pi 24 Outrageous Cat Memes Zip-Zapping in Zoomies and Entering Fuzzy Freaky Feline Overdrive By cheezburger.com Published On :: Wed, 13 Nov 2024 10:00:00 -0800 Zoom zoom zoom. Your cat entered the zoomies mode! They zip and zap all around the house, making human parkour professionals look like crawling babies compared to them. Your cat runs fast, fast, fast - way 2 fast, way 2 furious. Your cat can definitely star in the next Fast and Furious film, preferably as the main villain. He'll be so hard to defeat. Or he might take Keanu Reeves and star in a Speed sequel, because this cat's speed seems like it's endless, boundless, limitless.Until your cat calms down from what seems to be an endless zoomies overdrive, you might want to watch some cat memes to pass the time. You can look at some outrageous cat memes that match the zip-zap energy of your zooming cat, which will eventually relax from his fuzzy freaky feline overdrive. ZOOM ZOOM Zoom Zoom zoom zoom… There, he slowed down. Now you can look at these cat memes together. Full Article funny cat memes hilarious funny memes Memes funny cats hilarious memes Cats hilarious cats funny cat memes
pi A Hissterical Helping of Cool Cat Snaps Creating Christmas Morning Meowgic With Huggable Holiday Hilariousness By cheezburger.com Published On :: Wed, 13 Nov 2024 08:00:00 -0800 Ah, the meowliday season. The smell of turkeys in the oven, the cozy warmth of the fireplace, and our cats actually wanting to snuggle with us because there's a chill in the air (little do they know that we keep the thermostat low for this very specific purrrpose). These last two months of the year are filled with feline festivities, purrfect presents, and meowliday cheer. Even though we're still more than a month away from Christmas, we wanted to give you an early present, one that keeps on giving no matter what state you're reading this in: hissterical cat snaps.These silly snaps may remind you of the meowgic you feel when opening up presents on Christmas morning. But who needs Christmas to enjoy huggable holiday hilariousness? At I Can Has Cheezburger, we think that you should be feline pawsitively pleasant every day, so get on your comfiest jammies and run downstairs faster than a cat with zoomies to open up these cool cat snaps (giggle all meowrning long). Full Article funny cat memes christmas hilarious cat snaps lol funny cats Cats funny animals holidays magic cat memes
pi 'You didn't sign up to be a hotel': Free-spirit couple with 5 and 7-year-old kids sells their home to take "extended vacation," begs brother for help By cheezburger.com Published On :: Wed, 13 Nov 2024 12:00:00 -0800 If you suddenly showed up at your sibling's home and asked to live with them for 10 months, it would make things awkward, that's for certain. You can't just ask someone to live with them for that long without having a big discussion about what it would mean for you both. And this woman isn't just asking her brother to stay there alone… she wants to bring her entire family, including her two young children. While we always want to be there for the family members we adore, living with someone is a whole other ball game. This guy has his own home that he's spent a decade paying off. Now suddenly, his younger sister is begging to move in with him because of her own ill-fated adventures. She was living the dream: she sold her family's home in order to travel full-time. While many of us dream of doing things like that, there's a reason most people can't. It's just too expensive to maintain. The sister found this out within just two months of her perma-vacation… but should her brother really be expected to house his sister just because she intentionally chose to give up her house? Check out the full story below and see if you agree with commenters telling this guy to avoid housing her and possibly even cut her off. Up next, read about the drama that one stage mom started when she decided to divorce her long-distance husband over email, while also CC'ing his entire family, friend group, and workplace. Full Article family drama housing aita kids brother house Travel family sister
pi Synduality: Ellie Spinoff Manga Ends With 2nd Volume By www.animenewsnetwork.com Published On :: Wed, 13 Nov 2024 18:00:00 -0500 Second volume ships on January 28 Full Article Manga
pi FLOSS Weekly Episode 809: Pi4J – Stable and Boring on the Raspberry Pi By hackaday.com Published On :: Wed, 13 Nov 2024 19:30:43 +0000 This week, Jonathan Bennett and David Ruggles chat with Frank Delporte about Pi4J, the friendly Java libraries for the Raspberry Pi, that expose GPIO, SPI, I2C and other IO interfaces. …read more Full Article Hackaday Columns Podcasts FLOSS Weekly java raspberry pi
pi Pie I Will Be Eating: All of It By cheezburger.com Published On :: Sat, 19 Nov 2011 16:44:48 -0800 Full Article best of week Pie Chart pumpkin pie
pi BEER PINT foam delicious cool beer undrinkable warm crap By cheezburger.com Published On :: Tue, 20 Jul 2010 16:14:42 -0700 Full Article alcohol beer glass
pi Can't Tell if Epileptic, or Awesome Dancer By cheezburger.com Published On :: Wed, 09 Nov 2011 14:20:34 -0800 Full Article best of week dancing dubstep
pi Why does Pharrell's biopic sidestep Blurred Lines? By www.bbc.com Published On :: Thu, 14 Nov 2024 03:48:22 GMT Williams was fined $5m in a plagiarism lawsuit, but a film about his life doesn't touch on the issue. Full Article
pi Apple accused of trapping and ripping off 40m iCloud customers By www.bbc.com Published On :: Thu, 14 Nov 2024 00:08:40 GMT Which? is seeking a £3bn payout for UK users as a result of the legal action it is launching. Full Article
pi Transcutaneous Spinal Cord Stimulation for Children With Acute Flaccid Myelitis By www.medindia.net Published On :: Acute Flaccid Myelitis (AFM) is an uncommon but severe neurological disorder that causes bsudden paralysis in children/b. Researchers at the International Full Article
pi Transcutaneous Spinal Cord Stimulation for Children With Acute Flaccid Myelitis By www.medindia.net Published On :: Learn how Transcutaneous Spinal Cord Stimulation is revolutionizing treatment for children with Acute Flaccid Myelitis, offering improved mobility and hope. Full Article
pi Dusit International and TDF collaborate to drive excellence in the hospitality sector By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 09:34:41 +0200 Dusit International, one of Thailand’s leading hotel and property development companies, has signed a Memorandum of Understanding (MoU) with Tourism Development Fund (TDF), the national enabler of the tourism sector in Saudi Arabia, to establish a preliminary framework for developing hospitality projects that will enhance the country’s tourism infrastructure. Full Article
pi Valor Hospitality Partners And Campbell Gray Hotels Announce Strategic Initiative In The Middle East By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 16:18:00 +0200 Valor Hospitality Partners, a leading full-service global hospitality management company is launching a strategic partnership with Campbell Gray Hotels & Resorts. This collaboration marks a key milestone for both companies, focused on elevating Valor Hospitality’s management portfolio of luxury properties across the Middle East. The partnership aims to enhance operational efficiency, improve guest experiences and drive commercial success for Valor properties alongside Campbell Gray. Full Article
pi Munich room rates spiked for Expo Real By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 10:14:48 +0200 Munich hotels saw a spike in average daily rate (ADR) and revenue per available room (RevPAR) during Expo Real, according to October preliminary data from CoStar. CoStar is a leading provider of online real estate marketplaces, information, and analytics in the property markets. Full Article
pi Lopesan Hotel Group and Stoneweg Hospitality join forces to acquire Hotel Miguel Angel in Madrid By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 12:10:00 +0200 Lopesan Hotel Group, the leading hotel company from the Canary Islands, in partnership with the investment firm Stoneweg Hospitality, has acquired the Hotel Miguel Angel, previously owned by General Mediterranean Holding S.A SPF, an iconic luxury hotel in the heart of Madrid’s Paseo de la Castellana. Full Article
pi Nearly Half of Europe’s Hotel Construction Pipeline is Under Construction at the end of Q3 2024 By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 15:07:00 +0200 According to the Q3 2024 Europe Hotel Construction Pipeline Trend Report from Lodging Econometrics (LE), analysts report that the region’s total pipeline stands at 1,645 projects/244,548 rooms. Full Article
pi Upscale and Upper Midscale Hotel Projects Dominate China’s Pipeline at Q3 2024, Commanding 59% of Total Construction Pipeline By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 09:37:21 +0200 In the Q3 2024 China Hotel Construction Pipeline Trend Report by Lodging Econometrics (LE), at the end of the quarter, China’s total hotel construction pipeline reached a record high project count of 3,853 projects with 703,312 rooms, up 4% by projects and 3% by rooms year-over-year (YOY). Full Article
pi Tharaldson Hospitality Management Celebrates Opening of Hampton Inn & Suites by Hilton Porter Ranch Los Angeles By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 12:27:08 +0200 Tharaldson Hospitality Management proudly announces the grand opening of their 88th hotel, the Hampton Inn & Suites by Hilton Porter Ranch Los Angeles. This milestone marks another significant achievement in THM’s continued expansion and commitment to delivering exceptional hospitality experiences. Located in the vibrant and rapidly growing area of Porter Ranch, CA, the new Hampton Inn & Suites by Hilton boasts 100 modern and beautifully designed guest rooms, providing visitors with the perfect blend of comfort and convenience. Guests can enjoy premium amenities, including complimentary breakfast, free Wi-Fi, a state-of-the-art fitness center, and a refreshing outdoor pool. The opening of this new hotel comes thanks to the hard work and dedication of the entire THM team, who have worked tirelessly to ensure a seamless and successful launch. THM extends sincere gratitude to every team member for their unwavering commitment and efforts. The Hampton Inn & Suites by Hilton Porter Ranch Lo... Full Article
pi ONYX Hospitality Group Transforms Thailand’s The Tide Resort By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 12:30:28 +0200 ONYX Hospitality Group, a leading management company for hotels, resorts, serviced apartments, and luxury residences in Southeast Asia, has signed an agreement to manage Amari The Tide Bangsaen. This property, which is a significant transformation of The Tide Resort, and has been reimagined as Amari The Tide Bangsaen, is set to reveal its new look in the second quarter of 2025. Located in Thailand in the Chonburi Province, a region poised for significant economic growth, especially in tourism, this property reflects Amari’s commitment to delivering exceptional experiences in Thailand’s most promising destinations. With a focus on enhancing the guest experience to create memorable moments for Thai and international tourists, it is set to cater to a wide range of traveller needs and preferences across leisure and business segments On 7 November 2024, a signing ceremony for a business partnership agreement to manage Amari The Tide Bangsaen was held between Five Leader Group Co., Ltd. and... Full Article
pi Hospitality Thought Leadership: Thinking for Innovation and Advancement By www.hospitalitynet.org Published On :: Wed, 13 Nov 2024 07:46:00 +0200 The pandemic had the hospitality industry rethinking its operating models for safety, security and survival. This crisis event promoted innovation and new concepts and applications in all businesses, including hospitality and tourism. Full Article
pi Pioneering Data Engineering Innovations in Enterprise Analytics By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 14:38:21 +0530 Teradata's capabilities make it ideal for handling complex, high-volume workloads, while Snowflake's flexibility offers a scalable cloud solution. Full Article
pi Bengal bypolls: Trinamool leader injured in shootout dies in hospital By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 15:33:02 +0530 The first casualty in the bypolls for six Assembly constituencies in West Bengal has been reported, as a Trinamool Congress leader who was severely injured in a shootout at Jagatdal adjacent to Naihati Assembly constituency in North 24 Parganas district, died on Wednesday. Full Article
pi Swiggy-backed Rapido sees net loss at Rs 371 crore in FY24 By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 15:35:00 +0530 Homegrown ride-sharing platform Rapido registered a net loss of Rs 371 crore last fiscal (FY24) from Rs 675 crore in FY23. Full Article
pi Heavy rains hit Tamil Nadu: Health department predicts spike in viral infections and fevers By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 15:59:14 +0530 As the heavy rainfall continues to batter several districts of Tamil Nadu, the State Health Department has issued a public advisory warning of a potential surge in viral infections. These include dengue, influenza, and other fever-related illnesses. Full Article
pi John Ratcliffe is Trump's pick to head CIA By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 16:09:00 +0530 US President-elect Donald Trump has named John Ratcliffe, a former congressman and Director of National Intelligence, as his Director of the Central Intelligence Agency, contrary to feverish speculation that the job was going to Kash Patel, an Indian-American. Full Article
pi Trump picks army veteran and TV celeb Hegseth as Defence Secretary By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 17:02:29 +0530 US President-elect Donald Trump has announced Pete Hegseth, an army veteran and TV personality, as his Defence Secretary, filling up another key position in his incoming cabinet. Full Article
pi Navjot Singh Sidhu is back on Kapil Sharma's new show; netizens demand 'Justice for Archana Puran Singh' By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 15:47:26 +0530 Navjot Singh Sidhu's return on The Great Indian Kapil Show is expected to ruffle some feathers. Full Article
pi Salman Khan has no association with The Great Indian Kapil Show or its legal disputes By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 17:07:56 +0530 In a recent development, Salman Khan's representative has clarified that the actor has no association with the show "The Great Indian Kapil Show" on Netflix. Full Article
pi Mendis, Fernando and spinners star as Sri Lanka clinch rain-affected ODI opener - Cricbuzz By news.google.com Published On :: Wed, 13 Nov 2024 18:31:56 GMT Mendis, Fernando and spinners star as Sri Lanka clinch rain-affected ODI opener CricbuzzSri Lanka beat NZ to go 1-0 up DAWN.comKusal Mendis 143 and Avishka Fernando 100 put Sri Lanka 1-0 up ESPNcricinfoSri Lanka vs New Zealand Highlights: Sri Lanka beat New Zealand by 45 runs (DLS method) MintSri Lanka vs New Zealand, 1st ODI Highlights: SL beat NZ by 45 runs via DLS method The Times of India Full Article
pi 'Absolutely box office...': Michael Vaughan picks this Indian player to watch out for in Australia - The Times of India By news.google.com Published On :: Thu, 14 Nov 2024 03:21:00 GMT 'Absolutely box office...': Michael Vaughan picks this Indian player to watch out for in Australia The Times of IndiaJasprit Bumrah pitted against India's biggest Australian nemesis; 'confrontation' to overshadow Kohli vs Cummins battle Hindustan TimesIND vs AUS: Virat Kohli played down as Adam Gilchrist lists key match-ups for BGT 2024-25 Cricket AddictorShami’s absence a major blow for India in BGT, says Paul Adams Morung ExpressMichael Vaughan predicts key battles for Border-Gavaskar Trophy, pits Bumrah against India's nemesis MSN Full Article
pi Donald Trump picks firebrand congressman Matt Gaetz for attorney general - The Times of India By news.google.com Published On :: Wed, 13 Nov 2024 23:59:00 GMT Donald Trump picks firebrand congressman Matt Gaetz for attorney general The Times of IndiaMatt Gaetz: Trump's choice for attorney general shocks Washington BBC.comWhy Matt Gaetz's momination as attorney general in Trump’s cabinet has left many Republicans 'shocked' The Times of IndiaTrump names firebrand lawmaker Matt Gaetz U.S. Attorney General The HinduVideo | US Election: Trump Taps Gaetz For Attorney General, Gabbard For Intel Chief NDTV Full Article
pi Baba Siddique Shooter Waited Near Hospital For 30 Minutes To Confirm Death - NDTV By news.google.com Published On :: Thu, 14 Nov 2024 03:06:10 GMT Baba Siddique Shooter Waited Near Hospital For 30 Minutes To Confirm Death NDTVSuspect Watched From Hospital as NCP Leader Baba Siddique Died After Shooting | Mumbai News The Times of IndiaBaba Siddique murder case: Main accused Shivkumar Gautam makes another BIG revelation | DETAILS India TV NewsBaba Siddique killing: Camped outside Siddique’s house in morning, office in evening for a month, accused tells police The Indian ExpressBaba Siddique murder: Main shooter returned to murder spot, visited Lilavati Hospital to confirm death Hindustan Times Full Article
pi How This Professional Poker Player Became an AI Pioneer By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 19:10:00 GMT Sergio Suarez Jr., founder and CEO of Tackle AI, shares how he built a successful tech company from the ground up. Full Article false
pi Sunil Yadav vs Deen Dayal Upadhyay Hospital on 12 November, 2024 By indiankanoon.org Published On :: MANMOHAN, CJ : (ORAL) CM APPLs.65148-65149/2024 (Exemption) 1. Allowed, subject to all just exceptions. 2. Accordingly, the present applications stand disposed of. W.P.(C) 15514/2024 & CM APPL.65147/2024 3. Present writ petition has been filed seeking a direction to the respondent/Deen Dayal Upadhyay Hospital to open the financial bid of the petitioner and finalize the tender dated 12th June, 2024 for operating two kiosks at the premises of respondent hospital. Full Article
pi Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:08:08 +0000 Commerzbank analizează opțiunea de a achiziționa o bancă germană de dimensiuni medii ca parte a strategiei de a evita o posibilă preluare de către UniCredit, potrivit Reuters. Planurile sunt într-o etapă incipientă, iar posibilele ținte ar putea include Hamburg Commercial Bank sau Oldenburgische Landesbank. Potrivit surselor Reuters, Commerzbank încearcă să conceapă un plan de apărare, ... The post Commerzbank ia în considerare achiziționarea unui rival german pentru a respinge UniCredit appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
pi C–H activation-enabled synthesis of a piperazine-embedded azadibenzo[a,g]corannulene analogue By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00415A, Research ArticleLin Huang, Mengyu Qiu, Zhihao Chang, Duncan L. Browne, Jianhui HuangThe first example of an azadibenzo[a,g]corannulene analogue with an embedded piperazine ring on the flank of its polycyclic skeleton is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00072B, Research ArticleZhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er ChenA sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Spiro-centre substitution effects in the intramolecular spin–spin interactions of spirobiacridine diradicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00419A, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shinichi Ogawa, Takuya Kanetomo, Masaya EnomotoSpirodiradicals with the Si and Ge spiro atoms exhibit a S = 1 state. The magnetic interaction in the Si derivative was found to be lower than that in the Ge derivative, implying a negative effect on σ*(Si–Cα)–π* hyperconjugation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Visible-light-mediated catalyst-free synthesis of trifluoromethyl(spiro)-epoxides bearing contiguous quaternary centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00184B, Research ArticleJingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong ZhangHerein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Stereoselective skeletal modification of tryptanthrins to install chiral piperidine-2-ones enabled by Brønsted acid catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2171-2177DOI: 10.1039/D3QO02029K, Research ArticleRong Zeng, Xiang Zhang, Yuan-Yuan Lei, Zhuo-Zhuo Zhang, Min Jiang, Qing-Zhu Li, Jun-Long Li, Bo HanAn asymmetric formal [4 + 2] cyclisation between azlactones and aza-dienes derived from simple tryptanthrins has been developed. With this established protocol, yielding a series of novel piperidine-2-one-fused tryptanthrins with up to >99 : 1 er under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Prins cyclization of 1,3-dioxinone: synthesis of 11-epi-badkhysin By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2332-2338DOI: 10.1039/D4QO00162A, Research ArticleXiaoliang Xu, Ping Hua, Yiren Xu, Baoqing He, Jingfeng Zhao, Liang Li, Wen Chen, Hongbin ZhangThe asymmetric synthesis of highly functional 11-epi-badkhysin has been accomplished using a structure-unit based approach.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,2326-2331DOI: 10.1039/D4QO00064A, Research ArticleTing-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping DengAn efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Assembly of ionic supramolecular polymers using a decacationic pillar[5]arene to noncovalently crosslink hyaluronic acid for short DNA delivery By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00447G, Research ArticleQian Li, Danying Ma, Yue-Yang Liu, Hui Wang, Wei Zhou, Dan-Wei Zhang, Zhan-Ting LiA multicationic pillar[5]arene noncovalently crosslinks hyaluronic acid to afford ionic supramolecular polymers for intramolecular delivery of short DNA.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Aculeatones A and B, epimeric lovastatin derivatives with a 6/6/3-tricyclic carbon skeleton from Aspergillus aculeatus and their chemical transformation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00351A, Research ArticleFei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng ZhuLovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Visible-light Induced [1, 3]-Brook Rearrangements of α-Ketoacylsilanes and Its Subsequent Trapping in a Tandem Annulation with 1, 3, 5-Triazinanes and Azomethine Imines By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00463A, Research ArticleZhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng YuAn unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Fully atom-economic access to spiro-cyclic skeletons through photoredox-induced hydrogen transfer/Giese addition/dearomative cyclization/protonation cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00317A, Research ArticleGuohui Zeng, Hui Luo, Kai Jiang, Jianpeng Cai, Biaolin YinAmine-tethered spiro-cyclic skeletons were obtained through photo-induced 100%-atom-economic dearomatization, involving the cleavage of the α-C(sp3)–H of amines. Pentacyclic framework was achieved from pyridinyl ring within two steps.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO00347K, Research ArticleZhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping HuiA novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles. The methodology provides...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
pi Iridium-catalyzed asymmetric hydrogenation of 5-hydroxypicolinate pyridinium salts under batch and flow: stereodefined access to cis-configurated hydroxypiperidine esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00322E, Research ArticleZhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er ChenAn iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article