ability and ˙OH-responsive efficiency, has been applied for monitoring the variation in lysosomal ˙OH levels during ferroptosis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization By pubs.rsc.org Published On :: Polym. Chem., 2024, 15,4244-4254DOI: 10.1039/D4PY00931B, PaperMuhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed AkhterThis study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation By pubs.rsc.org Published On :: Polym. Chem., 2024, 15,4264-4280DOI: 10.1039/D4PY00899E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof MatyjaszewskiHeterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing By pubs.rsc.org Published On :: Polym. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4PY00926F, PaperYangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques LalevéeAbstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Alternating Radical Copolymerization of α-Styrylboronic Acid Pinacol Ester with Electron-Deficient Olefins By pubs.rsc.org Published On :: Polym. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4PY00976B, PaperYiyang Xiao, Zepeng Zhang, Yan Xu, Jianbo WangHere, α-styryl boronic acid pinacol ester (StBpin) has been found to undergo alternating radical copolymerization with electron-deficient olefin comonomers, including n-butyl acrylate, N,N-dimethylacrylamide, acrylonitrile, and N-ethylmaleimide. Compared with styrene, which...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Acrylate–methacrylate radical copolymerization kinetics of sparingly water-soluble monomers in polar and nonpolar solvents By pubs.rsc.org Published On :: Polym. Chem., 2024, 15,4542-4553DOI: 10.1039/D4PY01015A, PaperNoushin Rajabalinia, Fatemeh Salarhosseini, Robin A. HutchinsonThe influence of solvent on radical copolymerization kinetics is studied to provide insight to emulsion polymerization systems.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Lactobionic acid modified cobalt coordination polymer-coated peroxymonosulfate nanoparticles generate sulfate/hydroxy dual-radicals for targeted cancer therapy By pubs.rsc.org Published On :: J. Mater. Chem. B, 2024, Advance ArticleDOI: 10.1039/D4TB01777C, PaperJiahui Li, Jiaxuan Li, Zelong Chen, Yichen Wan, Yi Wang, Zhichao Pei, Yuxin PeiLCP NPs were prepared by forming a coordination polymer on peroxymonosulfate through the coordination between imidazole-2-carboxaldehyde and Co2+, then modified with lactobionic acid to improve the efficacy of sulfate/hydroxy dual-radical therapy.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Research Progress of Nitroxide Radical-Based MRI Contrast Agents: From Structure Design to Application By pubs.rsc.org Published On :: J. Mater. Chem. B, 2024, Accepted ManuscriptDOI: 10.1039/D4TB02272F, Review ArticleTao Luo, Bo Wang, Runxin Chen, Qi Qi, Ruodai Wu, Shunzi Xie, Hanbing Chen, Jialei Han, Dalin Wu, Shuaishuai CaoMagnetic resonance imaging (MRI) remains a cornerstone of diagnostic imaging, offering unparalleled insights into anatomical structures and pathological conditions. Gadolinium-based contrast agents have long been the standard in MRI enhancement,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Comparing coupled cluster and composite quantum chemical methods for computing activation energies and reaction enthalpies of radical propagation reactions By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27536-27543DOI: 10.1039/D4CP03676J, PaperTimothy B. Huber, Ralph A. WheelerThe accuracy of DLPNO-CCSD(T)/CBS and composite methods G3(MP2)-RAD and CBS-RAD is assessed against CCSD(T)/aug-cc-pVTZ for activation energies and reaction enthalpies in hydrocarbon radical addition reactions relevant to free radical polymerization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27669-27676DOI: 10.1039/D4CP03506B, PaperChing-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki EndoPure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Performance of functionalized graphene oxide with organic radical scavengers in proton exchange membranes By pubs.rsc.org Published On :: Phys. Chem. Chem. Phys., 2024, 26,27817-27828DOI: 10.1039/D4CP03151B, PaperYu Hu, Jiaxing Wang, Shuai Wang, Yuan FengA diazonium salt reaction is used to prepare benzoic acid-functionalized graphene oxide as a bi-functional filler for a Nafion membrane, and the corresponding composite membrane has improved chemical durability and proton conductivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond By pubs.rsc.org Published On :: Chem. Soc. Rev., 2024, Advance ArticleDOI: 10.1039/D3CS00889D, Review ArticleMikhail O. Zubkov, Alexander D. DilmanThe review summarizes advances in the radical chemistry of polyfluorinated arenes under photocatalytic conditions. The fluoroaryl fragment serves as enabling motif for the reaction design and efficient generation of reactive intermediates.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Radical anions of 1,1-azoliumdithiocarboxylates By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC05486E, CommunicationMartin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo RadiusThe 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization By pubs.rsc.org Published On :: Chem. Commun., 2024, Accepted ManuscriptDOI: 10.1039/D4CC04470C, CommunicationYuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai ZhaoPhotoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons By pubs.rsc.org Published On :: New J. Chem., 2024, Advance ArticleDOI: 10.1039/D4NJ00555D, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tomohito Shinozuka, Daiki Shimizu, Kenji MatsudaRadical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate By pubs.rsc.org Published On :: CrystEngComm, 2024, 26,1962-1975DOI: 10.1039/D4CE00099D, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee MartinWe present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical On the mechanism of carboxylate elimination from carbohydrate monoester-derived radicals By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00241E, Communication Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julia A. Turner, Hendrik Zipse, Mark S. TaylorComputational analysis of the HAT-induced expulsion of carboxylic acids from monoacylated pyranosides implicates concerted elimination through a hydrogen-bonded transition state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Catalyst- and base-free visible light-enabled radical relay trihalomethylation/functional group-migration/carbonylation with CX3SO2Cl By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00292J, PaperJinkai Hu, Chenglei Yang, Xiaotao Qin, Hui Liu, Tongtong Ma, Ao-tong Shi, Qing-Long Lv, Xingman Liu, Jinhui Yang, Dianjun LiA visible light-enabled photocatalyst-free radical trihalomethylation/cyano (or benzo[d]thiazol-2-yl) 1,4-migration/carbonylation reaction of 2-hydroxy-2-hex-5-enenitrile (or (benzo[d]thiazol-2-yl)-pent-4-enol) with CX3SO2Cl (X = F, Cl) is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, 22,2968-2973DOI: 10.1039/D4OB00129J, CommunicationXin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai WangAn Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical A Highly Diastereoselective One-Pot Ugi/Radical Spirocyclization/Aza-Michael Addition Sequence By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Accepted ManuscriptDOI: 10.1039/D4OB00610K, CommunicationChandra Volla, Salman Khan, Abhradeep Chatterjee, Akshay Murali NairWe hereby report a highly diastereoselective synthesis of chalcogenated azaspirotricycles via a one-pot Ugi/spirocyclization/ aza-Michael addition sequence. The reaction proceeded via a key visible light mediated spirocyclization step under mild,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction By pubs.rsc.org Published On :: Org. Biomol. Chem., 2024, Advance ArticleDOI: 10.1039/D4OB00363B, PaperSi-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong XieA three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Ov-rich γ-MnO2 enhanced electrocatalytic three-electron oxygen reduction to hydroxyl radicals for sterilization in neutral media By pubs.rsc.org Published On :: Nanoscale Horiz., 2024, 9,1999-2006DOI: 10.1039/D4NH00289J, CommunicationYingnan Qin, Tongzhu Han, Ligang Chen, Kexin Yan, Jing Wang, Ning Wang, Baorong HouThe synergistic interaction between Ov and γ-MnO2 significantly enhanced the performance of the neutral 3e− ORR, exhibiting impressive sterilization capabilities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Terrorist Attacks, Cultural Incidents and the Vote for Radical Parties: Analyzing Text from Twitter [electronic journal]. By encore.st-andrews.ac.uk Published On :: National Bureau of Economic Research Full Article
radical CuBr-mediated surface-initiated controlled radical polymerization in air By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06012A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Menglu Chen, Shuai You, Tingting Guo, Haohao Ren, Longzu Zhu, Peize Wang, Wenbo Sheng, Chenliang Gong, Wei LiCuBr-mediated surface-initiated controlled radical polymerization for polymer brushes with patterned and block architectures over large areas in air is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Simultaneous generation of hydroxyl and hydrogen radicals from H+/OH− pairs caused by water–solid contact electrification By pubs.rsc.org Published On :: Chem. Sci., 2024, Advance ArticleDOI: 10.1039/D4SC06227B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fengjie Chen, Jingde Wu, Dou Wang, Yu Xia, Qingyuan Song, Ying Liang, Pu Wang, Bolei Chen, Yong Liang, Yongguang Yin, Yawei Wang, Maoyong Song, Guibin JiangWater–solid contact electrification is a common physical phenomenon involving interfacial electron and ion transfer, recently discovered to trigger unique redox reactions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Manipur Police accuse radical outfit Arambai Tengol of extortion, assault By www.thehindu.com Published On :: Thu, 29 Feb 2024 21:29:32 +0530 Terming the abduction of an officer “unprecedented”, police in valley and hill districts ask for more forces of Assam Rifles, fearing a breach of peace due to the movement of armed civilians, underground outfits Full Article India
radical 604: VS Code Plugins, Git as a Radical Statement, Tailwind & Arc Drama By shoptalkshow.com Published On :: Mon, 26 Feb 2024 09:43:06 +0000 A follow up on jQuery conversation, Microsoft owning all the things, what VS Code plugins are your ride or die, the ability to Git from wherever you want, Tailwind drama, global design system follow up, Arc Search gets roasted, and Frontend Design Conference is back! Full Article All Episodes global design systems microsoft tailwind vs code
radical Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01382D, Research ArticleAjay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha MoorthyAn IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Unravelling the different pathways of cyclohexene oxidation via a peroxyl radical generated from tert-butyl hydroperoxide (TBHP) by various metal salts By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01681E, Research ArticleLu-Jian Zhou, Xiao-Hui Liu, Han-Wen Zhang, Can Xue, Han-Kang Zhong, Xian-Tai ZhouTwo different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl2 and VCl3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t-BuOO˙ radical in catalytic oxidations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Intermediate diradical character and thermal cis–trans isomerization of near-infrared absorbing thionated squaraine dyes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01722F, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Taishi Oka, Takeshi Maeda, Daisuke Sakamaki, Naoya Suzuki, Shigeyuki Yagi, Shintaro Kodama, Hideki FujiwaraNear-infrared absorbing squaraine dyes incorporating 4-membered thionated oxocarbon and chalcogenopyrylium moieties exhibit intermediate diradical character, which impacts thermal cis–trans isomerization.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Visible-light excited copper activating unactivated alkyl iodides for radical addition/cyclization to access oxindole derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6380-6384DOI: 10.1039/D4QO01329H, Research ArticleHang Luo, Fangnian Yu, Luqing LinThe photocopper catalyst facilitates halogen atom transfer to give unactivated alkyl radicals, which is critical for achieving radical cyclization in the absence of an exogenous photocatalyst.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Anomalous magnetic behaviour induced by a structural phase transition with anisotropic thermal expansion in a spirodiradical By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6495-6502DOI: 10.1039/D4QO01098A, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Takuya Kanetomo, Daigo Matsunaga, Shinichi Ogawa, Masaya EnomotoA Ge-centred spirodiradical exhibited anomalous magnetic behaviour, influenced by two key structural factors: negative thermal expansion and a structural phase transition.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01827C, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu ChenMechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Folding of a dynamic macrocyclic system to stabilize its cation radical state By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01566E, Research ArticleArnab Dutta, Krzysztof Dzieszkowski, Marco Farinone, Łukasz Orzeł, Krzysztof Kruczała, Monika Kijewska, Miłosz PawlickiA precisely designed π-extended system responds to different stimuli by folding the structure, which prevents overoxidation and stabilizes the cation radical.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Complexes between 2,2'-azobis(2-methylpropionamidine) dihydrochloride (AAPH) and cucurbit[n]uril hosts modulate the yield and fate of photolytically-generated AAPH radicals By pubs.rsc.org Published On :: RSC Adv., 2024, 14,35980-35991DOI: 10.1039/D4RA07150F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Angie C. Forero-Girón, Mauricio Oyarzún, Kevin Droguett, Denis Fuentealba, Soledad Gutiérrez-Oliva, Barbara Herrera, Alejandro Toro-Labbé, Eduardo Fuentes-Lemus, Michael J. Davies, Camilo López-Alarcón, Margarita E. AliagaAAPH-cucurbit[n]uril systems were experimentally and theoretically studied. Radical yields formed upon photolysis of AAPH were altered by complexation with CB[8] in a stoichiometry-dependent manner, however, radical yields were not changed by CB[6].The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical Paris Olympics 2024 | Inside the radical transformation in Indian sports and the making of a medal-winning champion By www.thehindu.com Published On :: Fri, 05 Jul 2024 12:50:00 +0530 Over the last decade, not-for-profit organisations as well as private academies and training centres have come forward to train Indian athletes, bringing them on a par with global standards Full Article Sport
radical Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18047-18053DOI: 10.1039/D4DT02567A, PaperHui Li, He ZhengInsights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
radical One-pot synthesis of conjugated vinylene-extended viologen ionic radical polyacetylenes for visible light-promoted photocatalytic CO2 cycloaddition By pubs.rsc.org Published On :: Green Chem., 2024, 26,10876-10885DOI: 10.1039/D4GC03683B, PaperYanan Chang, Shuo Wang, Juan Chen, Zixuan Xu, Qing Shi, Yunjie Mao, Yanli Gai, Zhouyang Long, Guojian ChenIn situ synthesis of a conjugated vinylene-extended viologen ionic radical polyacetylene (VIRP-2) for visible light-promoted photocatalytic CO2 cycloaddition under ambient conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article