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Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones

Org. Chem. Front., 2024, 11,6510-6517
DOI: 10.1039/D4QO01517G, Research Article
Yu Sun, Yi Wang, Zhijun Zuo
A novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Trust deficit exists between citizens and healthcare system: former IAS officer




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Carbonate weakens the interactions between potassium and calcareous soil

RSC Adv., 2024, 14,35275-35285
DOI: 10.1039/D4RA05988C, Paper
Open Access
Wei Du, Shifeng Wang, Yizhe Yang, Chenyang Xu, Feinan Hu, Wuquan Ding, Jialong Lv
Adsorption energies of K+ in carbonate-removed (CREM) and carbonate-reserved (CRES) calcareous soil.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Complexes between 2,2'-azobis(2-methylpropionamidine) dihydrochloride (AAPH) and cucurbit[n]uril hosts modulate the yield and fate of photolytically-generated AAPH radicals

RSC Adv., 2024, 14,35980-35991
DOI: 10.1039/D4RA07150F, Paper
Open Access
Angie C. Forero-Girón, Mauricio Oyarzún, Kevin Droguett, Denis Fuentealba, Soledad Gutiérrez-Oliva, Barbara Herrera, Alejandro Toro-Labbé, Eduardo Fuentes-Lemus, Michael J. Davies, Camilo López-Alarcón, Margarita E. Aliaga
AAPH-cucurbit[n]uril systems were experimentally and theoretically studied. Radical yields formed upon photolysis of AAPH were altered by complexation with CB[8] in a stoichiometry-dependent manner, however, radical yields were not changed by CB[6].
The content of this RSS Feed (c) The Royal Society of Chemistry




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Clarifying the Relationship Between Popovers and Dialogs

Pop quiz! What's the difference between a Popover element and a Dialog element? The answer is not all that clear and is widely misunderstood, but Zell has a clear way to explain it so that you know which element to reach for in your work.


Clarifying the Relationship Between Popovers and Dialogs originally published on CSS-Tricks, which is part of the DigitalOcean family. You should get the newsletter.




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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Caught between principle and party, Sandeep Varier says it’s for BJP to take a call

In a chat with The Hindu, the BJP State committee member reaffirms that he is weighing no options. “I’m not planning anything. I shall act according to the changing situation. But I shall continue to be a dedicated karyakartha of the BJP,” he says




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Bihar News: Railway Employee Crushed To Death After Getting Trapped Between Engine & Bogie

It took rescue personnel nearly two hours to retrieve the body of the deceased railway employee, leaving an atmosphere of shock and grief at the station.




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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Dominant role of zeolite in coordination between metal and acid sites on an industrial catalyst for tetralin hydrocracking

React. Chem. Eng., 2024, 9,940-949
DOI: 10.1039/D3RE00605K, Paper
Jiayao Qi, Hanqiong Jia, Fei Wang, Hang Gao, Bo Qin, Xinwei Zhang, Jinghong Ma, Yanze Du, Ruifeng Li
An effective approach for upgrading light cycle oil (LCO) is the targeted conversion of poly-aromatic hydrocarbons to valuable monoaromatic hydrocarbons.
The content of this RSS Feed (c) The Royal Society of Chemistry




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In vivo mechanism of interaction between trimethylamine lyase expresssion and glycolytic pathways

Food Funct., 2024, Accepted Manuscript
DOI: 10.1039/D4FO03809F, Paper
Qian Li, Di Wu, Yu Song, Lu Zhang, Ting Wang, Min Zhang
Recent findings have confirmed that the interaction between host and gut microbiota can alter the formation of the disease-associated metabolite, trimethylamine (TMA), via intestinal microbial TMA lyase. Nevertheless, little is...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Correlation between vitamin D metabolic pathway-related gene polymorphisms and cardiovascular disease

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO03234A, Review Article
Jiao Pang, Chunshuo Yang, Jiaqi Liu, Zhilin Wang, Xueshu Tao, Zhipeng Cao
Polymorphisms in key genes in the vitamin D metabolic pathway affect susceptibility to cardiovascular disease (CVD) and play potential roles in the pathogenesis of CVD.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Association between olive oil consumption and all-cause, cardiovascular and cancer mortality in adult subjects: a systematic review and meta-analysis

Food Funct., 2024, Advance Article
DOI: 10.1039/D4FO04161E, Paper
Andrea del Saz-Lara, Alicia Saz-Lara, Iván Cavero-Redondo, Carlos Pascual-Morena, Carmen Mazarío-Gárgoles, Francesco Visioli, María-Carmen López de las Hazas, Alberto Dávalos
Fourteen studies were systematically reviewed and seven were included in the meta-analysis. Consumption of OO is associated with a reduction of cardiovascular mortality (16%), all-cause mortality (15%) and cancer mortality (11%) in adult population.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Progress in trade between India and Russia: Jaishankar

Since the war in Ukraine and Russia ouster from the international SWIFT payment system, payments have emerged as a major bottleneck between India and Russia




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Unexpected link between nickel toxicity, cholesterol levels found

In a new study, fungi that lacked the Sre1 protein were found to be highly sensitive to nickel; the gene that encodes for this protein is conserved in all animals, including humans




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Mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds: a DFT study

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00995A, Paper
Tiantian Liu, Kang Lv, Xiaoguang Bao
A detailed computational study was performed to shed light on the mechanistic differences between the Ru(II) and Zn(II)-catalyzed cross-coupling of cyclopropenes with diazo compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic dehydrogenative C(sp2)–P coupling reaction between dibenzo[b,f][1,4]oxazepanes and phosphine oxides

Catal. Sci. Technol., 2024, 14,6176-6179
DOI: 10.1039/D4CY00955J, Communication
Zhaotian Wu, Xuefei Sha, Shan Wang, Huan Yang, Shaojun Zheng, Chunhui Jiang, Shu-Yang Chen, Hongfei Lu
Visible-light-induced cross-dehydrogenative coupling between cyclic imines and diaryl phosphine oxides has been developed to afford their oxyphosphide derivatives, using rhodamine B as a photocatalyst.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines

Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Interplay between superconducting fluctuations and weak localization in disordered TiN thin films

Nanoscale, 2024, 16,20319-20330
DOI: 10.1039/D4NR02639J, Paper
Sachin Yadav, Bikash Gajar, R. P. Aloysius, Sangeeta Sahoo
The interplay between superconducting fluctuations (SFs) and weak localization (WL) has been probed by temperature dependent resistance [R(T)] and magnetoresistance (MR) measurements in two-dimensional disordered superconducting TiN thin films.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A liposome-based assay for cancer biomarker detection: exploring the correlation between platelet-derived microvesicles and NSCLC-associated miRNAs

Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR03704A, Paper
Mohamed Aimene Benariba, Kanza Hannachi, Sha Zhu, Yuting Zhang, Xiaoli Wang, Nandi Zhou
This research reveals a significant correlation between PMVs and their associated miRNA. Additionally, the liposome-based assay demonstrates enhanced sensitivity with calcium-induced platelet activation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Telomerase: a nexus between cancer nanotherapy and circadian rhythm

Biomater. Sci., 2024, Advance Article
DOI: 10.1039/D4BM00024B, Minireview
Pramit Kumar Ghosh, Maddila Jagapathi Rao, Chandra Lekha Putta, Sandipan Ray, Aravind Kumar Rengan
The use of nanoparticles for identifying and suppressing telomerase presents promising opportunities for anticancer strategies, particularly in relation to circadian regulation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The need to differentiate between entrepreneurship education and enterprise education

How is enterprise education different from entrepreneurship education? Why do students need both?




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NCLAT accepts settlement proposal between Byju’s and BCCI, sets aside insolvency order

The appellate tribunal also dismissed the allegation of round-tripping levelled by Byju's U.S.-based lenders, saying they failed to provide any evidence for the same




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Officials plan express road network between Visakhapatnam and Bhogapuram for the upcoming international airport

Chief Minister mentioned about this road project in a recent meeting and we are currently preparing preliminary plans, says a senior VMRDA official




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Call to bridge the gap between the youth and elderly




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Between rock and hard place: housing dilemma of urban poor in Vijayawada

In August, Vijayawada experienced its heaviest rain in a century, highlighting a major issue—safe housing for the urban poor. Six people from the over three lakh residents living in rockslide-prone hilly areas died when a boulder crushed them during the rains. Despite the lurking danger, many continue to live there due to the proximity to their workplaces and unable to afford the high cost of housing in the plain area, writes Nellore Sravani




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Between the stones, there is no binding

An architectural marvel is tucked away in the folds of forests and peaks near Panaji in Goa.




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Between hope and hubris: Innocence, glumness, despair, gratitude after the World Cup final

This is sport. Unexpectedness and upsets are what it thrives on.




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Money, happiness and the connection between the two 

Nobel Prize winning behavioural economist Daniel Kahneman led a famous study which concluded that happiness increases with income until it plateaus at $75,000 a year




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Russia committed on signing free trade pact between India and EAEU, says Manturov

Jaishankar, Manturov direct working groups to work towards enhancing market access to meet $100 bn trade target by 2030




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Between a rock and a hard place

Most Indians seem to be caught between a ‘pretentious Left’ and a self-righteous, sanctimonious Hindu Right with a diabolical communal agenda and the space for a rational, reasoned debate is shrinking alarmingly.




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AIADMK leader alleges lack of coordination between T.N. govt. departments during northeast monsoon

AIADMK leader and former Revenue Minister R.B. Udayakumar visited a few low-lying areas in Madurai city that were affected by the recent spell of rains




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Apple Vision Pro 2 powered by new M5 chip to be released between late 2025 and early 2026: Report

Gurman noted that the new model will likely look similar to the original Apple Vision Pro headset, and that most changes would include the upgrade in processing capabilities




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Psychedelics forge connections between neurons

Study in rats and fruit flies suggests that these drugs could inspire better, ketamine-like antidepressants




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The college principal who serves as a bridge between Bengal’s Dalit literature and the world

Dr. Jaydeep Sarangi, who is a published and well-anthologised poet with 10 collections in English, has probably translated more works of Dalit writers in Bengal than anyone else




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Hidden Stories: How Kumbharwada and Dengle Bridge forge a link between Pune’s history and Diwali celebrations




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From Jangpura to Kalyan, between metropolis and mofussil




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Sport24.co.za | Russell explains diffrence between real and sim racing

Williams driver George Russell is enjoying sim racing online while Formula 1 is suspended but admits he doesn't get the same sense of speed or fear.




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Assessing the danger of war: parallels and differences between Europe in 1914 and East Asia in 2014

12 November 2014 , Volume 90, Number 6

Joachim Krause




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FOX RUN CIR IS CLOSED BETWEEN OWLS NEST RD AND RT 72 UNTIL MAY 17, 2020




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N ADAMS ST IS EXPERIENCING A LEFT LN CLOSURE BETWEEN 10TH STREET/12TH STREET DUE TO CONSTRUCTION TIL 5PM




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DE-141 NB BETWEEN JAY DR AND COMMONS BLVD IS EXPERIENCING A RIGHT LANE CLOSURE DUE TO CONSTRUCTION UNTIL 7/1/20 UNTIL MIDNIGHT




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DE-141 NB BETWEEN DE-48 AND BARLEY MILL PLAZA IS EXPERIENCING A RIGHT LANE CLOSURE DUE TO CONSTRUCTION UNTIL 6:00 AM




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LOW BRIDGE ON CASHO MILL RD BETWEEN JULIE LN AND MUNRO RD - VEHICLES OVER 8' 7" WILL NOT FIT.



  • Special Travel Alert

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Mercedes-AMG GLC 43 Coupe Road Test Review: Great balance between performance and daily drive

Most performance cars are not designed for Indian conditions, but does the GLC 43 AMG strike the perfect balance to be usable every day of the week and satisfy the enthusiast?




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OgilvyOne's Fletcher on Ending the Battle Between Data and Creativity

In Focus: Marketing Hall of Femme honoree Mish Fletcher, chief marketer of OgilvyOne Worldwide, discusses the rewards of not-so-delicately balancing data with creativity.




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Oil market should reach balance between supply and demand in Q1: UAE energy minister

Opec, Russia and other non-Opec producers — an alliance known as Opec+ —agreed to reduce supply by 1.2 million bpd from January 1.




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Flashback: Nokia's Touch and Type blurred the lines between smart and feature phones

The division between smartphones and feature phones has often been murky. In the past, it used to be about how well the device ran user-installed apps and games, these days it's mostly touch screen vs. keypad. But there always were devices that straddled the line between those two categories. Nokia X3-02 Touch and Type official photos Before Nokia released the no-quite-smartphone Asha phones, there were the two Touch and Type models. As we said, these phones tried to have it both ways. The Nokia X3-02 and C3-01 both came out in late 2010. What made them special was that...




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UFC 249: Russia's Alexey Oleynik enjoys a LIE DOWN between rounds, then DEFEATS former UFC champ Fabricio Werdum (VIDEO)

In the 73rd fight of his professional career, Russia's Alexey Oleynik swapped grappling for striking as he threw caution to the wind, and defeated former UFC heavyweight champion Fabricio Werdum at UFC 249 in Jacksonville.
Read Full Article at RT.com