chemical

Revealing the diverse electrochemistry of nanoparticles with scanning electrochemical cell microscopy

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00115J, Paper
Lachlan F. Gaudin, Cameron L. Bentley
Through presenting and discussing these findings, this article seeks to highlight complications in single-NP SECCM experiments, particularly those arising from issues with sample preparation.
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chemical

Scanning electrochemical probe microscopy: towards the characterization of micro- and nanostructured photocatalytic materials

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00136B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Giada Caniglia, Sarah Horn, Christine Kranz
The feasibility of fabricating micro- and sub-micro-sized AFM probes based on Pt-B electrodeposition for the electrochemical detection of H2 evolution is demonstrated.
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chemical

Controlling the droplet cell environment in scanning electrochemical cell microscopy (SECCM) via migration and electroosmotic flow

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00080C, Paper
Open Access
Samuel F. Wenzel, Heekwon Lee, Hang Ren
The contributions of migration and electroosmotic flow induced by electrochemical redox molecules in dual-barrel SECCM were characterised.
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chemical

Chemical models for dense solutions

Faraday Discuss., 2024, 253,79-99
DOI: 10.1039/D4FD00084F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
J.-F. Dufrêche, B. Siboulet, M. Duvail
Here we examine the question of the chemical models widely used to describe dense solutions, particularly ionic solutions.
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chemical

Nafion coated nanopore electrode for improving electrochemical aptamer-based biosensing

Faraday Discuss., 2024, Advance Article
DOI: 10.1039/D4FD00144C, Paper
Open Access
Grayson F. Huldin, Junming Huang, Julius Reitemeier, Kaiyu X. Fu
Nafion blocks the aptamer's active sites from planar gold, while the aptamer retains its redox activity from nanoporous gold.
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chemical

Emerging investigator series: in-depth chemical profiling of tire and artificial turf crumb rubber: aging, transformation products, and transport pathways

Environ. Sci.: Processes Impacts, 2024, 26,1703-1715
DOI: 10.1039/D4EM00326H, Paper
Open Access
Madison H. McMinn, Ximin Hu, Katherine Poisson, Phillip Berger, Paola Pimentel, Xinwen Zhang, Pranali Ashara, Ella L. Greenfield, Jessica Eig, Zhenyu Tian
Chemical profiling of artificial turf crumb rubber reveals time-based trends in transformation products and transport pathways.
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chemical

Pollution characteristics and risk assessment of endocrine-disrupting chemicals in surface water of national (freshwater) aquatic germplasm resource reserves in Guangdong Province

Environ. Sci.: Processes Impacts, 2024, 26,1898-1911
DOI: 10.1039/D4EM00425F, Paper
Tao Zhou, Jie Li, Weizhen Zhang, Yanyi Zeng, Yuan Gao, Haiyan Li, Wanling Yang, Yongzhan Mai, Qianfu Liu, Caiqin Hu, Chao Wang
EE2, E1, BPA, NP, and E2 were identified as high-risk substances based on comprehensive ecological risk evaluation and fish are the most sensitive organisms.
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chemical

Critical insights into data curation and label noise for accurate prediction of aerobic biodegradability of organic chemicals

Environ. Sci.: Processes Impacts, 2024, 26,1780-1795
DOI: 10.1039/D4EM00431K, Paper
Open Access
Paulina Körner, Juliane Glüge, Stefan Glüge, Martin Scheringer
The newly developed classifier has a balanced accuracy of 94.2%, better than any other classification model for aerobic biodegradability so far. During the model development, some data points needed to be excluded due to a very high variance.
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chemical

The gas phase ozonolysis and secondary OH production of cashmeran, a musk compound from fragrant volatile chemical products

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00452C, Paper
Ayomide A. Akande, Nadine Borduas-Dedekind
We quantified the lifetime of cashmeran, a musk compound, against 20 ppbv of O3 to be 85 days. In the presence of O2, cashmeran may influence the oxidative capacity indoors via production of secondary OH radicals (up to 5.1 × 105 molec cm−3).
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chemical

Quantitative read-across structure–property relationship (q-RASPR): a novel approach to estimate the bioaccumulative potential for diverse classes of industrial chemicals in aquatic organisms

Environ. Sci.: Processes Impacts, 2024, Advance Article
DOI: 10.1039/D4EM00374H, Paper
Prodipta Bhattacharyya, Pabitra Samanta, Ankur Kumar, Shubha Das, Probir Kumar Ojha
The Bioconcentration Factor (BCF) is used to evaluate the bioaccumulation potential of chemical substances in reference organisms, and it directly correlates with ecotoxicity.
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chemical

A Perspective on the Future of Quantum Chemical Software: The Example of the ORCA Program Package

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00056K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Frank Neese
TBC
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chemical

Mapping inorganic crystal chemical space

Faraday Discuss., 2024, Accepted Manuscript
DOI: 10.1039/D4FD00063C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hyunsoo Park, Anthony Onwuli , Keith Butler, Aron Walsh
The combination of elements from the Periodic Table defines a vast chemical space. Only a small fraction of these combinations yields materials that occur naturally or are accessible synthetically. Here,...
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chemical

Significant adsorption enhancements driven by pore microenvironment tuning for efficient C2H2/C2H4 separation in a chemically stable Ni7-cluster-based framework

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01856G, Research Article
Yunli Wang, Rizhao Zhang, Jin-Peng Xue, Yuqiao Chai, Bao Li, Jia Li
This study presents a stable Ni7-cluster MOF with enhanced adsorption through pore microenvironment tuning. Two types of guest-free frameworks achieve C2H2/C2H4 separation, providing deep insights into separation mechanisms.
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chemical

Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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chemical

The „chemical tug-of-war” in carborane clusters: distinct tuning on different sides of the cluster

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02566K, Research Article
Dalma Gál, Daniel Buzsaki, Balázs Szathmári, Tamas Holczbauer, Antal Udvardy, Júlia Kertész Szilágyiné, Denis Kargin, Clemens Bruhn, Rudolf Pietschnig, Zsolt Kelemen
The special C-C bond in the icosahedral closo-dicarbadodecaboranes and its high plasticity have been highlighted several times, which is reflected in the ease of tuning the C-C bond distance with...
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chemical

Exploring the optimal post-treatment strategy for boosting the electrochemical performances of a new bimetal–organic framework-based supercapacitor

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02314E, Research Article
Xinwen Dou, Mingyue Liu, Tian Cao, Chan Wang, Yingjie Zhang, Yuhang Jia, Qiang Ju, Zhenlan Fang
Effects of four kinds of post-treatment strategies on the structures, morphologies, and electrochemical behaviors of MOF derivatives are systematically investigated for the first time.
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chemical

Rationally reconstructing the surface microstructure of a chemical bath deposited electron transport layer for efficient and stable perovskite solar cells

Inorg. Chem. Front., 2024, 11,7910-7920
DOI: 10.1039/D4QI01808G, Research Article
Xinxuan Yang, Lexin Wang, Meihan Liu, Jiahui Jin, Lili Yang, Lin Fan, Maobin Wei, Huilian Liu, Haoran Chen, Jinghai Yang, Yulei Chang, Fengyou Wang
A reconstruction strategy is designed to manipulate the surface microstructure of a CBD SnO2 ETL, yielding PSCs with a high PCE >24%.
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chemical

A miniprotein receptor electrochemical biosensor chip based on quantum dots

Lab Chip, 2024, 24,1875-1886
DOI: 10.1039/D3LC01100C, Paper
Yunong Zhao, Juan Han, Jing Huang, Qing Huang, Yanbing Tao, Ruiqin Gu, Hua-Yao Li, Yang Zhang, Houjin Zhang, Huan Liu
We developed an on-chip laboratory for biomolecule interactions and kinetics analysis based on the three-electrode and high electron mobility transistor (HEMT) chip platform.
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chemical

Technoeconomic analysis of fine chemical electrosynthesis: a case study using electrooxidation of 2-methylnaphthelene to vitamin K3

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00346B, Paper
Qifeng Yang, Liping Liang, Ning Xu, Yang Li, Zhihui Wang, Dadong Shen, Yiming Mo
A cerium-mediated electrooxidation method was developed for synthesizing vitamin K3 in a green and efficient manner. A systematic technoeconomic analysis was provided to understand its potential for practical implementation.
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chemical

Two-temperature model of the non-thermal chemical dissociation of CO2

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00300D, Paper
Q. Shen, A. Pikalev, F. J. J. Peeters, J. Gans, M. C. M. van de Sanden
A two-temperature model with a vibrational temperature different from the gas temperature is presented for the decomposition of CO2.
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chemical

Catalytic pyrolysis and in situ carbonization of walnut shells: poly-generation and enhanced electrochemical performance of carbons

RSC Adv., 2024, 14,12255-12264
DOI: 10.1039/D4RA01608D, Paper
Open Access
Wenjing He, Keling Liu, Lanjun Zhang, Muxin Liu, Zhengjie Ni, Yueyang Li, Duoduo Xu, Minjie Cui, Yibo Zhao
Coupling catalytic pyrolysis and carbonization of walnut shells in one step can indeed lead to improvements in both the quality of bio-oil and gas produced, as well as the electrochemical performance of the resulting carbons.
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chemical

Gamma-irradiated stibnite thin films set a remarkable benchmark performance for photoelectrochemical water splitting

RSC Adv., 2024, 14,12475-12495
DOI: 10.1039/D4RA01382D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adel Chihi
The study sets out to show the positive impact of sulfur vacancy engineering on the structural, morphological, optical, electrical, and photoelectrochemical (PEC) properties of Sb2S3 films synthesized using the spin coating technique.
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chemical

Tunable thermal diffusivity of silk protein assemblies based on their structural control and photo-induced chemical cross-linking

RSC Adv., 2024, 14,12449-12453
DOI: 10.1039/D3RA06473E, Paper
Open Access
Michihiro Tanaka, Toshiki Sawada, Keiji Numata, Takeshi Serizawa
The tunable thermal diffusivity of silk fibroin-based assemblies (films) is demonstrated here. The control of secondary structures and subsequent photo-induced chemical cross-linking are essential for heat conduction in the films.
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chemical

Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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chemical

Correction: Facile fabrication of a graphene-based chemical sensor with ultrasensitivity for nitrobenzene

RSC Adv., 2024, 14,12633-12633
DOI: 10.1039/D4RA90041C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ali Raza, Zaka Ullah, Adnan Khalil, Rashida Batool, Sajjad Haider, Kamran Alam, Nazmina Imrose Sonil, Alvi Muhammad Rouf, Muhammad Faizan Nazar
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chemical

High performance electrochemical CO2 reduction over Pd decorated cobalt containing nitrogen doped carbon

RSC Adv., 2024, 14,13017-13026
DOI: 10.1039/D4RA01641F, Paper
Open Access
Shayan Gul, Fatima Nasim, Waheed Iqbal, Amir Waseem, Muhammad Arif Nadeem
Efficient electrocatalytic CO2 reduction reaction (eCO2RR) to various products, such as carbon monoxide (CO), is crucial for mitigating greenhouse gas emissions and enabling renewable energy storage.
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chemical

Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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chemical

Chemically engineered exogenous organic reactions in living cells for in situ fluorescence imaging and biomedical applications

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01925C, Review Article
Gang Song, Zhiwen Yang, Yiming Huang, Haotian Bai, Fengting Lv, Shu Wang
Key intracellular in situ synthesis processes, including the synthesis of near-infrared fluorescent dyes, intracellular oxidative cross-linking, polymerization, and bioorthogonal reactions, as well as their biomedical applications were summarized.
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chemical

Towards the rational design of N-(1,3-dimethylbutyl)-N'-phenyl-1,4-benzenediamine (6PPD) electrochemical sensor

Analyst, 2024, 149,5165-5173
DOI: 10.1039/D4AN00973H, Paper
Emily Dominique, Christophe Renault
The strong adsorption of 6PPD onto glassy carbon and its reversible two electron oxidation enables simple and sensitive electrochemical detection with an LOD of 10 nM.
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chemical

A cerium-doped tungsten trioxide-functionalized sensing platform for photoelectrochemical detection of ascorbic acid with high sensitivity

Analyst, 2024, 149,5206-5212
DOI: 10.1039/D4AN01165A, Paper
Xueying Zhu, Tikai Liang, Dianping Tang
A highly efficient photoelectrochemical (PEC) strategy was proposed for the determination of ascorbic acid (AA).
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chemical

Reference-free quantitative mass spectrometry in the presence of nonlinear distortion caused by in situ chemical reactions among constituents

Analyst, 2024, 149,5320-5328
DOI: 10.1039/D4AN00961D, Paper
Yusuke Hibi
Nonlinear reference-free analysis in pyrolysis-MS enables accurate compositional analysis even in reactive and interactive systems.
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chemical

Detection of several volatile organic compounds through Ar+ induced chemical ionisation using inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS)

Analyst, 2024, 149,5174-5183
DOI: 10.1039/D4AN00996G, Paper
Takafumi Hirata, Kyoko Kobayashi, Hui Hsin Khoo, Osamu Shikino, Hisashi Asanuma
A new analytical technique for detection of organic compounds using inductively coupled plasma-tandem mass spectrometry (ICP-MS/MS) is described.
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chemical

Current trends in electrochemical approaches for liver biomarker detection: a mini-review

Analyst, 2024, 149,5156-5164
DOI: 10.1039/D4AN01109K, Minireview
Open Access
Derya Yaman, Melanie Jimenez, Sofia Ferreira Gonzalez, Damion Corrigan
Electrochemical detection of liver biomarkers, including aspartate aminotransferase (AST), alanine aminotransferase (ALT), bilirubin, gamma-glutamyl transferase (GGT), alkaline phosphatase (ALP), and albumin, all with vital physiological functions.
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chemical

Alterations of the chemical profile of cholesterol in cancer tissue as traced with ToF-SIMS

Analyst, 2024, 149,5344-5352
DOI: 10.1039/D4AN01050G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Auraya Manaprasertsak, Julhash U. Kazi, Catharina Hagerling, Kenneth J. Pienta, Per Malmberg, Emma U. Hammarlund
This study uses Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) to analyze cholesterol alterations in cancer tissue, revealing changes in fragmentation and isotopes that suggest potential diagnostic vulnerabilities.
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chemical

Electrochemical and imaging evaluations of electrochemically activated screen-printed gold electrodes

Analyst, 2024, 149,5401-5410
DOI: 10.1039/D4AN00990H, Paper
Nor Dyana Zakaria, Ibrahim Luqman Salih, Hairul Hisham Hamzah, Turgut Sönmez, Muhamad Huzaifah Omar, Noorhashimah Mohamad Nor, Khairunisak Abdul Razak, Venugopal Balakrishnan
The graphic abstract displays the integration of the SPGE measurement system with an electrochemical cell-based 3D printing to evaluate the electrochemical behaviors and 3D images of both unactivated and activated SPGEs.
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chemical

Effects of media composition and light exposure on the electrochemical current response during scanning electrochemical microscopy live cell imaging

Analyst, 2024, 149,5555-5562
DOI: 10.1039/D4AN01075B, Paper
Nikita Thomas, Mengzhen Lyu, Jadon Khouv, Dhésmon Lima, Sabine Kuss
The cellular electrochemical current response is impacted by media composition and light exposure during scanning electrochemical microscopy (SECM).
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chemical

Electrochemical Sensing of Sodium ions present in Bovine Serum using 4-tert Butylcalix[4]arene as Receptor

Analyst, 2024, Accepted Manuscript
DOI: 10.1039/D4AN01297F, Paper
Adrian Ebenazer Paul, Gaurav Gaur, Abdullah Alswieleh, Jerry J. Wu, Sambandam Anandan
The concentration of sodium ions can cause severe imbalances (high pressure on blood vessels, swelling of the muscular tissues, and misfunctioning of the whole nervous system) to the system in...
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chemical

Electrochemically modulated surface plasmon waves for characterization and interrogation of DNA-based sensors

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01164C, Paper
Anil Sharma, Thomas Hulse, Aymen H. Qatamin, Monica Moreno, Klester S. Souza, Marcelo B. Pereira, Fabricio S. Campos, Leandro B. Carneiro, Antonio M. H. de Andrade, Paulo M. Roehe, Flavio Horowitz, Sergio B. Mendes
This article focuses on the application of electrochemically modulated surface plasmon waves for structural characterization and for assessing signal transduction performance of redox-labeled DNA-based sensing platforms.
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chemical

Comparing coupled cluster and composite quantum chemical methods for computing activation energies and reaction enthalpies of radical propagation reactions

Phys. Chem. Chem. Phys., 2024, 26,27536-27543
DOI: 10.1039/D4CP03676J, Paper
Timothy B. Huber, Ralph A. Wheeler
The accuracy of DLPNO-CCSD(T)/CBS and composite methods G3(MP2)-RAD and CBS-RAD is assessed against CCSD(T)/aug-cc-pVTZ for activation energies and reaction enthalpies in hydrocarbon radical addition reactions relevant to free radical polymerization.
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chemical

Electrochemical system of nitrogen-doped TiO2, Fe–N–C, and copper hexacyanoferrate electrodes for photo-assisted energy conversion in acidic wastewater treatment

Phys. Chem. Chem. Phys., 2024, 26,27498-27509
DOI: 10.1039/D4CP02063D, Paper
Bianca Tainá Ferreira, Matheus Martins, Fritz Huguenin
This study examines the electrochemical performance of nitrogen-doped TiO2, Fe–N–C, and CuHCF electrodes for energy conversion in acidic solution neutralization, capturing 62.9 kJ per mole of protons.
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chemical

Fundamental basis of mechanochemical reactivity

Phys. Chem. Chem. Phys., 2024, 26,27245-27247
DOI: 10.1039/D4CP90153C, Editorial
Adam A. L. Michalchuk, Francesco Delogu
This themed collection includes a collection of articles on the fundamental basis of mechanochemical reactivity.
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chemical

Insight into physico-chemical properties of oxalatoborate-based ionic liquids through combined experimental-theoretical characterization

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02296C, Paper
Open Access
Matteo Palluzzi, Giorgia Mannucci, Akiko Tsurumaki, Matteo Busato, Maria Assunta Navarra, Paola D’Angelo
An anion–anion attraction was inferred from the thermal behavior of oxalate-borate ionic liquids and confirmed through computational methods.
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chemical

Exploring the electrochemical properties and lithium insertion mechanisms in akaganeite (β-FeOOH) – a combined DFT/experimental study

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02947J, Paper
Paulo Roberto Garcês Gonçalves, Heitor Avelino De Abreu, Luciano Andrey Montoro, Gabriela Cordeiro Silva, Angela de Mello Ferreira, Hélio Anderson Duarte
Unveiling the unique charge/discharge characteristics of akaganeite offers valuable insights into electron transfer mechanisms through experimental and DFT calculations.
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chemical

Investigation on the combustion mechanism for NF3/H2 in DF/HF chemical lasers: a new perspective based on deep potential molecular dynamics simulations

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03014A, Paper
Yinhua Ma, Dongmei Mu, Meiheng Lv, Nan Wang, Huaxin Liu, Fangjian Shang, Jianyong Liu
Combustion-driven deuterium fluoride/hydrogen fluoride (DF/HF) lasers are a crucial type of chemical lasers.
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chemical

Theoretical Insights into the Vibrational Spectra and Chemical Bonding of Ln(III) Complexes with a Tripodal N4O3 Ligand Along the Lanthanide Series

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03677H, Paper
Francielle C Machado, Mateus M Quintano, Carlos Vital dos Santos Junior, Albano Carneiro Neto, Elfi Kraka, Ricardo Luiz Longo, Renaldo Tenorio Moura Jr.
{This study provides new theoretical insights into the vibrational spectra of Ln(III) complexes, along the lanthanide series by utilizing the LModeAGen protocol and integrating cutting-edge topological ideas. It provides a...
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chemical

Multi-scale study on the electrochemical behavior and corrosion mechanism of 5083 aluminum alloy with different microstructures in a NaCl environment

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03380A, Paper
Zhijie Dai, Zhengbing Xiao, Dahong Zhao, Sunhang Xiao, Yuanchun Huang, Qingsong Dai
Multi-scale study on the electrochemical behavior and corrosion mechanism of 5083 aluminum alloy with different microstructures in a NaCl environment.
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chemical

Magnetic field enhanced discharge and water activation of atmospheric pressure plasma jet: effect of assistance region and underlying physico-chemical mechanism

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03938F, Paper
Xiongfeng Zhou, Bin Chen, Hua Liao, Kun Liu
Magnetic field-assistance holds the promise of becoming a new or complementary approach to enhance the efficiency of atmospheric pressure plasma jet (APPJ), but there is currently a lack of research...
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chemical

Sixty years of electrochemical optical spectroscopy: a retrospective

Chem. Soc. Rev., 2024, 53,3579-3605
DOI: 10.1039/D3CS00734K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Chao-Yu Li, Zhong-Qun Tian
After sixty years of development, electrochemical optical spectroscopy has evolved from the early phase of proof-of-concept to an advanced phase with various spectroscopic modes and has contributed significantly to the field of electrochemistry.
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chemical

Electrochemical coupling in subnanometer pores/channels for rechargeable batteries

Chem. Soc. Rev., 2024, 53,3829-3895
DOI: 10.1039/D3CS01043K, Review Article
Yao-Jie Lei, Lingfei Zhao, Wei-Hong Lai, Zefu Huang, Bing Sun, Pauline Jaumaux, Kening Sun, Yun-Xiao Wang, Guoxiu Wang
This review categorizes subnanometer pores/channels (SNPCs) from structural perspective and demonstrates electrochemical couplings in SNPCs for batteries while proposing corresponding challenges and future research directions.
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chemical

Synthesis of environmentally friendly energetic cocrystal derived from commodity chemicals

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04037F, Communication
Open Access
Kazuki Inoue, Yosuke Nishiwaki, Mieko Kumasaki, Shinya Matsumoto, Ken Okada
Ammonium nitrate/glycine (2 : 1) energetic cocrystal was synthesized to address two drawbacks of ammonium nitrate: phase transitions and hygroscopicity. The cocrystal did not show phase transitions and exhibited decreased hygroscopicity.
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