La decisión del tribunal de Schleswig-Holstein de autorizar la entrega a España del prófugo Puigdemont tiene un sabor agridulce al limitarla a la malversación, no a la rebelión o sedición. Hay una cierta justicia poética en que se le reconozca la condición de justiciable en tanto que chorizo o mangante, pero se le ampare en tanto que rebelde o sedicioso.

Manga about supernatural detective launched in September 2023

Series debuted in February 2023

Second volume ships on January 28

Ajichika to illustrate series with composition by Aoi Kujira

Train No. 12133 Mumbai CSMT-Mangaluru Junction Superfast Express will get an LHB rake from March 1 while its pairing service, Train No. 12134 Mangaluru Junction-Mumbai CSMT Superfast Express, will get an LHB rake from March 2

Yang, C; Xu, H; Yin, R; Wang, L; Wu, C; Grasby, S E; Gao, J. Ore Geology Reviews 158, 105530, 2023 p. 1-9, https://doi.org/10.1016/j.oregeorev.2023.105530
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20230270.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20230270.jpg" title="Ore Geology Reviews 158, 105530, 2023 p. 1-9, https://doi.org/10.1016/j.oregeorev.2023.105530" height="150" border="1" /></a>

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[The Conversation Africa] Professor Noel Chabani Manganyi, who has died at the age of 84, was a torchbearer in psychology, literature and African intellectual thought.

Former Shrewsbury Town striker Andy Mangan is a candidate to take over as Salop head coach, reports BBC Radio Shropshire.

We explain analysis of RIXS, HERFD and XR-HERFD data to discover new physical processes in manganese and manganese-containing materials, by applying our new technique XR-HERFD, developed from high resolution RIXS and HERFD.

The manganese title complex, [Mn(C7H5N2O4)2(C7H6N2O4)2(H2O)2]·2H2O, is one of the first 4-amino 3-nitro­benzoic acid (4 A3NBA) monoligand metal complexes to be synthesized. It crystallizes in the centrosymmetric monoclinic space group P21/n with the complex mol­ecules located on inversion centers. Four 4 A3NBA ligand mol­ecules are monodentately coordinated by the Mn2+ ion through the carb­oxy­lic oxygen atoms while the other two positions of the inner coordination sphere are occupied by water mol­ecules, giving rise to a distorted octa­hedron, and two water mol­ecules are in the outer coordination sphere. There are two intra­molecular hydrogen bonds in the complex mol­ecule. The first is of the common N—H⋯O=N type, while the second is a rarely occurring very strong hydrogen bond in which a common proton is shared by two uncoordinated oxygen atoms of neighboring carboxyl­ate groups. In the crystal, an intricate system of inter­molecular hydrogen bonds links the complex mol­ecules into a three-dimensional-network.

The title compound, trans-di­bromido­tetra­kis­(5-methyl-1H-pyrazole-κN2)manganese(II), [MnBr2(C4H6N2)4] or [Mn(3-MePzH)4Br2] (1) crystallizes in the triclinic Poverline{1} space group with the cell parameters a = 7.6288 (3), b = 8.7530 (4), c = 9.3794 (4) Å and α = 90.707 (4), β = 106.138 (4), γ = 114.285 (5)°, V = 542.62 (5) Å3, T = 120 K. The asymmetric unit contains only half the mol­ecule with the manganese atom is situated on a crystallographic inversion center. The 3-MePzH ligands are present in an AABB type manner with two methyl groups pointing up and the other two down. The supra­molecular architecture is characterized by several inter­molecular C—H⋯N, N—H⋯Br, and C—H⋯π inter­actions. Earlier, a polymorphic structure of [Mn(3-MePzH)4Br2] (2) with a similar geometry and also an AABB arrangement for the pyrazole ligands was described [Reedijk et al. (1971). Inorg. Chem. 10, 2594–2599; a = 8.802 (6), b = 9.695 (5), c = 7.613 (8) Å and α = 105.12 (4), β = 114.98 (4), γ = 92.90 (3)°, V = 558.826 (5) Å3, T = 295 K]. A varying supra­molecular pattern was reported, with the structure of 1 featuring a herringbone type pattern while that of structure 2 shows a pillared network type of arrangement along the a axis. A nickel complex [Ni(3-MePzH)4Br2] isomorphic to 1 and the analogous chloro derivatives of FeII, CoII and CuII are also known.

In the title compound, [Mn(C68H44N12O4)(C5H8N2)]·2C6H5Cl, the central MnII ion is coordinated by four pyrrole N atoms of the porphyrin core in the basal sites and one N atom of the 2,5-di­methyl­imidazole ligand in the apical site. Two chloro­benzene solvent mol­ecules are also present in the asymmetric unit. Due to the apical imidazole ligand, the Mn atom is displaced out of the 24-atom porphyrin mean plane by 0.66 Å. The average Mn—Np (p = porphyrin) bond length is 2.143 (8) Å, and the axial Mn—NIm (Im = 2,5-di­methyl­imidazole) bond length is 2.171 (8) Å. The structure displays inter­molecular and intra­molecular N—H⋯O, N—H⋯N, C—H⋯O and C—H⋯N hydrogen bonding. The crystal studied was refined as a two-component inversion twin.

Here, the novel technique of extended-range high-energy-resolution fluorescence detection (XR-HERFD) has successfully observed the n = 2 satellite in manganese to a high accuracy. The significance of the satellite signature presented is many hundreds of standard errors and well beyond typical discovery levels of three to six standard errors. This satellite is a sensitive indicator for all manganese-containing materials in condensed matter. The uncertainty in the measurements has been defined, which clearly observes multiple peaks and structure indicative of complex physical quantum-mechanical processes. Theoretical calculations of energy eigenvalues, shake-off probability and Auger rates are also presented, which explain the origin of the satellite from physical n = 2 shake-off processes. The evolution in the intensity of this satellite is measured relative to the full Kα spectrum of manganese to investigate satellite structure, and therefore many-body processes, as a function of incident energy. Results demonstrate that the many-body reduction factor S02 should not be modelled with a constant value as is currently done. This work makes a significant contribution to the challenge of understanding many-body processes and interpreting HERFD or resonant inelastic X-ray scattering spectra in a quantitative manner.

Scientists have found a link between manganese deficiency and both inflammatory bowel disease (IBD) and increased inflammation and damage in the intestine.

Scientists have found a link between manganese deficiency and both inflammatory bowel disease (IBD) and increased inflammation and damage in the intestine.

Scientists have found a link between manganese deficiency and both inflammatory bowel disease (IBD) and increased inflammation and damage in the intestine.

Scientists have found a link between manganese deficiency and both inflammatory bowel disease (IBD) and increased inflammation and damage in the intestine.

El artista y también productor se diferenció de sus contemporáneos al incluir tintes sobrenaturales en obras como 'Reptilia' y 'El chico de ojos de gato' con las que alcanzó el éxito y le otorgaron el apodo de 'dios del manga de terror' Leer

Location: Main Media Collection - Video record 42295 DVD

La Luciérnaga se enciende para hablar de el ministro del Interior, Luis Fernando Velasco, quien aseguró que es una actitud totalmente bipolar de los dirigentes del ELN anunciar un supuesto cese al fuego, pero seguir con actos ‘aberrantes’ como hostigamientos, asesinatos y secuestro. Además, hablamos sobre el escándalo de Odebrecht, pues Alexander Vega Rocha, registrador nacional, rompió el silencio en medio de la polémica por los audios que prueban que Óscar Iván Zuluaga sí sabía del ingreso de dineros de Odebrecht a su campaña presidencial. También, ciudadanos en Bucaramanga agarraron a piedras y prendieron fuego a la motocicleta de un agente de Tránsito, luego de la muerte de un conductor en lo que habría sido un accidente por no atender el llamado de los uniformados que realizaban un retén en el carril exclusivo de Metrolínea.
La Luciérnaga, un espacio de humor y opinión de Caracol Radio que acompaña desde hace más de 30 años a sus oyentes en el regreso a casa.

Escuche el programa de este lunes 17 de junio. La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.

Escuche el programa de este miércoles 18 de septiembre. La Luciérnaga, un espacio de humor y opinión de Caracol Radio que desde hace 31 años acompaña a sus oyentes en su regreso casa.

La Feria de Libro de Bucaramanga cumple 21 años siendo la celebración de la palabra en Santander. Al respecto habló Juan Camilo Montoya Bozzi, Rector de la Universidad Autónoma de Bucaramanga.

En 10AM Hoy por Hoy de Caracol Radio estuvo Jaime Andrés Beltrán, alcalde de Bucaramanga, para hablar de la estrategia ‘Caza-infractores’, que permitirá controlar de mejor manera el tránsito en la ciudad.

En este programa analizamos la llegada de Hernán Darío Gómez al Atlético Bucaramanga. También dialogamos con el presidente del equipo santandereano.

Jefferson Mena, autor del gol de la victoria del Bucaramanga ante Jaguares, se mostró esperanzado en los resultados que pueda tener el equipo durante este campeonato. El jugador de 34 años sueña en poder alcanzar el primer título de Liga para los santandereanos.

En Caracol Radio estuvo Henry Bello, comandante de la Policía Metropolitana de Bucaramanga

Eduardo Méndez, presidente de Independiente Santa Fe, aseguró, en diálogo con 6AM Hoy por Hoy de Caracol Radio, que, de permitirse el ingreso a la hincha del Atlético Bucaramanga en el juego de este sábado en El Campín por la gran final del fútbol colombiano, ellos deberán pagar el valor de la boleta más costosa, siendo recíprocos con lo que vivió la afición bogotana en el estadio Alfonso López.

Jaime Beltrán insistió en que si hay acuerdos establecidos entre los equipos sobre el ingreso de la hinchada visitante y pidió que estos se respeten.