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Facile controlled synthesis of core–shell/yolk–shell/hollow ZIF-67@Co-LDH/SiO2via a self-template method

Inorg. Chem. Front., 2020, 7,1643-1650
DOI: 10.1039/C9QI01684H, Research Article
Duoyu Lin, Pan Duan, Weiting Yang, Yanfeng Liu, Qinhe Pan
Through the protection effect of CTAB, a facile controlled synthesis of core–shell/yolk–shell/hollow ZIF-67@Co-LDH/SiO2 under ambient conditions by adjusting the reaction time was realized.
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Semi-sacrificial template synthesis of single-atom Ni sites supported on hollow carbon nanospheres for efficient and stable electrochemical CO2 reduction

Inorg. Chem. Front., 2020, 7,1719-1725
DOI: 10.1039/C9QI01688K, Research Article
Cheng-Zong Yuan, Li-Yuan Zhan, Shou-Jie Liu, Feng Chen, Hongjun Lin, Xi-Lin Wu, Jianrong Chen
Atomically dispersed Ni species on nitrogen-doped hollow carbon spheres (SA-Ni/N-CS) were synthesized via a semi-sacrificial template assisted strategy for an efficient and stable CO2RR.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A MOF-derived CuCo(O)@ carbon–nitrogen framework as an efficient synergistic catalyst for the hydrolysis of ammonia borane

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00023J, Research Article
Yao Yuan, Xiaoyu Chen, Xing Zhang, Zumin Wang, Ranbo Yu
A CuCo(O)-embedded nitrogen-enriched porous carbon framework catalyst derived from doped metal–organic frameworks for efficient hydrolysis of ammonia borane.
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Intermetallic borides: structures, synthesis and applications in electrocatalysis

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00146E, Review Article
Hui Chen, Xiaoxin Zou
This review summarizes structural features and recent synthesis methods of structurally ordered intermetallic borides, and the theoretical–experimental advances in the emerging boride-catalyzed reactions.
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Controllable synthesis of a mesoporous NiO/Ni nanorod as an excellent catalyst for urea electro-oxidation

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00316F, Research Article
Qing Li, Nan Li, Jing An, Huan Pang
Mesoporous rod-like structured composites of NiO/Ni have been successfully prepared via a low temperature heat treatment of the precursor NiC2O4·2H2O in N2.
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A one-pot synthesis of hetero-Co9S8–NiS sheets on graphene to boost lithium–sulfur battery performance

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QI01691K, Research Article
Liang Chen, Xuefang Xie, Zhian Zhang, Xiangzhong Kong, Shuquan Liang, Anqiang Pan
Graphene decorated with hetero-Co9S8–NiS sheets have abundant active sites, which can efficiently catalyze the electrochemical conversion of lithium polysulfides in Li–S battery.
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Synthesis of dual emitting iodocuprates: can solvents switch the reaction outcome?

Inorg. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QI00346H, Research Article
Alexander V. Artem'ev, Alexey S. Berezin, Ilya V. Taidakov, Irina Yu. Bagryanskaya
An unprecedented structure-directing effect of solvents in halocuprate self-assembly reactions was discovered. The compounds presented show remarkable dual luminescence, strongly changing the emission color upon varying temperature.
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Coral-like ZnFe2O4–ZnO mesoporous heterojunction architectures: synthesis and enhanced sensing properties for triethylamine

Inorg. Chem. Front., 2020, 7,1918-1926
DOI: 10.1039/D0QI00134A, Research Article
Tianye Yang, Xiaodong Yang, Mingming Zhu, Hongwei Zhao, Mingzhe Zhang
A unique coral-like ZnFe2O4–ZnO heterojunction architecture based sensor has been synthesized and shows excellent sensing performance for TEA with a particularly fast response time of 0.9 s.
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Effect of Fast Heating and Cooling in the Hydrothermal Synthesis on LiFePO<sub>4</sub> Microparticles

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00518




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[ASAP] Impact of Ni/Mg/Al Catalyst Composition on Simultaneous H<sub>2</sub>-Rich Syngas Recovery and Toxic HCN Removal through a Two-Step Polyurethane Pyrolysis and Steam Reforming Process

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00931




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[ASAP] Synthesis of Hierarchical TS-1 Nanocrystals with Controllable Grain Size and Mesoporosity: Enhanced Performance for Chloropropylene Epoxidation

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.9b06490




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[ASAP] New Approach for Controllable Synthesis of N-MnO<sub><italic toggle="yes">x</italic></sub> Microflowers and Their Superior Catalytic Performance for Benzoxazole Synthesis

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00746




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[ASAP] Investigation of Plausible Mechanism of the Synthesized Inorganic Polymeric Coagulant and Its Application toward Fluoride Removal from Drinking Water

Industrial & Engineering Chemistry Research
DOI: 10.1021/acs.iecr.0c00760




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Proceedings of the 13th International Conference on Synchrotron Radiation Instrumentation - SRI2018: conference date, 11-15 June 2018: location, Taipei, Taiwan / editors, Shangjr Gwo, Di-Jing Huang and Der-Hsin Wei

Online Resource




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Synchrotron Light Sources and Free-Electron Lasers: Accelerator Physics, Instrumentation and Science Applications / edited by Eberhard Jaeschke, Shaukat Khan, Jochen R. Schneider, Jerome B. Hastings

Online Resource




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Conical intersections in physics: an introduction to synthetic gauge theories / Jonas Larson, Erik Sjöqvist, Patrik Öhberg

Online Resource




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Retrosynthetic strategies and their impact on synthesis of arcutane natural products

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01441A, Minireview
Open Access
Shelby V. McCowen, Nicolle A. Doering, Richmond Sarpong
Decisions, decisions, decisions: the interplay between different retrosynthetic strategies in the synthesis of the highly bridged, polycyclic arcutane natural products.
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Allylic C(sp3)–H alkylation via synergistic organo- and photoredox catalyzed radical addition to imines

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00819B, Edge Article
Open Access
Jiaqi Jia, Rajesh Kancherla, Magnus Rueping, Long Huang
A new catalytic method for the direct alkylation of allylic C(sp3)–H bonds from unactivated alkenes via synergistic organo- and photoredox catalysis is described.
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Programmable synthesis of multiply arylated cubanes through C–H metalation and arylation

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01909G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ryo Okude, Genki Mori, Akiko Yagi, Kenichiro Itami
Cubane has attracted attention due to its unique 3D structure. Herein, we report the programmable synthesis of multiply arylated cubanes. The developed reaction allows the late-stage and regioselective installation of aryl groups.
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Expedient synthesis of conjugated triynes via alkyne metathesis

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01124J, Edge Article
Open Access
Idriss Curbet, Sophie Colombel-Rouen, Romane Manguin, Anthony Clermont, Alexandre Quelhas, Daniel S. Müller, Thierry Roisnel, Olivier Baslé, Yann Trolez, Marc Mauduit
The first synthesis of symmetrical and dissymmetrical conjugated triynes by self- and cross-metathesis was successfully achieved thanks to the use of hindered diynes.
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Asymmetric synthesis of primary amines catalyzed by thermotolerant fungal reductive aminases

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC02253E, Edge Article
Open Access
Juan Mangas-Sanchez, Mahima Sharma, Sebastian C. Cosgrove, Jeremy I. Ramsden, James R. Marshall, Thomas W. Thorpe, Ryan B. Palmer, Gideon Grogan, Nicholas J. Turner
Fungal reductive aminases as effective biocatalysts for the preparation of chiral primary amines.
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General and selective synthesis of primary amines using Ni-based homogeneous catalysts

Chem. Sci., 2020, 11,4332-4339
DOI: 10.1039/D0SC01084G, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kathiravan Murugesan, Zhihong Wei, Vishwas G. Chandrashekhar, Haijun Jiao, Matthias Beller, Rajenahally V. Jagadeesh
A Ni-triphos based homogeneous catalyst enabled the synthesis of all kinds of primary amines by reductive amination of carbonyl compounds with ammonia and hydrogenation of nitroarenes.
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Intramolecular Csp3–H/C–C bond amination of alkyl azides for the selective synthesis of cyclic imines and tertiary amines

Chem. Sci., 2020, 11,4482-4487
DOI: 10.1039/C9SC05522C, Edge Article
Open Access
Xiaojin Wen, Xinyao Li, Xiao Luo, Weijin Wang, Song Song, Ning Jiao
A novel intramolecular cyclization of alkyl azides for the synthesis of cyclic imines and tertiary amines has been developed. The aliphatic C–H or C–C bond was selectively cleaved with the efficient formation of two C–N single bonds or a CN double bond.
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Chemical synthesis and immunological evaluation of new generation multivalent anticancer vaccines based on a Tn antigen analogue

Chem. Sci., 2020, 11,4488-4498
DOI: 10.1039/D0SC00544D, Edge Article
Open Access
Carlo Pifferi, Ane Ruiz-de-Angulo, David Goyard, Claire Tiertant, Nagore Sacristán, Diego Barriales, Nathalie Berthet, Juan Anguita, Olivier Renaudet, Alberto Fernández-Tejada
A fully-synthetic anticancer vaccine candidate incorporating an hexadecavalent Tn antigen analogue display via oxime linkages induced tumor-specific IgG antibodies and cellular immune responses in mice coadministered with QS-21 as an adjuvant.
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Enantioselective total synthesis of (−)-myrifabral A and B

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC01141J, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tyler J. Fulton, Anthony Y. Chen, Michael D. Bartberger, Brian M. Stoltz
A catalytic enantioselective approach to the Myrioneuron alkaloids (−)-myrifabral A and (−)-myrifabral B is described.
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Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC00002G, Edge Article
Open Access
Chenting Yan, Masato Takeshita, Jun-ya Nakatsuji, Akihiro Kurosaki, Kaoko Sato, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, Ko Furukawa, Ryohei Kishi, Masayoshi Nakano
Structural characterization of hypervalent electron-rich pentacoordinate nitrogen species has long been a synthetic challenge. Here we report the first nitrogen cationic radical (11-N-5) species featuring a weak hypervalent 3c-5e interaction.
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Correction: Enantioselective synthesis of isochromans and tetrahydroisoquinolines by C–H insertion of donor/donor carbenes

Chem. Sci., 2020, Advance Article
DOI: 10.1039/D0SC90081H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Leslie A. Nickerson, Benjamin D. Bergstrom, Mingchun Gao, Yuan-Shin Shiue, Croix J. Laconsay, Matthew R. Culberson, Walker A. Knauss, James C. Fettinger, Dean J. Tantillo, Jared T. Shaw
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Synthesis of unstrained Criegee intermediates: inverse α-effect and other protective stereoelectronic forces can stop Baeyer-Villiger rearrangement of γ-hydroperoxy-γ-peroxylactones

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC01025A, Edge Article
Open Access
Vera A. Vil', Yana Barsegyan, Leah Kuhn, Maria V. Ekimova, Egor A. Semenov, Alexander Korlyukov, Alexander Olegovich Terent'ev, Igor Alabugin
How far can we push the limits in removing stereoelectronic protection from an unstable intermediate? We address this question by exploring the interplay between the primary and secondary stereoelectronic effects...
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Global creation : space, mobility, and synchrony in the age of the knowledge economy / Simon Marginson, Peter Murphy and Michael A. Peters

Marginson, Simon




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Asynchronous circuit applications / Jia Di; Scott C. Smith [Eds]

Online Resource




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Monitoring tissue-level remodelling during inflammatory arthritis using a three-dimensional synovium-on-a-chip with non-invasive light scattering biosensing

Lab Chip, 2020, 20,1461-1471
DOI: 10.1039/C9LC01097A, Paper
Open Access
Mario Rothbauer, Gregor Höll, Christoph Eilenberger, Sebastian R. A. Kratz, Bilal Farooq, Patrick Schuller, Isabel Olmos Calvo, Ruth A. Byrne, Brigitte Meyer, Birgit Niederreiter, Seta Küpcü, Florian Sevelda, Johannes Holinka, Oliver Hayden, Sandro F. Tedde, Hans P. Kiener, Peter Ertl
We demonstrate that the integration of complex human synovial organ cultures in a lab-on-a-chip provides reproducible and reliable information on how systemic stress factors affect synovial tissue architectures using light scatter biosensing.
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Nanocrystal synthesis, μfluidic sample dilution and direct extraction of single emission linewidths in continuous flow

Lab Chip, 2020, Advance Article
DOI: 10.1039/D0LC00213E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ioannis Lignos, Hendrik Utzat, Moungi G. Bawendi, Klavs F. Jensen
We present a flow-based system coupled with an optical interferometry setup for the extraction of single nanocrystal properties.
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[ASAP] Cov_FB3D: A De Novo Covalent Drug Design Protocol Integrating the BA-SAMP Strategy and Machine-Learning-Based Synthetic Tractability Evaluation

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b01197




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[ASAP] The Synthesizability of Molecules Proposed by Generative Models

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00174




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[ASAP] Context Aware Data-Driven Retrosynthetic Analysis

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.9b01141




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[ASAP] Nanomaterial Synthesis Insights from Machine Learning of Scientific Articles by Extracting, Structuring, and Visualizing Knowledge

Journal of Chemical Information and Modeling
DOI: 10.1021/acs.jcim.0c00199




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The mammalian auditory pathways: synaptic organization and microcircuits / Douglas L. Oliver, Nell B. Cant, Richard R. Fay, Arthur N. Popper, editors

Online Resource




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Gideon the ninth / Tamsyn Muir

Dewey Library - PR9639.4.M85 G53 2019




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[ASAP] Expanding Ligand Space: Preparation, Characterization, and Synthetic Applications of Air-Stable, Odorless Di-<italic toggle="yes">tert</italic>-alkylphosphine Surrogates

ACS Catalysis
DOI: 10.1021/acscatal.0c01414




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[ASAP] Removal of Hydrogen Poisoning by Electrostatically Polar MgO Support for Low-Pressure NH<sub>3</sub> Synthesis at a High Rate over the Ru Catalyst

ACS Catalysis
DOI: 10.1021/acscatal.0c00954




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[ASAP] Methanol Synthesis from CO<sub>2</sub> Hydrogenation over a Potassium-Promoted Cu<italic toggle="yes"><sub>x</sub></italic>O/Cu(111) (<italic toggle="yes">x</italic> = 2) Model Sur

ACS Catalysis
DOI: 10.1021/acscatal.9b05226




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[ASAP] Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis

ACS Catalysis
DOI: 10.1021/acscatal.0c01174




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[ASAP] Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications

ACS Catalysis
DOI: 10.1021/acscatal.0c00690




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[ASAP] Comprehensive Insights into the Catalytic Mechanism of Middle East Respiratory Syndrome 3C-Like Protease and Severe Acute Respiratory Syndrome 3C-Like Protease

ACS Catalysis
DOI: 10.1021/acscatal.0c00110




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[ASAP] Fragrant Venezuelaenes A and B with A 5–5–6–7 Tetracyclic Skeleton: Discovery, Biosynthesis, and Mechanisms of Central Catalysts

ACS Catalysis
DOI: 10.1021/acscatal.0c01575




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[ASAP] Isolated Pd Sites as Selective Catalysts for Electrochemical and Direct Hydrogen Peroxide Synthesis

ACS Catalysis
DOI: 10.1021/acscatal.0c01305




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[ASAP] Pd/Cu-Catalyzed Dehydrogenative Coupling of Dimethyl Phthalate: Synchrotron Radiation Sheds Light on the Cu Cycle Mechanism

ACS Catalysis
DOI: 10.1021/acscatal.0c00918




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Science Podcast - Treating Down Syndrome and a news roundup (28 Feb 2014)

Treatment trials for Down Syndrome; roundup of daily news with David Grimm.




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Podcast: Killing off stowaways to Mars, chasing synthetic opiates, and how soil contributes to global carbon calculations

This week, how to avoid contaminating Mars with microbial hitchhikers, turning mammalian cells into biocomputers, and a look at how underground labs in China are creating synthetic opioids for street sales in the United States with Online News Editor Catherine Matacic. Caitlin Hicks Pries joins Julia Rosen to discuss her study of the response of soil carbon to a warming world. And for this month’s book segment, Jen Golbeck talks to Rob Dunn about his book Never Out of Season: How Having the Food We Want When We Want It Threatens Our Food Supply and Our Future. Listen to previous podcasts. Download the show transcript. Transcripts courtesy of Scribie.com. [Image: NASA/JPL-Caltech; Music: Jeffrey Cook]




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The design and synthesis of two imidazole fluorescent probes for the special recognition of HClO/NaHSO3 and their applications

Anal. Methods, 2020, Advance Article
DOI: 10.1039/D0AY00334D, Paper
Hong-Lin Ding, Yan-Qing Pu, Da-Ying Ye, Zi-Yue Dong, Man Yang, Cheng-Wei Lü, Yue An
The design and synthesis of two imidazole fluorescent probes for the special recognition of HClO/NaHSO3 and their applications are shown.
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