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Deciphering the hydrogen-bonding scheme in the crystal structure of tri­phenyl­methanol: a tribute to George Ferguson and co-workers

The crystal structure of tri­phenyl­methanol, C19H16O, has been redetermined using data collected at 295 and 153 K, and is compared to the model published by Ferguson et al. over 25 years ago [Ferguson et al. (1992). Acta Cryst. C48, 1272–1275] and that published by Serrano-González et al., using neutron and X-ray diffraction data [Serrano-González et al. (1999). J. Phys. Chem. B, 103, 6215–6223]. As predicted by these authors, the hy­droxy groups are involved in weak inter­molecular hydrogen bonds in the crystal, forming tetra­hedral tetra­­mers based on the two independent mol­ecules in the asymmetric unit, one of which is placed on the threefold symmetry axis of the Roverline{3} space group. However, the reliable determination of the hy­droxy H-atom positions is difficult to achieve, for two reasons. Firstly, a positional disorder affects the full asymmetric unit, which is split over two sets of positions, with occupancy factors of ca 0.74 and 0.26. Secondly, all hy­droxy H atoms are further disordered, either by symmetry, or through a positional disorder in the case of parts placed in general positions. We show that the correct description of the hydrogen-bonding scheme is possible only if diffraction data are collected at low temperature. The pro­chiral character of the hydrogen-bonded tetra­meric supra­molecular clusters leads to enanti­omorphic three-dimensional graphs in each tetra­mer. The crystal is thus a racemic mixture of supS and supR motifs, consistent with the centro­symmetric nature of the Roverline{3} space group.




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89 percent increase in loyalty program fraud, Forter reveals

(The Paypers) Forter has released the seventh edition of its Fraud Attack Index, tracking shifting behaviours...




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Auto runs program for start up.




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Startup Programs List Download




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Create Elevated Shortcut to run a Program to Bypass UAC Prompt




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How To Temporarily Disable Your Anti-virus, Firewall And Anti-malware Programs




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Program won't work in 2020




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Vehicle Emissions Inspection Programs Should Target Worst Polluters

By expending too many resources to inspect cleaner low-emitting vehicles, coupled with a lack of effective ways to deal with the dirtiest ones, states are missing opportunities to reduce air pollution.




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Federal Fuel Economy Standards Program Should Be Retooled

Although the federal program that sets fuel economy standards for cars and light-duty trucks has helped reduce U.S. dependence on imported oil and lower emissions of greenhouse gases, changes to the program could further cut the nations petroleum dependence and provide more flexibility to carmakers.




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Assessment of U.S. Doctoral Programs Released, Offers Data On More Than 5,000 Programs Nationwide

The National Research Council today released its assessment of U.S. doctoral programs, which includes data on over 5,000 programs in 62 fields at 212 universities nationwide.




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Current Test-Based Incentive Programs Have Not Consistently Raised Student Achievement in U.S. - Improved Approaches Should Be Developed and Evaluated

Despite being used for several decades, test-based incentives have not consistently generated positive effects on student achievement, says a new report from the National Research Council.




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New Report Examines Implications of Growing Gap in Life Span by Income for Entitlement Programs

As the gap in life expectancy between the highest and lowest earners in the U.S. has widened over time, high earners have disproportionately received larger lifetime benefits from government programs such as Social Security and Medicare, says a new congressionally mandated report from the National Academies of Sciences, Engineering, and Medicine.




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Possible to Account for Disadvantaged Populations in Medicare’s Value-Based Payment Programs and Improve Payment Status Quo, Says New Report

A new report from the National Academies of Sciences, Engineering, and Medicine says that Medicare’s value-based payment programs could take into account social risk factors – such as low socio-economic position, residence in disadvantaged neighborhoods, or race and ethnicity – but any proposal to do so will entail both advantages and disadvantages that need to be carefully considered.




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Revisions to WIC Program Needed - Changes Would Save Money Over Time

A new congressionally mandated report from the National Academies of Sciences, Engineering, and Medicine proposes updated revisions to the Special Supplemental Nutrition Program for Women, Infants, and Children (WIC) to better align with the Dietary Guidelines for Americans and promote and support breast-feeding.




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New Report Details Accomplishments of U.S. Global Change Research Program

The U.S. Global Change Research Program (USGCRP) has made significant accomplishments to advance the science of global environmental change and improve the understanding of its impact on society through activities such as developing Earth-observing systems, improving Earth-system modeling capabilities, and advancing understanding of carbon-cycle processes, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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ARPA-E Making Progress Toward Achieving Mission, Says New Assessment

The Advanced Research Projects Agency-Energy (ARPA-E) is making progress toward achieving its statutory mission and goals, says a new congressionally mandated report by the National Academies of Sciences, Engineering, and Medicine.




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Statement on Stop-Work Order for National Academies Study on the Department of the Interior’s Offshore Oil and Gas Operations Inspection Program

The U.S. Department of the Interior’s Bureau of Safety and Environmental Enforcement has ordered the National Academies of Sciences, Engineering, and Medicine to suspend all work on a study to review and update the bureau’s offshore oil and gas operations inspection program to enhance safety.




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National Academies’ Gulf Research Program Awards $5.3 Million to Enhance Environmental Restoration Outcomes and Improve Oil Spill Risk Assessment

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced grant awards for seven new projects totaling $5.3 million.




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EPA’s IRIS Program Has Made Substantial Progress, Says New Report

The U.S. Environmental Protection Agency’s (EPA) Integrated Risk Information System (IRIS) program has made “substantial progress” in implementing recommendations outlined in past reports by the National Academies of Sciences, Engineering, and Medicine, improving the program’s overall scientific and technical performance, says a new Academies report.




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National Academies Gulf Research Program Awards Over $340,000 to Assist Scientific Research Impacted by Hurricanes Harvey and Irma

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced 11 grant awards totaling $341,283 to assist in the recovery of Gulf Coast scientific research efforts impacted by hurricanes Harvey and Irma.




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New Report Says Programs and Services for Children With Disabilities Should Coordinate Care Across Service Sectors, Focus on Long-Term Goals

While a variety of services and programs exist to support the needs of children with disabilities and their families, a focus on achieving specific near- and long-term goals that help prepare for adulthood and coordination of care within and across service sectors are integral to encouraging healthy growth and development, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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National Academies Gulf Research Program Awards Over $287,000 to Assist Scientific Research Impacted by Hurricanes Harvey and Irma

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced 11 grant awards totaling $287,565 to assist in the recovery of Gulf of Mexico region scientific research efforts impacted by hurricanes Harvey and Irma.




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Winners Selected for the 2017-2018 TRB Airport Cooperative Research Program University Design Competition for Addressing Airport Needs

The Transportation Research Board’s Airport Cooperative Research Program (ACRP) recently selected winners for its University Design Competition for Addressing Airport Needs.




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Eight Health Professionals Selected for Robert Wood Johnson Foundation Health Policy Fellows Program at the National Academy of Medicine

The National Academy of Medicine (NAM) and Robert Wood Johnson Foundation (RWJF) today named the 2018-2019 class of RWJF Health Policy Fellows.




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National Academies’ Gulf Research Program and Sea Grant to Conduct Workshops Around the Country on Improving Regional Oil Spill Preparedness

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine is collaborating with the Sea Grant Oil Spill Science Outreach Program to convene a series of workshops aimed at improving community preparedness for future oil spills.




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Report Proposes Recommendations and New Framework to Speed Progress Toward Open Science

While significant progress has been made in providing open access to scientific research, a range of challenges -- including the economics of scientific publication and cultural barriers in the research enterprise -- must be overcome to further advance the openness of science, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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National Academies’ Gulf Research Program Announces $10 Million Grant Opportunity for Enhancing Coastal Community Resilience in the Gulf of Mexico Region

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced a new grant opportunity focused on enhancing coastal community resilience and well-being in the Gulf of Mexico region.




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National Academies Gulf Research Program Announces 2018 Science Policy Fellowships

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine today announced the recipients of its 2018 Science Policy Fellowships.




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NASA Makes Progress Toward Science Priorities Outlined in 2013-2022 Planetary Decadal Survey

Despite significant cuts to NASAs Planetary Science Division budget early in this decade, the space agency has made impressive progress in meeting goals outlined in the 2013-2022 planetary decadal survey by the National Academies of Sciences, Engineering, and Medicine, says a new midterm assessment from the National Academies.




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National Academies Gulf Research Program Announces 2018 Early-Career Research Fellowships

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine today announced the recipients of its 2018 Early-Career Research Fellowships.




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New Report Provides Guidance to USDA for Updating Its Data Programs to More Completely Understand American Agriculture

To ensure that U.S. agricultural policies are well-informed, data collection programs must be periodically revisited to reflect current realities of the agricultural sector, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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National Academies’ Gulf Research Program Awards $3.2 Million to Education Projects to Advance Scientific and Environmental Literacy in Coastal Regions

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced awards for nine new grant projects totaling $3.2 million.




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National Academies Gulf Research Program to Collaborate with Shell on Gulf of Mexico Ocean Observation Effort

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine today announced a new collaboration with Shell and others to provide $1 million in funding support for a pilot effort to convert an existing ocean mooring owned by Shell into the first long-term deep ocean observatory in the Gulf of Mexico.




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New Report Calls for Health Monitoring and Research Program on Gulf War and Post-9/11 Veterans and Descendants

To help determine if the descendants of Gulf War and post-9/11 veterans are at risk for health effects resulting from the service members’ exposure to toxicants during deployment, a new report from the National Academies of Sciences, Engineering, and Medicine recommends the creation of a health monitoring and research program (HMRP).




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National Academies Gulf Research Program Now Accepting Applications for 2019 Early-Career Research and Science Policy Fellowships

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine is now accepting applications for its Early-Career Research Fellowships and Science Policy Fellowships for 2019.




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Lauren Alexander Augustine Appointed to Lead National Academies’ Gulf Research Program

Lauren Alexander Augustine has been appointed executive director of the Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine.




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National Academies Gulf Research Program Opens New Funding Opportunity to Advance Safety Culture in the Offshore Oil and Gas Industry

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced it will award up to $10 million through a new funding opportunity to support research projects that will advance understanding and facilitate improvement of safety culture in the offshore oil and gas industry.




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National Academies Keck Futures Initiative Publishes Program Summary Sharing Lessons from 15 Years of Igniting Innovation at the Intersections of Disciplines

The National Academies Keck Futures Initiative (NAKFI) is pleased to announce the publication of Collaborations of Consequence - NAKFI’s 15 Years of Igniting Innovation at the Intersections of Disciplines.




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To Benefit From its Investments in Fusion Energy, U.S. Should Remain in ITER and Initiate a National Program of Burning Plasma Research and Technology

Along with participation in the International Thermonuclear Experimental Reactor (ITER) project – a large, international burning plasma experiment – the U.S. Department of Energy (DOE) should start a national program of accompanying research and technology to build a compact pilot plant that produces electricity from fusion at the lowest possible capital cost, says a new report from the National Academies of Sciences, Engineering, and Medicine.




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EPA Should Strengthen the Science in Its Permitting Program for Industry’s Management of Stormwater Pollution, Says Report

A new report from the National Academies of Sciences, Engineering, and Medicine offers guidance to the U.S. Environmental Protection Agency to inform the next revision of a permit program that requires industries to manage stormwater to minimize discharges of pollutants to the environment.




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New Report Identifies Ways Communities Can More Effectively Measure Progress Toward Resilience

A new report from the National Academies of Sciences, Engineering, and Medicine recommends steps U.S. communities can take to better measure their progress in building resilience to disasters, including measuring resilience around multiple dimensions of a community, and incentivizing the measurement of resilience.




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National Academies Gulf Research Program Announces 2019 Science Policy Fellowship Recipients

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine has announced the nine recipients of its 2019 Science Policy Fellowships.




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Twenty Scientists Awarded 2019 Early Career Research Fellowships by National Academies Gulf Research Program

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine announced today the recipients of its 2019 Early-Career Research Fellowships.




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National Academies’ Gulf Research Program Awards $10.7 Million in Grants to Four Gulf Coast Community Resilience Projects

The Gulf Research Program of the National Academies of Sciences, Engineering, and Medicine today announced $10.7 million in grant awards for four new projects focused on enhancing community resilience in the U.S. Gulf of Mexico region.




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Report Offers Promising Approaches to Make HHS Adolescent Health Programs More Effective

The U.S. Department of Health and Human Services (HHS) Office of the Assistant Secretary for Health (OASH) should focus funding on holistic, evidence-based, population-wide adolescent health programs that consider adolescent risk-taking as normative, according to a new report from the National Academies of Sciences, Engineering, and Medicine.




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Gulf Research Program Awards $7.25 Million to Eight Projects Working to Advance Safety Culture in the Offshore Oil and Gas Industry

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced $7.25 million in grant awards for eight projects focused on strengthening safety culture in the offshore oil and gas industry.




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Gulf Research Program Awards $2 Million to Seven Projects to Improve Understanding and Prediction of the Gulf of Mexico Loop Current System

The Gulf Research Program (GRP) of the National Academies of Sciences, Engineering, and Medicine today announced $2 million in grant awards for seven new projects through its Understanding Gulf Ocean Systems (UGOS) Grants 2 competition.




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Progress Made Toward Priorities Defined in 2013-2022 Solar and Space Physics Decadal Survey

NASA, NSF, and NOAA have made substantial progress in implementing the programs recommended in the 2013 decadal survey on solar and space physics (heliophysics) despite a challenging budgetary landscape, says a new midterm assessment from the National Academies of Sciences, Engineering, and Medicine.