meth

Comparing diverse extraction methodologies to infer the performance of 1,8-cineole extraction from Eucalyptus cinerea: process optimization, kinetics, and interaction mechanisms

RSC Adv., 2024, 14,35529-35552
DOI: 10.1039/D4RA06050D, Paper
Open Access
Divya Baskaran, Madhumitha Sathiamoorthy, Ramasamy Govindarasu, Hun-Soo Byun
Different extraction techniques were used to extract 1,8-cineole from Eucalyptus cinerea leaves, and their performance efficiency was evaluated through optimization and kinetic studies.
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meth

Statistically driven automated method for catalytic glucose conversion optimisation

RSC Adv., 2024, 14,35578-35584
DOI: 10.1039/D4RA06038E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joseph Install, Rui Zhang, Jukka Hietala, Timo Repo
A statistically driven, automated approach to optimize glucose transformations to platform chemicals, methyl lactate and levulinic acid, is reported.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Reaction of unsymmetrical α-bromo-1,3-diketones with N-substituted thioureas: regioselective access to 2-(N-arylamino)-5-acyl-4-methylthiazoles and/or rearranged 2-(N-acylimino)-3-N-aryl-4-methylthiazoles

RSC Adv., 2024, 14,35585-35600
DOI: 10.1039/D4RA05436A, Paper
Open Access
Ranjana Aggarwal, Shilpa Sharma, Naman Jain, Dionisia Sanz, Rosa M. Claramunt, Patricia Delgado, M. Carmen Torralba
Hantzsch's [3 + 2] cyclic condensation of α-bromo-1,3-diketones with N-substituted thioureas.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Complexes between 2,2'-azobis(2-methylpropionamidine) dihydrochloride (AAPH) and cucurbit[n]uril hosts modulate the yield and fate of photolytically-generated AAPH radicals

RSC Adv., 2024, 14,35980-35991
DOI: 10.1039/D4RA07150F, Paper
Open Access
Angie C. Forero-Girón, Mauricio Oyarzún, Kevin Droguett, Denis Fuentealba, Soledad Gutiérrez-Oliva, Barbara Herrera, Alejandro Toro-Labbé, Eduardo Fuentes-Lemus, Michael J. Davies, Camilo López-Alarcón, Margarita E. Aliaga
AAPH-cucurbit[n]uril systems were experimentally and theoretically studied. Radical yields formed upon photolysis of AAPH were altered by complexation with CB[8] in a stoichiometry-dependent manner, however, radical yields were not changed by CB[6].
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

A safe and efficient synthesis of N-Boc-β3-amino acid methyl esters from α-amino acids: applications in the formal synthesis of sedum alkaloids

RSC Adv., 2024, 14,36016-36021
DOI: 10.1039/D4RA07506D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bohua Long, Lijie Ren, Mengmeng Jiang, Shengquan Hu, Qianqian Jiang, Limin Li, Xuanluan Chen, Zhengzhi Wu
β3-Amino acids are essential components in the synthesis of biologically active compounds.
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meth

Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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meth

Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites

Dalton Trans., 2024, 53,18021-18026
DOI: 10.1039/D4DT02421D, Paper
Afif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki Motohashi
The oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).
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meth

Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02589J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef Holub
The objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.
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meth

Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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meth

Complete actor vs method hero

When Sivaji Ganesan fans locked horns with Dilp Kumar admirers




meth

Schema-focused working methods for arts and body-based therapies [electronic resource] : a practical guide / edited by Suzanne Haeyen.

New York, NY : Routledge , 2024.




meth

Simultaneous removal of acetaminophen, sulfamethoxazole, and iohexol from real wastewater in continuous mode by an immobilized sulfur-doped Bi2O3/MnO2 photocatalyst

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00501E, Paper
Vishal Kumar Parida, Mario Vino Lincy Gnanaguru, Suneel Kumar Srivastava, Shamik Chowdhury, Ashok Kumar Gupta
The photocatalytic potential of the Z-scheme 2S-Bi2O3/MnO2 immobilized photocatalyst for the simultaneous degradation of ACT, SMX, and IOX from MBBR-sand filter treated wastewater is studied for the first time, purely from a practical perspective.
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meth

Handbook of research methods in behavioural economics [electronic resource] : an interdisciplinary approach / edited by Morris Altman (Dean, University of Dundee School of Business, and Chair Professor of Behavioural and Institutional Economics and Co-ope

Cheltenham, UK ; Northampton, MA, USA : Edward Elgar Publishing, [2023]




meth

‘If you travel with a feeling that the country has something to teach you, it will always be an act of empathy’

The 84-year-old Colin Thubron on why travel books will endure and what draws him to remote places on earth like Siberia




meth

Congress should explain why Rahul is not fighting from Amethi; it is their cowardice: Madhya Pradesh Chief Minister Mohan Yadav

Mr. Yadav says the BJP’s strength lies in its collective leadership and that Congress leaders have no ideology



  • Lok Sabha Elections

meth

A robust data analytical method to investigate sequence dependence in flow-based peptide synthesis

React. Chem. Eng., 2024, 9,825-832
DOI: 10.1039/D3RE00494E, Paper
Open Access
Bálint Tamás, Pietro Luigi Willi, Héloïse Bürgisser, Nina Hartrampf
A new data analytical method for flow-based peptide synthesis enables robust and quantitative analysis of sequence-dependent difficult couplings.
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meth

Selective hydrogenation of 5-hydroxymethylfurfural to 2,5-bis(hydroxymethyl)furan over Ni–Ga intermetallic catalysts and its kinetic studies

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00129J, Paper
Weixiao Sun, Fuzeyu Zhong, Xiaohu Ge, Wenyao Chen, Gang Qian, Yueqiang Cao, Xuezhi Duan, Xinggui Zhou, Jing Zhang
5-Hydroxymethylfurfural (HMF) has been listed as the “TOP 14” most important biomass-derived platform molecules, which can be converted into 2,5-bis(hydroxymethyl)furan (BHF) via selective hydrogenation of the carbonyl group on HMF.
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meth

Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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meth

In vivo mechanism of interaction between trimethylamine lyase expresssion and glycolytic pathways

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO03809F, Paper
Qian Li, Di Wu, Yu Song, Lu Zhang, Ting Wang, Min Zhang
Recent findings have confirmed that the interaction between host and gut microbiota can alter the formation of the disease-associated metabolite, trimethylamine (TMA), via intestinal microbial TMA lyase. Nevertheless, little is...
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Protein-bound AGEs derived from methylglyoxal induce pro-inflammatory response and barrier integrity damage in epithelial cells by disrupting the retinol metabolism

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO00364K, Paper
Gang Yu, Jianxin He, Zhongshan Gao, Linglin Fu, Qiaozhi Zhang
Protein-bound advanced glycation end-products (AGEs) induce pro-inflammatory response and barrier integrity damage in epithelial cells by disrupting the retinol metabolism.
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meth

The quercetin metabolite 4-methylcatechol causes vasodilation via voltage-gated potassium (KV) channels

Food Funct., 2024, 15,11047-11059
DOI: 10.1039/D3FO04672A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Patrícia Dias, Rudy Salam, Jana Pourová, Marie Vopršalová, Lukáš Konečný, Eduard Jirkovský, Jurjen Duintjer Tebbens, Přemysl Mladěnka
One of important metabolites of dietary polyphenols is 4-methylcatechol (4-MC). This compounds causes vasodilation likely due to an effect on voltage-dependent potassium channels (KV) as suggested by our ex vivo and in silico docking study.
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A novel method for exploration and prediction of the bioactive target of rice bran-derived peptide (KF-8) by integrating computational methods and experiments

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO02493A, Paper
Rui Liang, Fangliang Song, Ying Liang, Yanpeng Fang, Jianqiang Wang, Yajuan Chen, Zhongxu Chen, Xiaorong Tan, Jie Dong
The diagram of the strategy to explore peptide targets based on model predictions and experiments.
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meth

Shining a light on methane dry reforming – exploring the impact of visible light on carbon formation over Co/xCeO2–Al2O3

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper
George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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meth

Synergy of Ag and Pd in bimetallic catalysts for the selective oxidation of 5-(hydroxymethyl)furfural

Catal. Sci. Technol., 2024, Accepted Manuscript
DOI: 10.1039/D4CY01028K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Dominik Neukum, Maya Eyleen Ludwig, Georgios Uzunidis, Ajai Raj Lakshmi Nilayam, Baerbel Krause, Silke Behrens, Jan-Dierk Grunwaldt, Erisa Saraçi
The synthesis of renewable bio-based monomers, like 2,5-furandicarboxylic acid (FDCA), is of high interest in the shift toward a circular economy. Bimetallic catalysts offer the variation of different properties, enabling...
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Mechanistic insights into the oxidative coupling of methane over a Li/MgO catalyst: an experimental and microkinetic modeling study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01132E, Paper
Zaili Xiong, Jijun Guo, Yuwen Deng, Meirong Zeng, Zhandong Wang, Zhongyue Zhou, Wenhao Yuan, Fei Qi
This study investigates the oxidative coupling of methane (OCM) using a Li/MgO catalyst in a packed bed reactor.
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meth

Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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meth

Exploring catalytic oxidation pathways of furfural and 5-hydroxymethyl furfural into carboxylic acids using Au, Pt, and Pd catalysts: a comprehensive review

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00821A, Review Article
Toyese Oyegoke, Franck Dumeignil, Baba E.-Yakubu Jibril, Carine Michel, Robert Wojcieszak
This review explores the mechanisms and factors influencing the selective oxidation of HMF and furfural into valuable products using gold, platinum, and palladium catalysts.
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meth

Directed evolution of C-methyltransferase PsmD for enantioselective pyrroloindole derivative production

Catal. Sci. Technol., 2024, 14,6298-6306
DOI: 10.1039/D4CY00657G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Diana A. Amariei, Julia Tenhaef, Thomas Classen, Benoit David, Tobias M. Rosch, Holger Gohlke, Stephan Noack, Jörg Pietruszka
The engineering of stereoselective C-methyltransferase PsmD through saturation mutagenesis led to improved activity for larger substrates. An automated process was designed and successfully applied for the mutant library production and screening.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Ag co-catalyst prepared by ultrasonic reduction method for efficient photocatalytic conversion of CO2 with H2O using ZnTa2O6 photocatalyst

Catal. Sci. Technol., 2024, 14,6207-6214
DOI: 10.1039/D4CY00564C, Paper
Kio Kawata, Shoji Iguchi, Shimpei Naniwa, Tsunehiro Tanaka, Masamu Nishimoto, Kentaro Teramura
Towards the realisation of carbon neutrality by utilising renewable energy sources, the photocatalytic conversion of CO2 with H2O—known as artificial photosynthesis—is important.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Selectively controlled synthesis of diethyl carbonate and methyl ethyl carbonate via transesterification of dimethyl carbonate over a KATriz/Al2O3 catalyst

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00979G, Paper
Open Access
Peixue Wang, Shimin Liu, Xinjiang Cui, Feng Shi
Effectively synthesis of methyl ethyl carbamate from dimethyl carbonate and ethanol using 14 wt% KATriz/Al2O3 in fixed bed mode.
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meth

Effect of metal loading sequences in CO2 methanation activity on samarium-doped ceria supported bimetallic catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01007H, Paper
Andrew C. Chien, Corinna C. Chi
The La/Ni/SDC catalyst from one pot microwave-heating gives higher methanation activity than La–Ni/SDC and Ni–La/SDC from stepwise heating.
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meth

Catalytic activity and stability of NiPt/C catalysts for the synthesis of iso-butanol from methanol/ethanol mixtures

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01061B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Joachim Pasel, Johannes Häusler, Ralf Peters, Detlef Stolten
The uniqueness and innovation of the Ni99Pt1/C catalyst lies in the fact that a promising activity for iso-butanol synthesis was already observed at a low temperature of 165 °C in methanolic solution and at a very low precious metal mass fraction.
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meth

Oxygen vacancy-dependent low-temperature performance of Ni/CeO2 in CO2 methanation

Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper
Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO2 methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Synergistic promotion of oxygen vacancy and Lewis acidity of Nb2O5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt

Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper
Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt1/Nb2O5, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb2O5 selectively promotes the hydrogenolysis of the –CH2OH group rather than the hydrogenation of the –CHO group.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO2 and methanol

Catal. Sci. Technol., 2024, 14,6513-6523
DOI: 10.1039/D4CY00702F, Paper
Niladri Maity, Samiyah A. Al-Jendan, Samir Barman, Nagendra Kulal, E. A. Jaseer
Heteroatom (N, S) assisted CeO2 nanorod materials exhibited enhanced catalytic efficiency in the synthesis of dimethyl carbonate from CO2 and methanol, attributed to their superior surface acidity, basicity, Ce3+ concentration, and oxygen vacancies.
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meth

Enhancing coking resistance of nickel-based catalysts for dry reforming of methane via nitric oxide abatement: a support study

Catal. Sci. Technol., 2024, 14,6678-6691
DOI: 10.1039/D4CY00936C, Paper
Open Access
Beatrice Senoner, Andrea Osti, Antonella Glisenti
How to enhance DRM and NO carbon-assisted coupling using a support?
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bifunctional catalysts based on PdZn/ZnO and hierarchical zeolites in the direct synthesis of dimethyl ether from CO-rich syngas: influence of the support and the Zn/Pd molar ratio

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00860J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bing Wang, Nicola Da Roit, Michael Zimmermann, Markus Boese, Thomas Zevaco, Silke Behrens
Pd/Zn-nanoparticles were used as precursors to study the influence of the molar Zn/Pd ratio and hierarchical HZSM-5 zeolites in the syngas-to-dimethyl ether process.
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meth

Deciphering the role of chemisorbed CO in CO2 methanation: kinetic and mechanistic investigation over monometallic (Ru) and bimetallic (Ru–Ni) catalysts

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01004C, Paper
Pavan Dongapure, Jyoti Tekawadia, V. Satyam Naidu, R. Nandini Devi
Supported metal catalysts have made prominent contributions to CO2 mitigation through conversion into useful chemicals.
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meth

High yield exfoliation of sub-micron hexagonal boron nitride using a solvent free method

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02850C, Paper
Diana Santiago, Maricela Lizcano, Sean P. McDarby, Ching-cheh Hung, Baochau N. Nguyen
Schematic of intercalation and exfoliation of submicron hBN.
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meth

Electrode Informatics Accelerated Optimization for Catalyst Layer Key Parameters in Direct Methanol Fuel Cells

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR03026E, Paper
Lishou Ban, Danyang Huang, Yanyi Liu, Pengcheng Liu, Xihui Bian, Kaili Wang, Yifan Liu, Xijun Liu, Jia He
As the core component of direct methanol fuel cell, the catalyst layer plays the key role of material, proton and electron transport channels. However, due to the complexity of its...
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

A mitochondria-targeting heptamethine cyanine-chlorambucil formulated polymeric nanoparticle to potentiate native tumor chemotherapeutic efficacy

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00003J, Paper
Jing Liu, Jie Zhang, Yongteng Zhang, Wei Wei, Meixiao Zhan, Zhiren Zhang, Bing Liu, Xianglong Hu, Weiling He
Facile conjugation of chlorambucil with IR775 chloride can afford IR775-Cbl with mitochondria-targeting potency for tumor cells, exhibiting distinct “1 + 1 > 2” tumor inhibition.
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meth

A nanoparticle reinforced microporous methacrylated silk fibroin hydrogel to promote bone regeneration

Biomater. Sci., 2024, 12,2121-2135
DOI: 10.1039/D3BM01901B, Paper
Ruideng Wang, Xi He, Zhengyang Chen, Shilong Su, Jinwu Bai, Haifeng Liu, Fang Zhou
A photo-crosslinked nanocomposite hydrogel was prepared by incorporating an osteo-inductive inorganic nanoparticle for endogenous bone regeneration.
The content of this RSS Feed (c) The Royal Society of Chemistry




meth

Exploring therapy transport from implantable medical devices using experimentally informed computational methods

Biomater. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4BM00107A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lesley Trask, Niamh A. Ward, Ruth Tarpey, Rachel Beatty, Eimear Wallace, Joanne O'Dwyer, William Ronan, Garry P. Duffy, Eimear B. Dolan
Implantable medical devices that can facilitate therapy transport to localized sites are being developed for a number of diverse applications, including the treatment of diseases such as diabetes and cancer,...
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meth

Check out Anu Merton’s new collection at Amethyst, Chennai

Anu Merton introduces the city to its soon-to-be-launched capsule that parades a colourful spectrum of semi-precious stones on the sturdy foundation of time-tested jewellery-making techniques




meth

OpenAI and rivals seek new path to smarter AI as current methods hit limitations

To overcome these challenges, researchers are exploring “test-time compute,” a technique that enhances existing AI models during the so-called “inference” phase, or when the model is being used




meth

Hybrid method boosts microscopy resolution

Combining expansion microscopy and STED improves resolution 30-fold relative to the diffraction limit




meth

EPA to ban methylene chloride in paint strippers

Agency commits to action on CH2Cl2 in consumer and commercial products




meth

Enerkem gets green light for Spanish waste-to-methanol plant




meth

Methane ice dunes spotted on Pluto

Nitrogen sublimation and gentle breezes may form the hills




meth

To shrink electronics further, innovative chemical deposition methods may save the day

Researchers experiment with area-selective atomic layer deposition to precisely place layers of conducting and insulating materials within circuits