carbon

Improved microbial water quality and ozone performance following coagulation: implications for carbon based advanced treatment for potable reuse

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00638K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christina M. Morrison, Ariel J. Atkinson, Daniel Gerrity, Eric C. Wert
Coagulation/flocculation of secondary effluent with FeCl3 (1) removed MS2 bacteriophage and bacterial endospores up to 2–3 LRVs, (2) removed rapid surrogates at levels correlative with microbial removal, and (3) improved downstream O3 performance.
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carbon

Faster decarbonization of heavy industries in low-carbon power grids: using process flexibility for handling grid congestions

Energy Environ. Sci., 2024, 17,8838-8854
DOI: 10.1039/D4EE03888F, Paper
Sverre Stefanussen Foslie, Brage Rugstad Knudsen, Sigurd Bjarghov, Magnus Korpås
This work highlights the importance of process flexibility in industry decarbonization, showing it can enhance transmission grid capacity at costs comparable to other grid reinforcement measures, thereby enabling faster electrification of demand.
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carbon

Anti-dissolving Fe2N6 site-based carbon fiber membranes for binder-free Zn–air batteries with a 200-day lifespan

Energy Environ. Sci., 2024, 17,8722-8733
DOI: 10.1039/D4EE03148B, Paper
Open Access
Zian Xu, Jian Zhu, Jingze Shao, Yu Xia, Pengfei Liu, Guangshe Li, Rouxi Chen, Shaoqing Chen, Jiacheng Wang, Shi Chen, Fuqiang Huang, Hsing-Lin Wang
The anti-dissolving Fe2N6 structure enables ZABs to operate over 200 days (record-breaking 14 500 cycles).
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carbon

Techno-economic insights and deployment prospects of permanent carbon dioxide sequestration in solid carbonates

Energy Environ. Sci., 2024, 17,8756-8775
DOI: 10.1039/D4EE03166K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andreas Mühlbauer, Dominik Keiner, Christian Breyer
While a rapid defossilisation of the energy system is the highest priority, additional post-fossil CDR for net-negative emissions will be necessary. Routes for mineralisation (in situ-, ex situ mineralisation, enhanced rock weathering) are examined.
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carbon

Giving shape to India’s carbon credit mechanism

India’s carbon credit mechanism needs to be aligned with international and domestic realities if it is to be effective




carbon

Co3O4 supported by ultrathin-layered graphitic carbon nitride for efficient electrocatalytic evolution of oxygen

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00020J, Paper
Ruixue Luo, Xi Li, Youping Guo, Renchun Fu
An efficient OER. Co3O4@g-C3N4 using layered g-C3N4-loaded Co3O4 was significantly higher than that using g-C3N4 or Co3O4.
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carbon

General synthesis of secondary imines via reductive coupling of carbonyl and nitro compounds employing a reusable cobalt catalyst

React. Chem. Eng., 2024, 9,925-929
DOI: 10.1039/D3RE00509G, Paper
Chaochong Zhang, Yurong He, Peng Zhou, Yuandie Ma, Ziliang Yuan, Guoqiang She, Zhe Zheng, Juncheng Hu, Qingqing Jiang, Jason Chun-Ho Lam, Bo Han, Zehui Zhang, Bing Liu
Reusable nitrogen-doped carbon-encapsulated Co nanoparticle catalysts are found robust for the synthesis of secondary imines via the reductive amination of carbonyl compounds with NH3 or directly with nitro compounds.
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carbon

Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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carbon

Novel TPMS carbon-based monolithic catalysts by three-dimensional printing for enhancement of nitrobenzene hydrogenation reaction

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00049H, Paper
Haoyang Wang, Haoran Tian, Qi Zhang, Li Zhang
Preparation of periodic curved surface, structured, carbon-based catalysts using a 3D printing method achieved good results in the hydrogenation of nitrobenzene to aniline in a packed-bed micro-reactor.
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carbon

Catalytic degradation of pine sawdust over heterotopic Ca–Fe and HZSM-5 to produce aromatic hydrocarbons

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00572K, Paper
Huifen Kang, Xintong Guo, Mei An, Conghua Ma, Guozhang Chang, Qingjie Guo, Jingjing Ma
Up to 90.47% aromatic proportion and a 31.02 mg g−1 BTEX yield were obtained by heterogeneous catalysis of Ca–Fe and HZSM-5.
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carbon

Global carbon dioxide emissions set to rise 0.8% over 2023, India’s contribution to go up 4.6%

In 2023, the largest absolute contributions to global fossil CO2 (carbon dioxide) emissions were from China (31%), followed by the United States with 13% and India taking up 8%




carbon

What are carbon credits?

Possessing one carbon credit gives you a licence to emit 1,000 kg of carbon dioxide




carbon

Astronomers just found complex carbon molecules in space – a step closer to deciphering the origins of life

A new study shows that complex organic molecules (with carbon and hydrogen) likely existed in the cold, dark gas cloud that gave rise to our Solar System.




carbon

Companies’ appetite for cheap carbon offsets stokes fears of greenwashing

When a company buys carbon offsets, it pays a project elsewhere to reduce greenhouse gas emissions on its behalf – by planting trees, for example, or generating renewable energy




carbon

Shining a light on methane dry reforming – exploring the impact of visible light on carbon formation over Co/xCeO2–Al2O3

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper
George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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carbon

Cycloaddition of CO2 with epoxides into cyclic carbonates catalyzed by a binary organocatalyst under mild conditions

Catal. Sci. Technol., 2024, 14,6215-6223
DOI: 10.1039/D4CY00639A, Paper
Wen-Wang Yu, Xiang-Guang Meng, Zi-Yu Gan, Wen Li, Yu-Lian Zhang, Jie Zhou
Highly efficient capture and conversion of CO2 into cyclic carbonates from flue gas under atmospheric pressure.
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carbon

Acrylamides from 1,2-dichloroethane via palladium-catalyzed carbonylation

Catal. Sci. Technol., 2024, 14,6180-6185
DOI: 10.1039/D4CY01117A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ren-Rui Xu, Chang-Sheng Kuai, Xiao-Feng Wu
An efficient strategy for the synthesis of acrylamides via palladium-catalyzed carbonylation, using 1,2-dichloroethane and amines as starting materials has been developed.
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carbon

Selectively controlled synthesis of diethyl carbonate and methyl ethyl carbonate via transesterification of dimethyl carbonate over a KATriz/Al2O3 catalyst

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper
Open Access
Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al2O3 in fixed bed mode.
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carbon

Mechanistic Study of DETA-Modified CdS for Carbon Dioxide Reduction

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01140F, Paper
Meiyan Guo, Wanxiang Yang, Yi Li, Yongfan Zhang, Wei Lin
Cadmium sulfide (CdS) exhibits remarkable light absorption capabilities and is widely employed in photocatalytic reduction of CO2. Nevertheless, the role of crystal facet effects on the micro-scale mechanisms governing CO2...
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carbon

Green Photocatalytic N-Debenzylations with Molecular Oxygen Catalyzed by Recyclable Metal-free Tubular Carbon Nitride

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY00981A, Paper
Yufeng Wu, Jiajie Kang, Li Jianing, Mingshu Bi, Qingwei Meng
Debenzylations are widely used in fields such as pharmaceuticals and fine chemicals. In this study, metal-free tubular carbon nitride (CN-T) was prepared and used to the photocatalytic debenzylations with molecular...
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carbon

Heteroatom-doped carbon nanomaterials as potential heterogeneous Fenton reaction catalysts

Catal. Sci. Technol., 2024, 14,6662-6669
DOI: 10.1039/D4CY00248B, Paper
Haobin Tan, Xiuli Hou, Chen Zhou, Shengbo Wang, Qiang Liu, Zhenhui Xu, Peng Zhang
A volcano relationship between the catalytic activity and the adsorption energies of reaction intermediates was found for the H2O2 dissociation on heteroatom-doped carbon nanomaterials.
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carbon

Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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carbon

Highly effective solar CO2 fixation via photocatalytic carboxylation of aromatic amines with carbon dioxide over a covalent organic framework (COF) as a photocatalyst

Catal. Sci. Technol., 2024, 14,6670-6677
DOI: 10.1039/D4CY00949E, Paper
Chandani Singh, Jae Young Kim, No-Joong Park, Rajesh Kumar Yadav, Jin-Ook Baeg
Facile synthesis of the Tp-DAMS COF as a photocatalyst for efficient solar carboxylation of aromatic amines with CO2. The CO2 conversion efficiency into carboxylic acid is 99.9% without the necessity of using stoichiometric metallic reductants.
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carbon

Boron–pyridine nitrogen cooperative catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

Catal. Sci. Technol., 2024, 14,6692-6700
DOI: 10.1039/D4CY01052C, Paper
Yu-Hui Luo, Sheng Tao, Fei Chen, Zhi-Hong Du, Hao Zhang, Min Li, Ning Liu
A type of N-heterocyclic carbene (NHC)-diboron adduct in combination with tetrabutylammonium iodide (TBAI) was used as a catalyst for the synthesis of cyclic carbonates from CO2 with epoxides.
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carbon

Magnetic dimeric metal–porphyrin rings mechanically bonded around carbon nanotubes: the role of nanotube defects modulating magnetic properties

Nanoscale, 2024, 16,20342-20353
DOI: 10.1039/D4NR02984D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Rocío Sánchez-de-Armas, Nicolás Montenegro-Pohlhammer, Emilio M. Pérez, Enrique Burzurí, Carmen J. Calzado
A DFT study of mechanically bonded magnetic Co2+ and Cu2+ dimeric metal–porphyrin rings around carbon nanotubes (mMINTs) points to defcts in the NT as responsible for the different dimer–nanotube interactions and the loss of the Co2+ EPR signal.
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carbon

Active site engineering of intermetallic nanoparticles by the vapour–solid synthesis: carbon black supported nickel tellurides for hydrogen evolution

Nanoscale, 2024, 16,20168-20181
DOI: 10.1039/D4NR03397C, Paper
Open Access
Daniel Garstenauer, Patrick Guggenberger, Ondřej Zobač, Franz Jirsa, Klaus W. Richter
The intermetallic phases Ni3Te2, NiTe, NiTe2−x & NiTe2 were synthesized as carbon-black supported nanoparticles using the vapour–solid synthesis approach and were characterized for their performance in electrocatalytic hydrogen evolution.
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carbon

Carbon-based nanocarriers for plant growth promotion: Fuelling when it needs

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03268C, Review Article
Mohammad Ashfaq, Govind Gupta, Nishith Verma
Climate change (i.e., rising temperature and precipitation) due to global warming is affecting soil fertility, thereby significantly causing a decrease in agriculture production worldwide. At the same time, increasing demands...
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carbon

DON encapsulated carbon dot–vesicle conjugate in therapeutic intervention of lung adenocarcinoma by dual targeting of CD44 and SLC1A5

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR00426D, Paper
Afreen Zaman, Aparajita Ghosh, Anup Kumar Ghosh, Prasanta Kumar Das
HACD–TMAV, a carbon dot–vesicle conjugate, selectively delivered glutamine inhibitor DON to CD44-enriched cancer cells, inducing ROS triggered apoptosis by dual targeting CD44 and SLC1A5 through downregulation of PI3K/AKT/mTOR signalling cascade.
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carbon

Current progress and frontiers in three-dimensional macroporous carbon-based aerogels for electromagnetic wave absorption: a review

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03738C, Review Article
Han Ding, Bo Hu, Yu Wang, Yunchen Du
This article provides a timely review on the construction of three-dimensional macroporous carbon-based aerogels and their application in the field of electromagnetic absorption.
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carbon

Ultra-low noise measurements of ionic transport within individual single-walled carbon nanotubes

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02941K, Paper
Laure Bsawmaii, Clément Delacou, Valerii Kotok, Sébastien Méance, Koutayba Saada, M. Amine Kribeche, Saïd Tahir, Christophe Roblin, Antonin Louiset, Hanako Okuno, Manoel Manghi, John Palmeri, François Henn, Adrien Noury, Vincent Jourdain
Nanofluidic devices incorporating an individual single-walled carbon nanotube, which achieve a 1–3 orders of magnitude noise reduction over conventional devices, were fabricated using high dielectric constant materials.
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carbon

Constructing Nickel Complex/Crystalline Carbon Nitride Hybrid with a Built-in Electric Field for Boosting CO2 Photoreduction

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03586K, Paper
Yanrui Li, Linda Wang, Bo Zhan, Liangqing Zhang, Xiaolin Zhu, Xiang Gao
Sluggish charge separation dynamics resulting from the amorphous structure and the lack of driving force for graphitic carbon nitride (GCN) limits its highly effective CO2 photoreduction performance. Herein, a built-in...
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carbon

CarbonCure links with Airgas for concrete




carbon

U.K. pilots carbon capture technology




carbon

U.S. industries ask Trump administration to endorse global hydrofluorocarbon deal

With EPA regulation overturned in court, companies seek political backing for reducing HFC use domestically




carbon

3-D printing start-up Carbon seeks to be found everywhere

The start-up is taking the technology deeper into manufacturing




carbon

A carbon fiber cluster grows in South Carolina

Teijin breaks ground on a $600 million plant in Greenwood as global demand grows for the strong, lightweight material




carbon

Cerium photocatalysis conquers light hydrocarbon chemistry

Method turns challenging gaseous alkanes into liquid products




carbon

Technique tracks carbon as soil microbes munch plastic

Isotope labeling and spectroscopy allow scientists to watch how soil microbes break down a mulch product used in agriculture




carbon

Technique tracks carbon as soil microbes munch plastic

Isotope labeling and spectroscopy allow scientists to watch how soil microbes break down a mulch product used in agriculture




carbon

Light-driven ultrafast dual C–C cleavage and coupling of dihydroxyacetone into high-purity carbon monoxide and ethylene glycol

Green Chem., 2024, 26,10859-10866
DOI: 10.1039/D4GC04180A, Paper
Fanhao Kong, Hongru Zhou, Zhiwei Chen, Zhaolin Dou, Min Wang
Reforming of biomass-based dihydroxyacetone to produce high-purity CO and ethylene glycol is achieved via a distinctive photochemical process under ambient conditions.
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carbon

Postliminary treatment of food-waste digestate via combined hydrothermal carbonization and microbial fuel cell for bio-energy recovery: a comparative life cycle impact assessment

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04081C, Paper
Shraddha Yadav, Manikanta M. Doki, Makarand M. Ghangrekar, Brajesh K. Dubey
Multiple resource recovery from food-waste digestate by deploying hydrothermal carbonisation and microbial fuel cells. A green route for environmental sustainability and economic gains.
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carbon

Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04502E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiajun Zhang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng Wu
This paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.
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carbon

Continuous-flow Synthesis of Cyclic Carbonates with Polymer-supported Imidazolium-based Ionic Liquid (Im-PSIL) Catalysts

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04499A, Communication
Open Access
Zhibo Yu, Haruro Ishitani, Shu Kobayashi
Carbon dioxide (CO2), a major greenhouse gas emitted through human activities, represents a valuable carbon source for chemical production. However, maximizing its efficiency requires novel methods for CO2 conversion that...
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carbon

Engineering in situ: N-doped porous carbon-confined FeF3 for efficient lithium storage

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04097J, Paper
Open Access
Jinlong Hu, Weijun Xu, Lingzhi Zhang
Achieving N-doped porous carbon-confined FeF3 with enhanced lithium storage performance via an innovative in situ engineering approach.
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carbon

CO2 catalyzed recycling of polyester and polycarbonate plastics

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04782F, Paper
Open Access
Qiao Zhang, Nan Wang, Chenyang Hu, Peng-Yuan Li, Fu-Quan Bai, Xuan Pang, Xuesi Chen, Xianhong Wang
CO2 was found to be an efficient catalyst for depolymerizing common waste polyesters and polycarbonates via alcoholysis, yielding valuable organic molecules. CO2 was considered a Lewis acid–base pair, activating both polymers and alcohol.
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carbon

Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review

Green Chem., 2024, 26,11061-11082
DOI: 10.1039/D4GC03829K, Tutorial Review
Zulfiqar Ali, Jiliang Ma, Runcang Sun
Biomass-derived organic acid for green and sustainable future.
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carbon

Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide

Green Chem., 2024, 26,11106-11124
DOI: 10.1039/D4GC04094E, Tutorial Review
Qiang Yuan, Xiao Cai, Weiping Ding, Yan Zhu
The homogeneous and heterogeneous catalyst systems applied in N-formylation reaction of amines and CO2 reaction from both homogeneous and heterogeneous systems are summarized.
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carbon

Augmentation of Pd-catalysed oxidative C–H/C–H carbonylation through alternating current electrosynthesis

Green Chem., 2024, 26,11177-11181
DOI: 10.1039/D4GC04569F, Paper
Haoran Li, Jiaqi Peng, Li Zeng, Linpu Zhou, Muhammad Shabbir, Feiran Xiao, Jiaxin Yuan, Hong Yi, Aiwen Lei
Unsymmetrical-waveform AC electrolysis facilitates Pd-catalysed oxidative C–H/C–H carbonylation. This methodology highlights the substantial benefits conferred by Pd-catalysed conversions in comparison to traditional DC electrolysis.
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carbon

Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04640D, Tutorial Review
Guanting Liao, Richard L. Smith Jr., Haixin Guo, Xinhua Qi
This work aims to review the latest developments in carbon-based electrocatalysts applied in electrocatalytic nitrate reduction, including pure carbon materials, heteroatom doping or metal-bonding catalysts, and carbon substrate-supported composites.
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carbon

Utilize rather than create: transforming phthalonitrile resin into N-rich hierarchical porous carbon for supercapacitor materials

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04103H, Paper
Yi Li, Qiancheng Liu, Qian Zhang, Xiaoxiao Li, Yang Yang, Pan Wang, Kui Li, Ying Li, Fei Zhong, Qi Liu, Yun Zheng, Xulin Yang, Peng Zhao
The “utilize rather than create” strategy employs the reaction product (RPH) as the precursor and the by-product (KCl) as the template for the synthesis of N-rich hierarchical porous carbon for high performance supercapacitor materials.
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