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Economic growth, sectoral structures, and environmental methane footprints [electronic journal].
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2020 International Conference on Probabilistic Methods Applied to Power Systems (PMAPS) [electronic journal].
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Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products
Nat. Prod. Rep., 2024, 41,1543-1578
DOI: 10.1039/D4NP00009A, Review Article
DOI: 10.1039/D4NP00009A, Review Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. Walker
This review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.
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This review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.
The content of this RSS Feed (c) The Royal Society of Chemistry
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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues
Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00343H, Research Article
DOI: 10.1039/D4QI00343H, Research Article
Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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The direct decomposition of nitromethane into nitrile compounds is a significant challenge due to the occurrence of severe side-reactions.
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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites
Inorg. Chem. Front., 2024, 11,2479-2488
DOI: 10.1039/D4QI00145A, Research Article
DOI: 10.1039/D4QI00145A, Research Article
Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
The content of this RSS Feed (c) The Royal Society of Chemistry
ECO of HMF to FDCA and ECR to BHMF with high yield have been studied on CuNi-based bimetallic catalysts. The presence of the Cu–O–Ni interfacial area was beneficial for promoting the catalytic performance in ECO.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Chelating Coordination Modulation Method for the Synthesis of Ti-MOF Single Crystals
Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00436A, Research Article
DOI: 10.1039/D4QI00436A, Research Article
Hui-Zi Li, Shangda Li, Fei Wang, Jian Zhang
Despite titanium-based metal-organic frameworks (Ti-MOFs) are promising as efficient photocatalysts, the high reactivity of titanium ions makes the synthesis and structure determination of new Ti-MOFs quite challenging. In this study,...
The content of this RSS Feed (c) The Royal Society of Chemistry
Despite titanium-based metal-organic frameworks (Ti-MOFs) are promising as efficient photocatalysts, the high reactivity of titanium ions makes the synthesis and structure determination of new Ti-MOFs quite challenging. In this study,...
The content of this RSS Feed (c) The Royal Society of Chemistry
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Manufacturing method of lab grown diamonds should be declared before export and import: CBIC
The new norms, which will help in quick processing and inspection of consignments, are to be effective from December 1
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Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction
Chem. Sci., 2024, 15,18161-18169
DOI: 10.1039/D4SC04318A, Edge Article
DOI: 10.1039/D4SC04318A, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan Li
A sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry
A sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article
DOI: 10.1039/D4SC06334A, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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Direct synthesis of N-perfluoro-tert-butyl secondary amines from N-trifluoromethyl secondary amines
Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06335J, Edge Article
DOI: 10.1039/D4SC06335J, Edge Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Leibing Wang, Zhongyu Feng, Zhen Luo, Zihao Guo, Jieping Wang, Wenbin Yi
The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
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The one-step direct synthesis of N-perfluoro-tert-butyl secondary amines utilizes TMSCF3 as the sole CF3 source and the starting material N-CF3 secondary amine itself as the hydrogen source. PFtB amines can be effectively employed in 19F MRI.
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The content of this RSS Feed (c) The Royal Society of Chemistry
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Effect of base methylation on binding and mobility of bacterial protein Hfq on double-stranded DNA
Lab Chip, 2024, 24,5137-5144
DOI: 10.1039/D4LC00628C, Paper
DOI: 10.1039/D4LC00628C, Paper
Jijo Easo George, Rajib Basak, Indresh Yadav, Chuan Jie Tan, Jeroen A. van Kan, Frank Wien, Véronique Arluison, Johan R. C. van der Maarel
Using nanofluidics to probe protein mobility on DNA reveals how DNA base methylation impacts protein–DNA interactions.
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Using nanofluidics to probe protein mobility on DNA reveals how DNA base methylation impacts protein–DNA interactions.
The content of this RSS Feed (c) The Royal Society of Chemistry
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HC tells authorities to prevent anti-social activities by other methods before resorting to KAAPA
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We have to go all the way back to Karpov and Kasparov on the top two boards to find something like India’s dominance: Peter Svidler
In this chat, Russian GM Svidler talks about India’s historic Olympiad, his experience of coaching Praggnanandhaa, his love affair with Test cricket and his assessment of the Global Chess League, not just as a chess player but also as a cricket fan who follows the IPL
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A novel in situ method for linear alkylbenzene sulfonate quantification in environmental samples using a digital image-based method
Anal. Methods, 2024, 16,2009-2018
DOI: 10.1039/D4AY00073K, Paper
DOI: 10.1039/D4AY00073K, Paper
Helayne S. de Sousa, Roxanny Arruda-Santos, Eliete Zanardi-Lamardo, Willian T. Suarez, Josiane L. de Oliveira, Renata A. Farias, Vagner Bezerra dos Santos
Surfactants spilled in water resulting in the contamination of aquatic environments being in situ monitored using a smartphone.
The content of this RSS Feed (c) The Royal Society of Chemistry
Surfactants spilled in water resulting in the contamination of aquatic environments being in situ monitored using a smartphone.
The content of this RSS Feed (c) The Royal Society of Chemistry
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A screening method for the quantitative determination of selective androgen receptor modulators (SARMs) in capsules by high resolution 19F- and 1H-NMR spectroscopy
Anal. Methods, 2024, 16,2135-2146
DOI: 10.1039/D4AY00188E, Paper
DOI: 10.1039/D4AY00188E, Paper
Alessandro Maccelli, Anna Borioni, Federica Aureli, Maria Cristina Gaudiano, Livia Manna, Mariangela Raimondo
A new method for rapid determination of selective androgenic receptor modulators (SARMs) andarine, cardarine, ligandrol, ostarine and S-23 in capsules by 1H- and 19F-high resolution NMR spectroscopy was described and validated.
The content of this RSS Feed (c) The Royal Society of Chemistry
A new method for rapid determination of selective androgenic receptor modulators (SARMs) andarine, cardarine, ligandrol, ostarine and S-23 in capsules by 1H- and 19F-high resolution NMR spectroscopy was described and validated.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Subtle adjustment of the cyclic potential on electro-activated glassy carbon electrodes for sensitive sensing of methyl parathion
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00079J, Paper
DOI: 10.1039/D4AY00079J, Paper
Yunyin Yang, Sian Chen, Changqiu Zhang, Yanqing Li, Xinrong Zong, Yitao Lv, Min Zhang
Upon experiencing a negligible change of 0.5 V which only takes 5 more seconds, the signal value of an e-GCE was efficiently enhanced from 2-fold to 30-fold compared with a bare GCE.
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Upon experiencing a negligible change of 0.5 V which only takes 5 more seconds, the signal value of an e-GCE was efficiently enhanced from 2-fold to 30-fold compared with a bare GCE.
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An on-line SPE-LC-MS/MS method for quantification of nucleobases and nucleosides present in biological fluids
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00100A, Paper
DOI: 10.1039/D4AY00100A, Paper
Yi-Ming Liu, Shuguan Wang, Amani Dickenson, Jinghe Mao, Xiaolin Bai, Xun Liao
A facile on-line SPE-LC-MS/MS method for quantification of nucleobases and nucleosides in urine and saliva.
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A facile on-line SPE-LC-MS/MS method for quantification of nucleobases and nucleosides in urine and saliva.
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Rapid and green quantification of phloridzin and trilobatin in Lithocarpus litseifolius (Hance) Chun (sweet tea) using an online pressurized liquid extraction high-performance liquid chromatography at equal absorption wavelength method
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00170B, Paper
DOI: 10.1039/D4AY00170B, Paper
Zhengming Qian, Qinggui Lei, Dan Tang, Guoying Tan, Qi Huang, Fucai Zhou, Wenhao Wang
Sweet tea is a functional herbal tea with anti-inflammatory, anti-diabetic, and other effects, in which phloridzin and trilobatin are two functional compounds.
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Sweet tea is a functional herbal tea with anti-inflammatory, anti-diabetic, and other effects, in which phloridzin and trilobatin are two functional compounds.
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Establishing a new methodology for determining the water absorbability of cellulose-derived materials via a vapor-monitoring headspace strategy
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D3AY02209A, Communication
DOI: 10.1039/D3AY02209A, Communication
Yi-Xian Gong, Wei-Qi Xie
In this research, for the first time, we introduce a vapor-monitoring headspace strategy to establish a new methodology for determining the water absorbability of cellulose-derived materials.
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In this research, for the first time, we introduce a vapor-monitoring headspace strategy to establish a new methodology for determining the water absorbability of cellulose-derived materials.
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A comprehensive HRMS methodology using LC-(ESI)-/GC-(APCI)-QTOF MS complementary platforms for wide-scope target screening of >750 pesticides in olive oil
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00181H, Paper
DOI: 10.1039/D4AY00181H, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Sofia K. Drakopoulou, Stefanos E. Kokolakis, Apostolos L. Karagiannidis, Marilena E. Dasenaki, Niki C. Maragou, Nikolaos S. Thomaidis
This study presents a robust and validated HRMS method for the determination of 771 pesticides in olive oil. LC-ESI/GC-APCI-QTOF MS was employed for the analysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry
This study presents a robust and validated HRMS method for the determination of 771 pesticides in olive oil. LC-ESI/GC-APCI-QTOF MS was employed for the analysis.
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The content of this RSS Feed (c) The Royal Society of Chemistry
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Field method for preservation of total mercury in waters, including those associated with artisanal scale gold mining
Anal. Methods, 2024, Advance Article
DOI: 10.1039/D3AY02216A, Paper
DOI: 10.1039/D3AY02216A, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David C. P. King, Michael J. Watts, Elliott M. Hamilton, Robert J. G. Mortimer, Mike Coffey, Odipo Osano, Maureene Auma Ondayo, Marcello Di Bonito
A method was developed for sampling and preserving total Hg from water samples, recovering >75% Hg over 4 weeks of storage. The method was assessed using water samples at artisanal gold mining sites in Kenya.
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The content of this RSS Feed (c) The Royal Society of Chemistry
A method was developed for sampling and preserving total Hg from water samples, recovering >75% Hg over 4 weeks of storage. The method was assessed using water samples at artisanal gold mining sites in Kenya.
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A complementary method with PFBBr-derivatization based on a GC-EI-MS platform for the simultaneous quantitation of short-, medium- and long-chain fatty acids in murine plasma and feces samples
Anal. Methods, 2024, 16,2330-2339
DOI: 10.1039/D3AY02271D, Paper
DOI: 10.1039/D3AY02271D, Paper
Hong-Xu Zhou, Qing Jiang, Xin He, Xian Fu, Jun-Yan Liu
Fatty acids (FAs) are essential molecules in all organisms and are involved in various physiological and pathophysiological processes.
The content of this RSS Feed (c) The Royal Society of Chemistry
Fatty acids (FAs) are essential molecules in all organisms and are involved in various physiological and pathophysiological processes.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Discovery of highly potent SARS-CoV-2 nsp14 methyltransferase inhibitors based on adenosine 5'-carboxamides
RSC Med. Chem., 2024, 15,3469-3476
DOI: 10.1039/D4MD00422A, Research Article
DOI: 10.1039/D4MD00422A, Research Article
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hugo Kocek, Dominika Chalupská, Milan Dejmek, Alexandra Dvořáková, Michala Zgarbová, Michal Šála, Karel Chalupský, Petra Krafčíková, Tomáš Otava, Matúš Drexler, Eliška Procházková, Blanka Klepetářová, Milan Štefek, Ján Kozic, Helena Mertlíková-Kaiserová, Evzen Boura, Jan Weber, Radim Nencka
SARS-CoV-2 nsp14 methyltransferase inhibitors based on adenosine 5'-carboxamides.
The content of this RSS Feed (c) The Royal Society of Chemistry
SARS-CoV-2 nsp14 methyltransferase inhibitors based on adenosine 5'-carboxamides.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Continuous flow synthesis of N,N-dimethyltryptamine (DMT) analogues with therapeutic potential
RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00562G, Research Article
DOI: 10.1039/D4MD00562G, Research Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Andreas Simoens, Andreas Dejaegere, Marthe Vandevelde, Christian V. Stevens
Flow chemistry allows for the rapid and clean synthesis of therapeutically relevant tryptamines in good yields, including the large scale drug rizatriptan.
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Flow chemistry allows for the rapid and clean synthesis of therapeutically relevant tryptamines in good yields, including the large scale drug rizatriptan.
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592: Web Component Therapy, SEO Therapy, and Learning Something New like Swift
Talking web components, progressive enhancement, style-able components, having to pay before you get to see a demo, being annoyed at the business of SEO, and subscriptions vs ads.
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Innovations in traditional methods revolutionising farming in Rajasthan’s parched Shekhawati
The decline in the groundwater level is a major issue for agriculturists in all four districts of Shekhawati — Sikar, Jhunjhunu, Churu, and Neem Ka Thana
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Carboxymethyl cellulose-stabilized calcium phosphate particles for injectable hydrogel-based bone tissue engineering
Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00670D, Paper
DOI: 10.1039/D4SM00670D, Paper
Piyaporn Srisura, Yuwaporn Pinyakit, Umphan Ngoensawat, Pongsakorn Yuntasiri, Khoiria Nur Atika Putri, Theerapat Chanamuangkon, Waranyoo Phoolcharoen, Varol Intasanta, Voravee P. Hoven
Carboxymethyl cellulose-stabilized calcium phosphate particles well-dispersed in aqueous solution can be integrated into an injectable hydrogel made of methacrylated hyaluronic acid which is a promising material for bone regeneration applications.
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The content of this RSS Feed (c) The Royal Society of Chemistry
Carboxymethyl cellulose-stabilized calcium phosphate particles well-dispersed in aqueous solution can be integrated into an injectable hydrogel made of methacrylated hyaluronic acid which is a promising material for bone regeneration applications.
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Development of a coarse-grained molecular dynamics model for poly(dimethyl-co-diphenyl)siloxane
Soft Matter, 2024, 20,8480-8492
DOI: 10.1039/D4SM00875H, Paper
DOI: 10.1039/D4SM00875H, Paper
Weikang Xian, Amitesh Maiti, Andrew P. Saab, Ying Li
Polydimethylsiloxane and its copolymer systems have a wide range of application. We systematically develop a coarse-grained MD model for PDMS-co-PDPS system. The model preserves the structural and dynamic properties of the material quantitatively.
The content of this RSS Feed (c) The Royal Society of Chemistry
Polydimethylsiloxane and its copolymer systems have a wide range of application. We systematically develop a coarse-grained MD model for PDMS-co-PDPS system. The model preserves the structural and dynamic properties of the material quantitatively.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Bending of polymer films: a method for obtaining a compressive modulus of thin films
Soft Matter, 2024, 20,8589-8600
DOI: 10.1039/D4SM00084F, Paper
DOI: 10.1039/D4SM00084F, Paper
Akihiro Ohara, Ko Okumura
We constructed a theory and method for measuring the compressive modulus by combining tensile and bending tests. Elastic asymmetry was confirmed in an industrial PET film.
The content of this RSS Feed (c) The Royal Society of Chemistry
We constructed a theory and method for measuring the compressive modulus by combining tensile and bending tests. Elastic asymmetry was confirmed in an industrial PET film.
The content of this RSS Feed (c) The Royal Society of Chemistry
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Something old, something luxe
Want to own a pair of Jimmy Choos but the price tag deters you? Sites selling pre-loved, pre-owned luxury items might be your answer, writes PRIYADARSHINI PAITANDY
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Zeroing in on methane diplomacy, at COP29
The Baku meet is an opportunity for India to fast-track its efforts in reducing methane emissions
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Frobenius splitting methods in geometry and representation theory [electronic resource] / Michel Brion, Shrawan Kumar
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An introduction to the circle method [electronic resource] / M. Ram Murty, Kaneenika Sinha.
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Something for everyone
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Something old, something new
It is the festive season and you have all the excuses in the world to shop. Srishti brings to Coimbatore some of the best craftsmanship from the country
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Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01496K, Research Article
DOI: 10.1039/D4QO01496K, Research Article
Dawei Gong, Caiyu Gao, Qixuan Li, Yufei Li, Lina Zhao, Degong Kong
Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
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Trichloromethyl compounds are essential constituents in synthetic and medicinal chemistry.
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A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis
Org. Chem. Front., 2024, 11,6450-6458
DOI: 10.1039/D4QO01528B, Research Article
DOI: 10.1039/D4QO01528B, Research Article
Xiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi Han
A silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.
The content of this RSS Feed (c) The Royal Society of Chemistry
A silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.
The content of this RSS Feed (c) The Royal Society of Chemistry
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LiTMP-LiBr complex-induced lateral lithiation and cross ester condensation: direct access to isocoumarins from 2-methoxy o-toluate esters
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01678E, Research Article
DOI: 10.1039/D4QO01678E, Research Article
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Mintu Rehman, Sajib Daimary, Rasajna Madhusudhana, Rajendar Goreti
LiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.
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LiTMP-LiBr complex promotes cross-ester coupling of 2-methoxy o-toluate esters to directly yield isocoumarin is demonstrated. Method applied to many natural product precursors including synthesis of (+)- and (−)-lunatinins.
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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01388C, Research Article
DOI: 10.1039/D4QO01388C, Research Article
Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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A two-step Kinugasa/Conia-ene-type sequential reaction is developed. The process provided a simple and efficient access to chiral 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones.
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Catalyst-free C–H methylation of heteroarenes enabled by electron donor–acceptor complex photoactivation
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01309C, Research Article
DOI: 10.1039/D4QO01309C, Research Article
Jiayang Wang, Baoer Shao, Haixia Ge, Huiyu Xue, Xiangyuan Ding, Yuqi Li, Peiyao Sheng
A visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.
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A visible-light-induced direct C–H methylation of heterocycles (including quinoxalinones, pyrazinones, quinolinones and coumarins) with methylamines via EDA complex photoactivation was developed.
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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones
Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01771D, Research Article
DOI: 10.1039/D4QO01771D, Research Article
Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
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An efficient asymmetric cascade allylation/lactonization of methyl salicylates is achieved. The utilization of chiral-bridged biphenyl phosphoramidite ligand resulted in good results for the construction of a wide range of chiral benzodioxepinones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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meth
PIFA-Mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes
Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01589D, Research Article
DOI: 10.1039/D4QO01589D, Research Article
Xinya Liu, Olivier Provot, Christine Tran, Jean-Francois Soule, Abdallah Hamze
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
The content of this RSS Feed (c) The Royal Society of Chemistry
The well-decorated arylated benzo[b]thiophene scaffold is a pivotal structural motif with diverse applications in medicinal chemistry. This paper outlines a de novo synthesis of C3-arylated benzo[b]thiophenes, showcasing its flexibility and...
The content of this RSS Feed (c) The Royal Society of Chemistry
meth
Design, synthesis, biological evaluation, and in silico studies of novel N-substituted-2-(3,4,5-trimethoxyphenyl)-1H-benzo[d]imidazole-6-carboxamides as promising anticancer agents
RSC Adv., 2024, 14,35323-35335
DOI: 10.1039/D4RA04492D, Paper
DOI: 10.1039/D4RA04492D, Paper
Open Access
This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Navid Dastyafteh, Manica Negahdaripour, Mohammad Hosein Sayahi, Mina Emami, Younes Ghasemi, Elham Safaei, Homa Azizian, Zahra Pakrouh Jahromi, Mehdi Asadi, Mohammad Reza Mohajeri-Tehrani, Fateme Zare, Minoo Shahidi, Zahra Pooraskari, Sayed Mahmoud Sajjadi-Jazi, Bagher Larijani, Mohammad Mahdavi, Sara Ranjbar
Synthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.
The content of this RSS Feed (c) The Royal Society of Chemistry
Synthesis and cytotoxicity evaluation of novel benzimidazoles were explained. The most potent derivative was subjected to cell cycle, apoptosis, and in silico investigations. Compound 5o proved to be a promising anticancer agent.
The content of this RSS Feed (c) The Royal Society of Chemistry
meth
Surface science studies of the coverage dependent adsorption of methyl acetate and methyl propanoate on graphite
RSC Adv., 2024, 14,35373-35385
DOI: 10.1039/D4RA04466E, Paper
DOI: 10.1039/D4RA04466E, Paper
Open Access
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jack E. Fulker, Wendy A. Brown
The adsorption of methyl acetate and methyl propanoate has been studied on a graphite surface at 28 K. TPD data show that the desorption energy of both molecules is highly coverage dependent with repulsive interactions being seen at low coverages.
The content of this RSS Feed (c) The Royal Society of Chemistry
The adsorption of methyl acetate and methyl propanoate has been studied on a graphite surface at 28 K. TPD data show that the desorption energy of both molecules is highly coverage dependent with repulsive interactions being seen at low coverages.
The content of this RSS Feed (c) The Royal Society of Chemistry