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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Effects of nucleating agents on the II–I transition of iPB-1

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,1940-1951
DOI: 10.1039/D3CE01303K, Paper
Zhiqi Li, Jingqing Li, Shichun Jiang
For iPB-1, II–I transition is of industrial importance; whereas, the traditional solid–solid II–I transition mechanism encountered challenges. It is form I formation in amorphous phase that triggers II-I transition with crystal reorganizations.
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Modulating the active phase in perovskite LaCoO3 with B-site doping of Cu for efficient methanol reforming to produce hydrogen

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01268A, Paper
Weiling Zhang, Peiwei Han, Juan Li, Zizhen Niu, Guowei Wang, Nan Wang, Xiangnan Li, Lyumeng Ye, Xinjun Li
The structure transformation of Cu+–Ov–Co2+ and Cu2+–O–Co3+ on the efficient MSR reaction.
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Advanced MnOx/MnWO4 hetero-nanoflakes with abundant oxygen vacancies for high-performance flexible asymmetric supercapacitors with high energy density

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2087-2095
DOI: 10.1039/D4CE00052H, Paper
Yanli Yin, Jingli Wang, Sihao Chen, Nengneng Han, Zhiliang Chen, Yuezhou Jing, Yahui Zhang, Juan Xu, Zhongyang Li
High-performance flexible supercapacitors assembled with MnOx/MnWO4@C-3 hetero-nanoflake anodes, exhibiting a maximum areal energy density of 48.49 mW h cm−2.
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Coral-mimetic production of aragonite films from CO2 captured by biogenic polyamines

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2065-2071
DOI: 10.1039/D4CE00126E, Paper
Open Access
Kohei Takashina, Hiroto Watanabe, Yuya Oaki, Yoshikazu Ohno, Ko Yasumoto, Hiroaki Imai
We designed CaCO3 films comprised of aragonite nanorods by mimicking the microstructure and the formation process of the calcareous skeleton of a stony coral in the sea.
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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Highly efficient and durable P, Ru–CeO2 self-supporting electrodes toward industrial-level hydrogen production

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00143E, Paper
Wenguang Ma, Xiaodong Yang, Yanru Xu, Cuncheng Li, Yiqiang Sun, Qi Shen, Zhixin Sun
The electrolysis of seawater has become a preferred method for hydrogen production since the current shortage of freshwater resources, offering an effective strategy to address the energy crisis.
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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Shortening CN⋯Br–Csp3 halogen bonds via π-stacking

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2131-2135
DOI: 10.1039/D4CE00307A, Communication
Open Access
Kamil Kupietz, Rosa M. Gomila, Thierry Roisnel, Antonio Frontera, Rafael Gramage-Doria
An extremely short N⋯Br distance between a nitrile group and a Csp3-linked bromine atom was encountered in the solid-state and rationalized by DFT calculations, which emphasized the role of π-stacking for bringing both partners at close proximity.
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A highly stable hydrogen-bonded organic framework for hydrogen storage

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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India-Russia trade target of $100 bn realistic but urgent need for balance: Jaishankar

By www.thehindubusinessline.com
Published On :: Mon, 11 Nov 2024 13:27:01 +0530

Russia’s First Deputy PM Denis Manturov begins two-day India visit, attends India-Russia Business Forum


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Sack security agency: Press Club to Tatas

By www.thehindu.com
Published On :: Mon, 07 Nov 2016 00:00:00 +0530


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A perturbational approach for approximating heterogeneous agent models [electronic resource] / Anmol Bhandari, Thomas Bourany, David Evans, Mikhail Golosov

By darius.uleth.ca
Published On ::

Cambridge, MA. : National Bureau of Economic Research, 2023


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Youth labor force participation, education, and human capital in Asia, by gender, 1990-2019 [electronic resource] / Barbara M. Fraumeni

By darius.uleth.ca
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Cambridge, Mass. : National Bureau of Economic Research, 2023


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Elgar companion to Herbert Simon [electronic resource]/ edited by Gerd Gigerenzer (Herbert Simon Society; Max Planck Institute for Human Development, Berlin, Germany), Shabnam Mousavi (Center for Artificial Intelligence (CENTAI), Turin, Italy) and Riccar

By darius.uleth.ca
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Cheltenham, UK ; Northampton, Massachusetts : Edward Elgar Publishing, [2024]


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Artificial intelligence [electronic resource] : economic perspectives and models / Wim Naudé, Rheinisch-Westfälische Technische Hochschule, Aachen, Germany, Thomas Gries, Universität Paderborn, Germany, Nicola Dimitri, Università degli

By darius.uleth.ca
Published On ::

Cambridge, United Kingdom ; New York : Cambridge University Press , 2024.


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The Turing Transformation [electronic resource] : artificial intelligence, intelligence augmentation, and skill premiums / Ajay K. Agrawal, Joshua S. Gans, Avi Goldfarb

By darius.uleth.ca
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Cambridge, MA. : National Bureau of Economic Research, 2023


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Cong. against reservation, its only agenda is to divide people on basis of caste: PM

By www.thehindu.com
Published On :: Fri, 08 Nov 2024 14:22:20 +0530

PM Modi makes open challenge at the Maha Vikas Aghadi alliance to make Congress leaders including Rahul Gandhi to praise Vinayak Damodar Savarkar and Hindutva scion Bal Thackeray.  


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Malaika: 'He Was A Gentle Soul'

By www.rediff.com
Published On :: Wed, 11 Sep 2024 21:26:32 +0530

Malaika Arora's father Anil Mehta died by suicide, the police say.


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Convergence and job replacement is the key to energy transition

By www.thehindubusinessline.com
Published On :: Sun, 01 Oct 2023 16:25:19 +0530

The switch to renewable energy requires technology upgradation, funding and a collective push from public and private stakeholders


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Clean facts about green hydrogen versus blue hydrogen

By www.thehindubusinessline.com
Published On :: Sun, 24 Dec 2023 16:31:54 +0530

Suitability of blue or green hydrogen as a future fuel is premised on how much water is consumed for their production


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Pezzella to miss Argentina's World Cup qualifiers due to injury

By www.newkerala.com
Published On :: Tue, 12 Nov 2024 18:12:02 +0530


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PIX: Brazil edge past Chile; Argentina held

By www.rediff.com
Published On :: Fri, 11 Oct 2024 10:15:37 +0530

Brazil pulled off a last-gasp 2-1 away victory over Chile in the South American World Cup qualifiers on Thursday.


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PIX: Spain's first transgender football team

By www.rediff.com
Published On :: Mon, 14 Oct 2024 12:32:02 +0530

Fenix's first game of the season on September 21 ended with a 19-0 defeat. But for its fans and players, trans men having the right to play their favourite sport on equal terms is far more important than the score.


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PIX: Messi magic leads Argentina to win; Brazil cruise

By www.rediff.com
Published On :: Wed, 16 Oct 2024 09:22:54 +0530

Lionel Messi scored a hat-trick and had a hand in two more goals as Argentina crushed Bolivia 6-0 in South American qualifiers for the 2026 World Cup.


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Can microbial communities regenerate? [electronic resource] : uniting ecology and evolutionary biology / S. Andrew Inkpen and W. Ford Doolittle.

By darius.uleth.ca
Published On ::

Chicago, IL : The University of Chicago Press , 2022.


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India will be one of the biggest intelligence markets: Mukesh Ambani

By www.thehindubusinessline.com
Published On :: Thu, 24 Oct 2024 19:06:50 +0530

Reliance would like to build AI infrastructure in the country that would make a similar impact like Jio did for telecom infrastructure, says Mukesh Ambani, speaking at the Nvidia AI summit in Mumbai


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Revolutionising data security: IBM introduces Guardium Data Security Centre with GenAI capabilities

By www.thehindubusinessline.com
Published On :: Fri, 25 Oct 2024 10:10:36 +0530

The centre incorporates GenAI features for generating risk summaries and improving productivity among security teams.


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AI agents more effective than GenAI for enterprise productivity: Deloitte study

By www.thehindubusinessline.com
Published On :: Sun, 10 Nov 2024 10:27:39 +0530

The study says that GenAI use cases have mostly been limited to standalone applications


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Electrochemical selective divergent C–H chalcogenocyanation of N-heterocyclic scaffolds

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00448E, Communication
Kusum Ucheniya, Pooja Kumari Jat, Amreen Chouhan, Lalit Yadav, Satpal Singh Badsara
An electrochemical direct selective C–H chalcogenocyanation approach for indolizine derivatives under mild conditions has been described.
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Copper catalyzed dehydrogenative cyclization, alkenylation towards dihydroquinolinones

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00134F, Paper
Pari Keerthana, Fazlur-Rahman Nawaz Khan
An efficient copper-catalysized one-pot sequential synthesis of alkenylated quinolinyldihydroquinolinones is reported utilizing ketones, 1,3-cyclohexanediones, and benzyl alcohols via dehydrogenative cyclisation, followed by alkenylation. This highly straightforward method provides a mild...
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Rapid in situ generation of 2-(halomethyl)-5-phenylfuran and nucleophilic addition in a microflow reactor

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00358F, Paper
Open Access
Yuma Matsuura, Shinichiro Fuse
Various 2,5-disubstituted furans were synthesized via 5-substituted 2-halomethylfurans using microflow technology.
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Generation of sulfones utilizing β-sulfinyl esters as masked aryl sulfinates under redox-neutral conditions

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00238E, Communication
Yixin Zhang, Zhu Yang, Hongjun Yang, Xuefeng Li, Lu Yang
A method for generation of SVI sulfones from β-sulfinyl esters (SIV) under transition-metal-free non-oxidative mild conditions is presented.
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Not exclusively the activity, but the sweet spot: a dehydrogenase point mutation synergistically boosts activity, substrate tolerance, thermal stability and yield

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, 22,3009-3018
DOI: 10.1039/D4OB00211C, Paper
Yu-Ke Cen, Lin Zhang, Yue Jiang, Xiang-Fu Meng, Yuan Li, Chao Xiang, Ya-Ping Xue, Yu-Guo Zheng
A single-point mutation of 7α-HSDH achieved the highest activity and synergistically improved substrate tolerance, thermal stability, cofactor affinity, and conversion rate.
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Photogenerated chlorine radicals activate C(sp3)–H bonds of alkylbenzenes to access quinazolinones

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, 22,2968-2973
DOI: 10.1039/D4OB00129J, Communication
Xin-Yao Pan, Gui-Xia Sun, Fang-Ping Huang, Wen-Jian Qin, Qing-Hu Teng, Kai Wang
An Fe-catalyzed visible-light induced condensation of alkylbenzenes with anthranilamides has been developed.
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Photoproperties of Favipiravir and their 6-Substituted Analogues: Fluorescence Controlled through Halogen Substitution and Tautomerism

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00397G, Paper
Angel H Romero, Marcos Couto, Ivan E Romero, German Fuentes, Matías N. Möller
Herein, we showed the photophysical properties of the favipiravir and their 6-substituted analogues. Also, we interpreted the origin of the fluorescence of the favipiravir and their 6-substituted analogues as function...
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Isothiocyanates: Happy-Go-Lucky Reagents in Organic Synthesis

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00281D, Review Article
Bubul Das, Anjali Dahiya, Bhisma K Patel
: Owing to their unique structural features, isothiocyanates (ITCs) are a class of highly useful and inimitable reagents as the N=C=S group serves both as electrophile and nucleophile in organic...
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Synthesis of Deuteriodifluoromethylthiolated Isocoumarins-1- imines and Isocoumarins Enabled by Multi-Component Reagents System (MCRS)

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00328D, Communication
Xuemin Li, Haofeng Shi, Jiaxin He, Jialiang Wu, Fengxia Sun, Yunfei Du
The combining use of BnSCF2D, mCPBA and Tf2O serves as an efficient multi-component reagents system (MCRS) for the synthesis of deuteriodifluoromethylthiolated isocoumarins-1-imines/isocoumarins via intramolecular cyclization/ deuteriodifluoromethylthiolation of 2-alkynylbenzamide/2-alkynylbenzoates. The approach...
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Natural products from human microbiome: an emergent frontier in organic synthesis and drug discovery

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00236A, Review Article
Goverdhan Mehta, Saumitra Sengupta, Srihari Pabbaraja
Often referred to as “second genome”, human microbiome is at the epicenter of a complex inter-habitat biochemical network, such as the “gut-brain axis”, which have emerged as significant determinant of...
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New Generation of Highly Reactive Allylborating Agents For Cu(I)-Catalyzed Allylation of Chiral Sulfinylimines

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00291A, Paper
Michael S. Alexeev, Tatyana V. Strelkova, Michail M. Ilyin, Jr., Yulia V. Nelyubina, Ivan A. Bespalov, Michael Medvedev, Victor N Khrustalev, Nikolai Kuznetsov
The implementation of selective catalytic processes with highly active reagents is an attractive strategy that meets modern principles of sustainable development of chemistry. In the current study, we for the...
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Why opening the emergency door mid-flight is not possible

By www.thehindubusinessline.com
Published On :: Sun, 16 Oct 2022 21:00:00 +0530


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Apple Intelligence launches the iPhone into the AI era

By www.thehindu.com
Published On :: Tue, 29 Oct 2024 08:26:09 +0530

Apple has released a free software update that will inject its first dose of artificial intelligence into its iPhone 16 line-up as the trendsetting company tries to catch up with technology’s latest craze


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WHO to evacuate 1,000 Gazan women, children for urgent medical care

By www.thehindu.com
Published On :: Mon, 21 Oct 2024 16:02:57 +0530

Last week, U.N. investigators said Israel was deliberately targeting health facilities in Gaza, and killing and torturing medical personnel there, accusing the country of "crimes against humanity".


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Dietary restriction or good genes: new study tries to unpack which has greater impact on lifespan

By www.thehindu.com
Published On :: Mon, 21 Oct 2024 16:50:20 +0530

If we know that genetics and lifestyle affect how long you live, which one is more important? And how do they interact?


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Symposium stresses on the urgent need for integrated health strategies

By www.thehindu.com
Published On :: Wed, 06 Nov 2024 18:46:27 +0530


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Bengaluru start-up strives to bridge India’s genomics data gap to aid precision oncology

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 09:00:00 +0530

The company, 4baseCare, has come up with a gene panel for the Indian population after extensive research. This, according to the founders, will allow doctors to provide more evidence-based and data-backed treatment for cancer patients in the country


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WHO identifies 17 pathogens in urgent need of vaccines

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 13:30:00 +0530

The list reconfirms longstanding priorities for vaccine research and development: HIV, malaria, and tuberculosis -- three diseases that collectively kill nearly 2.5 million people each year


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Flipkart Big Diwali Sale 2024: Best deals on iPhone 16 Pro Max, others; buy Apple iPad 9th Gen for just Rs...

By www.dnaindia.com
Published On :: Mon, 28 Oct 2024 04:28:52 GMT

The iPhone 16 series made its debut in India in September, with the flagship iPhone 16 Pro Max starting at Rs. 1,44,900 for the 256GB variant.


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Role of soft skills in industrial and product design career success: Preparing next generation of designers

By www.dnaindia.com
Published On :: Wed, 30 Oct 2024 07:07:00 GMT

Kushal Karwa, a thought leader in design education, emphasizes the need for integrating soft skills training into career preparation programs to help young designers thrive in real-world environments.


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OnePlus 13 launched with Snapdragon 8 Gen 4 SoC: Price details, battery and other specifications

By www.dnaindia.com
Published On :: Fri, 01 Nov 2024 07:10:00 GMT

While the OnePlus 13 has only been revealed in China so far, speculations are that it will arrive on the global market in the coming months. In India, the phone is expected to be launched in January 2025.


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