mi

Round 2 in the Trump-vs-Mexico matchup looks ominous for Mexico

Mexico is facing a second Donald Trump presidency, and few countries can match its experience as a target of Trump’s rhetoric: There have been threats to close the border, impose tariffs and even send U.S. forces to fight Mexican drug cartels if the country doesn’t do more to stem the flow of migrants and drugs




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Market investors become poorer by ₹5.29 lakh crore amid massive correction in stocks

The BSE benchmark gauge tumbled 820.97 points or 1.03% to settle at 78,675.18




mi

Wagah: A misfire on many levels

Vast stretches of 'Wagah' play out like a dubbed movie.




mi

Mudinja Ivana Pudi: Mixed doubles

The film tries to subvert the classic evil-twin template.




mi

Missing on a Weekend: Who cares whodunit

A murder mystery with zero thrills




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'Kutrame Thandanai' review: thoughtfully made, but something’s missing




mi

Neer Dose: Serving up a heavy dose of misogyny




mi

Jack Reacher- Never Go Back : Less action thriller, more family drama

What starts out as a high-paced exciting action-fuelled film soon unravels to become a family drama.




mi

'Hannah Gadsby: Douglas' review: After 'Nanette', the extraordinary mind of Gadsby strikes again

The Australian’s charisma lies in her ability to be excruciatingly vulnerable to an audience with a swagger that’s both self-assured and relatable




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‘Anger Tales’ anthology review: Potpourri of hits and misses

The Telugu anthology ‘Anger Tales’ explores anger that stems from everyday situations through effective performances 




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‘Custody’ movie review: Venkat Prabhu’s mix of conflict and humour works for this Naga Chaitanya, Arvind Swami actioner

Director Venkat Prabhu’s Telugu-Tamil bilingual ‘Custody’ is not among his best, but has plenty going for it




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‘Mem Famous’ movie review: Sumanth Prabhas makes a promising debut in this partially engaging coming-of-age story

Newcomers led by Sumanth Prabhas get the carefree rural Telangana vibe right in the Telugu film ‘Mem Famous’, which shines in a few segments but falls short of being a roller coaster fun ride




mi

Senior living faces a supply gap, with Tamil Nadu seen as a key growth area for the sector

CEOs of key firms, in conversation with businessline, discuss Tamil Nadu’s potential due to its large senior population




mi

Bengaluru residential property micromarkets witness record hike in prices: Report

Prices in Bagaluru in North Bengaluru have surged by nearly 90 per cent in the past five years, while Whitefield has seen an 80 per cent rise in prices




mi

India in consultation with Indonesia at WTO over duty on ceramic tiles

Exports from India dipped since Indonesia imposed safeguard duties on the product




mi

Bengaluru residential real estate soars amid high demand and limited inventory

Areas such as Bagaluru, Hennur, Whitefield, and Varthur-Sarjapur are witnessing substantial price increases, attributed to pent-up demand from the pandemic




mi

Microsoft acquires 16.4-acre land in Pune for ₹520 crore

Microsoft acquired land from Indo Global Infotech City




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RMZ offers 0.3 million sqft of commercial space to Chevron Global Technology in Bengaluru

The CEO of RMZ Office and RMZ NXT, Thirumal Govindraj, highlighted India’s appeal for GCC expansion due to sophisticated, tech-powered workspaces and lower office rentals




mi

Mindspace REIT to build 3 data centres for Princeton Digital Group

The REIT has already developed two data centers for PDG with an area of 6.3 lakh square feet and the current contract will add 10 lakh square feet to its portfolio




mi

Shriram Finance raises $500 million via social bonds

Plans to list insurance arms and focus on retail bad loans




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Shriram Properties launches 1.1 million sq ft residential project in Chennai

“Located in the rapidly growing West Chennai corridor, this RERA-approved development offers a total saleable area of 1.1 million sq ft (msf) and has a revenue potential of around ₹550 crore to ₹600 crores”




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Poulomi Estates to build ₹800-crore residential project in Bengaluru

The project will have a total of 850 apartments, which are in the range of 1,450 sq ft to 2,550 sq ft




mi

Real estate transactions drop 71% in Q3 2024, private equity dominates

Despite the overall fall, the number of deals rose 5% quarter-on-quarter and 54% year-on-year, with a potential revival in Q4. 




mi

Bengaluru Airport City Ltd breaks ground for 2 million sqft Business Park to boost GCC growth

The Airport city is expected to host a network of business parks comprising 52 per cent of its overall development




mi

Micromitti Real Estate Ventures plans to launch REITs

Micromitti will use technology to enable fractional ownership to provide flexibility and strong returns for retail investors, says Founder & CEO Manoj Dhanotiya




mi

Mindspace REIT NOI crosses ₹500 cr for first time in Q2

The REIT reported 6 per cent higher revenue at ₹623 crore




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Biz families of Tier-II cities drive-up ultra luxury residential demand in North & West India

‘The Dahlias’ – realty major DLF’s upcoming super-luxury residential project in Gurgaon with units priced upwards of ₹80 crore – is witnessing active buyer interest from some of these Tier-II city-based business families




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Brigade to invest ₹800 crore to develop 1 million sq ft residential apartments in West Chennai

West Chennai is one of the fastest growing parts of the city




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Showcasing authentic Tamil art




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Draped in dynamism

Daksha Sheth and Devissaro talk about dance, music and their ensemble, Asima





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A looming crisis

Cheap Chinese silk is choking indigenous sericulturists and weavers.




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Mamallapuram to host Tamil Nadu International Kite Festival for the first time

The maiden edition of Tamil Nadu Kite Festival is set to see custom kites, brought in by professionals from USA, Thailand, Malaysia and India, take flight



  • Life & Style

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Label Erode’s debut collection blends the GI-tagged jamakkalam with Jimi Hendrix’s music

How a Mumbai-based fashion label is reviving the GI-tagged Bhavani jamakkalam through its debut collection




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An efficient approach to AviCys analogues via regio- and stereoselective hydrosulfuration of ynamides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01572J, Research Article
Zhenjia Zhang, Zhe Ding, Jinhua Yang, Yongli Zhao, Zhenguang Zhao, Can Liu, Norman Metanis, Junfeng Zhao
A novel synthetic strategy for the construction of AviCys analogues via a highly efficient regio- and stereoselective hydrosulfuration of ynamides was reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

All-thiophene dendrimers based on cyclooctatetrathiophene: synthesis and aggregation-induced emission (AIE) features

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01525H, Research Article
Pengfei Wang, Chunmei Zhao, Shuai Qiu, Wan Xu, Chunli Li, Zhiying Ma, Wei Cao, Li Xu, Hua Wang
A novel class of all-thiophene dendrimers with obvious AIE emissions was designed and synthesized based on saddle-shaped cyclooctatetrathiophene (COTh) as building blocks.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Multi-step chirality transfer and racemization kinetics of pillar [5]arenes by tuning the halogen substituents on the rims

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01799D, Research Article
Lizhi Fang, Xiaowen Guan, Yanling Shen, Dayang Zhou, Long Chen, Xiaochuan Chen, Wanhua Wu, Leyong Wang, Cheng Yang
Halogen-substituted pillar[5]arenes exhibited hindered hydroquinone subunit flipping, enabling enantioseparation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Synergy of prediction rule and total synthesis in solving the stereochemical puzzle of eucalactam B

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01777C, Research Article
Chenqi Wang, Junyang Liu, Tao Ye
The absolute configurations of the fungal-derived reduced polyketide eucalactam B were initially predicted using the “Biochemistry-based rule” and later confirmed through its first successful total synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01801J, Research Article
Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
An I2-promoted oxidative annulation of three different amines enables the assembly of nonsymmetrical 2,2'-biquinolines and related bis-azines through a [4π + 2σ] annulation reaction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01628A, Research Article
Feng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min Lin
A novel one-pot synthesis of multifunctional organic fluorescent imidates from quinolinium salt derivatives, nitrosoarenes and alcohols was presented. This method had a wide substrate scope and excellent isolated yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Total synthesis of spiro Ganoderma meroterpenoids spiroapplanatumines B, D, F, and H

Org. Chem. Front., 2024, 11,6333-6339
DOI: 10.1039/D4QO01147C, Research Article
Jia-Hao Zhang, Wen-Cai Luo, Wen-Tao Chen, Yu-Tao He, Ya-Jian Hu
The first total synthesis of spiroapplanatumines B, D, F, and H as well as the possibly undiscovered natural product spiroapplanatumine R has been achieved.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Org. Chem. Front., 2024, 11,6340-6346
DOI: 10.1039/D4QO01376J, Research Article
Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong Lian
We developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Structure determination of difficult-to-crystallize organic molecules by co-crystallization of a phosphorylated macrocycle

Org. Chem. Front., 2024, 11,6358-6366
DOI: 10.1039/D4QO01498G, Research Article
Heng Li, Zhijin Li, Juli Jiang, Chen Lin, Leyong Wang
This work reported that 37 different difficult-to-crystallize guest molecules were co-crystallized with the host macrocycle F[3]A1-[P(O)Ph]3 at room temperature, and the molecular structures of the guests could be determined by SCXRD.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Chiral synthetic unprecedented spiro[indoline-2,3'-thiophen]-3-ones via an organocatalytic asymmetric sulfa-Michael/aldol cascade reaction

Org. Chem. Front., 2024, 11,6426-6436
DOI: 10.1039/D4QO01551G, Research Article
Mao Zhang, Xing-Hai Fei, Gui-Ping Yang, Cheng Lin, Wen-Jie Li, Ming-Liang Rao, Meng Zhou, Chong Zhao, Bin He, Yong-Long Zhao
A cinchona-derived squaramide-catalyzed asymmetric sulfa-Michael/aldol cascade reaction of 2-ylideneoxindoles with 1,4-dithiane-2,5-diol was developed to realize the chiral synthesis of spiro[indoline-2,3'-thiophen]-3-ones.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Well-defined chiral dinuclear copper-catalyzed tandem asymmetric propargylic amination–carboxylative cyclization sequence toward chiral 2-oxazolidinone derivatives

Org. Chem. Front., 2024, 11,6319-6326
DOI: 10.1039/D4QO01368A, Research Article
Yu Lan, Peng Liu, Zekai Fang, Lili Shao, Qilong Cai, Xiaoming Wang
A variety of chiral 2-oxazolidinones was obtained via a dinuclear copper-catalyzed asymmetric propargylic amination–carboxylative cyclization sequence of propargylic esters with alkyl amine hydrochlorides and CO2.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

A pillar[5]arene-based three-component supramolecular copolymer for the fluorescence detection of spermine

Org. Chem. Front., 2024, 11,6293-6303
DOI: 10.1039/D4QO01470G, Research Article
Open Access
Martina Mazzaferro, Daniele Crisafulli, Francesca Mancuso, Marco Milone, Fausto Puntoriero, Anna Irto, Salvatore Patanè, Valentina Greco, Alessandro Giuffrida, Ilenia Pisagatti, Anna Notti, Melchiorre F. Parisi, Giuseppe Gattuso
A supramolecular copolymer, composed of a bis-pillar[5]arene diacid and complementary alkylidene- and perylene-bisimide-bis-imidazole comonomers, acts as an OFF/ON luminescent sensor for spermine.
The content of this RSS Feed (c) The Royal Society of Chemistry




mi

Electrochemical approach for upgrading the pollutant CS2: three-component N–H thiocarbamylation of sulfoximines

Org. Chem. Front., 2024, 11,6477-6482
DOI: 10.1039/D4QO01310G, Research Article
Peng Qian, Wenjing Xiong, Qian Meng, Jinxiu Liu, Xiyuan Li, Liangquan Sheng
We report an electrochemical approach for upgrading the pollutant CS2via the thiocarbamylation of sulfoximines, in which CS2 and amines are incorporated as a readily available source of dithiocarbamate.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sulfenylation of bioactive maleimides, acrylates and cyclohexenones under ambient organophotocatalysis

Org. Chem. Front., 2024, 11,6503-6509
DOI: 10.1039/D4QO01342E, Research Article
Debanjana Bag, Rajjakfur Rahaman, Anindya S. Manna, Subhasis Pal, Rajesh Nandi, Shobhon Aich, Narendra Nath Ghosh, Dilip K. Maiti
A novel visible light-induced sulfenylation of biologically important maleimides, acrylates and cyclohexenones has been developed using cheap and easily available organophotoredox catalyst Eosin Y with thiols under ambient conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Cobalt-catalyzed enantioselective reductive addition of ketimine with cyclopropyl chloride to construct chiral amino esters bearing cyclopropyl fragments

Org. Chem. Front., 2024, 11,6311-6318
DOI: 10.1039/D4QO01474J, Research Article
Jiangtao Hu, Tingting Xia, Xianqing Wu, Hongrui Feng, Jingping Qu, Yifeng Chen
Co-catalyzed asymmetric reductive addition of ketimine with cyclopropyl chloride has been realized to access diverse chiral amino esters bearing cyclopropyl fragments with broad functional group tolerance and excellent enantioselectivities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enantioselective Addition of 3-hydroxyquinolin-2(1H)-one to Isatin and Pyrazole-4,5-dione Derived Ketimines

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01895H, Research Article
Yue Wei, Guishun Bai, Jiamin Wu, Yi Hua, Tao Zhang, Congyong Yue, Hong Wang, Xiaoze Bao
The enantioselective reactivity of 3-hydroxyquinolin-2(1H)-ones was developed through their addition to isatin and pyrazole-4,5-dione derived ketimines, affording novel architectures featuring multiple natural products scaffolds in high yield with excellent enantioselectivities....
The content of this RSS Feed (c) The Royal Society of Chemistry