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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Enhanced photocatalytic activity of single-atom Au1/TiO2 catalysts prepared using cold plasma

CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper
Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au1/TiO2-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
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Color-resolved mechanoluminescence of Eu and Mn co-doped SrMg2(PO4)2

CrystEngComm, 2024, 26,2096-2102
DOI: 10.1039/D4CE00070F, Paper
Qingshan He, Yajing Yan, Ting Wang, Longchao Guo, Yang Yue, Nannan Zhu, Weifang Bu, Xin An, Bosong Duan, Xuanyu Zhu, Xue Yu
The linear relationship between the ML intensity ratio (MLIR) and stress of this phosphor leads to a change in ML color, resulting in visualization of ML performance of knee motion via the artificial skin based on SMP:Eu,Mn phosphor.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Enhanced Zn ion storage performance of polypyrrole coated Mn3O4 composites electrode

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00252K, Paper
Shilong Li, Ming Zhao, Weichao Zhang, Xiang Wu
Aqueous zinc ion batteries (AZIBs) possess significant application potential in energy storage field due to their large capacity, low redox potential and high safety. Among various materials, Mn3O4 electrode has...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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Coordinatively unsaturated 5-nitroisophthalate based cobalt(II) coordination polymers: efficient catalytic CO2 fixation and Hantzsch condensation

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00102H, Paper
Subham Sahoo, Rajesh Patra, Debajit Sarma
Labile-coordinated water-based CPs have been synthesized. SSICG-6 serves as an excellent heterogeneous catalyst in CO2 cycloaddition and one-pot Hantzsch condensation reactions compared to other 1D-reported CPs due to the presence of OMSs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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In situ P-doping induced Se vacancies enhance the supercapacitor performance of NiCo2Se4

CrystEngComm, 2024, 26,2197-2206
DOI: 10.1039/D4CE00048J, Paper
Miaomiao Wang, Weizhe Liu, Li Zhang, Huanli Liu, Xiao Yang
In this paper, we report the synthesis of P-doped NiCo2Sex nanomaterials with rich Se vacancies induced by P doping, which greatly improves the supercapacitor performance of electrode materials.
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han

WhatsApp to offer new Channels feature

Channels will be first available in select organisations in Colombia and Singapore.




han

Twitter under Jack Dorsey and team were in repeated, continuous violations of Indian law: Rajeev Chandrasekhar

The former Twitter Chief Executive Officer and Co-founder has alleged that the Indian government threatened to shut down Twitter during farmers protest




han

Instagram rolls out broadcast channel globally

Instagram started testing broadcast channels in February.




han

WhatsApp rolls out ‘channel notification’ feature for beta users

WhatsApp channel notification feature is available for both iOS and Android users




han

Musk says Twitter will change logo to X

Twitter’s brand toolkit page says the company is protective of its logo and offers guidelines on how to use it, Elon Musk apparently isn’t a fan




han

PM Modi joins WhatsApp channels

Announces that he has joined WhatsApp channels in a post on X




han

WhatsApp unveils ‘Secret Code’ feature to enhance privacy

The new feature allows users to set a distinct password that is separate from their phone unlock code




han

WhatsApp has been a game changer for India’s small businesses: Sandhya Devanathan

One of the key announcements included the Meta-verified badges on WhatsApp. In a one on one chat with businessline Sandhya Devanathan, VP, Meta in India explained the significance of these propositions for businesses on WhatsApp and consumers alike.




han

India’s kharif rice, foodgrain production estimated lower than last year

First advance estimate pegs foodgrain output 6.12 mt lower; record maize, sugarcane crop likely




han

The rise of India is deeply linked to the rise of technology: Jaishankar

‘Principle of economic strategic autonomy will hold the key to global re-balancing and big players will constantly strive to be more capable technologically’




han

Cheaper to live in India than US, UK and Germany: SBI report

If the household budget/ cost of living was Rs 100 in September 2021, it has increased by Rs 12 in both the US and India, but it has increased by Rs 20 in Germany and Rs 23 in the UK: Report




han

India’s coal bed methane output expected at 759 MSCM in FY23

India’s coal bed methane production is estimated to grow to 1,072 MSCM in FY24 and 1,508 MSCM in FY25




han

More than 5.57 lakh cos struck off due to non-compliance with companies law provisions

A special task force has recommended the use of certain red flag indicators as alerts to identify shell companies




han

Govt prepares draft to use Middleware for broadcasting TV channel content without Internet

Middleware can be used to deliver broadcast content to portable devices through Wireless LAN/WiFi




han

Eyeing ethanol, sugar industry ramps up investments to improve cane yield

Move is part of ISMA’s efforts to divert sugar for ethanol production




han

Rural retail inflation in 23 States/UTs higher than urban

Experts say elevated rural inflation likely to hurt the rural economy, as the pricing power is not with the rural households




han

Home demand resilient, inventory overhang dips: Eco Survey

Housing prices are trending up on a pan-India basis, the Survey showed




han

Songs of the River Ganga: Shantanu Moitra’s lyrical journey to self-discovery

The six-episode series traces the emotional and spiritual calling of the 55-year-old Bollywood music composer, explores his creative dimension and puts his physical mettle to the test



  • Life & Style

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Can the Dark Sky Reserve at Hanle be a gamechanger for stargazing in India?

As Hanle in Ladakh is poised to have India’s first Dark Sky Reserve, prospects for stargazing and astro tourism shine bright




han

India-Russia trade target of $100 bn realistic but urgent need for balance: Jaishankar

Russia’s First Deputy PM Denis Manturov begins two-day India visit, attends India-Russia Business Forum




han

Pinarayi thwarted chances of Dalit person becoming CM in future, alleges Kuzhalnadan




han

Police, NMMC probe hand behind hoardings against Tukaram Mundhe




han

Buldhana school rape: main accused not an employee, say cops




han

U.P.-bound private bus turns turtle in Thane, 16 injured




han

Boyfriend refuses to marry, Govandi teen hangs herself

Sameer Abdul Sheikh held for abetment to suicide




han

HC grants interim stay on order banning channel




han

The morning after: businesses run out of change

While chemists, toll booths were accepting the now-demonetised Rs. 500 and Rs. 1,000 currency notes, they ran out of change as people rushed to offload their notes




han

Gulshan Kumar murder convict deported, brought to Mumbai




han

How to lure tourists beyond Kerala, Goa, Rajasthan?




han

Thane cops bust illicit liquor racket in Mumbra




han

A perturbational approach for approximating heterogeneous agent models [electronic resource] / Anmol Bhandari, Thomas Bourany, David Evans, Mikhail Golosov

Cambridge, MA. : National Bureau of Economic Research, 2023




han

Sexual harassment in public spaces and police patrols [electronic resource] : experimental evidence from urban India / Sofia Amaral, Girija Borker, Nathan Fiala, Anjani Kumar, Nishith Prakash, Maria Micaela Sviatschi

Cambridge, MA. : National Bureau of Economic Research, 2023




han

Treatment for mental health and substance use [electronic resource] : spillovers to police safety / Monica Deza, Thanh Lu, Johanna Catherine Maclean, Alberto Ortega

Cambridge, MA.: National Bureau of Economic Research, 2024




han

Bitcoin and carbon dioxide emissions [electronic resource] : evidence from daily production decisions / Anna Papp, Douglas Almond, Shuang Zhang

Cambridge, MA. : National Bureau of Economic Research, 2023




han

The labor demand and labor supply channels of monetary policy [electronic resource] / Sebastian Graves, Christopher K. Huckfeldt, Eric T. Swanson

Cambridge, MA. : National Bureau of Economic Research, 2024




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Real effects of rollover risk [electronic resource] : evidence from hotels in crisis / Anthony A. DeFusco, Charles G. Nathanson, Michael Reher

Cambridge, Mass. : National Bureau of Economic Research, 2023




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Will hand over next tranche of land for new Bombay High Court building: State govt to SC

The State government said possession of 30.16 acre of land will be handed over to the High Court in a phased manner, adding the first tranche measuring 4.39 acres has already been given