carbon Zero-carbon beer, no-waste cocktails: how the alco-bev industry is turning green By www.thehindu.com Published On :: Fri, 04 Aug 2023 15:45:58 +0530 By monitoring water use, adopting renewable tech, and taking to recyclable packaging, alcohol brands across the country are attempting to move towards a greener future Full Article Food
carbon Brimstone – the world’s first carbon negative portland cement By www.redferret.net Published On :: Tue, 24 Jan 2023 12:17:53 +0000 Californian company Brimstone has announced the development of the world’s first carbon negative cement product. It’s a bold statement, and if true could revolutionize the global building industry and lead to a new era of carbon neutral construction. Cement is a big deal. Every year and estimated 4.4 billion tons of the stuff is produced to craft our buildings. But there’s a hidden cost to the environment. If cement was a country, it would be the third largest CO2 emitter... The post Brimstone – the world’s first carbon negative portland cement appeared first on The Red Ferret Journal. Full Article Eco Friendly carbon capture cdr cement CO2 concrete construction sustainable building
carbon Global Carbon Emissions Hit New Record in 2024, Still No Peak in Sight By scienceblog.com Published On :: Wed, 13 Nov 2024 13:00:52 +0000 Full Article Earth Energy & Environment
carbon New plant captures carbon dioxide for fizzy drinks By www.bbc.com Published On :: Tue, 12 Nov 2024 07:28:09 GMT The new electricity plant plans to use the gas rather than releasing it into the atmosphere. Full Article
carbon Plans for carbon capture facility at incinerator By www.bbc.com Published On :: Wed, 13 Nov 2024 06:16:19 GMT The business says it is welcoming public feedback on the proposal. Full Article
carbon Carbon's 3rd Birthday By pzf.fremantle.org Published On :: Wed, 08 Feb 2012 13:25:00 +0000 Three years ago I blogged about WSO2 Carbon for the first time. I enthused about a composable server architecture and why it was important for a SOA platform. At that point there were just 4 Carbon products. Today there are 13 products, the core framework, Stratos, and Carbon Studio all based around the Carbon Architecture. There are two really important things I think have worked really well: The composability is obviously important and we now have a set of customers doing exactly that - using p2 to combine the correct components and effectively "build your own server" with the right function for their specific needs and requirements. But even more interesting for those customers has been the consistency and completeness of the platform that has arisen out of Carbon. The fact that there is a "menu" or palette of low-level components (features) and high level components (products) that all interoperate, behave the same, use the same identity, clustering, registry, key management, etc has really offered customers the opportunity to build out compelling architectures. The kernelization is almost just a corollary of componentization: as you build the components and identify which ones to re-use, we found a common core across those 13 products. The result is that when we came to address cloud - starting later in 2009 - we very quickly realized that there were just a few core places in which to address multi-tenancy, elasticity and metering. I have to admit this was something I for one hadn't thought of, but has been probably the most powerful driver behind the success of StratosLive and Stratos. There were certainly people then who doubted that OSGi was a stable basis for an ESB or Server and I hope that the 1bn+ transactions a day that eBay are doing through WSO2 ESB are enough to disprove that. All in all, it is amazing to see how far Carbon has come and what it has enabled in 3 years. Full Article
carbon Data as a potential path for the automotive aftersales business to remain active through and after the decarbonisation By www.inderscience.com Published On :: 2024-04-30T23:20:50-05:00 This study aims to identify and understand the perspectives of automotive aftersales stakeholders regarding current challenges posed by decarbonisation strategies. It examines potential responses that the automotive aftersales business could undertake to address these challenges. Semi-structured interviews were undertaken with automotive industry experts from Europe and Latin America. This paper focuses primarily on impacts of decarbonisation upon automotive aftersales and the potential role of data in that business. Results show that investment in technology will be a condition for businesses that want to remain active in the industry. Furthermore, experts agree that incumbent manufacturers are not filling the technology gap that the energy transition is creating in the automotive sector, a consequence of which will be the entrance of new players from other sectors. The current aftersales businesses will potentially lose bargaining control. Moreover, policy makers are seen as unreliable leaders of the transition agenda. Full Article
carbon Nosler Releases Limited Edition M21 Carbon Rifle By www.ammoland.com Published On :: Tue, 12 Nov 2024 16:40:18 +0000 Imagine a rifle that doesn't just shoot; it speaks to the soul of the hunter, the adventurer, the collector. Enter the Nosler Limited Edition M21 Carbon Rifle. Full Article Firearm News Hunting Rifles Limited Editions Nosler
carbon Alphacool Apex Pro Skeleton Carbon Case Featured Build and more @ NT Compatible By www.majorgeeks.com Published On :: Sun, 10 Nov 2024 02:56:34 -0500 ... Full Article
carbon Carbon pollution from high-flying rich in private jets soars By www.washingtontimes.com Published On :: Thu, 07 Nov 2024 11:07:20 -0500 Carbon pollution from private jets has soared in the past five years, with most of those small planes spewing more heat-trapping carbon dioxide in about two hours of flying than the average person does in about a year, a new study finds. Full Article
carbon Cement Producers Strive to Mitigate Carbon Footprint, Driving Digitalization Investing By www.wconline.com Published On :: Fri, 26 Apr 2024 12:00:00 -0400 Cement production and processes emit over 5 percent of all carbon dioxide emitted by human activity. Reducing that environmental impact is a high priority among cement producers. Cement producers are now publishing their Environmental, Social and Governance credentials concerning energy use in their operations, greenhouse gas emissions and water usage. Full Article
carbon O’Shaughnessy Ventures Invests in Furno Materials, Aiming to Decarbonize Cement By www.wconline.com Published On :: Sun, 04 Aug 2024 12:00:00 -0400 O’Shaughnessy Ventures LLC, a family office that invests in ambitious seed and pre-seed startups, announced Feb. 2 that it has invested in Furno Materials Inc. Full Article
carbon Industry Decarbonization Plans Outlined at White House Concrete Innovation Summit By www.wconline.com Published On :: Sat, 20 Jul 2024 12:00:00 -0400 The Portland Cement Association, representing America’s cement manufacturers, demonstrated the cement industry’s commitment to carbon neutrality to key executive branch decision-makers at the White House’s Concrete Innovation Summit – as well as outlined what steps must be taken to further reduce cement sector emissions. Full Article
carbon New York’s “City of Yes” Spurs Urban Decarbonization and Growth by Zoning Reform By www.wconline.com Published On :: Sun, 28 Jul 2024 00:00:00 -0400 Following the 2023 debut of its “City of Yes” strategy to permit more housing faster in New York City, Mayor Eric Adams’ administration unveiled a raft of zoning changes last winter intended to make the proposed growth carbon-neutral, according to Adam Friedberg, a Buro Happold expert behind similar initiatives in the region and worldwide. Full Article
carbon OSHA issues bulletin on carbon monoxide explosion hazards in electric arc furnaces By www.safetyandhealthmagazine.com Published On :: Wed, 16 Dec 2015 00:00:00 -0500 Washington – OSHA has released a bulletin with information on how to protect workers from carbon monoxide explosion hazards related to electric arc furnaces in the steelmaking industry. Full Article
carbon Portable carbon dioxide gas monitor By www.safetyandhealthmagazine.com Published On :: Sun, 28 Jan 2018 00:00:00 -0500 The newly improved GD-888 Series of Portable Carbon Dioxide Gas Monitors include a digital display, a built-in air pump, backlighting, alarms and an optional data-logger. Full Article
carbon Report examines cause of Chevron hydrocarbon release By www.safetyandhealthmagazine.com Published On :: Wed, 20 Feb 2013 00:00:00 -0500 Washington – The ruptured steel pipe at the center of the 2012 hydrocarbon release and fire at the Chevron U.S.A. Inc. refinery in Richmond, CA, was corroded and should have been replaced, concludes a report released by the Chemical Safety Board and the California Division of Occupational Safety and Health. Full Article
carbon NIOSH issues recommended exposure limit for carbon nanomaterials By www.safetyandhealthmagazine.com Published On :: Wed, 01 May 2013 00:00:00 -0400 Washington – NIOSH on April 24 issued a recommended worker exposure limit of 1 microgram per cubic meter of air for carbon nanotubes and carbon nanofibers. Full Article
carbon SALTO Systems Earns Certified Carbon Neutral Certification By www.sdmmag.com Published On :: Tue, 14 Jul 2020 08:00:00 -0400 SALTO Systems, a manufacturer of electronic access control solutions, has received carbon-neutral certification across all of its operations. Full Article
carbon NTSB warns pilots and airline mechanics about carbon monoxide poisoning By www.safetyandhealthmagazine.com Published On :: Mon, 09 Oct 2017 00:00:00 -0400 Washington – The National Transportation Safety Board has released two safety alerts and a pair of videos cautioning airline pilots and mechanics about the dangers of carbon monoxide emissions. Full Article
carbon Higher carbon dioxide levels in cockpit affect airline pilot performance: study By www.safetyandhealthmagazine.com Published On :: Tue, 02 Oct 2018 00:00:00 -0400 Boston — Higher levels of carbon dioxide in airplane cockpits may diminish commercial pilots’ ability to perform maneuvers, recent research from the Harvard T.H. Chan School of Public Health indicates. Full Article
carbon Carbon monoxide: Know the facts By www.safetyandhealthmagazine.com Published On :: Sun, 28 Jul 2019 00:00:00 -0400 Detecting invisible workplace risks is always a challenge. One such hidden hazard is carbon monoxide, a colorless and odorless gas. Full Article
carbon FACE Report: Land clearing and forest product company owner overcome by carbon monoxide By www.safetyandhealthmagazine.com Published On :: Sun, 24 Apr 2022 00:00:00 -0400 The 54-year-old owner of a land clearing and forest product company was overcome by carbon monoxide as he was checking on a wood chip-powered boiler system. Full Article
carbon FACE Report: Trucker poisoned by carbon monoxide in cab By www.safetyandhealthmagazine.com Published On :: Tue, 23 Jul 2024 00:00:00 -0400 A 61-year-old truck driver who worked for a general freight carrier parked his truck at his employer’s terminal yard and slept overnight in the truck’s sleeper berth. Full Article
carbon EPA proposes partial ban of carbon tetrachloride By www.safetyandhealthmagazine.com Published On :: Tue, 08 Aug 2023 00:00:00 -0400 Washington — The Environmental Protection Agency wants to protect workers against exposure to the chemical substance carbon tetrachloride – and ban uses that already have been phased out. Full Article
carbon CarbonX By www.safetyandhealthmagazine.com Published On :: Mon, 30 Mar 2015 00:07:00 -0400 Constructed to be truly non-flammable and lightweight, CarbonX® RepelTM provides maximum comfort while delivering extraordinary protection against heat, flame, molten metal, certain chemicals, and flammable liquids. Sparks, spatter and splash simply roll off the material. CarbonX offers a choice of Repel fabric options. Visit www.carbonx.com or call (801) 415-0025. Click here for more information from CarbonX Full Article
carbon Carbon monoxide: The silent killer By www.safetyandhealthmagazine.com Published On :: Sun, 29 Aug 2021 00:00:00 -0400 Do your employees use gas-powered equipment at work? If so, they may be exposed to carbon monoxide. Full Article
carbon Don’t be overcome by carbon monoxide By www.safetyandhealthmagazine.com Published On :: Mon, 24 Mar 2014 00:00:00 -0400 Workers who operate equipment such as cutting saws, pumps and generators in buildings or semi-enclosed spaces are at risk for carbon monoxide poisoning – even in areas that appear well-ventilated. Full Article
carbon CarbonX By www.safetyandhealthmagazine.com Published On :: Mon, 22 Dec 2014 00:06:00 -0500 Stay safe and warm with the CarbonX® Ultimate™ Baselayer. The Ultimate Baselayer delivers the highest level of protection and comfort. Truly non-flammable, it will not burn, melt or ignite – even after intense exposure to flame and heat. For more information, visit www.carbonx.com or call (801) 415-0025. Click here for more information from CarbonX Full Article
carbon Carbon monoxide: The ‘silent killer’ By www.safetyandhealthmagazine.com Published On :: Sun, 23 Jul 2017 00:00:00 -0400 You can’t smell it, taste it or see it, but it can be deadly. Carbon monoxide – sometimes referred to as the “silent killer” – prevents oxygen from going into the body and can result in death in a short period of time, the Michigan Department of Community Health states. But how does carbon monoxide form, and when are workers at risk? Full Article
carbon CarbonX By www.safetyandhealthmagazine.com Published On :: Sat, 01 Aug 2015 00:07:00 -0400 Booth #3426 (Chapman Innovations) CarbonX® with Z-Flex® Aluminization enhances both protection and comfort for individuals working in molten-metal and high-heat environments. Unlike other aluminized fabrics that can be rigid and heavy, CarbonX aluminized solutions are flexible and lightweight yet still provide maximum temperature resistance and extraordinary protection against splash, spatter and sparks. Visit www.carbonx.com. Click here for more information from CarbonX Product information is provided by manufacturers. This publication has not independently tested manufacturers' products and cannot assume responsibility for the validity of product claims. Full Article
carbon Future Salad Carbon Neutral Drinkable Salad By www.preparedfoods.com Published On :: Wed, 09 Oct 2024 11:00:00 -0400 The nutritious drink aids detoxification, supporting gut health and enhancing energy, skin clarity, and overall vitality. Full Article
carbon Interface Pioneers Embodied Carbon Metrics on Floor Plans, Empowering Sustainable Design By www.floortrendsmag.com Published On :: Fri, 11 Oct 2024 11:00:00 -0400 Interface introduces project-specific embodied carbon metrics on all floor plans created by its Design Studio. This industry-first initiative allows customers to easily understand the carbon impact of their flooring choices, comparing Interface products to industry averages. Full Article
carbon Mars Touts Progress on Decarbonization Initiatives By www.foodengineeringmag.com Published On :: Wed, 24 Jul 2024 09:48:00 -0400 When Mars published the Mars Net Zero Roadmap in 2023, the company committed to investing more than $1 billion over three years – and continuing to commit financial resources as needed until net zero is achieved. Full Article
carbon Carbon dioxide chiller provides ample cold for dairy and replaces propane heat for hot water By www.foodengineeringmag.com Published On :: Wed, 23 Feb 2022 15:00:00 -0500 With this carbon dioxide chiller installed at a dairy, not only does it cool the milk better, it also provides heat for washing equipment. Full Article
carbon Raise Cold-chain Temps From 0°F To 5°F, Save Energy and Slash Carbon Emissions By www.foodengineeringmag.com Published On :: Tue, 14 May 2024 05:02:14 -0400 What’s not to like about improving sustainability and protecting the environment while saving energy and money—and best of all, no equipment or software expenditures are necessary. Full Article
carbon From Tree Tops to Deep Roots: The Role of Eastern Forests as Carbon Sinks By indianapublicmedia.org Published On :: 15 Nov 2024 00:00:00 GMT Virtual Zoom event Thursday, November 14, 2024, 7 – 8:30pm Sycamore Land Trust and Citizens’ Climate Lobby Indiana present a free lecture and Q&A with Dr. Richard Phillips “From Tree Tops to Deep Roots: The Role of Eastern Forests as Carbon Sinks.” We’ll discuss how eastern forest ecosystems serve as important carbon sinks that can help mitigate rapid climate change, and explore above- and below-ground processes in forests and how they contribute to the land sink for carbon. Dr. Richard Phillips is a Professor of Biology at Indiana University, Bloomington, Director of the Ecology and Evolutionary Biology Graduate Program, and Science Director at IU Research and Teaching Preserve. Presenter: Sycamore Land Trust and Citizens' Climate Lobby Indiana Contact: Kate Hammel, Communications Director Cost: Free Ticket Phone: 812-336-5382 Ticket Web Link: sycamorelandtrust.org… Communities: Bedford, Bloomington, Brown County, Columbus, Franklin, French Lick/West Baden, Greencastle, Greene County, Greensburg, Greenwood, Indianapolis, Kokomo, Martinsville, Seymour, Spencer, Statewide, Terre Haute More info: sycamorelandtrust.org… Full Article 2024/11/14 (Thu)
carbon TrusTrace spotlights ‘Data-Driven Decarbonisation’ at COP29: Navigating Fashion’s Path to Net Zero By www.retailtechnologyreview.com Published On :: Thu, 13 Nov 3000 17:31:48 +0000 TrusTrace, a global SaaS company with a platform for product traceability and supply chain compliance in fashion and retail, host a key session at COP29 entitled, ‘Data-Driven Decarbonisation: Navigating Fashion’s Path to Net Zero’ on November 16th from 13.00-13.40 at the Swedish Pavilion, C17, COP29 Blue Zone. Full Article Retail Supply Chain Data Capture Exhibitions and Events
carbon Hydrocarbon systems - British Geological Survey By news.google.com Published On :: Thu, 24 Sep 2020 01:15:52 GMT Hydrocarbon systems British Geological Survey Full Article
carbon Effect of thickness and noise on angular correlation analysis from scanning electron nanobeam diffraction of disordered carbon By journals.iucr.org Published On :: The impact of sample thickness and experimental noise on angular correlation analysis from scanning electron nanobeam diffraction patterns of disordered carbon are investigated and analyzed regarding the interpretability of the analysis results. Full Article text
carbon Crystal structure of a solvated dinuclear CuII complex derived from 3,3,3',3'-tetraethyl-1,1'-(furan-2,5-dicarbonyl)bis(thiourea) By journals.iucr.org Published On :: In the title compound, [Cu2(L)2]·2CH2Cl2, the CuII ions coordinate two (S,O)-chelating aroylthiourea moieties of doubly deprotonated furan-2,5-dicarbonylbis(N,N-diethylthiourea) (H2L) ligands. The coordination geometry of the metal centers is best described as a flat isosceles trapezoid with a cis arrangement of the donor atoms. Full Article text
carbon Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N']rhenium(I) By journals.iucr.org Published On :: Crystallization of the title compound from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorph adopt a six-coordinate octahedral geometry with three facially-oriented carbonyl ligands, one bromido ligand, and two nitrogen atoms from one chelating ligand ppt-OMe. In the crystal, both polymorph α and β form di-periodic sheet-like architectures supported by multiple hydrogen bonds. Full Article text
carbon Crystal structures of two polymorphs for fac-bromidotricarbonyl[4-(4-methoxyphenyl)-2-(pyridin-2-yl)thiazole-κ2N,N']rhenium(I) By journals.iucr.org Published On :: 2024-11-08 Crystallization of the title compound, fac-[ReBr(ppt-OMe)(CO)3] (ppt-OMe = C15H12N2OS), from CH2Cl2/n-pentane (1:5 v/v) at room temperature gave two polymorphs, which crystallize in monoclinic (P21/c; α form) and orthorhombic (Pna21; β form) space groups. The ReI complex molecules in either polymorph adopt a six-coordinate octahedral geometry with three facially-oriented carbonyl ligands, one bromido ligand, and two nitrogen atoms from one chelating ligand ppt-OMe. In the crystal, both polymorph α and β form di-periodic sheet-like architectures supported by multiple hydrogen bonds. In polymorph α, two types of hydrogen bonds (C—H...O) are found while, in polymorph β, four types of hydrogen bonds (C—H...O and C—H...Br) exist. Full Article text
carbon Crystal structure of a solvated dinuclear CuII complex derived from 3,3,3',3'-tetraethyl-1,1'-(furan-2,5-dicarbonyl)bis(thiourea) By journals.iucr.org Published On :: 2024-11-08 Reaction between equimolar amounts of 3,3,3',3'-tetraethyl-1,1'-(furan-2,5-dicarbonyl)bis(thiourea) (H2L) and CuCl2·2H2O in methanol in the presence of the supporting base Et3N gave rise to a neutral dinuclear complex bis[μ-3,3,3',3'-tetraethyl-1,1'-(furan-2,5-dicarbonyl)bis(thioureato)]dicopper(II) dichloromethane disolvate, [Cu2(C16H22N4O3S2)2]·2CH2Cl2 or [Cu2(L)2]·2CH2Cl2. The aroylbis(thioureas) are doubly deprotonated and the resulting anions {L2–} bond to metal ions through (S,O)-chelating moieties. The copper atoms adopt a virtually cis-square-planar environment. In the crystal, adjacent [Cu2(L)2]·2CH2Cl2 units are linked into polymeric chains along the a-axis direction by intermolecular coordinative Cu...S interactions. The co-crystallized solvent molecules play a vital role in the crystal packing. In particular, weak C—Hfuran...Cl and C—Hethyl...Cl contacts consolidate the three-dimensional supramolecular architecture. Full Article text
carbon Methyl N-{(1R)-2-[(methoxycarbonyl)oxy]-1-phenylethyl}carbamate By journals.iucr.org Published On :: 2024-03-21 The title molecule, C12H15NO5, is a methyl carbamate derivative obtained by reacting (R)-2-phenylglycinol and methyl chloroformate, with calcium hydroxide as heterogeneous catalyst. Supramolecular chains are formed in the [100] direction, based on N—H⋯O hydrogen bonds between the amide and carboxylate groups. These chains weakly interact in the crystal, and the phenyl rings do not display significant π–π interactions. Full Article text
carbon trans-Diaquatetrakis(tetrahydrofuran-κO)iron(II) μ-carbonyl-tetradecacarbonyltetrachlorido-μ-dimethylsilanediolato-tetragalliumtetrairon(7 Ga–Fe)(Fe–Fe) tetrahydro By journals.iucr.org Published On :: 2024-06-28 The title compound, [Fe(C4H8O)4(H2O)2][Fe4Ga4(C2H6O2Si)Cl4(CO)15]·4C4H8O, consists of an iron(II) cation octahedrally coordinated by two water molecules (trans) with four tetrahydrofurans (THF) at equatorial sites. Two additional THF molecules are hydrogen bonded to each of the water molecules. The dianion of the title compound is an organometallic butterfly complex with a dimethyl siloxane core and two iron-gallium fragments. The lengths of the iron to gallium metal–metal bonds range from 2.3875 (6) to 2.4912 (6) Å. Full Article text
carbon Dicarbonyl-1κ2C-μ-chlorido-2:3κ2Cl:Cl-pentachlorido-2κ2Cl,3κ3Cl-[1(η6)-toluene]digallium(III)ruthenium(I)(Ru—Ga) By journals.iucr.org Published On :: 2024-07-09 The title compound, [RuGa2Cl6(C7H8)(CO)2] or [(CO)2(GaCl2)(η6-toluene)Ru]+[GaCl4]−, was isolated from the reaction of Ga2Cl4 with diphenylsilanediol in toluene, followed by the addition of Ru3(CO)12. The compound contains a ruthenium–gallium metal–metal bond with a length of 2.4575 (2) Å. Full Article text
carbon 1-Ethoxy-3-[4-(ethoxycarbonyl)phenyl]-3-hydroxy-1-oxopropan-2-aminium chloride By journals.iucr.org Published On :: 2024-10-31 The title compound, C14H20NO5+·Cl−, was prepared as a racemate of R,R- and S,S-enantiomers by reduction of the corresponding hydroxyiminoketone. In the crystal, layers are formed via hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected via interdigitated benzoic ester groups. Full Article text
carbon From X-ray crystallographic structure to intrinsic thermodynamics of protein–ligand binding using carbonic anhydrase isozymes as a model system By journals.iucr.org Published On :: 2024-06-10 Carbonic anhydrase (CA) was among the first proteins whose X-ray crystal structure was solved to atomic resolution. CA proteins have essentially the same fold and similar active centers that differ in only several amino acids. Primary sulfonamides are well defined, strong and specific binders of CA. However, minor variations in chemical structure can significantly alter their binding properties. Over 1000 sulfonamides have been designed, synthesized and evaluated to understand the correlations between the structure and thermodynamics of their binding to the human CA isozyme family. Compound binding was determined by several binding assays: fluorescence-based thermal shift assay, stopped-flow enzyme activity inhibition assay, isothermal titration calorimetry and competition assay for enzyme expressed on cancer cell surfaces. All assays have advantages and limitations but are necessary for deeper characterization of these protein–ligand interactions. Here, the concept and importance of intrinsic binding thermodynamics is emphasized and the role of structure–thermodynamics correlations for the novel inhibitors of CA IX is discussed – an isozyme that is overexpressed in solid hypoxic tumors, and thus these inhibitors may serve as anticancer drugs. The abundant structural and thermodynamic data are assembled into the Protein–Ligand Binding Database to understand general protein–ligand recognition principles that could be used in drug discovery. Full Article text
carbon Crystal structure of tricarbonyl[η4-6-exo-(triphenylphosphino)cyclohepta-2,4-dien-1-one]iron(0) tetrafluoroborate By journals.iucr.org Published On :: 2024-06-18 The molecular structure of tricarbonyl[η4-6-exo-(triphenylphosphino)cyclohepta-2,4-dien-1-one]iron(0) tetrafluoroborate dichloromethane hemisolvate, [Fe(C28H22O4)(CO)3]BF4·0.5CH2Cl2, as determined by single-crystal X-ray diffraction is reported. The two independent tricarbonyl[η4-6-exo-(triphenylphosphino)cyclohepta-2,4-dien-1-one] iron(0) cations and their corresponding anions form dimers, which constitute the asymmetric unit of the structure parallel to the (100) plane. Solid-state stability within that asymmetric unit as well as between neighboring dimeric units is afforded by C—H⋯O and C—H⋯F hydrogen bonds and C—H⋯π and Y—X⋯π (Y = B, C; X = F, O) interactions, which yield diperiodic sheets and a three-dimensional extended network. Full Article text