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Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01827C, Research Article
Open Access
Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu Chen
Mechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regio- and stereoselective azidation of activated N-allenamides: an entry to α, β, γ and δ-amido-azides

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01802H, Research Article
Dorian Schutz, Maxime Hourtoule, Laurence Miesch
A totally controlled regiodivergent azidation of activated N-allenamides is described, offering a broad range of diverse functionalized amido-azide derivatives.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Folding of a dynamic macrocyclic system to stabilize its cation radical state

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01566E, Research Article
Arnab Dutta, Krzysztof Dzieszkowski, Marco Farinone, Łukasz Orzeł, Krzysztof Kruczała, Monika Kijewska, Miłosz Pawlicki
A precisely designed π-extended system responds to different stimuli by folding the structure, which prevents overoxidation and stabilizes the cation radical.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01600A, Research Article
Yongfeng Wang, Ruijun Chu, Yanxiao Wang, Mengyuan Zhou, Yuan Chen, Cheng Xu, Jingyu Sun, Guodong Yin
A novel class of heterocyclic AIEgens has been synthesized via a multicomponent reaction of isatins, 2,3-diaryl cyclopropenones, and alkyl bromides.
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Catalytic asymmetric synthesis of chiral sulfilimines via S-C bond formation

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01963F, Highlight
Yingying Shi, Shuiyun Zheng, Jiapian Huang, Fu-Sheng He, Min Yang, Jie Wu
As the aza-analogues of sulfoxides, sulfilimines bearing S(IV) stereogenic centers hold tremendous potential in synthetic chemistry and medicinal chemistry. However, the catalytic asymmetric synthesis of chiral sulfilimines are much less...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Probing Intersystem Crossing in Multi-brominated Eumelanin through Transient Absorption and Surface Hopping Dynamics

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01832J, Research Article
Open Access
Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh Hariharan
Achieving intersystem crossing (ISC) through structural tuning in biological systems is an evolving area for therapeutic and materials research. Eumelanin, a natural pigment, offers huge potential for bio-inspired material design,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
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Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01794C, Research Article
Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
The mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01879F, Research Article
Yuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin Fan
Oxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01828A, Review Article
Kazutaka Shoyama, Frank Wuerthner
Polycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01816H, Research Article
Sheng-Jiao Yan, Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao
Skeletal editing is a highly efficient strategy for modifying the core scaffolds of drug molecules, with multi-atomic editing as an emergent approach. Herein, we present a protocol for constructing N-substituted...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Intermolecular Defluorinative 1,2-Diamination of Fluoroalkenyl Iodides with Sulfonamides: Synthesis of Acyclic and Cyclic Fluorinated 1,2-Enediamines

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01913J, Research Article
Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
Alkene diamination represents one of the most straightforward strategies for 1,2-diamine derivatives synthesis. However, transition-metal-free 1,2-diamination of fluoroalkenes has been less studied. Here we report an intermolecular defluorinative vicinal diamination...
The content of this RSS Feed (c) The Royal Society of Chemistry




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At Via Milano in Hyderabad, the pizza can wait, go for the chops




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TGSRTC Karimnagar region to operate special buses to Arunachala Hill in Tamil Nadu on November 13




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Moneylenders push family to end life, man his daughter die, wife survives

Head of the family was being harassed and intimidated by two Nizamabad-based moneylenders




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Owaisi hails Supreme Court ruling on AMU’s minority status

The Modi government should take this judgement in its stride, says Asad




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No more parties without permission: Telangana Excise Dept. to farmhouse owners




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District Consumer Commission dismisses complaint against Google Pay due to lack of evidence




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Mental health and resilience in higher education institutions as a mission 

A two-day conclave started at IIT Hyderabad with an aim to foster healthy and harmonious environment in higher education institutions with the goal of reducing suicide rates and enhancing student and faculty wellbeing




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Man arrested for kidnapping, marrying, sexually assaulting minor




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Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months

45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data




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Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe

Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice




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Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana




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Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat

The new order comes into effect from November 11 until further notice, said the commissioner




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Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy




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People’s committee slams BJP, BRS for ‘opposing’ caste survey in Telangana




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66% of gamers in India are from non-metro cities: Lumikai annual report

Average weekly time spent on gaming increased by 30% to 13 hours




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GHMC’s claims for budget allocations delayed due to absence of full time commissioner




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IND vs NZ third Test: India shoots itself in the foot after dominating most of the day

A combination of reckless batting and decision-making undoes all the good work done by Jadeja and Washington in restricting New Zealand to a modest 235




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I want to be a complete batter and a complete spinner: Tanush Kotian’s mission statement 

The Mumbai all-rounder’s consistent match-winning feats have catapulted him into national reckoning. Judging by the challenges he has overcome so far, as well as his clear-headed approach to cricket, the 26-year-old will be keen to test himself on India-A’s tour of Australia




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India vs New Zealand, 3rd Test, Day 2: Spinners dominate, time for batters to salvage pride; Test poised for exciting finish

New Zealand ended day two with an overall lead of 143, which might look small but even a target in the vicinity of 150 will pose serious challenge for the Indian batters




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Ball-change controversy involving Kishan dominates India A's 7-wicket loss to Australia A

Resuming at the overnight score of 139 for 3 while chasing 225, skipper Nathan McSweeney (88 not out) and Beau Webster (61) remained unbeaten, stitching unconquered 141 runs for the fourth wicket to ensure the comfortable win for the hosts.




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Crisis manager Cummins guides Australia to tense win over Pakistan

Playing his first ODI since last year's World Cup in India, Cummins produced a nerveless knock of 32 from 31 balls to push the hosts past Pakistan's modest total of 203 with 16.3 overs to spare




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Shami's return to competitive cricket delayed; not to play for Bengal against Karnataka, M.P.

Other than Shami, Bengal will also miss the services of prolific opener Abhimanyu Easwaran, wicketkeeper batter Abhishek Porel and pacer Mukesh Kumar, who are with India A squad in Australia.




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NZ series whitewash might awaken sleeping giant India: Josh Hazlewood

“The results are obviously good for us in a way,” said the Aussie fast bowler.




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Ranji Trophy | Powerful Tamil Nadu holds all the aces against Assam

Sai Kishore’s return boosts the visiting team; Ghadigaonkar & Co. will have to rack up big scores to provide meaningful competition




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Ben Stokes missing from IPL’s list of 1,574 players ahead of mega auction

IPL mega auction list includes marquee Indian players like Pant, Iyer, and Rahul, with a total purse of ₹120 crore




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Koushik’s five-for helps Karnataka dismiss Bengal for 301

Abhinav Manohar, who scored his maiden First Class 50, and Shreyas Gopal steady the ship for the home side after some initial stutters




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Denish leads Assam’s fightback against Tamil Nadu

The skipper compiles a patient unbeaten 54 and forges an unbroken 71-run stand with southpaw Sibsankar Roy, denying the opposition bowlers a breakthrough till close of play




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Ageing Kohli, Rohit must rekindle youthful mindset to rediscover lost glory: Greg Chappell

According to Chappell, the ageing Sharma and Kohli must summon the same drive and focus that once marked their prime years if India hopes to reclaim its form on foreign soil




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The building and breaching of Fortress India: chronicling a cycle of cricket dominance

India was invincible at home for 12 years, winning 18 consecutive Test series before New Zealand snapped the record streak in a historic clean sweep. What went into the making of the unbeaten run, what are the consequences of defeat and what does the future look like?




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Indian students can even work in UK after studies: UK minister




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The challenge of Economics

How prepared are you to face the CBSE exam on this application-oriented subject?




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Therapists for the mind

Psychology, a field with critical shortage of experts in India as well as all over the world, offers numerous specialisations to choose from.




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K.N. Rao: Committed to literature

Passion for his mother tongue drives 92-year-old K.N. Rao to continue to bring out translation works.




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JPL Gwynn: Smitten by the land and language

Remembering the British ICS officer whose love for Telugu language is well known.



  • History & Culture

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IDDARU MITHRULU (1961)

Starring A. Nageswara Rao, Gummadi, Relangi, Rajasulochana, E.V. Saroja, Sarada. M L Narasimham.



  • History & Culture

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Milestone for Indian diaspora poets

English language poets of the Indian diaspora were celebrated at a recent event in London.




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The Complete to Planning Your Estate in Florida: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Florida Residents

What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […]




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The Complete to Planning Your Estate in Pennsylvania: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Pennsylvania Residents

What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […]