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Solid-phase microextraction using a β-ketoenamine-linked covalent organic framework coating for efficient enrichment of synthetic musks in water samples

Anal. Methods, 2020, Advance Article
DOI: 10.1039/C9AY02755F, Paper
Lian Wen, Peng Wu, Lei-Lei Wang, Li-Zong Chen, Ming-Lin Wang, Xia Wang, Jin-Ming Lin, Ru-Song Zhao
This study indicated the promising applicability of the TpPa-1 as a solid-phase microextraction fiber coating for reliably detecting synthetic musks at trace levels from environmental samples.
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One-step synthesis of mitochondrion-targeted fluorescence carbon dots and fluorescent detection of silver ions

Anal. Methods, 2020, Accepted Manuscript
DOI: 10.1039/D0AY00622J, Paper
Yue Hou, Hanxiao Liu, Zhanxian Li, Hongyan Zhang, Liuhe Wei, Mingming Yu
Silver ions (Ag+) are the most representative harmful ions found in water pollution and widely used in many industries, excessive ingestion of Ag+ in the human body may interact with...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hydrothermal synthesis of Auricularia auricula derived nitrogen, phosphorus-doped carbon dots and application in Ag(I) and 4-nitrophenol detection and bioimaging

Anal. Methods, 2020, 12,2237-2243
DOI: 10.1039/D0AY00316F, Paper
Yujiao Tu, Suping Wang, Xiaotian Yuan, Pengfei Song, Yunlin Wei, Kunhao Qin, Qi Zhang, Xiuling Ji
Schematic of the synthetic route for fluorescent Aa N,P-CDs and their application in the detection of 4-NP and Ag(I) and bioimaging.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis, evaluation and molecular modelling of piceatannol analogues as arginase inhibitors

RSC Med. Chem., 2020, Advance Article
DOI: 10.1039/D0MD00011F, Research Article
J. Muller, B. Cardey, A. Zedet, C. Desingle, M. Grzybowski, P. Pomper, S. Foley, D. Harakat, C. Ramseyer, C. Girard, M. Pudlo
A quantum chemistry guided optimisation (leading to piceatannol analogue 3t) with a good understanding of the catechol binding mode to the bimanganese cluster of arginase.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and 18F-radiolabeling of thymidine AMBF3 conjugates

RSC Med. Chem., 2020, Advance Article
DOI: 10.1039/D0MD00054J, Research Article
Antonio A. W. L. Wong, Jerome Lozada, Mathieu L. Lepage, Chengcheng Zhang, Helen Merkens, Jutta Zeisler, Kuo-Shyan Lin, François Bénard, David M. Perrin
One step radiofluorination of two thymidine bioconjugates for positron emission tomography (PET) imaging; proof concept with clinical-grade 18F-labeling and preliminary mouse images.
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Unveiling the active isomer of cycloalanopine, a cyclic opine from Lactobacillus rhamnosus LS8, through synthesis and analog production

RSC Med. Chem., 2020, 11,528-531
DOI: 10.1039/D0MD00033G, Research Article
Isaac Antwi, Sorina Chiorean, Marco J. van Belkum, John C. Vederas
Stereochemistry of the antimicrobial isomer of a cyclic opine was determined by synthesis using oxidative cyclisation of a bis-hydrazide.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Managing state transportation research programs: a synthesis of highway practice / Donald Ludlow, Vivek Sakhrani, Camille Wu

Barker Library - TE7.N2755 no.522




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Prioritization of freight investment projects: a synthesis of highway practice / Mario M. Monsreal, Matthew Miller, Madison Metsker-Galarza, Madison Graham, Juan Carlos Villa

Barker Library - TE7.N2755 no.542




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[ASAP] Structural Characterization of Individual a-Synuclein Oligomers Formed at Different Stages of Protein Aggregation by Atomic Force Microscopy-Infrared Spectroscopy

Analytical Chemistry
DOI: 10.1021/acs.analchem.0c00593




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Synthetic seeds: germplasm regeneration, preservation and prospects / Mohammad Faisal, Abdulrahman A. Alatar, editors

Online Resource




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A practical guide to active colloids: choosing synthetic model systems for soft matter physics research

Soft Matter, 2020, 16,3846-3868
DOI: 10.1039/D0SM00222D, Review Article
Wei Wang, Xianglong Lv, Jeffrey L. Moran, Shifang Duan, Chao Zhou
This review article provides practical, experimentally relevant details on six common types of active colloids useful for soft matter research.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mix and match—a versatile equilibrium approach for hybrid colloidal synthesis

Soft Matter, 2020, Advance Article
DOI: 10.1039/D0SM00202J, Communication
Matan Yah Ben Zion, Yaelin Caba, Ruojie Sha, Nadrian C. Seeman, Paul M. Chaikin
We outline a simple yet general equilibrium technique for a scalable, high-purity, hybrid-colloidal synthesis with controlled valency. The method is applicable for liquid and solid particles and to a range of particle interactions.
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Lipid-core/polymer-shell hybrid nanoparticles: synthesis and characterization by fluorescence labeling and electrophoresis

Soft Matter, 2020, 16,4173-4181
DOI: 10.1039/D0SM00077A, Paper
Sophie Bou, Xinyue Wang, Nicolas Anton, Redouane Bouchaala, Andrey S. Klymchenko, Mayeul Collot
New hybrid nanoparticles have been obtained by simple nanoprecipitation using fluorescent labeling of both the oily core (BODIPY) and the polymeric shell (rhodamine) thus allowing the use of electrophoresis to assess their formation and stability.
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Ionic effects on synthetic polymers: from solutions to brushes and gels

Soft Matter, 2020, 16,4087-4104
DOI: 10.1039/D0SM00199F, Review Article
Haiyang Yuan, Guangming Liu
In this review, the polymer solutions, brushes, and gels are employed to exemplify the ionic effects on synthetic polymers.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Structural characterization of fibrous synthetic hydrogels using fluorescence microscopy

Soft Matter, 2020, 16,4210-4219
DOI: 10.1039/C9SM01828J, Paper
Open Access
Johannes Vandaele, Boris Louis, Kaizheng Liu, Rafael Camacho, Paul H. J. Kouwer, Susana Rocha
The structural features of the matrix surrounding the cells play a crucial role in regulating their behavior.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Protonated state and synergistic role of Nd3+ doped barium cerate perovskite for the enhancement of ionic pathways in novel sulfonated polyethersulfone for H2/O2 fuel cells

Soft Matter, 2020, 16,4220-4233
DOI: 10.1039/D0SM00427H, Paper
R. Gayathri, M. Ramesh Prabhu
1.8 times higher current density and power density were obtained for a Nd3+ doped barium cerate membrane compared to pure SPES.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Simulations of Interpenetrating Networks Microgel Synthesis

Soft Matter, 2020, Accepted Manuscript
DOI: 10.1039/D0SM00287A, Paper
Vladimir Yurievich Rudyak, Elena Kozhunova, Alexander V. Chertovich
In this paper we implement the sequential template synthesis of the interpenetrating network (IPN) microgels in computer simulations and study the behavior of such particles. We explore the influence of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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KNPP unit 1 synchronised with southern power grid, generates 160 MW power

The synchronisation coincided with Prime Minister Manmohan Singh's three-day visit to Russia.




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An electrochemical study of oxidative dissolution of synthetic nickel-iron-sulphide minerals in aqueous media [electronic resource] / by Terence Edwin Warner

Warner, Terence E., 1960-




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Zeolites : synthesis, chemistry, and applications / Moisey K. Andreyev and Olya L. Zubkov, editors




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Chemical and electrochemical leaching studies of synthetic and natural ilmenite in hydrochloric acid solutions / by Nurul Ain Jabit

Jabit, Nurul Ain, author




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001 JSJ Asynchronous Programming

The panelists discuss asynchronous programming.




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081 JSJ Promises for Testing Async JavaScript with Pete Hodgson

Pete Hodgson crosses over from the iPhreaks podcasts to talk with the Jabber gang about testing asynchronous Javascript with promises.




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114 JSJ Asynchronous UI and Non-Blocking Interactions with Elliott Kember

The panelists talk to Elliot Kember about asynchronous UI and non-blocking interactions.




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JSJ 329: Promises, Promise.finally(), and Async/await with Valeri Karpov

Panel:

  • Charles Max Wood
  • AJ O’Neal
  • Aimee Knight

Special Guests: Valeri Karpov 

In this episode, the panel talks with programmer, Valerie Karpov from Miami, Florida. He is quite knowledgeable with many different programs, but today’s episode they talk specifically about Async/Await and Promise Generators. Val is constantly busy through his different endeavors and recently finished his e-book, “Mastering Async/Await.” Check-out Val’s social media profiles through LinkedIn, GitHub, Twitter, and more.

Show Topics:

1:20 – Val has been on previous episodes back in 2013 & 2016.

1:37 – Val’s background. He is very involved with multiple companies. Go checkout his new book!

2:39 – Promises generators. Understand Promises and how things sync with Promises. Val suggests that listeners have an integrated understanding of issues like error handling.

3:57 – Chuck asks a question.

6:25 – Aimee’s asks a question: “Can you speak to why someone would want to use Async/Await?”

8:53 – AJ makes comments.

10:09 – “What makes an Async/Await not functional?” – Val

10:59 – “What’s wrong with Promises or Async/Await that people don’t like it?” - AJ

11:25 – Val states that he doesn’t think there really is anything wrong with these programs it just depends on what you need it for. He thinks that having both gives the user great power.

12:21 – AJ’s background is with Node and the Python among other programs.

12:55 – Implementing Complex Business Logic.

15:50 – Val discusses his new e-book.

17:08 – Question from Aimee.

17:16 – AJ answers question. Promises should have been primitive when it was designed or somewhat event handling.

17:46 – The panel agrees that anything is better than Call Backs.

18:18 – Aimee makes comments about Async/Await.

20:08 – “What are the core principles of your new e-book?” – Chuck

20:17 – There are 4 chapters and Val discusses, in detail, what’s in each chapter.

22:40 – There could be some confusion from JavaScript for someone where this is their first language. Does Async/Await have any affect on the way you program or does anything make it less or more confusing in the background changes?

24:30 – Val answers the before-mentioned question. Async/Await does not have anyway to help with this (data changes in the background).

25:36 – “My procedural code, I know that things won’t change on me because it is procedural code. Is it hard to adjust to that?” – AJ

26:01 – Val answers the question.

26:32 – Building a webserver with Python

27:31 – Aimee asks a question: “Do you think that there are cases in code base, where I would want to use Promises? Not from a user’s perspective, but what our preferences are, but actual performance. Is there a reason why I would want to use both or be consistent across the board?”

28:17 – Val asks for some clarification to Aimee’s question.

29:14 – Aimee: “My own personal preference is consistency. Would I want to use Promises in ‘x’ scenario and/or use Async/Await in another situation?”

32:28 – Val and AJ are discussing and problem solving different situations that these programs

33:05 – “When would you not want to use Async/Await?” – AJ

33:25 – Val goes through the different situations when he would not use Async/Await. 

33:44 – Chuck is curious about other features of Async/Await and asks Val.

36:40 – Facebook’s Regenerator

37:11 – AJ: “Back in the day, people would be really concerned with JavaScript’s performance even with Chrome.” He continues his thoughts on this topic.

38:11 – Val answers the AJ’s question.

39:10 – Duck JS probably won’t include generators.

41:18 – Val: “Have anyone used Engine Script before?” The rest of the panel had never heard of this before.

42:09 – Windows Scripting Host

42:56 – Val used Rhino in the past.

43:40 – Val: “Going back to the web performance question...”

47:08 – “Where do you see using Async/Await the most?” – Chuck

47:55 – Val uses Async/Await for everything on the backend because it has made everything so easy for him.

48:23 – “So this is why you really haven’t used Web Pack?” – AJ

49:20 – Let’s go to Aimee’s Picks!

50:18 – AJ’s story, first, before we get to Promises.

54:44 – Let’s transition to Promises Finally.

54:53 – Val talks about Promises Finally.

59:20 – Picks

Links:

Sponsors:

Picks:

Charles

Aimee

AJ

Val




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JSJ 399: Debugging with Async/Await with Valeri Karpov

Valeri Karpov is a maintainer on Mongoose, has started a few companies, and works for a company called Booster Fuels. Today’s topic debugging with Async/Await. The panel talks about some of the challenges of debugging with Async. AJ, however, has never encountered the same problems, so he shares his debugging method. 

Valeri differentiates between .catch vs try...catch, and talks about why he prefers .catch. There are two ways to handle all errors in an async function without leading to an unhandled promise rejection. The first is to wrap the entire body of the async function in a try...catch, has some limitations. Calling an async function always returns a promise, so the other approach is calling .catch on the promise to handle any errors that occur in that function body. One of the key differences is if you return a promise within an async function, and that return promise is wrapped in a try...catch, the catch block won’t get called if that promise is rejected, whereas if you call .catch on the promise that the function returns, you’ll actually catch that error. There are rare instances where this can get tricky and unintuitive, such as where you have to call new promise and have resolve and reject, and you can get unexpected behavior.

The panel discusses Valeri’s current favorite JS interview question, which is,  “Given a stream, implement a function called ‘stream to promise’ that, given a stream, returns a promise that resolves to the concatenation of all the data chunks emitted by the stream, or rejects if the stream emits an error event.” It’s really simple to get this qustion right, and really simple to get it wrong, and the difference can be catastrophic. AJ cautions listeners to never use the data event except in the cases Val was talking about, only use the readable event.

The conversation turns to the function of a readable event. Since data always pushes data, when you get a readable event, it’s up to you to call read inside the function handler, and then you get back a chunk of data, call read again and again until the read returns null. When you use readable, you are in control and you avoid piling functions into RAM. In addition, the right function will return true or false to let you know if the buffer is full or not. This is a way to mix imperative style into a stream.

The next discussion topics are the differences between imperative style and reactive style and how a waits and promises work in a normal four loop. A wait suspends the execution of a function until the promise is resolved. Does a wait actually stop the loop or is it just transpiling like a promise and it doesn’t stop the loop. AJ wrote a module called Batch Async to be not as greedy as promise.all but not as limited as other options.

The JavaScript panelists talk about different async iterators they’ve used, such as Babel. They discuss the merits of Babel, especially since baseline Android phones (which a significant portion of the population of the world uses) run UC Browser that doesn’t support Babel, and so a significant chunk of the population of the world. On the other hand, if you want to target a large audience, you need to use Babel.

Since frameworks in general don’t handle async very well, the panel discusses ways to mitigate this. They talk about different frameworks like Vue, React, and Express and how they support async functions. They discuss why there is no way for you to actually cancel an async option in an actual case, how complex canceling is, and what you are really trying to solve for in the cancellation process. 

Canceling something is a complex problem. Valeri talks about his one case where he had a specific bug that required non-generic engineering to solve, and cancelling actually solved something. When AJ has come across cancellation issues, it’s very specific to that use case. The rest of the panelists talk about their experiences with having to cancel something. 

Finally, they talk about their experience with async generator functions. A generator is a function that lets you enter into the function later. This makes sense for very large or long running data sets, but when you have a bounded items, don’t complicate your code this way. When an async generator function yields, you explicitly need to call next in order for it to pick up again. If you don’t call ‘next’, it’s essentially cancelled. Remember that object.keys and object.values are your friends. 

Panelists

  • Christopher Buecheler

  • AJ O’Neal

  • Charles Max Wood

With special guest: Valeri Karpov

Sponsors

Links

Follow DevChatTV on Facebook and Twitter

Picks

AJ O’Neal:

Christopher Buecheler:

Charles Max Wood:

Valeri Karpov:




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Syncope in a Woman Returning From a Long Flight

A 58-year-old woman presents with no relevant medical history with syncope, elevated troponin and D-dimer levels, and multiple large bilateral pulmonary emboli. What would you do next?




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Bad Gene Hunting—Sudden Unexplained Death and Familial Long QT Syndrome

This essay describes a physician’s experience of the sudden, unexplained death of her brother and her family’s discovery of the genetic cause.




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Palladium-catalyzed synthesis of [60]fullerene-fused furochromenones and further electrochemical functionalization

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00264J, Research Article
Majid Hussain, Chuang Niu, Guan-Wu Wang
The palladium-catalyzed heteroannulation of [60]fullerene with 4-hydroxycoumarins affords [60]fullerene-fused furochromenones, which can be further derivatized via an electrochemical method to synthesize 1,2,3,4-adducts.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Total synthesis of tumor-associated KH-1 antigen core nonasaccharide via photo-induced glycosylation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00314J, Research Article
Bo-Han Li, Wenlong Yao, Hong Yang, Congying Wu, De-Cai Xiong, Yuxin Yin, Xin-Shan Ye
KH-1 antigen core nonasaccharide was efficiently assembled by photo-induced glycosylation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rh-Catalyzed nitrene alkyne metathesis/formal C–N bond insertion cascade: synthesis of 3-iminoindolines

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00294A, Research Article
Kemiao Hong, Su Zhou, Wenhao Hu, Xinfang Xu
A Rh-catalyzed nitrene/alkyne metathesis (NAM) cascade reaction terminated by a formal C–N bond insertion has been developed, which provides facile access to the tricyclic 3-iminoindolines in good yields with broad substrate scope.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Topomeric aza/thia cryptands: synthesis and theoretical aspects of in/out isomerism using n-alkyl bridging

Org. Chem. Front., 2020, 7,1164-1176
DOI: 10.1039/D0QO00123F, Research Article
Ian S. Taschner, Tia L. Walker, Sharath Chandra M., Briana R. Schrage, Christopher J. Ziegler, Xinfeng Gao, Steven E. Wheeler
A series of heterobicyclic aza/thia-lactams and cryptands incorporating changes in n-alkyl bridging length have been synthesized, characterized, chelated to heavy metals and computationally assessed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and biological evaluation of suffrutines A, B and their N-fused analogues

Org. Chem. Front., 2020, 7,1122-1131
DOI: 10.1039/D0QO00050G, Research Article
Zefeng Zhu, Chun Chen, Jingxing Jiang, Qianzhong Zhang, Zhibo Du, Shuxian Wei, Xianheng Song, Jie Tang, Jinping Lei, Zhuofeng Ke, Yong Zou
The synthesis, structure confirmation, stability and isomerization features of suffrutines A, B and their N-fused analogues were reported. Biological tests showed that the introduction of nitrogen atom might be beneficial to the anticancer activity.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Direct synthesis of annulated indoles through palladium-catalyzed double alkylations

Org. Chem. Front., 2020, 7,1149-1157
DOI: 10.1039/D0QO00135J, Research Article
Yadong Gao, Jianhua Li, Songlin Bai, Daoquan Tu, Chao Yang, Zhiwen Ye, Bingcheng Hu, Xiangbing Qi, Chao Jiang
A facile, one-step synthesis of annulated indoles from (N–H) indoles and dibromoalkanes was developed through a palladium-catalyzed double alkylation process.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nanostructures & nanomaterials : synthesis, properties & applications / Guozhang Cao

Cao, Guozhong




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Environmental applications of nanomaterials : synthesis, sorbents and sensors / editors, Glen E. Fryxell, Guozhong Cao




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Nanotechnology for a sustainable world : global artificial photosynthesis as nanotechnology's moral culmination / T. Faunce

Faunce, T




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Complex-shaped metal nanoparticles : bottom-up syntheses and applications / edited by Tapan K. Sau and Andrey L. Rogach ; with a foreword by Catherine J. Murphy




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Nanostructures & nanomaterials : synthesis, properties, and applications / Guozhong Cao, Ying Wang

Cao, Guozhong




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Biogenic production of gold and silver nanoparticles using extracts from indigenous Australian plants : their synthesis, optimisation, characterisation and antibacterial activities / Monali Shah

Shah, Monali, author




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[ASAP] Stereodivergent Asymmetric Synthesis of a,ß-Disubstituted ß-Aminoalkylboronic Acid Derivatives via Group-Selective Protodeboronation Enabling Access to the Elusive Anti Isomer

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03207




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[ASAP] Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03941




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[ASAP] The First Quantitative Synthesis of a Closed Three-Link Chain (6<sub arrange="stack">1</sub><sup arrange="stack">3</sup>) Using Coordination and Noncovalent Interactions-Driven Self-Assembly

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c01406




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[ASAP] Synthesis, Cytotoxicity, and Genotoxicity of 10-Aza-9-oxakalkitoxin, an <italic toggle="yes">N</italic>,<italic toggle="yes">N</italic>,<italic toggle="yes">O</italic>-Trisubstituted

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03763




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[ASAP] Sugar-Pirating as an Enabling Platform for the Synthesis of 4,6-Dideoxyhexoses

Journal of the American Chemical Society
DOI: 10.1021/jacs.9b13766




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[ASAP] Iterative Catalysis in the Biosynthesis of Mitochondrial Complex II Inhibitors Harzianopyridone and Atpenin B

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03438




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[ASAP] Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c01895




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[ASAP] Chemical Equivalent of Arene Monooxygenases: Dearomative Synthesis of Arene Oxides and Oxepines

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c02724




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[ASAP] Molecular Mechanism for the Suppression of Alpha Synuclein Membrane Toxicity by an Unconventional Extracellular Chaperone

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c01894