carbon

Structural constraint at a P–P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06581F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijun You, Daniel Roth, Lutz Greb
A structural constraint approach at a P–P bond is presented that enables the phosphinophosphination of alkynes, alkenes, and carbonyls with high regio- and diastereoselectivity. The apolar nature of the P–P bond facilitates a concerted mechanism.
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carbon

Rare-earth metal complexes bearing electrophilic and nucleophilic carbon centres and their unique reactivity patterns towards pyridine derivatives

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04197F, Edge Article
Open Access
weikang Wu, Thayalan Rajeshkumar, Shan Zhu, Fuxiang Chai, Dongjing Hong, ZeMing Huang, Qingbing Yuan, Laurent Maron, Shaowu Wang
The rare-earth metal dialkyl complexes (κ2-L1)RE(CH2SiMe3)2(THF)2 [RE = Lu(1a), Yb(1b), Er(1c), Y(1d), Dy(1e)] (L1 = 1-(2-N-C5H10NCH2CH2)-3-(2,6-iPr2C6H3N=CH)-C8H4N) and the rare-earth metal monoalkyl complexes (κ2-L1)2RE(CH2SiMe3)(THF)n [n = 0, RE = Lu(2a), Yb(2b);...
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carbon

India and Brazil to collaborate on SAF, leverage biofuel expertise to decarbonise aviation

The joint statement emphasised collaboration in technology exchange, joint research, and development initiatives to optimize SAF production processes and create frameworks encouraging investment in SAF production.




carbon

Nitrogen-doped biomass-derived carbon dots for fluorescence determination of sunset yellow

Anal. Methods, 2024, 16,2063-2070
DOI: 10.1039/D3AY01944F, Paper
Qian Zhang, Xiaoqi Wang, Lili Yuan, Lina Yu, Congying Shao, Hongxing Jia, Shun Lu
Schematic of preparation of N-CDs and their sensing mechanism for sunset yellow.
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carbon

A portable fluorescence detection device based on a smartphone employing carbon nanodots for Mn2+ sensing

Anal. Methods, 2024, 16,2101-2110
DOI: 10.1039/D4AY00027G, Paper
Pijika Mool-am-kha, Samuch Phetduang, Kessarin Ngamdee, Chayada Surawanitkun, Xiang-Kui Ren, Wittaya Ngeontae
A low-cost, portable, and low-energy consumption fluorescence reader-based smartphone device employing carbon nanodots for detection of Mn2+.
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carbon

Construction of a three-mode sensor based on gold nanoparticles and carbon quantum dots as probes for the detection of thiosemicarbazone

Anal. Methods, 2024, 16,2127-2134
DOI: 10.1039/D4AY00256C, Paper
Zhili Liu, Xiaojun Wang, Jing Li, Wenfeng Zhou, Haixiang Gao, Runhua Lu
A three-mode sensor for thiocarbazone (TSC) was constructed based on gold nanoparticles and carbon quantum dots (CQDs). (A) Synthesis process of CQDs using ginkgo leaves. (B) Colorimetric and chrominance TSC detection. (C) Fluorescence detection of TSC.
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carbon

Nanocubic cobalt-containing Prussian blue analogue-derived carbon-coated CoFe alloy nanoparticles for noninvasive uric acid sensing

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00121D, Paper
Yunting Qin, Dan Xiao, Xilan Gao, Xicui Zhang, Yanxue Xu
This work describes an electrochemical sensor for the fast noninvasive detection of uric acid (UA) in saliva.
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carbon

Subtle adjustment of the cyclic potential on electro-activated glassy carbon electrodes for sensitive sensing of methyl parathion

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00079J, Paper
Yunyin Yang, Sian Chen, Changqiu Zhang, Yanqing Li, Xinrong Zong, Yitao Lv, Min Zhang
Upon experiencing a negligible change of 0.5 V which only takes 5 more seconds, the signal value of an e-GCE was efficiently enhanced from 2-fold to 30-fold compared with a bare GCE.
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carbon

Discrimination of Diptera order insects based on their saturated cuticular hydrocarbon content using a new microextraction procedure and chromatographic analysis

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00214H, Paper
Open Access
Lixy Olinda León-Morán, Marta Pastor-Belda, Pilar Viñas, Natalia Arroyo-Manzanares, María Dolores García, María Isabel Arnaldos, Natalia Campillo
The nature and proportions of hydrocarbons in the cuticle of insects is characteristic of the species and age. Chemical analysis of cuticular hydrocarbons allows species discrimination, which is of great...
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carbon

Dual-signal detection of tannin acid in red wines based on peroxidase activity carbon dots

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00526K, Paper
Bin Liu, Yu Yin, qianwen Li, wanwan Li, Fubing Xiao, Jinquan Liu, Yan Tan, Shengyuan Yang
Herein, a novel sort of phosphorus and iron-doped carbon dots (P,Fe-CDs) with outstanding peroxidase activity and excellent fluorescence performance was hydrothermally synthesized to colorimetrically and fluorimetrically detect tannic acid (TA)....
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carbon

Fe3+-induced luminescence quenching in carbon dots – mechanism unveiled

Anal. Methods, 2024, 16,2349-2358
DOI: 10.1039/D3AY02202A, Paper
Varsha Raveendran P.T., Anjali C., Renuka Neeroli Kizhakayil
Luminescence quenching in carbon dots with an increase in Fe3+ concentration and the quantitative variation in luminescence intensity with added ferric ions.
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carbon

Design and fabrication of La-based perovskites incorporated with functionalized carbon nanofibers for the electrochemical detection of roxarsone in water and food samples

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00264D, Paper
Mariya Antony John Felix, Santhiyagu Sahayaraj Rex Shanlee, Shen-Ming Chen, Sundaresan Ruspika, Ramachandran Balaji, Narendhar Chandrasekar, Periyanayagam Arockia Doss
Fabrication of potent electrocatalyst, La-based perovskites coupled with functionalized carbon nanofibers (LMO/f-CNF) for ultrasensitive electrochemical detection of roxarsone in edible and water samples.
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carbon

​Fair trade: On the 29th COP and India’s carbon market

India must develop a transparent carbon trade policy 




carbon

Discovery and optimisation of pyrazolo[1,5-a]pyrimidines as aryl hydrocarbon receptor antagonists

RSC Med. Chem., 2024, 15,3477-3484
DOI: 10.1039/D4MD00266K, Research Article
Raitis Bobrovs, Svetlana Terentjeva, Ninni Elise Olafsen, Zilvinas Dambrauskas, Antanas Gulbinas, Toivo Maimets, Indrek Teino, Aigars Jirgensons, Jason Matthews, Kristaps Jaudzems
The aryl hydrocarbon receptor (AHR) is a versatile ligand-dependent transcription factor involved in diverse biological processes, from metabolic adaptations to immune system regulation.
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carbon

Novel benzenesulfonamides containing a dual triazole moiety with selective carbonic anhydrase inhibition and anticancer activity

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00617H, Research Article
Aida Buza, Cüneyt Türkeş, Mustafa Arslan, Yeliz Demir, Busra Dincer, Arleta Rifati Nixha, Şükrü Beydemir
In this research, a series of sulfonamides incorporating a 1,2,3-triazolyloxime substituted 1,2,3-triazolyl moiety was conceptualized, synthesized, and investigated as carbonic anhydrase inhibitors.
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carbon

Chennai’s mega carbon footprint

Chennai emerges as India’s No. 1 greenhouse gas emitter in a study done among seven major cities. Poor city and building design is the main culprit.




carbon

Carbon credits to boost incomes of Jharkhand village farmers 

The Birsa Harit Gram project serves as a potential model for agro-forestry, which is gaining ground because the buyers of carbon credits prefer — pay a premium — for credits based on Nature Based Solution, as opposed to offsetting projects like renewable energy or projects like carbon capture.




carbon

Emulsifying mechanisms of phospholipids in high-pressure homogenization of perfluorocarbon nanoemulsions

Soft Matter, 2024, 20,8373-8384
DOI: 10.1039/D4SM00828F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Larissa J. Lubitz, Harden Rieger, Gero Leneweit
An optimized PFC/W emulsion contains 1 mM lipid per 1% (v/v) dispersed phase for an emulsifying monolayer; higher ratios result in triple layers. Low viscosity ratios ηD/ηC ≤ 5 and low PFC volume fractions lead to smaller monodisperse droplets.
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carbon

Revealing microscale bulk structures in polymer–carbon nanocomposites using spin-echo SANS

Soft Matter, 2024, 20,8663-8674
DOI: 10.1039/D4SM00578C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
L. V. Tiihonen, M. P. Weir, A. J. Parnell, S. C. Boothroyd, D. W. Johnson, R. M. Dalgliesh, M. Bleuel, C. P. Duif, W. G. Bouwman, R. L. Thompson, K. S. Coleman, N. Clarke, W. A. Hamilton, A. L. Washington, S. R. Parnell
Spin-echo small-angle neutron scattering (SESANS) revealed structure in polymer–carbon nanocomposites over multiple length scales with unprecedented range (10 nm–16 μm). Data from two SESANS instruments and other methods were analysed with SasView.
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carbon

Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01312C, Research Article
Yi Chen, Jianing Wu, Yongzheng Ding, Hanmin Huang
Transition metal-catalyzed hydrocarbonylation of alkenes has been widely studied; however, the hydrocarbonylation reaction that took place between two alkenes has been largely unexplored.
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carbon

Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01570C, Research Article
Fei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing Wu
A novel palladium-catalyzed cascade reaction of o-iodostyrenes, internal alkynes and formates to access various indene-1-acetates through sequential double carbopalladation and aryloxycarbonylation under a palladium/air system was developed.
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carbon

Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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carbon

Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
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carbon

Recent advances in carbon atom addition for ring-expanding single-atom skeletal editing

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01806K, Review Article
Ting Yuan, Lei Shi
This review focuses on recent advances in carbon atom addition for ring-expanding single-atom skeletal editing.
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carbon

Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01831A, Research Article
Jiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang Li
A method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.
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carbon

Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01714E, Research Article
Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
Transition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.
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carbon

Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01641F, Research Article
Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai Li
An FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.
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carbon

Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
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carbon

Carbonate weakens the interactions between potassium and calcareous soil

RSC Adv., 2024, 14,35275-35285
DOI: 10.1039/D4RA05988C, Paper
Open Access
Wei Du, Shifeng Wang, Yizhe Yang, Chenyang Xu, Feinan Hu, Wuquan Ding, Jialong Lv
Adsorption energies of K+ in carbonate-removed (CREM) and carbonate-reserved (CRES) calcareous soil.
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carbon

Transient crystallisation of rare earth carbonates during the hydrothermal oxidation of siderite

RSC Adv., 2024, 14,35305-35322
DOI: 10.1039/D4RA05212A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maddin M., Rateau R., Szucs A. M., Terribili L., Rodriguez-Blanco J. D.
The researchers investigated the interaction between multi-component rare earth element-bearing aqueous solutions and siderite grains under hydrothermal conditions.
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carbon

Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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carbon

N-doped carbon quantum dots for the selective detection of OCl− ions, bioimaging, and the production of Fe3O4 nanoparticles utilized in the synthesis of substituted imidazole

RSC Adv., 2024, 14,35448-35459
DOI: 10.1039/D4RA06474G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Namrata Priyadarshini Hota, Sathiyanarayanan Kulathu Iyer
Nitrogen-doped quantum dots (NCQD) were synthesized by solvothermal means using o-phenylenediamine and L-tartaric acid.
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carbon

Synthesis and characterization of carbonyl functionalized organotellurium(IV) derivatives

RSC Adv., 2024, 14,35650-35656
DOI: 10.1039/D4RA06023G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Puspendra Singh, Mariya Khan, Andrew Duthie, Ray J. Butcher
Aryltellurium trichlorides, ArTeCl3 (Ar = C6H5, Ph; 4-Me-C6H4, p-Tol; 1-C10H7, 1-Nap; 2,4,6-Me3C6H2, Mes) react under mild conditions with acetylacetone/benzoylacetone to give carbonyl functionalized organotellurium(IV) derivatives.
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carbon

Piezoresistivity and strain-sensing behaviour of poly(butylene adipate-co-terephthalate)/multiwalled carbon nanotube nanocomposites

RSC Adv., 2024, 14,35715-35726
DOI: 10.1039/D4RA04826A, Paper
Open Access
Kedar Nath Dhakal, Ralf Lach, Wolfgang Grellmann, Beate Krause, Jürgen Pionteck, Rameshwar Adhikari
The interconnectedness of the exfoliated multi-walled carbon nanotubes well dispersed in the PBAT matrix (TEM image; left) leads to strain-sensing properties at lower strains as illustrated by the variation of ΔR/R0 as a function of mechanical strain with time (right).
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carbon

Synthesis of new-type, cost-effective and insensitive energetic materials via nitration of solid bituminous hydrocarbons

RSC Adv., 2024, 14,35971-35979
DOI: 10.1039/D4RA06329E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sahar Abdolahi, Mohammad Soleiman-Beigi
A global trend for the development of energetic materials using various sources is promoted by researchers annually.
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carbon

Exploring heterocyclic scaffolds in carbonic anhydrase inhibition: a decade of structural and therapeutic insights

RSC Adv., 2024, 14,35769-35970
DOI: 10.1039/D4RA06290F, Review Article
Open Access
Nafeesa Naeem, Amina Sadiq, Gehan Ahmed Othman, Habab M. Yassin, Ehsan Ullah Mughal
Heterocyclic compounds represent a prominent class of molecules with diverse pharmacological activities.
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carbon

Synthesis of green fluorescent carbon dots and their application in mercury ion detection

RSC Adv., 2024, 14,36273-36280
DOI: 10.1039/D4RA06635A, Paper
Open Access
Juan Hou, Qinqin Chen, Xiangzhi Meng, Huiling Liu, Wei Feng
Green fluorescent carbon dots were prepared for effective detection of Hg2+ ions through fluorescence quenching, demonstrating high sensitivity and selectivity.
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carbon

Fight over including carbon border tax in agenda delays climate talks on day one

Agenda disputes are common at UN climate conferences but this one is especially significant as countries have limited time to agree on a new climate finance goal.




carbon

Global carbon market gets green signal at COP29 under Paris Agreement's Article 6

It offers two pathways for countries and companies to trade carbon offsets, supporting the achievement of emission reduction targets set in their climate action plans, or nationally determined contributions




carbon

Global carbon market gets green signal at COP29

Such a market would allow countries to trade carbon credits among themselves




carbon

UN COP29 climate summit: What is a carbon credit? What is Article 6 of the Paris Agreement?

Officials are keen to secure an early "win" on Article 6 at this year's climate conference in Azerbaijan




carbon

UN climate talks to focus on money to help poor nations cut carbon pollution

About 77% of the heat-trapping gas in the atmosphere now comes from the G20 rich nations, many of whom are now cutting back on their pollution, something that is not happening in most poor nations or China




carbon

LDH-derived Co0.5Ni0.5Te2 Dispersed in 3D Carbon Sheets as Separator Modifier to Enable Kinetics-Accelerated Lithium-Sulfur Batteries

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02619E, Paper
Chunmei Li, kan Mi, Kai Xu, Zhuo Jia, Xiaolei Jiang, Huili Peng, Xiuwen Zheng, Hongjiao Nie
Lithium-sulfur battery is considered as a powerful candidate for the next generation of advanced energy storage systems relying on its high energy density and theoretical specific capacity. However, its practical...
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carbon

Fe/Fe3C particles encapsulated in hollow carbon nanoboxes for high performance zinc–air batteries

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02396J, Paper
Chuyun Huang, Wenyuan Zhang, Xuezhi Hu, Shiliang Fei, Fhulufhelo Nemangwele, Nnditshedzeni Eric Maluta, Yangsen Hu, Hui Lv, Pei Hu, Zhuo Peng
Zinc–air batteries are recognized for their environmental friendliness and high energy density; however, the slow kinetics of the oxygen reduction reaction (ORR) at the air electrode hinder their commercial viability.
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carbon

Metal–organic framework-derived Se-blended ZrO2 with a nitrogen-doped carbon heterostructure for electrocatalytic overall water splitting

Dalton Trans., 2024, 53,17918-17933
DOI: 10.1039/D4DT02542C, Paper
Krishnendu M. Nair, Pavithra Shankar, Selvaraju Thangavelu
Electrocatalytic overall water splitting is achieved with ease at 1.58 V together with exciting stability over 48 h.
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carbon

Gold nanoparticle-decorated amorphous carbon for oxidative cyclization of anthranilamide and aryl alcohols

Dalton Trans., 2024, 53,17976-17988
DOI: 10.1039/D4DT02355B, Paper
The Thai Nguyen, Huyen-Tran Thi Nguyen, Thu Anh Nguyen, Khuong Quoc Vo, Phuong Hoang Tran
Various 2-phenylquinazolin-4(3H)-ones were produced in moderate-to-good yields (44–80%) via the oxidative cyclization of anthranilamide and benzyl alcohols using gold nanoparticle-decorated amorphous carbon as an efficient catalyst.
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carbon

Carbon flows and biochar stability during co-pyrolysis of human faeces with wood biomass

Environ. Sci.: Water Res. Technol., 2024, 10,2709-2722
DOI: 10.1039/D4EW00513A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
M. E. Koulouri, M. Qiu, M. R. Templeton, G. D. Fowler
The systematic quantification of carbon flows and biochar stability when co-pyrolysing human faeces with wood biomass at different blending ratios and temperatures.
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carbon

Carbon quantum dot (CQD)-dithizone-based thin-film chemical sensors for the specific detection of lead ions in water resources

Environ. Sci.: Water Res. Technol., 2024, 10,2858-2868
DOI: 10.1039/D4EW00452C, Paper
Tanmay Vyas, Hritik Kumar, Sandeep Choudhary, Abhijeet Joshi
Dithizone-CQD-based thin-film chemical sensors for the detection of lead ions in various water resources.
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carbon

Production of birnessite-type manganese oxides by biofilms from oxygen-supplemented biological activated carbon (BAC) filters

Environ. Sci.: Water Res. Technol., 2024, 10,2844-2857
DOI: 10.1039/D4EW00208C, Paper
Amanda Larasati, Olga Bernadet, Gert Jan W. Euverink, H. Pieter J. van Veelen, Maria Cristina Gagliano
The application of a novel enrichment approach revealed the potential of manganese-oxidizing bacteria (MnOB) from full-scale biofilters treating wastewater to produce manganese oxides as crystalline, efficient birnessite catalysts.
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carbon

A review of carbon recovery in sewage treatment and analysis of product options for a typical water recycling plant

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00160E, Critical Review
Arash Mohseni, Linhua Fan, Li Gao, Joel Segal, Felicity Roddick
Reviewed existing and emerging technologies for carbon recovery from WWTPs, best options investigated as case study for typical conventional plant.
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