El presidente de Castilla-La Mancha, Emiliano García-Page, ha mostrado su satisfacción por la decisión del Gobierno central de crear un Alto Comisionado destinado a agilizar la reconstrucción en las zonas afectadas por la reciente DANA (Depresión Aislada en Niveles Altos). Durante un discurso en Puertollano, García-Page expresó su confianza en que la Administración central no […]

Artículo publicado en : Page Celebra la Creación del Alto Comisionado y Exige al Estado Compromiso en la Restauración de los Cauces

With this Camisole, you can declare to your self that you are stylish, hip, cool, youthful and comfortable with whom you are by saying, "I am Not Old... I'm... Retro". - I am not old! I am Retro! Do you think you are old? Have you ever felt old? Just remember, you are only as old as you feel, you are only old if you let yourself feel old. Nowadays, with retro styles, retro attitudes and all things of the past being very hip, cool and popular, it is even easier not to feel old and not be old. Now is your chance to declare to yourself and to the world that you are not old. Declare to your self that you are stylish, hip, cool and comfortable with whom you are by saying, "I am Not Old... I'm... Retro". After all, you are not old, you are retro!

WARNING: Approach With Caution Camisole - Let other people know that you need to be approached with caution with the "WARNING: Approach With Caution" 3D Industrial Metal Looking Sign Mega Cool Shirts, Sweatshirts, Clocks, Stickers, Mugs And More. Makes an excellent gift for those that are slighty tempermental too!

University of South Australia PhD student Belinda Lees has explored how screenwriters could create more nuanced and complex child-free women protagonists in biopics, after uncovering the barrage of often negative portrayals in existing media.

In the crystal structure of the title compound, {[Co(C11H9NSO5)(C10H9N3)]0.5C3H7NO·H2O}n or {[Co(dmtb)(dpa)]·0.5DMF·H2O}n (dmtb2– = 5-[(di­meth­yl­amino)­thioxometh­oxy]-1,3-benzene­dicarboxyl­ate and dpa = 4,4'-di­pyridyl­amine), an assembly of periodic [Co(C11H9NSO5)(C10H9N3)]n layers extending parallel to the bc plane is present. Each layer is constituted by distorted [CoO4N2] octa­hedra, which are connected through the μ2-coordination modes of both dmtb2– and dpa ligands. Occupationally disordered water and di­meth­yl­formamide (DMF) solvent mol­ecules are located in the voids of the network to which they are connected through hydrogen-bonding inter­actions.

The title compound, [Ag2(C19H20N2)4]Cl·0.5C2H4Cl2, can be readily generated by treatment of (1-benzyl-3-(2,4,6-tri­methyl­phen­yl)imidazolium chloride with sodium bis­(tri­methyl­sil­yl)amide followed by silver chloride. The mol­ecular structure of the compound was confirmed using NMR spectroscopy and single-crystal X-ray diffraction analysis. The crystal structure of the title compound at 110 K has monoclinic (P21/c) symmetry. The represented silver compound is of inter­est with respect to anti­bacterial properties and the structure displays a series of weak inter­molecular hydrogen-bonding inter­actions with the chloride counter-anion.

A new triazole-based N-heterocyclic carbene IrI cationic complex with a tetra­fluorido­borate counter-anion and hemi-solvating di­chloro­methane, [Ir(C8H12)(C8H15N3)(C18H15P)]BF4·0.5CH2Cl2, has been synthesized and structurally characterized. There are two independent ion pairs in the asymmetric unit and one di­chloro­methane solvent mol­ecule per two ion pairs. The cationic complex exhibits a distorted square-planar conformation around the IrI atom, formed by a bidentate cyclo­octa-1,5,diene (COD) ligand, a tri­phenyl­phosphane ligand, and an N-heterocyclic carbene (NHC). There are several close non-standard H⋯F hydrogen-bonding inter­actions that orient the tetra­fluorido­borate anions with respect to the IrI complex mol­ecules. The complex shows promising catalytic activity in transfer hydrogenation reactions. The structure was refined as a non-merohedral twin, and one of the COD mol­ecules is statistically disordered.

The asymmetric unit of the title compound, 2C31H28N2O4S·C2H6O, contains a parent mol­ecule and a half mol­ecule of ethanol solvent. The main compound stabilizes its mol­ecular conformation by forming a ring with an R12(7) motif with the ethanol solvent mol­ecule. In the crystal, mol­ecules are connected by C—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C—H⋯π inter­actions also strengthen the mol­ecular packing.

Reaction of copper(I)chloride with 2,3-di­methyl­pyrazine in ethanol leads to the formation of the title compound, poly[[μ-chlorido-μ-(2,3-di­methyl­pyrazine)-copper(I)] ethanol hemisolvate], {[CuCl(C6H8N2)]·0.5C2H5OH}n or CuCl(2,3-di­methyl­pyrazine) ethanol hemisolvate. Its asymmetric unit consists of two crystallographically independent copper cations, two chloride anions and two 2,3-di­methyl­pyrazine ligands as well as one ethanol solvate mol­ecule in general positions. The ethanol mol­ecule is disordered and was refined using a split model. The methyl H atoms of the 2,3-di­methyl­pyrazine ligands are also disordered and were refined in two orientations rotated by 60° relative to each other. In the crystal structure, each copper cation is tetra­hedrally coordinated by two N atoms of two bridging 2,3-di­methyl­pyrazine ligands and two μ-1,1-bridg­ing chloride anions. Each of the two copper cations are linked by pairs of bridging chloride anions into dinuclear units that are further linked into layers via bridging 2,3-di­methyl­pyrazine coligands. These layers are stacked in such a way that channels are formed in which the disordered solvent mol­ecules are located. The topology of this network is completely different from that observed in the two polymorphic modifications of CuCl(2,3-di­methyl­pyrazine) reported in the literature [Jess & Näther (2006). Inorg. Chem. 45, 7446–7454]. Powder X-ray diffraction measurements reveal that the title compound is unstable and transforms immediately into an unknown crystalline phase.

Kamala Harris can and should be critiqued for her political résumé—but criticism rooted in misogynoir should have no place in political discourse.

Despite muted microphones during the first debate between former President Donald Trump and Vice President Kamala Harris, each candidate's face spoke volumes.

El portavoz 'popular' Iñaki García Calvo pretende que el Ayuntamiento de Vitoria presione a Lakua para que Foronda sea el "aeropuerto transoceánico" vasco. El alcalde de Bilbao "emocionado" por la decisión de United Airlines operar tres vuelos semanales desde Nueva York en mayo de 2025. Leer

Radio Liechtenstein acapara más del 70% de la financiación del estado para los medios, lo que le da una ventaja injustificada Leer

A new collection of Meshed princess panels camisole set by Sensual Mystique®.

Two piece meshed princess panels, lace appliqu, and adjustable straps with matching panty. Light, soft and comfortable fabric.

* Designed in USA

Panelistas resaltan que medidas adoptadas por el gobierno no son suficiente; plantean que la conectividad debe tener una estructurada política de Estado.

Escuche el programa de este lunes 23 de septiembre. La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.

En Caracol Radio estuvo Juan Alberto Londoño, ex ministro de Hacienda, conversando sobre la posibilidad de una reforma relacionada con la entrega de vigencias futuras en temas de construcción

En Caracol Radio estuvo Armando Novoa, jefe del equipo negociador del Gobierno con la Segunda Marquetalia de ‘Iván Márquez, conversando sobre los compromisos del grupo armado ilegal

En 6AM de Caracol Radio estuvo Juan Ramón Guzmán, Presidente de la Junta directiva y Co-fundador de BIVIEN, para hablar sobre en qué consiste “Compromiso territorio” y cuál será la estrategia para cerrar la brecha social en el norte del Cauca.

En 6AM de Caracol Radio estuvo Mabel Lara, secretaria de Turismo de Cali, para hablar sobre la iniciativa ‘Cali es donde debes estar’ y cómo buscarán potencializar a Colombia ante el mundo.

An email containing a racist trope had already leaked.

A hearty noodle bowl recipe. Whole grain noodles and asparagus are tossed with a creamy, walnut-miso dressing plus a dollop of chile paste.

Continue reading Walnut Miso Noodles on 101 Cookbooks

Tumor hypoxia, an integral biomarker to guide radiotherapy, can be imaged with ¹⁸F-fluoromisonidazole (¹⁸F-FMISO) hypoxia PET. One major obstacle to its broader application is the lack of standardized interpretation criteria. We sought to develop and validate practical interpretation criteria and a dedicated training protocol for nuclear medicine physicians to interpret ¹⁸F-FMISO hypoxia PET. Methods: We randomly selected 123 patients with human papillomavirus–positive oropharyngeal cancer enrolled in a phase II trial who underwent 123 ¹⁸F-FDG PET/CT and 134 ¹⁸F-FMISO PET/CT scans. Four independent nuclear medicine physicians with no ¹⁸F-FMISO experience read the scans. Interpretation by a fifth nuclear medicine physician with over 2 decades of ¹⁸F-FMISO experience was the reference standard. Performance was evaluated after initial instruction and subsequent dedicated training. Scans were considered positive for hypoxia by visual assessment if ¹⁸F-FMISO uptake was greater than floor-of-mouth uptake. Additionally, SUV_max was determined to evaluate whether quantitative assessment using tumor-to-background ratios could be helpful to define hypoxia positivity. Results: Visual assessment produced a mean sensitivity and specificity of 77.3% and 80.9%, with fair interreader agreement ( = 0.34), after initial instruction. After dedicated training, mean sensitivity and specificity improved to 97.6% and 86.9%, with almost perfect agreement ( = 0.86). Quantitative assessment with an estimated best SUV_max ratio threshold of more than 1.2 to define hypoxia positivity produced a mean sensitivity and specificity of 56.8% and 95.9%, respectively, with substantial interreader agreement ( = 0.66), after initial instruction. After dedicated training, mean sensitivity improved to 89.6% whereas mean specificity remained high at 95.3%, with near-perfect interreader agreement ( = 0.86). Conclusion: Nuclear medicine physicians without ¹⁸F-FMISO hypoxia PET reading experience demonstrate much improved interreader agreement with dedicated training using specific interpretation criteria.

Sukhbinder Kumar
Jun 30, 2021; 41:5762-5770
Neurobiology of Disease

Two weeks before he died, the legendary astronaut wrote a letter in recognition of Jeff Bezos' work, read at the 2016 American Ingenuity Awards Smithsonian magazine American #IngenuityAwards

MISO's long implementation date for Order 2222 is another reason FERC should schedule a technical conference sooner than later.

La enseñanza bíblica en profundidad de John MacArthur lleva la verdad transformadora de la Palabra de Dios a millones de personas cada día.

La enseñanza bíblica en profundidad de John MacArthur lleva la verdad transformadora de la Palabra de Dios a millones de personas cada día.

Kamala Harris is blasting Donald Trump for vowing to protect women whether they “like it or not” at the same time he is calling for Republican Liz Cheney to be shot in the face. We get response from The Nation's abortion access correspondent Amy Littlefield and talk about 10 states with abortion rights on the ballot, including Arizona, Nevada, Florida, South Dakota and Missouri. Trump's remarks are a “succinct and clear definition of patriarchy,” says Littlefield. She argues the 2024 election will be decided in large part by white women and whether they will vote for abortion rights. Trump is “laying out the bargain that white patriarchy has offered for white women in this country,” says Littlefield. “He is saying, 'White women, we will protect you from Brown and Black men.'”

If you were to make a multi-part Venn diagram combining my favorite salad things, you could nestle this right in the center. It’s one part wedge salad, the fork and steak knife kind, something I am so into I talked my podcast co-host Kenji (okay, it wasn’t hard) into dedicating a whole episode to it. And it contains cabbage, and not just cabbage but Napa cabbage, which I think deserves more credit as a salad green. [This can be convenient to know as it often comes in heads large enough to feed a small family for a week.] Napa cabbage is a little leafy, a little crunchy, and yet kind of juicy too and I’ve used it, sliced thin, in everything from this Italian-style salad to a classic Caesar.
Read more »

Women take two types of pills for abortion during their pregnancy: medlinkmisoprostol/medlink, which causes the womb to contract, and medlinkmifepristone/medlink,

Milton Park, Abingdon, Oxon ; New York, NY : Routledge, 2022.

The title com­pound, C34H24O4S·0.5CH2Cl2, crystallizes with two independent mol­ecules and one di­chloro­methane solvent mol­ecule in the asymmetric unit. The crystal packing is consolidated by C—H⋯O hydrogen bonds.

The title Schiff base compound, C13H9ClN4O5·0.5CH3CN, crystallizes as an aceto­nitrile hemisolvate; the solvent mol­ecule being located on a twofold rotation axis. The mol­ecule is nearly planar, with a dihedral angle between the two benzene rings of 3.7 (2)°. The configuration about the C=N bond is E, and there is an intra­molecular N—H⋯Onitro hydrogen bond present forming an S(6) ring motif. In the crystal, mol­ecules are linked by O—H⋯O and N—H⋯O hydrogen bonds, forming layers lying parallel to (10overline{1}). The layers are linked by C—H⋯Cl hydrogen bonds, forming a supra­molecular framework. Within the framework there are offset π–π stacking inter­actions [inter­centroid distance = 3.833 (2) Å] present involving inversion-related mol­ecules. The DFT study shows that the HOMO and LUMO are localized in the plane extending from the phenol ring to the 2,4-di­nitro­benzene ring, and the HOMO–LUMO gap is found to be 0.13061 a.u.

In the title com­plex, [Cu(C18H12F6N2O4)]·0.5C6H6O2, the CuII ion has a square-planar coordination geometry, being ligated by two N and two O atoms of the tetra­dentate open-chain Schiff base ligand 6,6'-{(1E,1'E)-[ethane-1,2-diylbis(aza­nylyl­idene)]bis­(methanylyl­idene)}bis­[2-(tri­fluoro­meth­oxy)phenol]. The crystal packing is stabilized by intra­molecular O—H⋯O and inter­molecular C—H⋯F, C—H⋯O and C—H⋯π hydrogen bonds. In addition, weak π–π inter­actions form a three-dimensional structure. Hirshfeld surface analysis and two-dimensional fingerprint plots were performed and created to analyze the inter­molecular inter­actions present in the crystal, indicating that the most important contributions for the crystal packing are from F⋯H/H⋯F (25.7%), H⋯H (23.5%) and C⋯H/H⋯C (12.6%) inter­actions.

The title compound, [IrZnI2(C10H15)(C3H9P)2]·0.5C6H6 or [Cp*(PMe3)2Ir]-[ZnI2] (Cp* = cyclo-C5Me5) was obtained and characterized as its benzene solvate [Cp*(PMe3)2Ir]-[ZnI2]·0.5C6H6. The bimetallic complex in this structure contains the Lewis-acidic fragment ZnI2 bonded to the Lewis-basic fragment Cp*(PMe3)2Ir, with an Ir—Zn bond distance of 2.452 (1) Å. The compound was obtained by reacting [Cp*(PMe3)IrI2] with 2-Ad2Zn (2-Ad = 2-adamant­yl), resulting in the reduction of the IrIII complex and formation of the IrI–ZnII adduct. The crystal studied was a twin by non-merohedry with a refined BASF parameter of 0.223 (1).

Misophonia, the 'hatred of sound', sends sufferers into a rage over sounds that other may be able to ignore. Chomping and lip smacking may be annoying to many,

Minamisoma, Japan 2014 Follow me @benhuang.photography

Minamisoma, Japan 2014 Follow me @benhuang.photography

The song “Closing Time” by the American rock band Semisonic came out in March 1998. It hit #1 on the Alternative charts, and was nominated for a Grammy for Best Rock Song. It gets played in stadiums, Weird Al covered it, and it’s the last song of the night in countless bars.

Since then, Dan Wilson, the lead singer and songwriter of Semisonic, has become a powerhouse songwriter who has written or co-written for artists like John Legend and Taylor Swift. And he’s won Grammys for his songwriting with the Dixie Chicks and Adele. But over two decades ago, Dan and his bandmates John Munson and Jacob Slichter were in Minneapolis, getting ready to start work on their second album, Feeling Strangely Fine. In this episode of Song Exploder, Dan breaks down how that process led to "Closing Time."

songexploder.net/semisonic

(Court of Appeals of New York) - In a negligence action, the Appellate Division's grant of defendant's motion for summary judgment is reversed where there is a material question as to whether the escape of defendant's calf onto the road was a proximate cause of decedent's death in car accident while she was trying to assist.

The NHL on Wednesday condemned misogynistic comments made by Washington Capitals forward Brendan Leipsic and Florida Panthers prospect Jack Rodewald in a group chat on social media.

Stimați și dragi timișoreni