sca Validation study of small-angle X-ray scattering tensor tomography By scripts.iucr.org Published On :: 2020-04-22 Small-angle scattering tensor tomography (SASTT) is a recently developed technique able to tomographically reconstruct the 3D reciprocal space from voxels within a bulk volume. SASTT extends the concept of X-ray computed tomography, which typically reconstructs scalar values, by reconstructing a tensor per voxel, which represents the local nanostructure 3D organization. In this study, the nanostructure orientation in a human trabecular-bone sample obtained by SASTT was validated by sectioning the sample and using 3D scanning small-angle X-ray scattering (3D sSAXS) to measure and analyze the orientation from single voxels within each thin section. Besides the presence of cutting artefacts from the slicing process, the nanostructure orientations obtained with the two independent methods were in good agreement, as quantified with the absolute value of the dot product calculated between the nanostructure main orientations obtained in each voxel. The average dot product per voxel over the full sample containing over 10 000 voxels was 0.84, and in six slices, in which fewer cutting artefacts were observed, the dot product increased to 0.91. In addition, SAXS tensor tomography not only yields orientation information but can also reconstruct the full 3D reciprocal-space map. It is shown that the measured anisotropic scattering for individual voxels was reproduced from the SASTT reconstruction in each voxel of the 3D sample. The scattering curves along different 3D directions are validated with data from single voxels, demonstrating SASTT's potential for a separate analysis of nanostructure orientation and structural information from the angle-dependent intensity distribution. Full Article text
sca Linearly polarized X-ray fluorescence computed tomography based on a Thomson scattering light source: a Monte Carlo study By scripts.iucr.org Published On :: 2020-04-06 A Thomson scattering X-ray source can provide quasi-monochromatic, continuously energy-tunable, polarization-controllable and high-brightness X-rays, which makes it an excellent tool for X-ray fluorescence computed tomography (XFCT). In this paper, we examined the suppression of Compton scattering background in XFCT using the linearly polarized X-rays and the implementation feasibility of linearly polarized XFCT based on this type of light source, concerning the influence of phantom attenuation and the sampling strategy, its advantage over K-edge subtraction computed tomography (CT), the imaging time, and the potential pulse pile-up effect by Monte Carlo simulations. A fan beam and pinhole collimator geometry were adopted in the simulation and the phantom was a polymethyl methacrylate cylinder inside which were gadolinium (Gd)-loaded water solutions with Gd concentrations ranging from 0.2 to 4.0 wt%. Compared with the case of vertical polarization, Compton scattering was suppressed by about 1.6 times using horizontal polarization. An accurate image of the Gd-containing phantom was successfully reconstructed with both spatial and quantitative identification, and good linearity between the reconstructed value and the Gd concentration was verified. When the attenuation effect cannot be neglected, one full cycle (360°) sampling and the attenuation correction became necessary. Compared with the results of K-edge subtraction CT, the contrast-to-noise ratio values of XFCT were improved by 2.03 and 1.04 times at low Gd concentrations of 0.2 and 0.5 wt%, respectively. When the flux of a Thomson scattering light source reaches 1013 photons s−1, it is possible to finish the data acquisition of XFCT at the minute or second level without introducing pulse pile-up effects. Full Article text
sca LamNI – an instrument for X-ray scanning microscopy in laminography geometry By scripts.iucr.org Published On :: 2020-04-06 Across all branches of science, medicine and engineering, high-resolution microscopy is required to understand functionality. Although optical methods have been developed to `defeat' the diffraction limit and produce 3D images, and electrons have proven ever more useful in creating pictures of small objects or thin sections, so far there is no substitute for X-ray microscopy in providing multiscale 3D images of objects with a single instrument and minimal labeling and preparation. A powerful technique proven to continuously access length scales from 10 nm to 10 µm is ptychographic X-ray computed tomography, which, on account of the orthogonality of the tomographic rotation axis to the illuminating beam, still has the limitation of necessitating pillar-shaped samples of small (ca 10 µm) diameter. Large-area planar samples are common in science and engineering, and it is therefore highly desirable to create an X-ray microscope that can examine such samples without the extraction of pillars. Computed laminography, where the axis of rotation is not perpendicular to the illumination direction, solves this problem. This entailed the development of a new instrument, LamNI, dedicated to high-resolution 3D scanning X-ray microscopy via hard X-ray ptychographic laminography. Scanning precision is achieved by a dedicated interferometry scheme and the instrument covers a scan range of 12 mm × 12 mm with a position stability of 2 nm and positioning errors below 5 nm. A new feature of LamNI is a pair of counter-rotating stages carrying the sample and interferometric mirrors, respectively. Full Article text
sca Identification of Ca-rich dense granules in human platelets using scanning transmission X-ray microscopy By scripts.iucr.org Published On :: 2020-03-16 Whole-mount (WM) platelet preparation followed by transmission electron microscopy (TEM) observation is the standard method currently used to assess dense granule (DG) deficiency (DGD). However, due to the electron-density-based contrast mechanism in TEM, other granules such as α-granules might cause false DG detection. Here, scanning transmission X-ray microscopy (STXM) was used to identify DGs and minimize false DG detection of human platelets. STXM image stacks of human platelets were collected at the calcium (Ca) L2,3 absorption edge and then converted to optical density maps. Ca distribution maps, obtained by subtracting the optical density maps at the pre-edge region from those at the post-edge region, were used to identify DGs based on the Ca richness. DGs were successfully detected using this STXM method without false detection, based on Ca maps for four human platelets. Spectral analysis of granules in human platelets confirmed that DGs contain a richer Ca content than other granules. The Ca distribution maps facilitated more effective DG identification than TEM which might falsely detect DGs. Correct identification of DGs would be important to assess the status of platelets and DG-related diseases. Therefore, this STXM method is proposed as a promising approach for better DG identification and diagnosis, as a complementary tool to the current WM TEM approach. Full Article text
sca A design of resonant inelastic X-ray scattering (RIXS) spectrometer for spatial- and time-resolved spectroscopy By scripts.iucr.org Published On :: 2020-04-16 The optical design of a Hettrick–Underwood-style soft X-ray spectrometer with Wolter type 1 mirrors is presented. The spectrometer with a nominal length of 3.1 m can achieve a high resolving power (resolving power higher than 10000) in the soft X-ray regime when a small source beam (<3 µm in the grating dispersion direction) and small pixel detector (5 µm effective pixel size) are used. Adding Wolter mirrors to the spectrometer before its dispersive elements can realize the spatial imaging capability, which finds applications in the spectroscopic studies of spatially dependent electronic structures in tandem catalysts, heterostructures, etc. In the pump–probe experiments where the pump beam perturbs the materials followed by the time-delayed probe beam to reveal the transient evolution of electronic structures, the imaging capability of the Wolter mirrors can offer the pixel-equivalent femtosecond time delay between the pump and probe beams when their wavefronts are not collinear. In combination with some special sample handing systems, such as liquid jets and droplets, the imaging capability can also be used to study the time-dependent electronic structure of chemical transformation spanning multiple time domains from microseconds to nanoseconds. The proposed Wolter mirrors can also be adopted to the existing soft X-ray spectrometers that use the Hettrick–Underwood optical scheme, expanding their capabilities in materials research. Full Article text
sca Fluorescence-detected quick-scanning X-ray absorption spectroscopy By scripts.iucr.org Published On :: 2020-04-06 Time-resolved X-ray absorption spectroscopy (XAS) offers the possibility to monitor the state of materials during chemical reactions. While this technique has been established for transmission measurements for a number of years, XAS measurements in fluorescence mode are challenging because of limitations in signal collection as well as detectors. Nevertheless, measurements in fluorescence mode are often the only option to study complex materials containing heavy matrices or in samples where the element of interest is in low concentration. Here, it has been demonstrated that high-quality quick-scanning full extended X-ray absorption fine-structure data can be readily obtained with sub-second time resolution in fluorescence mode, even for highly diluted samples. It has also been demonstrated that in challenging samples, where transmission measurements are not feasible, quick fluorescence can yield significant insight in reaction kinetics. By studying the fast high-temperature oxidation of a reduced LaFe0.8Ni0.8O3 perovskite type, an example where the perovskite matrix elements prevent measurements in fluorescence, it is shown that it is now possible to follow the state of Ni in situ at a 3 s time resolution. Full Article text
sca Development of a scanning soft X-ray spectromicroscope to investigate local electronic structures on surfaces and interfaces of advanced materials under conditions ranging from low vacuum to helium atmosphere By scripts.iucr.org Published On :: 2020-03-18 A scanning soft X-ray spectromicroscope was recently developed based mainly on the photon-in/photon-out measurement scheme for the investigation of local electronic structures on the surfaces and interfaces of advanced materials under conditions ranging from low vacuum to helium atmosphere. The apparatus was installed at the soft X-ray beamline (BL17SU) at SPring-8. The characteristic features of the apparatus are described in detail. The feasibility of this spectromicroscope was demonstrated using soft X-ray undulator radiation. Here, based on these results, element-specific two-dimensional mapping and micro-XAFS (X-ray absorption fine structure) measurements are reported, as well as the observation of magnetic domain structures from using a reference sample of permalloy micro-dot patterns fabricated on a silicon substrate, with modest spatial resolution (e.g. ∼500 nm). Then, the X-ray radiation dose for Nafion® near the fluorine K-edge is discussed as a typical example of material that is not radiation hardened against a focused X-ray beam, for near future experiments. Full Article text
sca Estimating signal and noise of time-resolved X-ray solution scattering data at synchrotrons and XFELs By scripts.iucr.org Published On :: 2020-03-31 Elucidating the structural dynamics of small molecules and proteins in the liquid solution phase is essential to ensure a fundamental understanding of their reaction mechanisms. In this regard, time-resolved X-ray solution scattering (TRXSS), also known as time-resolved X-ray liquidography (TRXL), has been established as a powerful technique for obtaining the structural information of reaction intermediates and products in the liquid solution phase and is expected to be applied to a wider range of molecules in the future. A TRXL experiment is generally performed at the beamline of a synchrotron or an X-ray free-electron laser (XFEL) to provide intense and short X-ray pulses. Considering the limited opportunities to use these facilities, it is necessary to verify the plausibility of a target experiment prior to the actual experiment. For this purpose, a program has been developed, referred to as S-cube, which is short for a Solution Scattering Simulator. This code allows the routine estimation of the shape and signal-to-noise ratio (SNR) of TRXL data from known experimental parameters. Specifically, S-cube calculates the difference scattering curve and the associated quantum noise on the basis of the molecular structure of the target reactant and product, the target solvent, the energy of the pump laser pulse and the specifications of the beamline to be used. Employing a simplified form for the pair-distribution function required to calculate the solute–solvent cross term greatly increases the calculation speed as compared with a typical TRXL data analysis. Demonstrative applications of S-cube are presented, including the estimation of the expected TRXL data and SNR level for the future LCLS-II HE beamlines. Full Article text
sca Saturation and self-absorption effects in the angle-dependent 2p3d resonant inelastic X-ray scattering spectra of Co3+ By journals.iucr.org Published On :: It is shown that the 2p3d resonant inelastic X-ray scattering intensity is distorted by saturation and self-absorption effects, i.e. by incident-energy-dependent saturation and by emission-energy-dependent self-absorption. Full Article text
sca Classification of grazing-incidence small-angle X-ray scattering patterns by convolutional neural network By journals.iucr.org Published On :: Convolutional neural networks are useful for classifying grazing-incidence small-angle X-ray scattering patterns. They are also useful for classifying real experimental data. Full Article text
sca A novel methodology to study nanoporous alumina by small-angle neutron scattering By scripts.iucr.org Published On :: 2019-06-28 Nanoporous anodic aluminium oxide (AAO) membranes are promising host systems for confinement of condensed matter. Characterizing their structure and composition is thus of primary importance for studying the behavior of confined objects. Here a novel methodology to extract quantitative information on the structure and composition of well defined AAO membranes by combining small-angle neutron scattering (SANS) measurements and scanning electron microscopy (SEM) imaging is reported. In particular, (i) information about the pore hexagonal arrangement is extracted from SEM analysis, (ii) the best SANS experimental conditions to perform reliable measurements are determined and (iii) a detailed fitting method is proposed, in which the probed length in the fitting model is a critical parameter related to the longitudinal pore ordering. Finally, to validate this strategy, it is applied to characterize AAOs prepared under different conditions and it is shown that the experimental SANS data can be fully reproduced by a core/shell model, indicating the existence of a contaminated shell. This original approach, based on a detailed and complete description of the SANS data, can be applied to a variety of confining media and will allow the further investigation of condensed matter under confinement. Full Article text
sca Crystallography at the nanoscale: planar defects in ZnO nanospikes By scripts.iucr.org Published On :: 2019-08-29 The examination of anisotropic nanostructures, such as wires, platelets or spikes, inside a transmission electron microscope is normally performed only in plan view. However, intrinsic defects such as growth twin interfaces could occasionally be concealed from direct observation for geometric reasons, leading to superposition. This article presents the shadow-focused ion-beam technique to prepare multiple electron-beam-transparent cross-section specimens of ZnO nanospikes, via a procedure which could be readily extended to other anisotropic structures. In contrast with plan-view data of the same nanospikes, here the viewing direction allows the examination of defects without superposition. By this method, the coexistence of two twin configurations inside the wurtzite-type structure is observed, namely [2 {overline 1} {overline 1} 0]^{ m W}/(0 1 {overline 1} 1) and [2 {overline 1} {overline 1} 0]^{ m W}/(0 1 {overline 1} 3), which were not identified during the plan-view observations owing to superposition of the domains. The defect arrangement could be the result of coalescence twinning of crystalline nuclei formed on the partially molten Zn substrate during the flame-transport synthesis. Three-dimensional defect models of the twin interface structures have been derived and are correlated with the plan-view investigations by simulation. Full Article text
sca Improving grazing-incidence small-angle X-ray scattering–computed tomography images by total variation minimization By scripts.iucr.org Published On :: 2020-02-01 Grazing-incidence small-angle X-ray scattering (GISAXS) coupled with computed tomography (CT) has enabled the visualization of the spatial distribution of nanostructures in thin films. 2D GISAXS images are obtained by scanning along the direction perpendicular to the X-ray beam at each rotation angle. Because the intensities at the q positions contain nanostructural information, the reconstructed CT images individually represent the spatial distributions of this information (e.g. size, shape, surface, characteristic length). These images are reconstructed from the intensities acquired at angular intervals over 180°, but the total measurement time is prolonged. This increase in the radiation dosage can cause damage to the sample. One way to reduce the overall measurement time is to perform a scanning GISAXS measurement along the direction perpendicular to the X-ray beam with a limited interval angle. Using filtered back-projection (FBP), CT images are reconstructed from sinograms with limited interval angles from 3 to 48° (FBP-CT images). However, these images are blurred and have a low image quality. In this study, to optimize the CT image quality, total variation (TV) regularization is introduced to minimize sinogram image noise and artifacts. It is proposed that the TV method can be applied to downsampling of sinograms in order to improve the CT images in comparison with the FBP-CT images. Full Article text
sca BornAgain: software for simulating and fitting grazing-incidence small-angle scattering By scripts.iucr.org Published On :: 2020-02-01 BornAgain is a free and open-source multi-platform software framework for simulating and fitting X-ray and neutron reflectometry, off-specular scattering, and grazing-incidence small-angle scattering (GISAS). This paper concentrates on GISAS. Support for reflectometry and off-specular scattering has been added more recently, is still under intense development and will be described in a later publication. BornAgain supports neutron polarization and magnetic scattering. Users can define sample and instrument models through Python scripting. A large subset of the functionality is also available through a graphical user interface. This paper describes the software in terms of the realized non-functional and functional requirements. The web site https://www.bornagainproject.org/ provides further documentation. Full Article text
sca Li-ion half-cells studied operando during cycling by small-angle neutron scattering By scripts.iucr.org Published On :: 2020-01-31 Small-angle neutron scattering (SANS) was recently applied to the in situ and operando study of the charge/discharge process in Li-ion battery full-cells based on a pouch cell design. Here, this work is continued in a half-cell with a graphite electrode cycled versus a metallic lithium counter electrode, in a study conducted on the SANS-1 instrument of the neutron source FRM II at the Heinz Maier-Leibnitz Zentrum in Garching, Germany. It is confirmed that the SANS integrated intensity signal varies as a function of graphite lithiation, and this variation can be explained by changes in the squared difference in scattering length density between graphite and the electrolyte. The scattering contrast change upon graphite lithiation/delithiation calculated from a multi-phase neutron scattering model is in good agreement with the experimentally measured values. Due to the finite coherence length, the observed SANS contrast, which mostly stems from scattering between the (lithiated) graphite and the electrolyte phase, contains local information on the mesoscopic scale, which allows the development of lithiated phases in the graphite to be followed. The shape of the SANS signal curve can be explained by a core–shell model with step-wise (de)lithiation from the surface. Here, for the first time, X-ray diffraction, SANS and theory are combined to give a full picture of graphite lithiation in a half-cell. The goal of this contribution is to confirm the correlation between the integrated SANS data obtained during operando measurements of an Li-ion half-cell and the electrochemical processes of lithiation/delithiation in micro-scaled graphite particles. For a deeper understanding of this correlation, modelling and experimental data for SANS and results from X-ray diffraction were taken into account. Full Article text
sca Quantifying nanoparticles in clays and soils with a small-angle X-ray scattering method By scripts.iucr.org Published On :: 2020-02-01 Clays and soils produce strong small-angle X-ray scattering (SAXS) because they contain large numbers of nanoparticles, namely allophane and ferrihydrite. These nanoparticles are amorphous and have approximately spherical shape with a size of around 3–10 nm. The weight ratios of these nanoparticles will affect the properties of the clays and soils. However, the nanoparticles in clays and soils are not generally quantified and are sometimes ignored because there is no standard method to quantify them. This paper describes a method to quantify nanoparticles in clays and soils with SAXS. This is achieved by deriving normalized SAXS intensities from unit weight of the sample, which are not affected by absorption. By integrating the normalized SAXS intensities over the reciprocal space, one obtains a value that is proportional to the weight ratio of the nanoparticles, proportional to the square of the difference of density between the nanoparticles and the liquid surrounding the nanoparticles, and inversely proportional to the density of the nanoparticles. If the density of the nanoparticles is known, the weight ratio of the nanoparticles can be calculated from the SAXS intensities. The density of nanoparticles was estimated from the chemical composition of the sample. Nanoparticles in colloidal silica, silica gels, mixtures of silica gel and α-aluminium oxide, and synthetic clays have been quantified with the integral SAXS method. The results show that the errors of the weight ratios of nanoparticles are around 25% of the weight ratio. It is also shown that some natural clays contain large fractions of nanoparticles; montmorillonite clay from the Mikawa deposit, pyrophillite clay from the Shokozan deposit and kaolinite clay from the Kanpaku deposit contain 25 (7), 10 (2) and 19 (5) wt% nanoparticles, respectively, where errors are shown in parentheses. Full Article text
sca Simulation of small-angle X-ray scattering data of biological macromolecules in solution By scripts.iucr.org Published On :: 2020-02-18 This article presents IMSIM, an application to simulate two-dimensional small-angle X-ray scattering patterns and, further, one-dimensional profiles from biological macromolecules in solution. IMSIM implements a statistical approach yielding two-dimensional images in TIFF, CBF or EDF format, which may be readily processed by existing data-analysis pipelines. Intensities and error estimates of one-dimensional patterns obtained from the radial average of the two-dimensional images exhibit the same statistical properties as observed with actual experimental data. With initial input on an absolute scale, [cm−1]/c[mg ml−1], the simulated data frames may also be scaled to absolute scale such that the forward scattering after subtraction of the background is proportional to the molecular weight of the solute. The effects of changes of concentration, exposure time, flux, wavelength, sample–detector distance, detector dimensions, pixel size, and the mask as well as incident beam position can be considered for the simulation. The simulated data may be used in method development, for educational purposes, and also to determine the most suitable beamline setup for a project prior to the application and use of the actual beamtime. IMSIM is available as part of the ATSAS software package (3.0.0) and is freely available for academic use (http://www.embl-hamburg.de/biosaxs/download.html). Full Article text
sca Manual measurement of angles in backscattered and transmission Kikuchi diffraction patterns By scripts.iucr.org Published On :: 2020-03-25 A historical tool for crystallographic analysis is provided by the Hilton net, which can be used for manually surveying the crystal lattice as it is manifested by the Kikuchi bands in a gnomonic projection. For a quantitative analysis using the Hilton net, the projection centre as the relative position of the signal source with respect to the detector plane needs to be known. Interplanar angles are accessible with a precision and accuracy which is estimated to be ≤0.3°. Angles between any directions, e.g. zone axes, are directly readable. Finally, for the rare case of an unknown projection-centre position, its determination is demonstrated by adapting an old approach developed for photogrammetric applications. It requires the indexing of four zone axes [uvw]i in a backscattered Kikuchi diffraction pattern of a known phase collected under comparable geometric conditions. Full Article text
sca Reconstructing intragranular strain fields in polycrystalline materials from scanning 3DXRD data By scripts.iucr.org Published On :: 2020-02-21 Two methods for reconstructing intragranular strain fields are developed for scanning three-dimensional X-ray diffraction (3DXRD). The methods are compared with a third approach where voxels are reconstructed independently of their neighbours [Hayashi, Setoyama & Seno (2017). Mater. Sci. Forum, 905, 157–164]. The 3D strain field of a tin grain, located within a sample of approximately 70 grains, is analysed and compared across reconstruction methods. Implicit assumptions of sub-problem independence, made in the independent voxel reconstruction method, are demonstrated to introduce bias and reduce reconstruction accuracy. It is verified that the two proposed methods remedy these problems by taking the spatial properties of the inverse problem into account. Improvements in reconstruction quality achieved by the two proposed methods are further supported by reconstructions using synthetic diffraction data. Full Article text
sca Monte Carlo simulation of neutron scattering by a textured polycrystal By scripts.iucr.org Published On :: 2020-03-30 A method of simulating the neutron scattering by a textured polycrystal is presented. It is based on an expansion of the scattering cross sections in terms of the spherical harmonics of the incident and scattering directions, which is derived from the generalized Fourier expansion of the polycrystal orientation distribution function. The method has been implemented in a Monte Carlo code as a component of the McStas software package, and it has been validated by computing some pole figures of a Zircaloy-4 plate and a Zr–2.5Nb pressure tube, and by simulating an ideal transmission experiment. The code can be used to estimate the background generated by components of neutron instruments such as pressure cells, whose walls are made of alloys with significant crystallographic texture. As a first application, the effect of texture on the signal-to-noise ratio was studied in a simple model of a diffraction experiment, in which a sample is placed inside a pressure cell made of a zirconium alloy. With this setting, the results of two simulations were compared: one in which the pressure-cell wall has a uniform distribution of grain orientations, and another in which the pressure cell has the texture of a Zr–2.5Nb pressure tube. The results showed that the effect of the texture of the pressure cell on the noise of a diffractogram is very important. Thus, the signal-to-noise ratio can be controlled by appropriate choice of the texture of the pressure-cell walls. Full Article text
sca Microstructure and water distribution in catalysts for polymer electrolyte fuel cells, elucidated by contrast variation small-angle neutron scattering By journals.iucr.org Published On :: By using small-angle neutron scattering (SANS) reinforced by scanning electron microscopy, the fine structure of catalysts for polymer electrolyte fuel cells has been investigated. The experimental data resulting from contrast variation with mixed light and heavy water (H2O/D2O) are well described by a core–shell model with fluctuations in concentration between water and Nafion. Full Article text
sca A study of the strain distribution by scanning X-ray diffraction on GaP/Si for III–V monolithic integration on silicon By journals.iucr.org Published On :: The distribution of plastic relaxation defects is studied using a nondestructive sub-micrometre X-ray diffraction scanning technique. Full Article text
sca Diffracting-grain identification from electron backscatter diffraction maps during residual stress measurements: a comparison between the sin2ψ and cosα methods By journals.iucr.org Published On :: The sin2ψ and cosα methods are compared via diffracting-grain identification from electron backscatter diffraction maps. Artificial textures created by the X-ray diffraction measurements are plotted and X-ray elastic constants of the diffracting-grain sets are computed. Full Article text
sca Small-angle neutron scattering (SANS) and spin-echo SANS measurements reveal the logarithmic fractal structure of the large-scale chromatin organization in HeLa nuclei By journals.iucr.org Published On :: This paper reports on the two-scale fractal structure of chromatin organization in the nucleus of the HeLa cell. Full Article text
sca New attempt to combine scanning electron microscopy and small-angle scattering in reciprocal space By journals.iucr.org Published On :: An attempt has been made to combine small-angle scattering of X-rays or neutrons with scanning electron microscopy in reciprocal space, in order to establish a structural analysis method covering a wide range of sizes from micro- to macro-scales. Full Article text
sca Calculation of total scattering from a crystalline structural model based on experimental optics parameters By journals.iucr.org Published On :: A calculation procedure for X-ray total scattering and the pair distribution function from a crystalline structural model is presented. It allows one to easily and precisely deal with diffraction-angle-dependent parameters such as the atomic form factor and the resolution of the optics. Full Article text
sca Sub-millisecond time-resolved small-angle neutron scattering measurements at NIST By journals.iucr.org Published On :: Instrumentation for sub-millisecond time-resolved small-angle neutron scattering measurements at NIST is described and applied to the reorientation dynamics of elongated hematite nanoparticles. Full Article text
sca sasPDF: pair distribution function analysis of nanoparticle assemblies from small-angle scattering data By journals.iucr.org Published On :: The sasPDF method, an extension of the atomic pair distribution function (PDF) analysis to the small-angle scattering (SAS) regime, is presented. The method is applied to characterize the structure of nanoparticle assemblies with different levels of structural order. Full Article text
sca Equatorial aberration of powder diffraction data collected with an Si strip X-ray detector by a continuous-scan integration method By journals.iucr.org Published On :: Exact and approximate formulas for equatorial aberration of a continuous-scan Si strip detector are compared. Full Article text
sca A novel experimental approach for nanostructure analysis: simultaneous small-angle X-ray and neutron scattering By journals.iucr.org Published On :: A portable small-angle X-ray scattering instrument with geometrical dimensions suitable for installation at the D22 instrument was designed and constructed for simultaneous small-angle X-ray and neutron scattering experiments at ILL. Full Article text
sca GIWAXS-SIIRkit: Scattering Intensity, Indexing, and Refraction Calculation Toolkit for Grazing Incidence Wide Angle X-ray Scattering of Organic Materials By journals.iucr.org Published On :: A software package for Grazing Incident Wide Angle X-ray Scattering (GIWAXS) geared toward weakly ordered materials, including: scattering intensity normalization/uncertainty, scattering pattern indexing, and refractive shift correction. Full Article text
sca Newly discovered Madagascar spider spins largest, toughest webs on record By insider.si.edu Published On :: Sat, 02 Oct 2010 10:42:40 +0000 Darwin's bark spider cast giant webs across streams, rivers and lakes, suspending the web’s orb above water and attaching it to plants on each riverbank. Bridgelines of these water-spanning webs have been measured as long as 25 meters. The post Newly discovered Madagascar spider spins largest, toughest webs on record appeared first on Smithsonian Insider. Full Article Animals Research News Science & Nature biodiversity insects National Museum of Natural History spiders
sca Tiger numbers could triple if large-scale landscapes are protected By insider.si.edu Published On :: Wed, 26 Jan 2011 16:07:05 +0000 The tiger reserves of Asia could support more than 10,000 wild tigers – three times the current number – if they are managed as large-scale […] The post Tiger numbers could triple if large-scale landscapes are protected appeared first on Smithsonian Insider. Full Article Animals Research News Science & Nature conservation conservation biology endangered species mammals Smithsonian's National Zoo
sca Video: A mummy ‘grows’ with CT scans and 3D digital technology By insider.si.edu Published On :: Tue, 16 Aug 2011 14:03:05 +0000 Using 2-dimensional and 3-dimensional CT scans, Natural History Museum anthropologists found that the brain and major organs were removed and rolls of linen filled out the abdominal cavity. This mummification method is evidence of superior embalming, indicating a person of higher status. The post Video: A mummy ‘grows’ with CT scans and 3D digital technology appeared first on Smithsonian Insider. Full Article Anthropology Science & Nature conservation digitization National Museum of Natural History osteology technology
sca Peruvian mummy as seen by a SOMATOM Emotion 6CT scanner By insider.si.edu Published On :: Thu, 10 Nov 2011 18:48:31 +0000 Viewed from inside the SOMATOM Emotion 6CT scanner used at the Smithsonian’s National Museum of Natural History, the skeleton and internal organs of this well-preserved […] The post Peruvian mummy as seen by a SOMATOM Emotion 6CT scanner appeared first on Smithsonian Insider. Full Article Anthropology Science & Nature Spotlight National Museum of Natural History Peru South America
sca Walrus whale 3-D skull scan By insider.si.edu Published On :: Mon, 09 Jul 2012 14:48:09 +0000 This image shows a 3-D scan of the type specimen of Odobenocetops, the walrus whale, in the Smithsonian’s National Museum of Natural History. The skull […] The post Walrus whale 3-D skull scan appeared first on Smithsonian Insider. Full Article Dinosaurs & Fossils Marine Science Science & Nature Spotlight digitization mammals National Museum of Natural History whales
sca One Scary Chicken—New species of large, feathered dinosaur discovered By insider.si.edu Published On :: Wed, 19 Mar 2014 21:01:21 +0000 Finding a fossil is the first step, recognizing it for what it truly is, is the real challenge. While closely studying three fossil skeletons from […] The post One Scary Chicken—New species of large, feathered dinosaur discovered appeared first on Smithsonian Insider. Full Article Dinosaurs & Fossils Research News Science & Nature birds dinosaurs exhibitions extinction fossils National Museum of Natural History new acquisitions new species prehistoric
sca Urban landscapes becoming increasingly bird-unfriendly By insider.si.edu Published On :: Mon, 14 Jul 2014 18:56:14 +0000 Tasty and easy to find, the heath hen was a favorite dish of America’s colonial settlers. This beautiful little bird, however, was no match for […] The post Urban landscapes becoming increasingly bird-unfriendly appeared first on Smithsonian Insider. Full Article Animals Research News Science & Nature bird strikes birds conservation conservation biology endangered species extinction National Museum of Natural History pollution Smithsonian's National Zoo veterinary medicine
sca The world’s scariest rabbit lurks within the Smithsonian’s collection By insider.si.edu Published On :: Fri, 31 Oct 2014 11:01:01 +0000 Among the bats, rats and other ferocious animals that lie within the storage drawers of the mammal collection in the Smithsonian’s National Museum of Natural […] The post The world’s scariest rabbit lurks within the Smithsonian’s collection appeared first on Smithsonian Insider. Full Article Animals Research News Science & Nature mammals
sca These newly discovered pelican spiders will make you want to visit Madagascar By insider.si.edu Published On :: Thu, 11 Jan 2018 18:15:20 +0000 In 1854, a curious-looking spider was found preserved in 50 million-year-old amber. With an elongated neck-like structure and long mouthparts that protruded from the “head” […] The post These newly discovered pelican spiders will make you want to visit Madagascar appeared first on Smithsonian Insider. Full Article Animals Science & Nature National Museum of Natural History
sca Relativistic correction of atomic scattering factors for high-energy electron diffraction By scripts.iucr.org Published On :: 2019-10-24 Relativistic electron diffraction depends on linear and quadratic terms in the electric potential, the latter being neglected in the frequently used relativistically corrected Schrödinger equation. The quadratic electric potential term modifies atomic scattering amplitudes in particular for large-angle scattering and backscattering. The respective correction increases with increasing scattering angle, increasing atomic number and increasing kinetic energy. Conventional tabulations for electron scattering and its large-angle extrapolations can be amended in closed form by a universal correction based on the screened Coulomb potential squared. Full Article text
sca Converting three-space matrices to equivalent six-space matrices for Delone scalars in S6 By scripts.iucr.org Published On :: 2020-01-01 The transformations from the primitive cells of the centered Bravais lattices to the corresponding centered cells have conventionally been listed as three-by-three matrices that transform three-space lattice vectors. Using those three-by-three matrices when working in the six-dimensional space of lattices represented as Selling scalars as used in Delone (Delaunay) reduction, one could transform to the three-space representation, apply the three-by-three matrices and then back-transform to the six-space representation, but it is much simpler to have the equivalent six-by-six matrices and apply them directly. The general form of the transformation from the three-space matrix to the corresponding matrix operating on Selling scalars (expressed in space S6) is derived, and the particular S6matrices for the centered Delone types are listed. (Note: in his later publications, Boris Delaunay used the Russian version of his surname, Delone.) Full Article text
sca Chasing down scam / spam emails without going in-seine By www.bleepingcomputer.com Published On :: 2020-04-29T11:12:50-05:00 Full Article
sca sfc /scannow for Windows 8 By www.bleepingcomputer.com Published On :: 2013-06-03T23:17:54-05:00 Full Article
sca 3-D laser scanning is helping solve ancient mysteries at the Smithsonian By insider.si.edu Published On :: Sat, 05 Jan 2013 15:17:01 +0000 The post 3-D laser scanning is helping solve ancient mysteries at the Smithsonian appeared first on Smithsonian Insider. Full Article Anthropology Science & Nature Video National Museum of Natural History
sca 3-D Scanning “Greek Slave” at American Art By insider.si.edu Published On :: Wed, 15 Jul 2015 14:19:25 +0000 Vince Rossi and Jon Blundell from the Smithsonian’s Digitization Program Office (http://3d.si.edu) apply various 3-D capture methods on the pointed plaster model for the “Greek […] The post 3-D Scanning “Greek Slave” at American Art appeared first on Smithsonian Insider. Full Article Art Video digitization materials science technology visual arts
sca Bobcat escapes National Zoo enclosure By insider.si.edu Published On :: Tue, 31 Jan 2017 12:23:04 +0000 On the morning of Monday, Jan. 30, 2017 a 25-pound female bobcat cat was discovered missing from its exhibit at the Smithsonian’s National Zoo in […] The post Bobcat escapes National Zoo enclosure appeared first on Smithsonian Insider. Full Article Animals Science & Nature Video Smithsonian's National Zoo
sca Remove the Windows Defender Browser Protection Tech Support Scam By www.bleepingcomputer.com Published On :: Thu, 23 Jan 2020 18:12:04 EST The Windows Defender Browser Protection tech support scam is a fake web site alert that states that Windows Defender Browser Extension detected someone to hack your bank account.This article was published first at Remove the Windows Defender Browser Protection Tech Support Scam Full Article Spyware Removal Virus Removal Malware Removal Security Windows Defender Browser Protection Tech Support Scam Tech Support Scams
sca Escape of the invasives: Top six invasive plant species in the United States By insider.si.edu Published On :: Fri, 19 Apr 2013 19:11:03 +0000 Non-native plant species pose a significant threat to the natural ecosystems of the United States. Many of these invasive plants are escapees from gardens and […] The post Escape of the invasives: Top six invasive plant species in the United States appeared first on Smithsonian Insider. Full Article Plants Research News Science & Nature invasive species new species
sca VIDEO: 3-D scanning at the Smithsonian By insider.si.edu Published On :: Mon, 13 May 2013 13:11:37 +0000 What can you do to bring some of the Smithsonian’s 137 million objects to life? Put them in 3-D! This is a full-time job for […] The post VIDEO: 3-D scanning at the Smithsonian appeared first on Smithsonian Insider. Full Article Animals Anthropology Marine Science Plants Science & Nature biodiversity conservation conservation biology digitization insects materials science National Museum of American History National Museum of Natural History technology