radical

Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00322K, Paper
Haoyu Yu, Jianwei Shao, Dong Chen, Li Wang, Wantai Yang
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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radical

Online Tracing of Molecular Weight Evolution during Radical Polymerization via high-resolution FlowNMR spectroscopy

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00475H, Communication
Jeroen Hendrik Vrijsen, Isabel Anna Thomlinson, Martin Levere, Catherine L Lyall, Matthew G Davidson, Ulrich Hintermair, Tanja Junkers
High-resolution FlowNMR was coupled to a continuous flow reactor to monitor polymer molecular weight evolution online by diffusion ordered NMR spectroscopy. Polymers were synthesized by reversible addition fragmentation chain transfer...
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radical

Diphenyl Functional Porphyrins and Their Metal Complexes as Visible-Light Photoinitiators for Free-Radical, Cationic and Thiol-Ene Polymerizations

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00468E, Paper
Davy-Louis Versace, Yusuf Yagci, Agata Blacha-Grzechnik, Nicolas Bogliotti, V. Brezova, Jean-Pierre Malval, Marc Presset, Hugo Marcille
This investigation demonstrates the excellent photoinitiating properties of novel visible-light absorbing diphenylporphyrins (DPPs) for the free-radical (FRP), cationic (CP) and thiol-ene polymerizations under visible LEDs irradiation (405 and 530 nm)...
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radical

Content Inc.: how entrepreneurs use content to build massive audiences and create radically successful businesses / Joe Pulizzi

Dewey Library - HF5415.127.P8498 2016




radical

Medea muckt auf: Radikale Künstlerinnen hinter dem Eisernen Vorhang = The Medea insurrection: radical women artists behind the Iron Curtain / Herausgeber: Staatliche Kunstsammlungen Dresden, Susanne Altmann, Katarina Lozo, Hilke Wagner

Rotch Library - N8354.M43 2019




radical

A fragile inheritance: radical stakes in contemporary Indian art / Saloni Mathur

Rotch Library - N7304.M384 2019




radical

A heteroleptic diradical Cr(III) complex with extended spin delocalization and large intramolecular magnetic exchange

Chem. Commun., 2020, 56,4906-4909
DOI: 10.1039/D0CC00548G, Communication
Xiaozhou Ma, Elizaveta A. Suturina, Mathieu Rouzières, Fabrice Wilhelm, Andrei Rogalev, Rodolphe Clérac, Pierre Dechambenoit
Ligand-based successive reductions in a heteroleptic Cr(III) complex give rise to intended extremely strong metal–radical magnetic interactions.
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radical

A radical-mediated 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite: facile access to sulfonyl isoxazoles

Chem. Commun., 2020, Advance Article
DOI: 10.1039/D0CC01659D, Communication
Xin Yue, Ming Hu, Xingyi He, Shuang Wu, Jin-Heng Li
An unprecedented indium-promoted three-component 1,3,4-trifunctionalization cascade of 1,3-enynes with sulfinates and tert-butyl nitrite for producing 5-sulfonylisoxazoles via [3+2] annulation is reported.
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radical

Ring-opening iodination and bromination of unstrained cycloalkanols through β-scission of alkoxy radicals

Chem. Commun., 2020, 56,5002-5005
DOI: 10.1039/D0CC01720E, Communication
Jiang-Ling Shi, Yuankai Wang, Zixuan Wang, Bowen Dou, Jianbo Wang
Ring-opening iodination or bromination of unstrained cycloalkanols with NaI or NaBr and PhI(OAc)2 under visible light irradiation is developed.
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radical

Efficient generation of sulfate radicals in Fe (II)/S (IV) system induced by WS2 nanosheets and examined by its intrinsic chemiluminescence

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC01999B, Communication
Tong Sun, Yingying Su, Houjing Liu, Hongjie Song, Yi Lv
In this study, more 〖SO〗_4^( ∙-) and strong intrinsic chemiluminescence (CL) can be achieved through activating sulphite (〖SO〗_3^( 2-)) with ferrous ions (Fe2+) on the WS2 nanosheets with the thickness...
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radical

The quantum of explanation [electronic resource] : Whitehead's radical empiricism / Randall E. Auxier and Gary L. Herstein

Auxier, Randall E., 1961-




radical

Them goon rules: fugitive essays on radical Black feminism / Marquis Bey

Hayden Library - HQ1410.B49 2019




radical

American radicals: how nineteenth-century protest shaped the nation / Holly Jackson

Dewey Library - HN90.R3 J37 2019




radical

Militant acts: the role of investigations in radical political struggles / Marcelo Hoffman

Dewey Library - HN49.R33 H64 2019




radical

The radicalism of ethnomethodology: an assessment of sources and principles / Martyn Hammersley

Dewey Library - HM481.H36 2018




radical

Anti-Electra: the radical totem of the girl / Elisabeth von Samsonow ; translated by Anita Fricek and Stephen Zepke

Hayden Library - HQ1190.S2425 2019




radical

Postpolitics and the limits of nature: critical theory, moral authority, and radicalism in the anthropocene / Andy Scerri

Dewey Library - HN49.R33 S44 2019




radical

Take hold of our history: make America radical again / Harvey J. Kaye

Dewey Library - HN90.R3 K39 2020




radical

Cobalt-based Layered Double Hydroxides Revisited: evidence for an oxidizing radical generation

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00380H, Paper
Rafael dos Santos Macedo, Rodrigo Boni Fazzi, Ana Maria Da Costa Ferreira, Vera R._Leopoldo Constantino
Layered double hydroxides (LDHs) containing transition metal elements such as cobalt have been studied mainly for applications in electrochemical devices and as catalysts. Fundamental studies about Co-based LDHs are required...
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radical

Radical abundance: how a revolution in nanotechnology will change civilization / K. Eric Drexler

Dewey Library - T174.7.D745 2013




radical

Recent progress in (hetero)arene cation radical-based heteroarene modification

Org. Biomol. Chem., 2020, 18,2975-2990
DOI: 10.1039/D0OB00441C, Research Article
Hai-Lei Cui
This review summarizes the advances in heteroarene modification via transformations of in situ generated (hetero)arene cation radicals, ranging from 2010 to 2020.
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radical

Photocatalytic xanthate-based radical addition/cyclization reaction sequence toward 2-biphenyl isocyanides: synthesis of 6-alkylated phenanthridines

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00136H, Communication
Pedro López-Mendoza, Luis D. Miranda
A photocatalytic xanthate-based radical addition/cyclization reaction cascade toward 2-biphenylisocyanides is described as a practical and modular approach to 6-alkylated phenanthridines.
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radical

A silver-catalyzed radical ring-opening reaction of cyclopropanols with sulfonyl oxime ethers

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00055H, Paper
Xiaobao Zeng, Xin Wang, Yanan Zhang, Li Zhu, Yu Zhao
A simple and efficient method for the radical ring-opening reaction of cyclopropanols with sulfonyl oxime ethers catalyzed by AgNO3 is developed, affording γ-keto oxime ethers in moderate to good yields.
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radical

Lim: A Prosthetic That Radically Improves Lives

A new company called LIM is radically rethinking the way prosthetics fit the human body, so that wearers of artificial legs can walk farther than ever before.




radical

WIRED by Design - Radical Ideas for Reinventing College, From Stanford's D.School

Sarah Stein Greenberg at WIRED by Design, 2014. In partnership with Skywalker Sound, Marin County, CA. To learn more visit: live.wired.com




radical

SB 100 - Football Strategy's Radical, Tech-Fueled Revolution Has Begun

All those pretty plays designed by Vince Lombardi, Bill Walsh and Bill Belichick, and executed to perfection by Bart Starr, Joe Montana and Tom Brady will, in the future, be digitized and optimized into an ideal gameplan.




radical

This Radical Redesign Could Keep Gas Engines Pumping

Achates Power is reviving the century-old opposed piston layout to make gas-powered cars more efficient.




radical

Radical Markets: Glenn Weyl at WIRED25

Microsoft researcher and economics professor Glenn Weyl argues that we need to challenge fundamental institutions we take for granted, like private property and one-person-one-vote, to reduce inequality, increase productivity, and heal political divisions. A growing movement of entrepreneurs (especially in the blockchain space), artists, social activists, and researchers, is already helping achieve this vision of a richer and more cooperative society through what Weyl calls Radical Markets.




radical

[ASAP] Synthesis of Stable, High-SOMO Zwitterionic Radicals: Enabling Intermolecular Electron Transfer between Naphthalenediimides

Organic Letters
DOI: 10.1021/acs.orglett.0c01263




radical

[ASAP] Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process

Organic Letters
DOI: 10.1021/acs.orglett.0c01297




radical

From Spin-Crossover to Single Molecule Magnetism: Tuning Magnetic Properties of Co(II) bis-ferrocenylterpy Cations via Supramolecular Interactions with Organocyanide Radical Anions

J. Mater. Chem. C, 2020, Accepted Manuscript
DOI: 10.1039/D0TC00830C, Paper
Haomiao Xie, Kuduva R. Vignesh, Xuan Zhang, Kim R. Dunbar
TCNQ (7,7,8,8-Tetracyanoquinodimethane) anion-radical derivatives were used to fine tune the magnetic properties of the [CoII(Fctp)2]2+ (Fctp = 4'-(2-ferrocenyl)-2,2':6'2''-terpyridine) cation in the solid state. The cocrystallization of [CoII(Fctp)2]2+ with TCNQ⋅- yielded...
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radical

[ASAP] Poor Solvents Improve Yield of Grafting-Through Radical Polymerization of OEO<sub>19</sub>MA

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00245




radical

[ASAP] Atom Transfer Radical Polymerization of Acrylic and Methacrylic Acids: Preparation of Acidic Polymers with Various Architectures

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00246




radical

[ASAP] Aggregation-Induced Emission Active Polyacrylates via Cu-Mediated Reversible Deactivation Radical Polymerization with Bioimaging Applications

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00281




radical

Radical chemistry in oxidation flow reactors for atmospheric chemistry research

Chem. Soc. Rev., 2020, Advance Article
DOI: 10.1039/C9CS00766K, Review Article
Zhe Peng, Jose L. Jimenez
We summarize the studies on the chemistry in oxidation flow reactor and discuss its atmospheric relevance.
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radical

5 Companies Radically Shaped by the Faith of Their Owners

A vocation of ministry isn’t just for churches and nonprofits.




radical

Theoretical study of hydroxyl radical (OH˙) induced decomposition of tert-butyl methyl ether (MTBE)

Environ. Sci.: Processes Impacts, 2020, 22,1037-1044
DOI: 10.1039/C9EM00588A, Paper
Bassam S. Tawabini, Ole John Nielsen, Theis I. Sølling
We have characterized the various pathways for OH radical (OH˙) induced decomposition of tert-butyl methyl ether (MTBE) and found an oxidative pathway that leads to complete degradation under the prerequisite that OH radicals are present in excess.
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radical

[ASAP] Neutral Organic Radical Formation by Chemisorption on Metal Surfaces

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.0c00269




radical

[ASAP] Surface-Initiated Controlled Radical Polymerization Approach to In Situ Cross-Link Cellulose Nanofibrils with Inorganic Nanoparticles

Biomacromolecules
DOI: 10.1021/acs.biomac.0c00210




radical

The job: work and its future in a time of radical change / Ellen Ruppel Shell

Dewey Library - HD8072.5.S49 2018




radical

The body is not an apology: the power of radical self-love / Sonya Renee Taylor

Dewey Library - BF575.S37 T39 2018




radical

Corona pandemic presents the greatest opportunity for radical reforms: Arvind Virmani, ex CEA

"As 60% of the economy is already under lockdown, and some of this will take one or more quarters to be restored, any temporary adverse effects of policy change are even less than usual. At the same time the positive effects will start appearing as soon as the pandemic crisis is over," said the ex CEA in an interview with ET.




radical

[ASAP] Characterization and Water-Proton Longitudinal Relaxivities of Liposome-Type Radical Nanoparticles Prepared via a Supramolecular Approach

Langmuir
DOI: 10.1021/acs.langmuir.0c00610




radical

Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical

Inorg. Chem. Front., 2020, 7,1949-1956
DOI: 10.1039/D0QI00098A, Research Article
Juan Sun, Jing Xie, Licun Li, Jean-Pascal Sutter
New nitronyl nitroxide biradical-bridged 3d–4f chains have been constructed in which improved SCM behavior is observed.
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radical

Spin dynamics in radical pairs / Alan Lewis

Online Resource




radical

[ASAP] Visible-Light Photocatalytic Ozonation Using Graphitic C<sub>3</sub>N<sub>4</sub> Catalysts: A Hydroxyl Radical Manufacturer for Wastewater Treatment

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.9b00624




radical

[ASAP] When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

Accounts of Chemical Research
DOI: 10.1021/acs.accounts.0c00090




radical

Allylic C(sp3)–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00819B, Edge Article
Open Access
Jiaqi Jia, Rajesh Kancherla, Magnus Rueping, Long Huang
A new catalytic method for the direct alkylation of allylic C(sp3)–H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described.
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radical

Rapidly Self-deoxygenating Controlled Radical Polymerization in water via in-situ Disproportionation of Cu(I)

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01512A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Haddleton, Evelina Liarou, Yisong Han, Marc Walker, Ana Sanchez
The first rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(I)/Me6Tren in water towards Cu(II) and highly reactive Cu(0) leads to O2-free reaction environments within the first...
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radical

Mapping the multi-step mechanism of a photoredox catalyzed atom-transfer radical polymerization reaction by direct observation of the reactive intermediates

Chem. Sci., 2020, 11,4475-4481
DOI: 10.1039/D0SC01194K, Edge Article
Open Access
Luke Lewis-Borrell, Mahima Sneha, Aditi Bhattacherjee, Ian P. Clark, Andrew J. Orr-Ewing
Short-lived intermediates are tracked in real-time by transient absorption spectroscopy during a multi-step photoredox catalysed polymerization reaction.
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