The Latino Christian vote shifted strongly in support of President-elect Donald Trump in the 2024 presidential election, according to exit polls.

[Inter-Korea] :
North Korea and Russia have accused the United States and its allies of escalating tensions on the Korean Peninsula, with Moscow expressing its full support of the North's measures against the United States. Pyongyang and Moscow released press statements on Saturday, a day after a strategic dialogue ...

[more...]

Combined 100 ms resolved grazing-incidence small/wide-angle X-ray scattering and optical interferometry reveal that the additive diiodooctane can significantly double the solvent evaporation rate, thereby effectively suppressing the rapid spinodal decomposition process in the early stage of spin-coasting, favouring slow phase segregation kinetics with nucleation and growth.

The simulation of EXAFS spectra of thin films via ab initio methods is discussed. The procedure for producing the spectra is presented as well as an application to a two-dimensional material (WSe2) where the effectiveness of this method in reproducing the spectrum and the linear dichroic response is shown. A series of further examples in which the method has been employed for the structural determination of materials are given.

Multilayer gratings are increasingly popular optical elements at X-ray beamlines, as they can provide much higher photon flux in the tender X-ray range compared with traditional single-layer coated gratings. While there are several proprietary software tools that provide the functionality to simulate the efficiencies of such gratings, until now the X-ray community has lacked an open-source alternative. Here MLgrating is presented, a program for simulating the efficiencies of both multilayer gratings and single-layer coated gratings for X-ray applications. MLgrating is benchmarked by comparing its output with that of other software tools and plans are discussed for how the program could be extended in the future.

Platinum(II) complexes of square-planar geometry are interesting from a crystal engineering viewpoint because they exhibit strong luminescence based on the self-assembly of molecular units. The luminescence color changes in response to gentle stimuli, such as vapor exposure or weak mechanical forces. Both the molecular and the crystal designs for soft crystals are critical to effectively generate the chromic luminescence phenomenon of Pt(II) complexes. In this topical review, strategies for fabricating chromic luminescent Pt(II) complexes are described from a crystal design perspective, focusing on the structural regulation of Pt(II) complexes that exhibit assembly-induced luminescence via metal–metal interactions and structural control of anionic Pt(II) complexes using cations. The research progress on the evolution of various chromic luminescence properties of Pt(II) complexes, including the studies conducted by our group, are presented here along with the latest research outcomes, and an overview of the frontiers and future potential of this research field is provided.

The complex [Pt(C9H6NO)Cl(C2H4)], (I), was synthesized and structurally characterized by ESI mass spectrometry, IR, NMR spectroscopy, DFT calculations and X-ray diffraction. The results showed that the deprotonated 8-hy­droxy­quinoline (C9H6NO) coordinates with the PtII atom via the N and O atoms while the ethyl­ene coordinates in the η2 manner and in the trans position compared to the coordinating N atom. The crystal packing is characterized by C—H⋯O, C—H⋯π, Cl⋯π and Pt⋯π inter­actions. Complex (I) showed high selective activity against Lu-1 and Hep-G2 cell lines with IC50 values of 0.8 and 0.4 µM, respectively, 54 and 33-fold more active than cisplatin. In particular, complex (I) is about 10 times less toxic to normal cells (HEK-293) than cancer cells Lu-1 and Hep-G2. Furthermore, the reaction of complex (I) with guanine at the N7 position was proposed and investigated using the DFT method. The results indicated that replacement of the ethyl­ene ligand with guanine is thermodynamically more favorable than the Cl ligand and that the reaction occurs via two consecutive steps, namely the replacement of ethyl­ene with H2O and the water with the guanine mol­ecule.

Three organoplatinum(II) complexes bearing natural aryl­olefin and quinoline derivatives, namely, [4-meth­oxy-5-(2-meth­oxy-2-oxoeth­oxy)-2-(prop-2-en-1-yl)phen­yl](quinolin-8-olato)platinum(II), [Pt(C13H15O4)(C9H6NO)], (I), [4-meth­oxy-5-(2-oxo-2-propoxyeth­oxy)-2-(prop-2-en-1-yl)phen­yl](quinoline-2-carboxy­l­ato)platinum(II), [Pt(C15H19O4)(C10H6NO2)], (II), and chlorido­[4-meth­oxy-5-(2-oxo-2-propoxyeth­oxy)-2-(prop-2-en-1-yl)phen­yl](quinoline)­plat­inum(II), [Pt(C15H19O4)Cl(C9H7N)], (III), were synthesized and structurally characterized by IR and 1H NMR spectroscopy, and by single-crystal X-ray diffraction. The results showed that the cyclo­platinated aryl­olefin coordinates with PtII via the carbon atom of the phenyl ring and the C=Colefinic group. The deprotonated 8-hy­droxy­quinoline (C9H6NO) and quinoline-2-carb­oxy­lic acid (C10H6NO2) coordinate with the PtII atom via the N and O atoms in complexes (I) and (II) while the quinoline (C9H7N) coordinates via the N atom in (III). Moreover, the coordinating N atom in complexes (I)–(III) is in the cis position compared to the C=Colefinic group. The crystal packing is characterized by C—H⋯π, C—H⋯O [for (II) and (III)], C—H⋯Cl [for (III) and π–π [for (I)] inter­actions.

Peruvian fintech B89 has announced a partnership with Brazil-based...

Cloud banking provider Mambu has partnered with

The environmental effects of oil and gas exploration and production on Alaska s North Slope have been accumulating for more than three decades, says a new report from the National Academies National Research Council.

The U.S.-based Transportation Research Board (TRB) of the National Academies of Sciences, Engineering, and Medicine (NASEM) has formed a cooperative understanding with the Colombia-based Sociedad Panamericana de Investigación en Transporte y Logística (Pan-American Society of Transportation Research, PANAMSTR).

There are the telltale signs of aging — a few more wrinkles, graying hair, and changes in posture. Other changes are less obvious. Aging-related changes also occur within the gut microbiome — a collection of bacteria, viruses, and fungi that live in your digestive tract.

Brazi Bites has announced the launch of its new Homestyle Breakfast Sandwiches in four varieties: Bacon, Turkey Sausage, Double Egg and Turkey Bacon.

While fresh bread is the largest category in the bakery industry, it has remained relatively flat for the past several years. But several emerging trends have fostered growth, pointing the way toward future potential for the category.

Grain Processing Corp.’s INSCOSITY modified pre-gelatinized food starch improves moisture retention and shelf life in baked goods.

There are 52 million Hispanics in the U.S., representing 16.7% of the total U.S. population. That many people are certainly having an impact on the food industry, and there’s no question that Latinos are quickly changing America’s palate.

The deadline to submit an application is May 3.

With user-friendly plug-in installation and energy-saving thermostat control, the system is ideal for preventing ice from forming inside 3/4-inch to 6-inch diameter water lines in temperatures below -40°F (-40° C).

RainStick Shower co-founders Alisha McFetridge and Sean McFetridge share a longtime passion for water conservation. In 2019, the two began building the North American Market’s first water circulating shower. Supply House Times Chief Editor Natalie Forster sat down with Alisha McFetridge to dive into RainStick Shower’s backstory and plans for the future.

Renowned author, speaker, and radio/TV personality, Dr. Madelyn Blair, takes the spotlight in this very special profile. "Unlock" her hit series, explore her acclaimed work, and get ready for the return of Mental Espresso, reimagined for 2023.

Renowned author, speaker, and radio/TV personality, Dr. Madelyn Blair, takes the spotlight in this very special profile. "Unlock" her hit series, explore her acclaimed work, and get ready for the return of Mental Espresso, reimagined for 2023.

Dominican-American writer/director from Providence, RI, Vega Montañez, draws the support of undefeated UFC fighters, Hip Hop Icons, Media Personalities, and an Emmy Award winning producer to bring his next feature film to audiences around the world.

"We are pleased to be part of ALAS in bringing our scientific achievements, technological innovation, and expertise in the fields of sensors, IoT, Big-Data, narcotics, contraband, and explosives detection to the ALAS community," says Doron Shalom, C

License Plating version 1.97 expands mixed item tracking capabilities, boosts inventory accuracy, and optimizes workflows for manufacturers and distributors.

Gearbox repair and manufacture company reaches elite level with an almost perfect score

Our Platinum Blend, crafted by combining CBD Distillate and Full Spectrum Extract, offers unparalleled potency and efficacy. With the highest concentration of cannabidiol (CBD) available, this exceptional formula empowers you to continue activities.

Richard Runyon is set for success in 2024 with six more interviews, a book debut, a video web series, and more. Today we celebrate the storytelling journey that's redefining narratives and captivating audiences everywhere.

Richard Runyon debuts the sixth installment of 12 in his acclaimed interview series, "A Story to Tell." As Richard Runyon Ventures charts new horizons, this release marks just one of many exciting steps ahead.

Reaching its midpoint, 'A Story to Tell' Part 6 secures Platinum Flagship status for Q1 2024, bolstering Richard Runyon's legacy and the success of his renowned interview cycle. His 'Storybook' web series and a packed 2024-25 release schedule await.

Demonstrating Best-in-Class Implementation Expertise on Dassault Systèmes Solutions

"There's no one hot toy of the year, but a range of great toys for all ages and budgets" notes cofounder and child development expert, Stephanie Oppenheim.

Seamless Integration of Healthcare and Travel for a Holistic Patient Experience

Mexican Artist and Satirist José Guadalupe Posada Meets His Most Famous Creation the Calavera Catrina in a New One Act Play

US companies shift focus to Latin America, tapping into regional benefits with Biz Latin Hub's integrated services

NetCom Learning, a trusted Cisco Platinum Learning Partner, is gearing up to showcase its extensive Cisco training expertise at Cisco Live 2024 in Las Vegas.

A Florida appellate court ruled that a judge of compensation claims erroneously calculated a minor league baseball player’s average weekly wage. Austin Sodders entered into a seven-year minor league contract with…

América Latina y el Caribe es un importante protagonista en la producción y el comercio de productos agroalimentarios, ya que es el principal exportador neto de estos productos. La región cuenta con los recursos naturales (tierra, agua y energía renovable) y la capacidad necesaria para producir alimentos de manera sostenible y para satisfacer sus necesidades y abastecer al mundo. Sin embargo, durante 2021, la inseguridad alimentaria moderada o grave afectó al 40,6% de la población en la región (267,7 millones de personas), cifra considerablemente superior al promedio mundial (29,3%).

Identifying guidelines for the design of conditional credit programs to promote sustainable agricultural practices in Latin America

Tools for food system policy development.

The post Identifying guidelines for the design of conditional credit programs to promote sustainable agricultural practices in Latin America appeared first on IFPRI.

Navigating the Trade Landscape: A Latin American Perspective building on the WTO 13th Ministerial Conference

The governance of agricultural and food trade is facing unprecedented challenges in a rapidly evolving global landscape. As traditional agricultural trade issues, such as domestic support and market access, seem to lose their prominence and the feasibility of advancing with a multilateral strategy diminishes, the focus is shifting toward the environmental and nutritional dimensions of […]

The post Navigating the Trade Landscape: A Latin American Perspective building on the WTO 13th Ministerial Conference appeared first on IFPRI.

Identifying proteomic risk factors for cancer using prospective and exome analyses of 1463 circulating proteins and risk of 19 cancers in the UK Biobank  Nature.com

Words are never just words. They carry context and controversy; they can signal identity or sow discord. This week, TED speakers explore the history and politics of our ever-evolving language. Guests include linguists Anne Curzan and John McWhorter, social psychologist Dannagal Young and writer Mark Forsyth.

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Frenk is among 17 trailblazers recognized for their contributions to politics, business, culture, entertainment and other fields.

The chancellor-designate was one of 17 honorees, including actors, playwrights, corporate executives and others, honored for their influence and leadership.