A total of 7,740 dedicated Covid-19 facilities in 483 districts have been identified, the Union health ministry said on Sunday, asserting that adequa

A total of 7,740 dedicated COVID-19 facilities in 483 districts have been identified, the Union health ministry said on Sunday, asserting that adequate health infrastructure is in place to fight the pandemic.

75 nieuwe coronadoden, 83 nieuwe ziekenhuisopnames  De Standaard

LIVE. Laatste 24 uur 75 overlijdens gerapporteerd en 83 nieuwe ziekenhuisopnames  Het Laatste Nieuws

As per SOPA estimates, the actual area in Maharashtra is 36.390 lakh hectare, which is 10% less than the government estimates of 40.433 lakh hectare. Soyabean output in Maharashtra is estimated to rise by 32% to 38.4 lakh tonne for this year.

Outstanding promoters’ pledged shares were Rs 1.95 lakh crore, which is about 1.38% of the total BSE-500 Index’s market capitalisation in March 2019.

Debian Security Advisory DSA 830-1 - Drew Parsons noticed that the post-installation script of ntlmaps, an NTLM authorization proxy server, changes the permissions of the configuration file to be world-readable. It contains the user name and password of the Windows NT system that ntlmaps connects to and, hence, leaks them to local users.

176 cases of COVID-19 have been confirmed in Lagos State. The State Ministry of Health made the confirmation in a tweet on Saturday. It said the development brings the total number of confirmed cases in the state to 1683 The ministry tweeted, “176 new cases of #COVID19 Infection confirmed “Total confirmed cases in Lagos now […]

COVID-19: Lagos Govt confirms 176 new cases as toll hits 1683

The Deputy Information Commissioner has ruled that the Department for Business, Enterprise and Regulatory Reform (BERR) must release the names and addresses of respondents in Employment Tribunal cases under the Freedom of Information Act 2000, havin...

पिछले 9 दिनों में 8 राज्यों के 20 ग्रीन जिलों में 283 कोरोना संक्रमित मरीज सामने आ चुके हैं। कुछ राज्यों में तो इसी अवधि में संक्रमितों की संख्या 50 फीसदी से भी ज्यादा बढ़ोतरी हुई है।

सूरत से 2617 और लुधियाना से आए 1246 लोग  लुधियाना से आने वालों में 1174 मजदूर थे प्रतापगढ़ के

श्रीनगर में एक अस्पताल की दो नर्स व एक तीमारदार समेत कोरोना के और 12 मरीज शनिवार को सामने आए।

1.2 Notice to the respondent was dispensed with, as the respondent had not yet been summoned by the Trial Court.

2 A perusal of the impugned order reveals that the Ld. Trial Court declined to take cognizance of the complaint primarily for the reason that the complainant despite availing several opportunities had not filed the ECS mandate. Further the account statement filed did not bear any stamp and was not even signed. Therefore, noticing that several opportunities have already been afforded to the complainant, the complaint was dismissed. 3 Sh.Anish Bhola, counsel for the petitioner has assailed the CR No.-83/2020 Page No.-1 of 4 impugned Order on the ground that the Ld. MM committed a grave error in observing that the ECS mandate was not on record. It is pointed out that the petitioner/ complainant along with the complaint had placed on record a ' Debit Authorization Form issued by the customer" i.e. the respondent to the petitioner bank. It is argued that the Debit Authorization Form is akin to ECS mandate. . To link the Debit Authorization Form with the loan agreement involved, an account statement was placed on record. The petitioner/complainant had also placed on record along with the complaint a memorandum issued by the bank, intimating return of the mandate on account of insufficiency of funds. Sh.Bhola has, further, argued that the offence as envisaged u/sec.-25 of the Payments & Settlement Systems Act (hereinafter referred to as 'the PSS Act') was completed, when the respondent, who had taken a loan and had issued authorization to debit the amount each month from his account failed to maintain sufficient balance in his account, thereby, resulting in failure of debit of amount. It is, therefore, argued that the Ld. MM committed a grave error in dismissing the complaint as both the documents constituting the offence were on record.

The total death toll since the outbreak came to light on Feb. 21 now stands at 30,395 the agency said, the third highest in the world after those of the United States and Britain.

சென்னை : உலகக் கோப்பையை நாம்பெற்ற போது நிகழ்ந்த பல ஆச்சரியமான சம்பவங்களையும் உண்மை நிகழ்வுகளையும் 83 திரைப்படம் விவரிக்கிறது.‘ முன்னாள் இந்திய கிரிக்கெட் அணியின் கேப்டன் கபில்தேவ் அவர்களின் வாழ்க்கை பின்னணியில் நம் அணி உலகக்கோப்பையை வென்ற உண்மை சம்பவத்தை அடிப்படையாக வைத்து எடுக்கப்பட்டுள்ள படம் தான் 83. உலகக் கோப்பைக்கான தகுதிச்

జరిగింది ఒకటే సంఘటన కావచ్చు.. అక్కడి నుంచి చరిత్ర మొదలైంది. ఆ ఘటనను చూసే విధానంలో ఎన్నో కోణాలుంటాయ్. ఒక్కొక్కరు ఒక్కోలా చూస్తారు. ఇదంతా దేని గురించి అని అనుకుంటున్నారా? భారత చరిత్రలో సువర్ణాధ్యయంగా లిఖించబడిన సంవత్సరం 1983. ఎందుకు? ఆ ఏడాది అంత ప్రత్యేకమని ఏ భారతీయుడూ ప్రశ్నించడు. కపిల్ దేవ్ సారథ్యంలో భారత జట్టు

'83 is an upcoming Indian sports drama film directed by Kabir Khan which revolves around the true story of India's incredible cricket World Cup victory in 1983. There are several interesting aspects and facts from India's World Cup journey of how

कोरोना महामारी के चलते जरूरतमंदों की मदद के लिए बीलवा पंचायत के बाकोटी गांव के किसानों ने प्रशासन को 83 बोरी गेहूं की भेंट की है।

एसडीएम शिवपाल जाट ने कहा कि खेतड़ी के किसानों जरूरतमंदों की मदद की है। किसान अमर सिंह ने बताया कि बांकोटी के किसान हरीश डोई, बलवान भरगड़, चंद्रभान, प्रकाश, नरेश मेघवाल, राजपाल, राम सिंह, मुकेश यादव, धर्मपाल ने किसानों से संपर्क किया और देवनारायण मंदिर अनाज की बोरियां लाकर एकत्र की। प्रशासन को 83 क्विंटल अनाज सुपुर्द किया।

प्रशासन ने किसानों द्वारा दी गई 83 बोरी अनाज में से दस बोरी गेहूं गांव के ही जरूरतमंदों को वितरित कर दिया। इस दौरान ईमित्र संचालक गोपाल सिंह ने अधिकारियों को मास्क, सैनेटाइजर, पेन डायरी भेंट की। गांव के ही निवास टेलर ने एक हजार मास्क बना कर लोगों को वितरित किए। कुछ मास्क प्रशासन को भी सौंपे।

Archives, Room Use Only - HE7677.B2 P74 1883

Archives, Room Use Only - TK5613.C36 1900

Archives, Room Use Only - TK140.S5 E55 1953

Archives, Room Use Only - KFP301.A3 1884

Four people have died including one each in Delhi, Karnataka, Punjab and Maharashtra.

Of the total 452 deaths, Maharashtra tops the tally with 194 fatalities, followed by Madhya Pradesh at 57, Gujarat and Delhi at 38 each and Telengana 18.

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Erschienen 1477
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URN: urn:nbn:de:bvb:12-bsb00130335-2
URL: http://daten.digitale-sammlungen.de/~db/0013/bsb00130335/images/

The title compound, d-(+)-glucosa­mmonium potassium tetra­thio­cyanato­cobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosa­mine hydro­chloride (GlcN·HCl) and K2[Co(NCS)4]. The asymmetric unit contains a d-(+)-glucos­ammonium cation, a potassium cation, a tetra­iso­thio­cyanato­cobalt(II) complex anion and two water mol­ecules. The water mol­ecules coordinate to the potassium cation, which is further coordinated via three short K+⋯SCN− contacts involving three [Co(NCS)4]2− complex anions and via three O atoms of two d-(+)-glucosa­mmonium cations, leading to an overall eightfold coordination around the potassium cation. Hydrogen-bonding inter­actions between the building blocks consolidate the three-dimensional arrangement.

The title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2– units, two crystallographically distinct Cs+ ions and a free water mol­ecule. The crystal under investigation was twinned by reticular pseudomerohedry.

The coordination of the ligands with respect to the central atom in the complex bromido­tricarbon­yl[diphen­yl(pyridin-2-yl)phosphane-κ2N,P]rhenium(I) chloro­form disolvate, [ReBr(C17H14NP)(CO)3]·2CHCl3 or [κ2-P,N-{(C6H5)2(C5H5N)P}Re(CO)3Br]·2CHCl3, (I·2CHCl3), is best described as a distorted octa­hedron with three carbonyls in a facial conformation, a bromide atom, and a biting P,N-di­phenyl­pyridyl­phosphine ligand. Hirshfeld surface analysis shows that C—Cl⋯H inter­actions contribute 26%, the distance of these inter­actions are between 2.895 and 3.213 Å. The reaction between I and piperidine (C5H11N) at 313 K in di­chloro­methane leads to the partial decoord­ination of the pyridyl­phosphine ligand, whose pyridyl group is replaced by a piperidine mol­ecule, and the complex bromido­tricarbon­yl[diphen­yl(pyridin-2-yl)phosphane-κP](piperidine-κN)rhenium(I), [ReBr(C5H11N)(C17H14NP)(CO)3] or [P-{(C6H5)2(C5H5N)P}(C5H11N)Re(CO)3Br] (II). The mol­ecule has an intra­molecular N—H⋯N hydrogen bond between the non-coordinated pyridyl nitro­gen atom and the amine hydrogen atom from piperidine with D⋯A = 2.992 (9) Å. Thermogravimetry shows that I·2CHCl3 losses 28% of its mass in a narrow range between 318 and 333 K, which is completely consistent with two solvating chloro­form mol­ecules very weakly bonded to I. The remaining I is stable at least to 573 K. In contrast, II seems to lose solvent and piperidine (12% of mass) between 427 and 463 K, while the additional 33% loss from this last temperature to 573 K corresponds to the release of 2-pyridyl­phosphine. The contribution to the scattering from highly disordered solvent mol­ecules in II was removed with the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9-18] in PLATON. The stated crystal data for Mr, μ etc. do not take this solvent into account.

The title hydrated salt, tris­[hexa­amminecobalt(III)] tetraoxidorhenate(VII) tetra­kis­[hexa­fluorido­rhenate(IV)] hexa­hydrate, arose unexpectedly due to possible contamination of the K2ReF6 starting material with KReO4. It consists of octa­hedral [Co(NH3)6]3+ cation (Co1 site symmetry 1), tetra­hedral [ReVIIO4]− anions (Re site symmetry 1) and octa­hedral [ReIVF6]2− anions (Re site symmetries 1and overline{3}). The [ReF6]2− octa­hedral anions (mean Re—F = 1.834 Å), [Co(NH3)6]3+ octa­hedral cations (mean Co—N = 1.962 Å), and the [ReO4]− tetra­hedral anion (mean Re—O = 1.719 Å) are slightly distorted. A network of N—H⋯F hydrogen bonds consolidates the structure. The crystal studied was refined as a two-component twin.

The syntheses and crystal structures of three hybrid perovskites, viz. poly[1-methyl­piperizine-1,4-diium [tri-μ-bromido-potassium] hemihydrate], {(C5H14N2)[KBr3]·0.5H2O}n, (I), poly[1-methyl­piperizine-1,4-diium [tri-μ-bromido-rubidium] hemihydrate], {(C5H14N2)[RbBr3]·0.5H2O}n, (II), and poly[1-methyl­piperizine-1,4-diium [tri-μ-bromido-caesium] hemihydrate], {(C5H14N2)[CsBr3]·0.5H2O}n, (III), are described. These isostructural (space group Amm2) phases contain a three-dimensional, corner-sharing network of distorted ABr6 octa­hedra (A = K, Rb, Cs) with the same topology as the classical perovskite structure. The doubly protonated C5H14N22+ cations occupy inter­stices bounded by eight octa­hedra and the water mol­ecules lie in square sites bounded by four octa­hedra. N—H⋯Br, N—H⋯(Br,Br), N—H⋯O and O—H⋯Br hydrogen bonds consolidate the structures.

Highly Brønsted-acidic boron trifluoride monohydrate, a widely used `super acid-catalyst', is a colourless fuming liquid that releases BF3 at room temperature. Com­pared to the liquid com­ponents, i.e. boron trifluoride monohydrate and 1,4-dioxane, their 1:1 adduct, BF3H2O·C4H8O2, is a solid with pronounced thermal stability (m.p. 401–403 K). The crystal structure of the long-time-stable easy-to-handle and weighable com­pound is reported along with new preparative aspects and the results of 1H, 11B, 13C and 19F spectroscopic investigations, particularly documenting its high Brønsted acidity in aceto­nitrile solution. The remarkable stability of solid BF3H2O·C4H8O2 is attributed to the chain structure established by O—H⋯O hydrogen bonds of exceptional strength {O2⋯H1—O1 [O⋯O = 2.534 (3) Å] and O1—H1⋯O3i [2.539 (3) Å] in the concatenating unit >O2⋯H1—O1—H2⋯O3i<}, taking into account the mol­ecular (non-ionic) character of the structural moieties. Indirectly, this structural feature documents the outstanding acidification of the H2O mol­ecule bound to BF3 and reflects the super acid nature of BF3H2O. In detail, the C22(7) zigzag chain system of hydrogen bonding in the title structure is characterized by the double hydrogen-bond donor and double (κO,κO') hydrogen-bond acceptor functionality of the aqua ligand and dioxane molecule, respectively, the almost equal strength of both hydrogen bonds, the approximatety linear arrangement of the dioxane O atoms and the two neighbouring water O atoms. Furthermore, the approximately planar arrangement of B, F and O atoms in sheets perpendicular to the c axis of the ortho­rhom­bic unit cell is a characteristic structural feature.

Deuterated potassium orthophosphate hepta­hydrate, K3PO4·7D2O, crystallizes in the Sohnke space group P21, and its absolute structure was determined from 2017 Friedel pairs [Flack parameter 0.004 (16)]. Each of the three crystallographically unique K+ cations is surrounded by six water mol­ecules and one oxygen atom from the orthophosphate group, using a threshold for K—O bonds of 3.10 Å. The highly irregular coordination polyhedra are linked by corner- and edge-sharing into a three-dimensional network that is consolidated by an intricate network of O—D⋯O hydrogen bonds of medium strength.

A peptide biphenyl hybrid compound {systematic name: dimethyl 2,2'-[((2S,2'S)-2,2'-{[(2S,2'S)-1,1'-([1,1'-biphen­yl]-2,2'-dicarbon­yl)bis­(pyrrolidine-1,2-diyl-2-carbon­yl)]bis­(aza­nedi­yl)}bis­(3-phenyl­propano­yl))bis­(aza­nedi­yl)](2S,2'S)-dipropionate hemihydrate}, C50H56N6O10·0.5H2O, was prepared by coupling of [1,1'-biphen­yl]-2,2'-dicarbonyl dichloride, tri­ethyl­amine and the tripeptide Pro–Phe–Ala in CH2Cl2 at 273 K under an N2 atmosphere. In the crystal, the asymmetric unit contains the peptide biphenyl hybrid accompanied by one-half of a water mol­ecule. A C atom of one of the proline rings is disordered between two positions in a 0.746 (11):0.254 (11) ratio. An important structural aspect of peptide compounds is their capacity to self-associate mediated by inter­molecular and intra­molecular hydrogen bonding. This characteristic can be useful in understanding the inter­actions between peptides and biomacromolecular targets, as well as to explain peptide properties.

A new pseudopolymorph of dodeca­chloro­penta­silane, namely a benzene monosolvate, Si5Cl12·C6H6, is described. There are two half mol­ecules of each kind in the asymmetric unit. Both Si5Cl12 mol­ecules are completed by crystallographic twofold symmetry. One of the benzene mol­ecules is located on a twofold rotation axis with two C—H groups located on this rotation axis. The second benzene mol­ecule has all atoms on a general position: it is disordered over two equally occupied orientations. No directional inter­actions beyond normal van der Waals contacts occur in the crystal.

The redetermined structure [for the previous study, see: Godfrey & Waters (1975). Cryst. Struct. Commun. 4, 5–8] of ammonium μ-oxido-μ-[1,5,6-tri­hydroxy­hexane-2,3,4-tris­(olato)]bis­[dioxidomolybdenum(V)] monohydrate, NH4[Mo2(C6H11O6)O5]·H2O, was obtained from an attempt to prepare a glutamic acid complex from the [Co2Mo10H4O38]6− anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds. A Hirshfeld surface analysis was also performed.

The syntheses and crystal structures of three mol­ecular salts of protonated 3,4-di­amino­benzoic acid, viz. 2-amino-5-carb­oxy­anilinium chloride, C7H9N2O2+·Cl−, (I), 2-amino-5-carb­oxy­anilinium bromide, C7H9N2O2+·Br−, (II), and 2-amino-5-carb­oxy­anilinium nitrate monohydrate, C7H9N2O2+·NO3−·H2O, (III), are described. The cation is protonated at the meta-N atom (with respect to the carb­oxy group) in each case. In the crystal of (I), carb­oxy­lic acid inversion dimers linked by pairwise O—H⋯O hydrogen bonds are seen and each N—H group forms a hydrogen bond to a chloride ion to result in (100) undulating layers of chloride ions bridged by the inversion dimers into a three-dimensional network. The extended structure of (II) features O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds: the last of these generates C(7) chains of cations. Overall, the packing in (II) features undulating (100) sheets of bromide ions alternating with the organic cations. Inter­molecular inter­actions in the crystal of (III) include O—H⋯O, O—H⋯(O,O), N—H⋯O, N—H⋯N and O—H⋯N links. The cations are linked into (001) sheets, and the nitrate ions and water mol­ecules form undulating chains. Taken together, alternating (001) slabs of organic cations plus anions/water mol­ecules result. Hirshfeld surfaces and fingerprint plots were generated to give further insight into the inter­molecular inter­actions in these structures. The crystal used for the data collection of (II) was twinned by rotation about [100] in reciprocal space in a 0.4896 (15):0.5104 (15) ratio.

White, who was a student at Columbian College from Accomack County, Va., died of pneumonia and complications from a mitral heart defect. When his coffin was unearthed, his identity was a deep mystery.

The post Remains of William Taylor White (1837-1852) donated to Smithsonian with his coffin and clothing appeared first on Smithsonian Insider.

An extraordinary outburst produced by a black hole in a nearby galaxy has provided direct evidence for a population of old, volatile stellar black holes.

The post Astronomers witness black hole outburst in Spiral Galaxy M83 appeared first on Smithsonian Insider.

During investigations of the formation of hydrated magnesium carbonates, a sample of the previously unknown magnesium carbonate hexa­hydrate (MgCO3·6H2O) was synthesized in an aqueous solution at 273.15 K. The crystal structure consists of edge-linked isolated pairs of Mg(CO3)(H2O)4 octa­hedra and noncoordinating water mol­ecules, and exhibits similarities to NiCO3·5.5H2O (hellyerite). The recorded X-ray diffraction pattern and the Raman spectra confirmed the formation of a new phase and its transformation to magnesium carbonate trihydrate (MgCO3·3H2O) at room temperature.

During evaporation of natural and synthetic K–Mg–Cl brines, the formation of almost square plate-like crystals of potassium carnallite (potassium chloride magnesium dichloride hexa­hydrate) was observed. A single-crystal structure analysis revealed a monoclinic cell [a = 9.251 (2), b = 9.516 (2), c = 13.217 (4) Å, β = 90.06 (2)° and space group C2/c]. The structure is isomorphous with other carnallite-type com­pounds, such as NH4Cl·MgCl2·6H2O. Until now, natural and synthetic carnallite, KCl·MgCl2·6H2O, was only known in its ortho­rhom­bic form [a = 16.0780 (3), b = 22.3850 (5), c = 9.5422 (2) Å and space group Pnna].