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Fe3O4-decorated MXene for the effective removal of 133Ba and 137Cs: synthesis, characterization, and optimization via response surface methodology (RSM)

By pubs.rsc.org
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Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article
Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe3O4 decorated MXenes in the removal of highly toxic 133Ba and 137Cs using a radioactive indicator method.
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Simple Aliovalent Cation Substitution to Induce Strong Optical Anisotropy Enhancement in Rare Thioantimonates (V) Family

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02280G, Research Article
Qixian Ren, Wangfei Che, Mengmeng Chen, Chen Cui, Yabo Wu, Zhi Su
Thioantimonates containing high oxidation state Sb5+ have proven to exhibit excellent performance in the design of new materials such as infrared optics crystals and lithium-ion batteries. However, as described by...
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Digital strategies to improve the product quality and production efficiency of fluorinated polymers: 2. Heat removal performance of reactor with internal and external cooling systems

By pubs.rsc.org
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00203B, Paper
Xi-Bao Zhang, Yin-Ning Zhou, Hao Chen, Zheng-Hong Luo, Liyang Zhou, Guojun Yu, Wenwu Liu, Shiping Zhu
A reactor's heat transfer efficiency can be significantly enhanced and the fluid temperature uniformity can be controlled through introducing cooling water in the agitator and regulating the flow ratio of cooling water in the agitator and jacket.
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Removal of gaseous Hg0 by Cl-loaded carbonaceous material prepared from rice husk

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00414K, Paper
Naoto Tsubouchi, Momone Yoshizawa, Javzandogole Bud, Yuuki Mochizuki
The main objective of this study was to investigate the removal of gaseous Hg0 from the residue obtained during the chlorination of rice husk char to recover silica.
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Effects of Monovalent and Divalent Cations on the Rheology of Entangled DNA

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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D3SM00957B, Paper
Open Access
Jennifer Harnett, Simon Weir, Davide Michieletto
In this paper we investigate the effects of varying cation valency and concentration on the rheology of entangled Lambda DNA solutions. We show that monovalent cations moderately increase the viscoelasticty...
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Removal of diclofenac sodium from water using a polyacrylonitrile mixed-matrix membrane embedded with MOF-808

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RSC Adv., 2024, 14,12142-12146
DOI: 10.1039/D3RA08682H, Paper
Open Access
Xiao-Jing Hu, Yu-Lin Li, Hai-Xiong Liu, Shao-Ming Ying, Qi Yin, Tian-Fu Liu
Based on the excellent diclofenac sodium (DCF) removal capacity of MOF-808, a free-standing mixed-matrix membrane composed of polyacrylonitrile and MOF-808 was fabricated and used to remove DCF from water via an easily accessible filtration method.
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Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

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RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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Reducing Agent Triggered Templated Synthesis of Dynamic Covalent Poly(disulfide)s Nanonetwork: Remarkable Tuning in Noncovalent Encapsulation Stabilities and Cargo Release

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01109K, Paper
Arun Mondal, S. K. Sujauddin, Dhiman Mondal, Soumya Kolay, Shuvajyoti Sarkar, Mijanur Rahaman Molla
Here, we demonstrated a new methodology for the templated synthesis of cross-linked poly(disulfide)s based dynamic covalent nanonetwork as highly stable potential delivery vehicle in the field of chemotherapeutic applications. The...
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Single-ion quasi-solid-state electrolytes based on sulfonimide-functionalized covalent organic framework

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Polym. Chem., 2024, 15,4529-4541
DOI: 10.1039/D4PY00352G, Paper
Haomin Wu, Wencan Ma, Xin Huang, Yifeng Cai, Junheng Li, Qiaobo Liao, Kai Xi, Qiuhong Zhang, Xudong Jia
The COF based SIQSSEs with a high ionic conductivity of 4.3 × 10−4 S cm−1, a high LTN of 0.90. A high initial capacity (150.3 mA h g−1), high retention (99% after 100 cycles), good cycling stability and rate performance in Li/LFP battery test.
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Extracellular matrix mimetic supramolecular hydrogels reinforced with covalent crosslinked mesoporous silica nanoparticles

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00499J, Paper
Open Access
Aygül Zengin, Shahzad Hafeez, Pamela Habibovic, Matthew Baker, Sabine van Rijt
Here we present a promising strategy to create hybrid, biomimetic supramolecular injectable hydrogels reinforced covalent crosslinked mesoporous silica nanoparticles for tissue engineering applications.
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Participation of transition metal atoms in noncovalent bonds

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Phys. Chem. Chem. Phys., 2024, 26,27382-27394
DOI: 10.1039/D4CP03716B, Paper
Steve Scheiner
All metals of the d-block are capable of forming σ and π-hole bonds to a nucleophile. Some of these bonds are typical of noncovalent bonds, but others are strong enough to be characterized as a covalent coordinate bond.
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Near equivalence of polarizability and bond order flux metrics for describing covalent bond rearrangements

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Phys. Chem. Chem. Phys., 2024, 26,27459-27465
DOI: 10.1039/D4CP03337J, Paper
Lukas Kim, Teresa Head-Gordon
Identification of the breaking point for the chemical bond is essential for our understanding of chemical reactivity.
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Effects of oxidizer concentration and abrasive type on interfacial bonding and material removal in 4H-SiC polishing processes

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Phys. Chem. Chem. Phys., 2024, 26,27791-27806
DOI: 10.1039/D4CP03544E, Paper
Yuqi Zhou, Kezhong Xu, Yuhan Gao, Ziniu Yu, Fulong Zhu
Two different modes of material removal are defined based on the difference in the mode of atom removal, i.e., mechanical removal and removal associated with interfacial bonding.
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Lattice thermal conductivity reduction in Ca3AlSb3 and Ca5Al2Sb6 by manipulating the covalent tetrahedral chain

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03574G, Paper
Chi Zhang, Wenya Zhai, Jingyu Li, Jianbo Zhu, Zengfu Ou, Lanwei Li, Peng-Fei Liu, Xiaobing Liu, Yuli Yan, Yongsheng Zhang
Exploring the origins of low thermal conductivity in Ca–Al–Sb compounds reveals structural interactions that enhance phonon scattering. Strategies involve substituting heavier atoms to disrupt covalent chains, thereby reducing thermal conductivity.
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ARCaDia: Single-round screening of a DNA-type targeted covalent binder possessing a latent warhead

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04594G, Communication
Open Access
Masumi Taki, Masayasu Kuwahara, Chaohui Li, Naoko Tomoda, Naoyuki Miyashita, Tetsuo Kan, Jay Yang
A covalent binder for a target protein was obtained by a direct single-round screening of a latent-warhead-modified DNA library via affinity/reactivity-based co-selection of aptameric deoxyribonucleic acid (ARCaDia), followed by a...
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Pyrazolate-supported Cr3(μ3-O) cores; homovalent CrIII3 and mixed-valent CrIII2CrIV

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05161K, Communication
Jessica M. López-Plá, Mohammed Obies, Georgia Zahariou, Michael Pissas, Yiannis Sanakis, John E. McGrady, Raphael G. Raptis
The thermally assisted reaction of Cr(NO3)3·9H2O, 4-Cl-pzH, and Et3N yielded electrochemically active trinuclear CrIII–oxo–pyrazolate complexes with formula (Ph4P)2[Cr3(μ3-O)(μ-4-Cl-pz)6X3], X = Cl (1) and Br (2).
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Hydrazone-linked Covalent Organic Frameworks for Fluorescence Detection of Hg2+

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05468G, Communication
Xuefeng Wang, Zhaowei Yang, Lingsuo Meng, Xuehui Li, Hongtao Wei, Jing Ning, Shitao Wang, Dapeng Cao, Long Hao
A hydrazone-linked COF (DvDf-C3XJ-COF) with hydrogen-bond reinforcement and abundant coordination sites was synthesized, exhibiting strong fluorescence and high sensitivity/selectivity for Hg²⁺ detection, with a detection limit of 1.65 × 10⁻⁶...
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Ambient temperature-prepared BiOBr-supported zero-pretreatment coal gasification fine slag for organic pollutant removal

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New J. Chem., 2024, 48,7256-7264
DOI: 10.1039/D3NJ05906E, Paper
Hele Hua, Jing Yang, Rui Li, Yunfang Wang, Caimei Fan, Jianxin Liu, Yawen Wang
The BiOBr/CGFS photocatalysts were synthesized at ambient temperature by a simple hydrolysis method with zero pre-treatment of CGFS. CGFS led to the improvement of the quantum efficiency of BiOBr and further promoted the photocatalytic performance.
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Magnetically recyclable nanophotocatalysts in photocatalysis-involving processes for organic pollutant removal from wastewater: current status and perspectives

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00906H, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zexiao Zheng, Juhua He, Zuyao Zhang, Ashutosh Kumar, Musharib Khan, Cheuk Wai Lung, Irene M. C. Lo
The critical review covers the applications, associated mechanisms, challenges, and prospects of magnetically recyclable nanophotocatalysts in photocatalysis-related processes.
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A novel CuAl2O4/MoS2/BaFe12O19 magnetic photocatalyst simultaneously coupling type I and Z-scheme heterojunctions for the sunlight-driven removal of tetracycline hydrochloride

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00970J, Paper
Mengjun Han, Shifa Wang, Xinmiao Yu, Xianlun Yu, Huajing Gao, Xianju Zhou, Dengfeng Li, Leiming Fang, Jagadeesha Angadi V., Mohd Ubaidullah, Bidhan Pandit
A novel CuAl2O4/MoS2/BaFe12O19 photocatalyst is synthesized that simultaneously couples type I and Z-scheme heterojunctions and exhibits high photocatalytic activity for the degradation of TC under simulated sunlight irradiation.
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Biowaste valorization: multifunctional hybrid lignin/TiO2 nanostructures for bacterial-biocide disinfection and dye removal

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00091A, Paper
Open Access
Marica Gallo, Virginia Venezia, Marica Muscetta, Rossella Grappa, Mariavittoria Verrillo, Gianluca Landi, Raffaele Marotta, Giuseppina Luciani
Hybrid lignin TiO2 nanoparticles: red-ox activity enables biocide disinfection and dye removal.
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High-efficiency removal of Cd(II) and As(III) from irrigation water using a S–Fe–C composite: performance and mechanisms

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Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00863K, Paper
Zihao Liang, Yanpeng Liang, Hua Lin, Yuxi Lu, Huawei Li, Jie Zhang, Honghu Zeng, Gongning Chen
SFC showcased exceptional Cd(II) and As(III) removal capacities of 405 mg g−1 and 349 mg g−1, respectively, while preserving magnetic recovery properties after repeated adsorption cycles, making it an environmentally sustainable functional material.
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Applications of bismuth-based nanoparticles for the removal of pollutants in wastewater: a review

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Environ. Sci.: Nano, 2024, 11,1332-1367
DOI: 10.1039/D3EN00983A, Critical Review
Shan Jiang, Yihang Zhang, Jianyu Gong
This review discusses the characteristics and synthesis methods of Bi-based NPs. It delves into the removal efficiency in wastewater, emphasizing traditional/emerging strategies to enhance the performance, mechanisms, toxicology, and challenges.
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Covalently linked thieno[2,3-b]thiophene-fullerene dimers: synthesis and physical characterization

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Org. Biomol. Chem., 2024, 22,2978-2984
DOI: 10.1039/D4OB00027G, Paper
Abdulrahman M. Alazemi, Mohammad H. BinSabt, Hamad M. Al-Matar, Alan L. Balch, Mona A. Shalaby
Linked thieno[2,3-b]thiophene-fullerene Dimers.
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Roll back approval to import used medical devices, med-tech industry urges PM

By www.thehindu.com
Published On :: Mon, 28 Oct 2024 20:20:33 +0530

The group said the move puts at risk patient safety and undermines the domestic med-tech sector. It said that refurbished machines are not subject to stringent quality checks applicable to new devices.


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Tailoring the adsorption properties of imidazole-based halogen bonded organic frameworks for anionic dye removal

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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article
Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]+ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
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Centre to give in-principle approval for AIIMS in Kozhikode: Union Minister

By www.thehindu.com
Published On :: Fri, 05 Aug 2022 20:52:48 +0530

‘State government has to acquire land and hand it over to Centre’


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Optimization of the electron transfer kinetics between a photoanode and biocathode for enhanced carbon-neutral pollutant removal in photocatalytic fuel cells

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Published On ::

J. Mater. Chem. A, 2024, 12,30371-30379
DOI: 10.1039/D4TA05290K, Paper
Xiaofei Gu, Jianyu Han, Zhi Wang, Yixin Hong, Tianyi Huang, Yafeng Wu, Yuanjian Zhang, Songqin Liu
A PFC system with collaborative dynamics between the photoanode and biocathode is constructed for using solar energy to efficiently convert refractory organic pollutants into green fuel and generate electricity.
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Strain and U driven phase transitions in monolayer intrinsic ferrovalley NbIn2As2Se2

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J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03637A, Paper
Jiajun Zhu, Heyun Zhao, Wanbiao Hu
Strain and U value driven topological phase transitions in monolayer NbIn2As2Se2.
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A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control

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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00521J, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shengbo Ge, Kexin Wei, Wanxi Peng, Runzhou Huang, Esther Akinlabi, Hongyan Xia, Muhammad Wakil Shahzad, Xuehua Zhang, Ben Bin Xu, Jianchun Jiang
Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement.
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Enhanced photocatalysis of metal/covalent organic frameworks by plasmonic nanoparticles and homo/hetero-junctions

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Mater. Horiz., 2024, 11,1611-1637
DOI: 10.1039/D3MH01645E, Review Article
Yannan Liu, Shengyun Huang, Xing Huang, Dongling Ma
Metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) photocatalysts face challenge in poor photocatalytic efficiency, which was promoted by the introduction of plasmonic nanoparticles (NPs) and junctions.
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Heterointerface regulation of covalent organic framework-anchored graphene via a solvent-free strategy for high-performance supercapacitor and hybrid capacitive deionization electrodes

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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00161C, Communication
Liming Xu, Yong Liu, Xiaoyang Xuan, Xingtao Xu, Yuquan Li, Ting Lu, Likun Pan
A 2D redox-active pyrazine-based COF was solvent-free anchored on graphene for heterointerface regulation, displaying exciting energy storage and desalination performances.
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Construction of phase-separated Co/MnO synergistic catalysts and integration onto sponge for rapid removal of multiple contaminants

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Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00285G, Communication
Mengting Liu, Wanyu Zhang, Ruiting Ni, Zhenxiao Wang, Hongyao Zhao, Xiu Zhong, Yanyun Wang, Danhong Shang, Zengjing Guo, Edison Huixiang Ang, Fu Yang
Novel metallic Co integration onto MnO nanorods enhances catalyst efficiency for wastewater treatment.
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Regulation with Experimentation: Ex Ante Approval, Ex Post Withdrawal, and Liability [electronic journal].

By encore.st-andrews.ac.uk
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Global Value Chains and the Removal of Trade Protection [electronic journal].

By encore.st-andrews.ac.uk
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Barriers to trade in environmental goods: How Important they are and what should developing countries expect from their removal [electronic journal].

By encore.st-andrews.ac.uk
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00304G, Review Article
Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
It outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Best Agrolife gets approval for patented herbicide ‘Shot Down’ and insecticide ‘Bestman’

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 17:25:02 +0530

These products are slated for launch in the fourth quarter of the fiscal year.


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IndiGo secures approval for wet lease renewals of 11 A320 aircraft

By www.thehindubusinessline.com
Published On :: Mon, 04 Nov 2024 19:20:52 +0530


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Rapid, Potent, and Persistent Covalent Chemical Probes to Deconvolute PI3Kα Signaling

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05459H, Edge Article
Open Access
Lukas Bissegger, Theodora Alexandra Alexandra Constantin, Erhan Keles, Luka Raguž, Isobel Barlow-Busch, Clara Orbegozo, Thorsten Schaefer, Valentina Borlandelli, Thomas Bohnacker, Rohitha SriRamaratnam, Alexander Schäfer, Matthias Gstaiger, John E. Burke, Chiara Borsari, Matthias Wymann
Chemical probes have gained importance in the elucidation of signal transduction in biology. Insufficient selectivity and potency, lack of cellular activity and inappropriate use of chemical probes has major consequences...
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Paytm gets Finmin approval for downstream investment into its payment services arm 

By www.thehindubusinessline.com
Published On :: Wed, 28 Aug 2024 18:57:52 +0530

PPSL will now resubmit application with RBI for Payment Aggregator licence


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A dozen industrial smart cities worth ₹28,602 cr get CCEA approval

By www.thehindubusinessline.com
Published On :: Wed, 28 Aug 2024 20:51:53 +0530

Projects to be completed by 2027, attract investment of ₹1.5 lakh crore, general 10 lakh direct jobs, says Piyush Goyal


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India enforces mandatory CCI approval for M&As over ₹2,000 crore under new regulations

By www.thehindubusinessline.com
Published On :: Tue, 10 Sep 2024 13:07:50 +0530

The updated regulations define ‘India nexus’ criteria, including user metrics and turnover, and introduce a ₹500 crore monetary threshold.  


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Polymeric membrane potentiometric sensors based on template-removal-free imprinted receptors for determination of antibiotics

By pubs.rsc.org
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Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D4AY00263F, Paper
Xinyao Wang, Guohua Cui, Rongning Liang, Wei Qin
Currently, Nernstian-response-based polymeric membrane potentiometric sensors using the molecularly imprinted polymers (MIPs) as the receptors have been successfully developed for determination of organic ionic species. However, the preparation of these...
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Homebuyers gain from removal of differential tax rates on preferred locations, lowering overall costs

By www.thehindubusinessline.com
Published On :: Tue, 10 Sep 2024 10:26:05 +0530

One third of the transaction value of an immovable property is attributed to land, which is excluded from and it is not included for calculation of GST calculation


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Enhanced removal efficiency of Tetradesmus obliquus for nevirapine removal via co-substrate supplementation: removal mechanisms, relative gene expression and metabolomics

By pubs.rsc.org
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Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00576G, Paper
Karen Reddy, Nirmal Renuka, Muneer Ahmad Malla, Brenda Moodley, Faizal Bux, Sheena Kumari
The bioremediation of pharmaceutical wastewater by microalgae has gained scientific attention due to its cost-effectiveness and environmental friendliness.
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DOM removal from Lake Kinneret by adsorption columns and biodegradation: a pilot study and modeling

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Environ. Sci.: Water Res. Technol., 2024, 10,2736-2751
DOI: 10.1039/D4EW00407H, Paper
Mario L. Kummel, Ofri B. Zusman, Shlomo Nir, Yael G. Mishael
A study on the removal of DOM from Lake Kinneret, the main surface drinking water source in Israel, was conducted applying an adsorption pilot plant with columns that included granular activated carbons, a clay–polymer nanocomposite and a combination of both.
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A novel graphene oxide–microalgae hybrid material for the removal of pentavalent arsenic from natural water and industrial wastewater

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Environ. Sci.: Water Res. Technol., 2024, 10,2796-2808
DOI: 10.1039/D4EW00308J, Paper
Eliana S. Lemos, Evelyn M. Valdés Rodríguez, Adrián Bonilla Petriciolet, Andrea M. Ray, Leticia B. Escudero
The adsorption process using bionanomaterials based on graphene oxide and green microalgae for the removal of arsenic from complex samples of natural water and industrial wastewater.
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