syn

Chemoenzymatic total synthesis of rotigotine via IRED-catalyzed reductive amination

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00072B, Communication
Dongyu Tang, Yaqing Ma, Jinping Bao, Shushan Gao, Shuli Man, Chengsen Cui
An engineered imine reductase (IRED) was developed specifically for 2-tetralone substrate, and utilized in the total synthesis of rotigotine.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

The synthesis of alk-2-ynl Weinreb amides via Pd/Cu-catalysed oxidative carbonylation of terminal alkynes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00290C, Paper
Bharati Mourya, Sandip T. Gadge, Bhalchandra M. Bhanage
Synthesis of alk-2-ynl-Weinreb amides via Pd-catalyzed oxidative carbonylation of terminal alkynes and N,O-dimethylhydroxylamine hydrochloride at room temperature under low CO/O2 pressure is reported for the first time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00383G, Paper
Debasish Bera, Rajib Sarkar, Tiyasa Dhar, Pinaki Saha, Prasanta Ghosh, Chhanda Mukhopadhyay
Dimethyl sulfoxide (DMSO)-promoted catalyst-free oxidative C–N coupling and C–O coupling under oxidant-free conditions are outlined.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of Asp-based lactam cyclic peptides using an amide-bonded diaminodiacid to prevent aspartimide formation

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00472H, Communication
Wen-Jie Li, Jun-You Chen, Hui-Xia Zhu, Yi-Ming Li, Yang Xu
A diaminodiacid (DADA) containing an amide bond can be used in Fmoc solid-phase peptide synthesis (SPPS) of an Asp-based lactam cyclic peptide with no aspartimide formation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of alkenylphosphine oxides via Tf2O promoted addition–elimination of ketones and secondary phosphine oxides

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00318G, Communication
Jiangkai Ma, Lianjie Wang, Anjiang Qiao, Zhongxian Li, Fengqian Zhao, Junliang Wu
An efficient method for the synthesis of alkenylphosphine oxides via the addition-elimination of SPOs to ketones has been developed. The reaction exhibits good yields and compatibility. Several conversions have also proven the value of this method.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Asymmetric total synthesis of humulane sesquiterpenoids alashanoids B, C, E, and F and 2,9-humuladien-6-ol-8-one

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00393D, Paper
Rasmita Barik, Samik Nanda
Naturally occurring sesquiterpenes having humulane frameworks are structurally intriguing and possess significant biological profiles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Total synthesis of diplofuranone A and diapolic acid A

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00433G, Communication
Dattatraya H. Dethe, Vimlesh Kumar, Nagabhushana C. Beeralingappa
The first and concise syntheses of the anticancer agent diplofuranone A and the fatty acid-derived metabolite diapolic acid A have been demonstrated using easily accessible and commercially available starting materials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Stereoselective Synthesis of gem-Dihalopiperidines via Halo-Aza-Prins Cyclization Reaction: Access to Piperidin-4-ones and Pyridines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00338A, Paper
Anil Kumar Saikia, Surjya Kumar Bora, Subhamoy Biswas, Bipin Kumar Behera
An efficient methodology for the synthesis of 4,4-dihalopiperidine derivatives has been developed from N-(3-halobut-3-en-1-yl)-4-methylbenzenesulfonamide and aldehyde catalyzed by In(OTf)3 in excellent yields. The reaction involves an initial formation of six...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Covalently linked thieno[2,3-b]thiophene-fullerene dimers: synthesis and physical characterization

Org. Biomol. Chem., 2024, 22,2978-2984
DOI: 10.1039/D4OB00027G, Paper
Abdulrahman M. Alazemi, Mohammad H. BinSabt, Hamad M. Al-Matar, Alan L. Balch, Mona A. Shalaby
Linked thieno[2,3-b]thiophene-fullerene Dimers.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Asymmetric synthesis of the fully functionalized six-membered A-ring of siphonol A

Org. Biomol. Chem., 2024, 22,2958-2962
DOI: 10.1039/D4OB00104D, Communication
Ying Sun, Shaomin Fu, Bo Liu
The asymmetric synthesis of the fully functionalized six-membered A-ring of siphonol A is presented.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Vinylogous and stereoselective domino synthesis of pyrano[2,3-c]pyrroles from alkylidene meldrum's acids

Org. Biomol. Chem., 2024, 22,2948-2952
DOI: 10.1039/D4OB00233D, Communication
Mariia Savchuk, Giang Vo-Thanh, Sylvain Oudeyer, Hélène Beucher, Jean-François Brière
An expeditious diatereoselective synthesis of pyrano[2,3-c]pyrroles thanks to a domino Vinylogous aza-Michael-Aldol-Cyclocondensation (aza-VMAC) reaction to alkylidene Meldrum's acid derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

2-Azabicyclo[3.2.1]octane scaffold: synthesis and applications

Org. Biomol. Chem., 2024, 22,2902-2915
DOI: 10.1039/D4OB00199K, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mariana Crespo Monteiro, João Rafael Vale, Filipa Siopa
This review focuses on the preparation and applications in total synthesis of 2-azabicyclo[3.2.1]octane structures, a class of natural and synthetic compounds with a range of biological activities.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Not exclusively the activity, but the sweet spot: a dehydrogenase point mutation synergistically boosts activity, substrate tolerance, thermal stability and yield

Org. Biomol. Chem., 2024, 22,3009-3018
DOI: 10.1039/D4OB00211C, Paper
Yu-Ke Cen, Lin Zhang, Yue Jiang, Xiang-Fu Meng, Yuan Li, Chao Xiang, Ya-Ping Xue, Yu-Guo Zheng
A single-point mutation of 7α-HSDH achieved the highest activity and synergistically improved substrate tolerance, thermal stability, cofactor affinity, and conversion rate.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Selective synthesis of an elusive C-functional bis-cyclam and study of its inhibition of the CXCR4 chemokine receptor

Org. Biomol. Chem., 2024, 22,3059-3067
DOI: 10.1039/D3OB02050A, Paper
Marie M. Le Roy, Sandra Claes, Nathalie Saffon-Merceron, Dominique Schols, Thibault Troadec, Raphaël Tripier
A rare example of C,C'-linked bis-cyclam has been synthesized with controlled manner in mild conditions thanks to the “bis-aminal” tool, and its good CXCR4-recognition properties could be demonstated in vitro.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Expanding the scope of the successive ring expansion strategy for macrocycle and medium-sized ring synthesis: unreactive and reactive lactams

Org. Biomol. Chem., 2024, 22,2985-2991
DOI: 10.1039/D4OB00285G, Paper
Open Access
Zhongzhen Yang, Marion Arnoux, Damien Hazelard, Owen R. Hughes, Joe Nabarro, Adrian C. Whitwood, Martin A. Fascione, Christopher D. Spicer, Philippe Compain, William P. Unsworth
New Successive Ring Expansion (SuRE) protocols are described for use on unreactive lactams, as well as iminosugar derived lactams.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

A phosphamide nucleotide analog: a substrate for polymerase synthesis of DNA

Org. Biomol. Chem., 2024, 22,2963-2967
DOI: 10.1039/D4OB00089G, Communication
Jiong Meng, Qiaqia Guo, Xiaona Zhai, Song Yang, Shuai Wang, Pengcheng Wang, Debin Ji
A phosphamide nucleotide analog (dNTPγNH2) exhibited higher stability than dNTPs and can be recognized by DNA polymerases in PCR.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of alkynyl sulfides via base-promoted nucleophilic ring-opening of α-bromostyrene sulfonium salt

Org. Biomol. Chem., 2024, 22,2953-2957
DOI: 10.1039/D4OB00203B, Communication
Junqi Zhou, Ziyu Wang, Hanmiao Xu, Mengke Su, Jian Wen
An effective method for synthesizing various alkynyl sulfides has been developed using tetramethylene sulfoxide as a sulfur source through base-promoted nucleophilic ring-opening reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Stereoselective synthesis of (R)- and (S)-1,2-diazetidine-3-carboxylic acid derivatives for peptidomimetics

Org. Biomol. Chem., 2024, 22,2974-2977
DOI: 10.1039/D4OB00278D, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Matthew Nutter, Henry Stone, Michael Shipman, Stefan Roesner
Stereoselective synthesis of both enantiomers of orthogonally protected 1,2-diazetidine-3-carboxylic acid (aAze) from homochiral glycidol and its application in peptidomimetics.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

3-Halo-5,6-dihydro-4H-1,2-oxazine N-oxides as synthetic equivalents of unsaturated nitrile oxides in the [3 + 2]-cycloaddition with arynes: synthesis of substituted 3-vinyl-1,2-benzisoxazoles

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00391H, Communication
Alexander A. Lukoyanov, Svetlana A. Aksenova, Andrey A. Tabolin, Alexey Yu. Sukhorukov
3-Halo-1,2-oxazine N-oxide derivatives act as surrogates of vinyl nitrile oxides in tandem [3 + 2]-cycloaddition/[3 + 2]-cyclofragmentation with arynes leading to benzisoxazoles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Electro-oxidative three-component cascade coupling of isocyanides with elemental sulfur and amines for the synthesis of 2-aminobenzothiazoles

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00432A, Paper
Peng-Fei Huang, Jia-Le Fu, Ying Peng, Jian-Hong Fan, Long-Jin Zhong, Kewen Tang, Yu Liu
2-Aminobenzothiazoles are commonly encountered in various functional compounds. Herein, we disclose an electro-oxidative three-component reaction for the effective synthesis of 2-aminobenzothiazoles under mild conditions, utilizing non-toxic and abundant elemental sulfur...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Design, synthesis, biological evaluation and molecular docking studies of quinoline-anthranilic acid hybrids as potent anti-inflammatory drugs

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00040D, Paper
Sidra Siddique, Khalid Hussain, Naureen Shehzadi, Muhammad Arshad, Muhammad Nadeem Arshad, Sadaf Iftikhar, Farhat Saghir, Ayisha Shaukat, Muhammad Sarfraz, Nisar Ahmed
Despite the high global prevalence, rheumatoid arthritis lacks a satisfactory treatment.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Isothiocyanates: Happy-Go-Lucky Reagents in Organic Synthesis

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00281D, Review Article
Bubul Das, Anjali Dahiya, Bhisma K Patel
: Owing to their unique structural features, isothiocyanates (ITCs) are a class of highly useful and inimitable reagents as the N=C=S group serves both as electrophile and nucleophile in organic...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of Deuteriodifluoromethylthiolated Isocoumarins-1- imines and Isocoumarins Enabled by Multi-Component Reagents System (MCRS)

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00328D, Communication
Xuemin Li, Haofeng Shi, Jiaxin He, Jialiang Wu, Fengxia Sun, Yunfei Du
The combining use of BnSCF2D, mCPBA and Tf2O serves as an efficient multi-component reagents system (MCRS) for the synthesis of deuteriodifluoromethylthiolated isocoumarins-1-imines/isocoumarins via intramolecular cyclization/ deuteriodifluoromethylthiolation of 2-alkynylbenzamide/2-alkynylbenzoates. The approach...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Natural products from human microbiome: an emergent frontier in organic synthesis and drug discovery

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00236A, Review Article
Goverdhan Mehta, Saumitra Sengupta, Srihari Pabbaraja
Often referred to as “second genome”, human microbiome is at the epicenter of a complex inter-habitat biochemical network, such as the “gut-brain axis”, which have emerged as significant determinant of...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

An FeCl3-catalyzed three-component reaction for the synthesis of β-(1,2,3-triazolyl)-ketones using DMF as a one-carbon source

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00207E, Communication
Ruilin Fang, Lei Zheng, Xuyang Chen, Can Wang, Yunfeng Chen
FeCl3-catalyzed oxidative condensation of NH-1,2,3-triazoles and aryl methyl ketones and DMF has been reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Design, synthesis, and biological application of A–D–A-type boranil fluorescent dyes

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00297K, Paper
Wei Luo, Yiling Li, Liang Wang, Yanhua Qin, Qiao Cheng, Guochang Hu, Chaoyi Yao, Xiangzhi Song
Acceptor–donor–acceptor boranil fluorescent dyes, CSU-BF-R (R = H, CH3, and OCH3), were developed with strong red fluorescence and large Stokes shifts. CSU-BF-OCH3 could selectively sense intracellular hypochlorous acid in living cells and zebrafish.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Facile synthesis of tetrahydroquinoline containing dithiocarbamate derivatives via one-pot sequential multicomponent reaction

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00490F, Communication
SIDDHARTHA KUMAR SENAPATI, Anit Pal, Animesh Das
An efficient sequential multi-component method for the synthesis of tertrahydroquinoline containing dithiocarbamate has been developed. This reaction involved a boronic acid-catalyzed reduction of quinoline to tertrahydroquinoline, followed by nucleophilic addition...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Regioselective synthesis of 4-arylamino-1,2-naphthoquinones in eutectogel as a confined reaction medium using LED light

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00140K, Communication
R. Vara Prasad, Yogendra Kumar, R. Arun Kumar, Tohira Banoo, Subbiah Nagarajan
The use of a simple carbohydrate-derived eutectogel facilitating a LED-light-induced regioselective synthesis of 4-arylamino-1,2-naphthoquinones in good yields is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Efficient synthesis of SCF3-containing 3-alkenylquinoxalinones via three-component radical cascade reaction

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00363B, Paper
Si-Yu Wang, Chu Liu, Wei Yang, Zhong-Ying Tian, Lin Yuan, Long-Yong Xie
A three-component cascade reaction of quinoxalinones, alkynes and AgSCF3 toward complete E-selective SCF3-containing 3-alkenylquinoxalinones was developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

K2CO3-Mediated (3+3-1) Annulation of 1,3-Acetonedicarboxylates with 2-Fluoro-1-nitroarenes: Synthesis of Indoles

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00488D, Paper
Meng-Yang Chang, Chin-Huey Ho, Hsing-Yin Chen
The K2CO3-mediated one-pot reaction of 1,3-acetonedicarboxylates with 2 equiv. of substituted 2-fluoro-1-nitrobenzenes has been developed to synthesize various 2,3-dicarboxylate indoles via a tandem (3 + 3 − 1) annulation pathway....
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

LGBTQ+ educators in Catholic schools: embracing synodality, inclusion, and justice / Ish Ruiz.

Lanham, MD : Rowman and Littlefield, 2024.




syn

(WO + ICG)@PLGA@lipid/plasmid DNA nanocomplexes as core–shell vectors for synergistic genetic/photothermal therapy

Mater. Chem. Front., 2024, 8,3747-3757
DOI: 10.1039/D4QM00330F, Research Article
Yang Bai, Guoqing Feng, Qingbin Yang, Tingting Hua, Bowen Li, Hao-Lin Guo, Yuan Liu, Qing Yuan, Niansong Qian, Bin Zheng
(WO + ICG)@PLGA@PL could not only achieve a synergistic therapy effect of gene delivery and photothermal effect but also effectively inhibit tumor growth.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of chiral graphene structures and their comprehensive applications: a critical review

Nanoscale Horiz., 2024, 9,1855-1895
DOI: 10.1039/D4NH00021H, Review Article
Animesh Sinha, Hongyun So
Chiral graphene, a “superlattice structure,” effectively engages with target substances. Its superconductivity, tunable electronic structure, and topological states could significantly contribute to advanced materials science technologies.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Emulation of neuron and synaptic functions in spin–orbit torque domain wall devices

Nanoscale Horiz., 2024, 9,1962-1977
DOI: 10.1039/D3NH00423F, Communication
Durgesh Kumar, Ramu Maddu, Hong Jing Chung, Hasibur Rahaman, Tianli Jin, Sabpreet Bhatti, Sze Ter Lim, Rachid Sbiaa, S. N. Piramanayagam
Neuromorphic computing based on spin–orbit torque driven domain wall (DW) devices is promising for energy-efficient computation. This study demonstrates energy efficient operations of DW neurons and synapses by novel reading and writing strategies.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

A universal synthetic method for preparing nanoassemblies of quantum dots and organic molecules

Nanoscale Horiz., 2024, 9,1853-1854
DOI: 10.1039/D4NH90063D, Editorial
Chao Wang
This article highlights the recent work of Biju, Takano et al. (Nanoscale Horiz., 2024, 9, 1128–1136, https://doi.org/10.1039/D4NH00134F) on using a unique bio-catalytic nanoparticle shaping method for preparing mesoscopic particles.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Polymer-confined synthesis of gram-scale high-entropy perovskite fluoride nanocubes for improved electrocatalytic reduction of nitrate to ammonia

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00341A, Communication
Open Access
Guohao Xue, Tianlu Wang, Hele Guo, Nan Zhang, Claire J. Carmalt, Johan Hofkens, Feili Lai, Tianxi Liu
A high-entropy perovskite fluoride with a well-defined nanocubic structure was successfully prepared via a polyvinylpyrrolidone-confined nucleation strategy, demonstrating excellent electrocatalytic activity for nitrate reduction.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Revealing a synergistic orbital coupling adsorption mechanism of the oxygen reduction reaction in dual-atom catalysts

J. Mater. Chem. A, 2024, 12,30676-30684
DOI: 10.1039/D4TA05099A, Paper
Yangfan Liu, Yejun Li, Xinghan Liu, Jinming Li, Gufei Zhang, Jun Gong, Yanbin Jiang, Zhou Li
A synergistic adsorption mechanism of the oxygen evolution reaction for the dual atom catalysts (DACs) was proposed, which dominates the adsorption strength of intermediate species, potential determining step, and catalytic activity of DACs.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

A soft molecular single-source precursor approach to synthesize a nanostructured Co9S8 (pre)catalyst for efficient water oxidation and biomass valorization

J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co9S8 (pre)catalyst derived from a novel {CoIIS4} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co9S8 reconstructs completely into a CoOOH active phase via S-leaching.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synthesis of a Cu@ZnO1−x/Al2O3 catalyst with high-density ZnO1−x–Cu interfacial sites for enhanced CO2 hydrogenation to methanol

J. Mater. Chem. A, 2024, 12,30692-30706
DOI: 10.1039/D4TA05801A, Paper
Yunshuo Wu, Haiqiang Wang, Zhongbiao Wu
The development of catalysts with high-density interfacial sites is crucial for enhancing catalytic performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Lewis acid sites and flexible active centers synergistically boost efficient electrochemical ammonia synthesis

J. Mater. Chem. A, 2024, 12,30476-30485
DOI: 10.1039/D4TA04884A, Paper
Li-Bo Chen, Tong-Hui Wang, Xing-You Lang, Qing Jiang
The Lewis acid sites enhance N2 adsorption and activation, while the flexible active center facilitates hydrogenation and NH4+ formation, regenerating the catalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Electrochemical synthesis of wormcast-like Pd-based polycrystalline high entropy aggregates for methanol water co-electrocatalysis

J. Mater. Chem. A, 2024, 12,30757-30767
DOI: 10.1039/D4TA06304J, Paper
Yaxing Liu, Wenhao Ding, Jiaxin Liu, Guizhe Zhao, Weiyin Li, Yaqing Liu
A wormcast-like nanostructure of PdFeCoNiCu-pHENs with enriched grain boundary defects was synthesized via electrodeposition. This work opens new possibilities for designing advanced nanomaterials aimed at efficient electrochemical energy conversion.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Rational engineering and synthesis of pyrene and thiazolo[5,4-d]thiazole-functionalized conjugated microporous polymers for efficient supercapacitor energy storage

J. Mater. Chem. A, 2024, 12,30508-30521
DOI: 10.1039/D4TA05908E, Paper
Abdul Basit, Yang-Chin Kao, Yasser A. El-Ossaily, Shiao-Wei Kuo, Mohamed Gamal Mohamed
The Py-Th-TzTz CMP was synthesized through a Schiff base reaction and exhibited a decomposition temperature (Td10) of 352 °C. In a three-electrode system, it demonstrated a specific capacitance of 652 F g−1.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Tailoring the electrocatalytic properties of novel microwave synthesized CuNd(2−x)GdxO4 nanoparticles for efficient total water splitting in alkaline media

J. Mater. Chem. A, 2024, 12,30850-30861
DOI: 10.1039/D4TA05919K, Paper
Anto Priyanka E, Sreenivasan Nagappan, J. Judith Vijaya, Angappan Sankaramahalingam, Subrata Kundu
CuNd(2−x)GdxO4 nanoparticles synthesized via microwave method as efficient OER and HER catalysts require low overpotentials exhibiting remarkable stability. Gd doping enhances charge transfer leading to optimized electrocatalysis.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Interfacial charge transfer modulation in laser-synthesized catalysts for efficient oxygen evolution

J. Mater. Chem. A, 2024, 12,30269-30278
DOI: 10.1039/D4TA06794K, Paper
Dong Hyeon Lee, Rahul Kerkar, Deepak Arumugam, Jayaraman Theerthagiri, Shankar Ramasamy, Soorathep Kheawhom, Myong Yong Choi
This study introduces a NiFe LDH-based catalyst via pulsed laser irradiation in liquids and microwave methods, achieving superior oxygen evolution performance. In situ electrode casting optimizes the catalyst for water-splitting applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Scalable Synthesis of N–Doped Graphene–Oxide–Supported FeCo(OH)x Nanosheets for Efficient Co–Doped Fe3O4 Nanoparticle-Based Oxygen Reduction Reaction Electrocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06684G, Paper
Open Access
Sunglun Kwon, Jong Hyeon Lee
Developing efficient and cost-effective materials is crucial for advancing electrochemical oxygen reduction reaction (ORR). This study presents a synthesis route for high-performance spinel Fe and Co oxide nanoparticles on N-doped...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synergetic Effects from a High-Entropy NASICON-type Cathode for Advanced Sodium-Ion Batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA06950A, Paper
Shouyue Wang, Taiding Xu, Huitao Leng, Shengyu Liang, Wei Zhang, Yuheng Jin, Jingxia Qiu, Sheng Li
Na3V2(PO4)3 (NVP) is recognized as one of the most promising NASICON-type cathodes for sodium-ion storage. Enhancing electronic conductivity and further ensuring long-term structural stability when activating the high-voltage V⁴⁺/V⁵⁺ redox...
The content of this RSS Feed (c) The Royal Society of Chemistry




syn

Synchronised polls are a smokescreen

The elephant in the room as far as poll reform is concerned, namely funding of elections, is conveniently obscured




syn

Syngene launches new protein production platform 

The platform supports different types of biomolecules, including monoclonal antibodies, biosimilars, bispecifics, antibody-drug conjugates, and other recombinant proteins




syn

Genetic Testing for Inherited Cancer Susceptibility Syndromes

A fact sheet about genetic testing for inherited cancer risk, including who should consider testing, how to understand test results, and who has access to a person’s test results. Also contains information about at-home, or direct-to-consumer, genetic tests.




syn

Synergistic in situ growth of a MOF on the surface of Ti3C2Tx MXene nanosheets with different tannic acid (TA) ratios for the photocatalytic degradation of pollutants

J. Mater. Chem. C, 2024, 12,17620-17634
DOI: 10.1039/D4TC02771J, Paper
Huanggen Yang, Pei Zhang, Qi Zheng, Asif Hayat, Hisham S. M. Abd-Rabboh, Saleem Raza, Duofu Li, Yan Sui
The integration of a two-dimensional (2D) transition metal carbide (MXene) with metal–organic frameworks (MOFs) presents a promising avenue for addressing the limitations of MXene materials in various applications.
The content of this RSS Feed (c) The Royal Society of Chemistry