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KSRTC seeks permits to operate services on six routes connecting areas on Mangaluru outskirts




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CAD Foundation of Mangaluru donates ECG machines for screening Sabarimala pilgrims in Kerala

With this, the foundation completes donating 1,000 ECG machines to many health facilities across India since 2018




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RTA makes pneumatic doors mandatory for mofussil and express buses operating from Mangaluru




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Traffic restrictions in place till 10 a.m. of November 10 for Mangalore Marathon

The Mangalore Marathon comprises of 42K, 32K, 21K, 10K, 10K students run, 5K, 5K student run and 2K Gammat run between Mangala Stadium and Tannirbhavi second beach




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Kudla Samskrutika Prathishtana to hold ‘Mangaluru Street Food Festival’ from January 15 to 19




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PRCI’s global communication conclave in Mangaluru on November 8




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Mangaluru International Airport handles the highest 2.02 lakh passengers in October




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Over 5,000 runners register for Mangalore Marathon on November 10




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Govt. Wenlock Hospital’s new surgical super speciality block begins functioning in Mangaluru

The building was constructed at the cost of ₹56 crore with grants from the Mangaluru Smart City Mission




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Rape and murder of 8-year-old girl in Mangaluru: Three accused sentenced to death




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Death of 47-year-old woman sparks protest by residents in Mangaluru




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Mangaluru International Airport handles 7,637 passengers on November 9; its highest




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Mangalore University winds up admission to seven PG programmes, including Tulu, Konkani for 2024-25

Alumni Association of Tulu Postgraduates upset that despite 11 applications, university denied admission to Tulu




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Hundreds take part in third edition of Mangalore Marathon




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Passenger train rakes to stop moving to Bunder Yard once additional stabling line comes up at Central Railway Station in Mangaluru

This will avoid frequent closure of Pandeshwar and Hoige Bazar level crossing gates as goods trains operations already shifted to Ullal and Panambur




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Air India flight from Mangaluru to Mumbai departs after over-three-hour delay

An Air India official attributed the delay to ‘technical issues’




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Suzlon CEO-New Business Mangal steps down




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Manganese(III) acetate in organic synthesis: a review of the past decade

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01499E, Review Article
Jian Wang, Yan Zhang, Ying Zhou, Xin Gu, Bingxu Han, Xuelu Ding, Shuai Liang
In this review, we summarize the latest developments and applications of Mn(OAc)3 in organic synthesis over the past decade, focusing on efforts to achieve milder reaction conditions while expanding the scope of synthesis possibilities.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02452D, Paper
Jing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang Yang
This study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




manga

Production of birnessite-type manganese oxides by biofilms from oxygen-supplemented biological activated carbon (BAC) filters

Environ. Sci.: Water Res. Technol., 2024, 10,2844-2857
DOI: 10.1039/D4EW00208C, Paper
Amanda Larasati, Olga Bernadet, Gert Jan W. Euverink, H. Pieter J. van Veelen, Maria Cristina Gagliano
The application of a novel enrichment approach revealed the potential of manganese-oxidizing bacteria (MnOB) from full-scale biofilters treating wastewater to produce manganese oxides as crystalline, efficient birnessite catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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The influence of magnesium and manganese cations on the chemical and bioactive properties of purple and green basil

Food Funct., 2024, 15,10644-10662
DOI: 10.1039/D4FO02820A, Paper
Izamara de Oliveira, Antonios Chrysargyris, Tiane C. Finimundy, Márcio Carocho, Celestino Santos-Buelga, Ricardo C. Calhelha, Nikolaos Tzortzakis, Lillian Barros, Sandrina A. Heleno
Effects of hydroponic cultivation with enriched concentrations of magnesium (+Mg), manganese (+Mn), combinations of +Mg and +Mn, or decreased concentrations of these minerals (control) on the chemical/bioactive attributes of basil, were investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mangaluru court rejects bail application of two theft accused




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Mangalore University to host Open House

The programme scheduled on Mangalagangotri will showcasePG courses and laboratory facilities




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Mangalam Seeds Ltd - Financial Results For The Quarter Ended June 30, 2019





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Fifth Indian Open of Surfing: Catch the waves in Mangaluru from May 31

The event, organized by the Surfing Swami Foundation and hosted by the Mantra Surf Club, will feature top Indiansurfers competing in various categories




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Zinc and manganese from batteries turned into nutrients




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Stranded migrant workers stage protest in Mangaluru, demand to be sent back home




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Mangaluru doctors develop 'bubble helmet' to help patients fight Covid-19




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First train with migrants leaves for Jharkhand from Mangaluru

A train with 1,140 migrant workers left Mangaluru Junction for Jharkhand on Saturday evening. The workers, who had registered on the Seva Sindhu app,




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Mangaluru: 'Smart' push to coastal health care

Work on the 37-bedded ICU at the new super specialty block of district Wenlock Hospital is in final stages of completion. Part of area-based development of Mangaluru Smart City mission, new ICU that is being set up will initially be used to handle need for this critical life support system that the global pandemic could bring forth




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Mangaluru people fume over migrant's arrival

Arrival of a migrant labourer from Bagalkot in a truck has created panic among residents of Urwa in the city. People in the area insisted that he should be quarantined and undergo tests for Covid-19. In fact, the migrant labourer, who is a native of Bagalkot, was working in Mangaluru. He had gone to his native place in Bagalkot before the lockdown announcement in March.




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Bis(quinolinium) tetra­bromido­manganate(II)

The title compound, (C9H8N)2[MnBr4], consists of two quinolinium cations and a [MnBr4]2− anion. The manganese(II) atom, which lies on a twofold rotation axis, is coordinated by four bromide ligands and exhibits a tetra­hedral coordination geometry. The [MnBr4]2− anion and the quinolinium cations are linked by N—H⋯Br hydrogen bonds. π–π stacking inter­actions are observed between the quinolinium cations.




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Poly[1-ethyl-3-methyl­imidazolium [tri-μ-iso­thio­cyanato-manganate(II)]]

The title compound, {(C9H11N2)[Mn(NCS)3]}n, has been obtained as a side product of the salt metathesis reaction of 1-ethyl-3-methyl­imidazolium bromide, (EMIm)Br, and K2[Mn(NCS)4]. The structure consists of discrete 1-ethyl-3-methyl­imidazolium cations and an anionic two-dimensional network of manganese(II)-based complex anions, inter­connected by thio­cyanate ions. Every Mn2+ ion is coordinated by three S atoms of three NCS− ions and three N atoms of further three NCS− ions in a meridional octa­hedral fashion.




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Bis(N-adamantyl-N'-ethyl­imidazolium) tetra­bromido­manganate(II)

The title compound, (C15H23N2)2[MnBr4], comprises two N-adamantyl-N'-ethyl­imidazolium cations and one tetra­hedral [MnBr4]2− anion. Next to Coulombic inter­actions, weak hydrogen bonds of the type C—H⋯Br consolidate the crystal packing, building up a three-dimensional network.




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Crystal structures of four dimeric manganese(II) bromide coordination complexes with various derivatives of pyridine N-oxide

Four manganese(II) bromide coordination complexes have been prepared with four pyridine N-oxides, viz. pyridine N-oxide (PNO), 2-methyl­pyridine N-oxide (2MePNO), 3-methyl­pyridine N-oxide (3MePNO), and 4-methyl­pyridine N-oxide (4MePNO). The compounds are bis­(μ-pyridine N-oxide)bis­[aqua­dibromido­(pyridine N-oxide)manganese(II)], [Mn2Br4(C5H5NO)4(H2O)2] (I), bis­(μ-2-methyl­pyridine N-oxide)bis­[di­aqua­dibromido­manganese(II)]–2-methyl­pyridine N-oxide (1/2), [Mn2Br4(C6H7NO)2(H2O)4]·2C6H7NO (II), bis­(μ-3-methyl­pyridine N-oxide)bis­[aqua­dibromido­(3-methyl­pyridine N-oxide)manganese(II)], [Mn2Br4(C6H7NO)4(H2O)2] (III), and bis­(μ-4-methyl­pyridine N-oxide)bis­[di­bromido­methanol(4-methyl­pyridine N-oxide)manganese(II)], [Mn2Br4(C6H7NO)4(CH3OH)2] (IV). All the compounds have one unique MnII atom and form a dimeric complex that contains two MnII atoms related by a crystallographic inversion center. Pseudo-octa­hedral six-coordinate manganese(II) centers are found in all four compounds. All four compounds form dimers of Mn atoms bridged by the oxygen atom of the PNO ligand. Compounds I, II and III exhibit a bound water of solvation, whereas compound IV contains a bound methanol mol­ecule of solvation. Compounds I, III and IV exhibit the same arrangement of mol­ecules around each manganese atom, ligated by two bromide ions, oxygen atoms of two PNO ligands and one solvent mol­ecule, whereas in compound II each manganese atom is ligated by two bromide ions, one O atom of a PNO ligand and two water mol­ecules with a second PNO mol­ecule inter­acting with the complex via hydrogen bonding through the bound water mol­ecules. All of the compounds form extended hydrogen-bonding networks, and compounds I, II, and IV exhibit offset π-stacking between PNO ligands of neighboring dimers.




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Synthesis and crystal structure of catena-poly[[bis[(2,2';6',2''-terpyridine)­manganese(II)]-μ4-penta­thio­dianti­monato] tetra­hydrate] showing a 1D MnSbS network

The asymmetric unit of the title compound, {[Mn2Sb2S5(C15H11N3)2]·4H2O}n, consists of two crystallographically independent MnII ions, two unique terpyridine ligands, one [Sb2S5]4− anion and four solvent water mol­ecules, all of which are located in general positions. The [Sb2S5]4− anion consists of two SbS3 units that share common corners. Each of the MnII ions is fivefold coordinated by two symmetry-related S atoms of [Sb2S5]4− anions and three N atoms of a terpyridine ligand within an irregular coordination. Each two anions are linked by two [Mn(terpyridine)]2+ cations into chains along the c-axis direction that consist of eight-membered Mn2Sb2S4 rings. These chains are further connected into a three-dimensional network by inter­molecular O—H⋯O and O—H⋯S hydrogen bonds. The crystal investigated was twinned and therefore, a twin refinement using data in HKLF-5 [Sheldrick (2015). Acta Cryst. C71, 3–8] format was performed.




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Crystal structures and Hirshfeld surface analysis of trans-bis­(thio­cyanato-κN)bis­{2,4,6-trimethyl-N-[(pyridin-2-yl)methyl­idene]aniline-κ2N,N'}manganese(II) and trans-bis­(thio­cyanato-κN)bis­{2,4,6-trimethyl-N-[(pyri

Two new mononuclear metal complexes involving the bidentate Schiff base ligand 2,4,6-trimethyl-N-[(pyridin-2-yl)methyl­idene]aniline (C15H16N2 or PM-TMA), [Mn(NCS)2(PM-TMA)2] (I) and [Ni(NCS)2(PM-TMA)2] (II), were synthesized and their structures determined by single-crystal X-ray diffraction. Although the title compounds crystallize in different crystal systems [triclinic for (I) and monoclinic for (II)], both asymmetric units consist of one-half of the complex mol­ecule, i.e. one metal(II) cation, one PM-TMA ligand, and one N-bound thio­cyanate anion. In both complexes, the metal(II) cation is located on a centre of inversion and adopts a distorted octa­hedral coordination environment defined by four N atoms from two symmetry-related PM-TMA ligands in the equatorial plane and two N atoms from two symmetry-related NCS− anions in a trans axial arrangement. The tri­methyl­benzene and pyridine rings of the PM-TMA ligand are oriented at dihedral angles of 74.18 (7) and 77.70 (12)° for (I) and (II), respectively. The subtle change in size of the central metal cations leads to a different crystal packing arrangement for (I) and (II) that is dominated by weak C—H⋯S, C—H⋯π, and π–π inter­actions. Hirshfeld surface analysis and two-dimensional fingerprint plots were used to qu­antify these inter­molecular contacts, and indicate that the most significant contacts in packing are H⋯H [48.1% for (I) and 54.9% for (II)], followed by H⋯C/C⋯H [24.1% for (I) and 15.7% for (II)], and H⋯S/S⋯H [21.1% for (I) and 21.1% for (II)].




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Synthesis and crystal structure of (1,4,7,10-tetra­aza­cyclo­dodecane-κ4N)(tetra­sulfido-κ2S1,S4)manganese(II)

The title compound, [Mn(S4)(C8H20N4)], was accidentally obtained by the hydro­thermal reaction of Mn(ClO4)2·6H2O, cyclen (cyclen = 1,4,7,10-tetra­aza­cyclo­dodeca­ne) and Na3SbS4·9H2O in water at 413 K, indicating that polysulfide anions might represent inter­mediates in the synthesis of thio­metallate compounds using Na3SbS4·9H2O as a reactant. X-ray powder diffraction proves that the sample is slightly contaminated with NaSb(OH)6 and an unknown crystalline phase. The crystal investigated was twinned with a twofold rotation axis as the twin element, and therefore a twin refinement using data in HKLF-5 format was performed. The asymmetric unit of the title compound consists of one MnII cation, one [S4]2− anion and one cyclen ligand in general positions. The MnII cation is sixfold coordinated by two cis-S atoms of the [S4]2− anions, as well as four N atoms of the cyclen ligand within an irregular coordination. The complexes are linked via pairs of N—H⋯S hydrogen bonds into chains, which are further linked into layers by additional N—H⋯S hydrogen bonding. These layers are connected into a three-dimensional network by inter­molecular N—H⋯S and C—H⋯S hydrogen bonding. It is noted that only one similar complex with MnII is reported in the literature.




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Synthesis and crystal structure of a penta­copper(II) 12-metallacrown-4: cis-di­aqua­tetra­kis­(di­methyl­formamide-κO)manganese(II) tetra­kis­(μ3-N,2-dioxido­benzene-1-carboximidate)penta­copper(II)

The title compound, [Mn(C3H7NO)4(H2O)2][Cu5(C7H4NO3)4]·C3H7NO or cis-[Mn(H2O)2(DMF)4]{Cu[12-MCCu(II)N(shi)-4]}·DMF, where MC is metallacrown, shi3− is salicyl­hydroximate, and DMF is N,N-di­methyl­formamide, crystallizes in the monoclinic space group P21/n. Two crystallographically independent metallacrown anions are present in the structure, and both anions exhibit minor main mol­ecule disorder by an approximate (non-crystallographic) 180° rotation with occupancy ratios of 0.9010 (9) to 0.0990 (9) for one anion and 0.9497 (8) to 0.0503 (8) for the other. Each penta­copper(II) metallacrown contains four CuII ions in the MC ring and a CuII ion captured in the central cavity. Each CuII ion is four-coordinate with a square-planar geometry. The anionic {Cu[12-MCCu(II)N(shi)-4]}2− is charged-balanced by the presence of a cis-[Mn(H2O)2(DMF)4]2+ cation located in the lattice. In addition, the octa­hedral MnII counter-cation is hydrogen bonded to both MC anions via the coordinated water mol­ecules of the MnII ion. The water mol­ecules form hydrogen bonds with the phenolate and carbonyl oxygen atoms of the shi3− ligands of the MCs.




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The City of Tokyo Releases "Be The Hero", a Video Aiming to Promote the Public Awareness Towards the Disabled Sports. 5 Famous Japanese Manga Artists Took Part in this Project

Let's become a Tokyo-born hero.




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James A. Manganello, PhD, MPH, BCETS, Presented with the Albert Nelson Marquis Lifetime Achievement Award by Marquis Who's Who

Dr. Manganello has been endorsed by Marquis Who's Who as a leader in the field of clinical psychology




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COVID-19: Mangaluru doctors claim to develop ‘bubble helmet’ for better safety of health workers

COVID-19: Mangaluru doctors claim to develop ‘bubble helmet’ for better safety of health workers





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Mangano Sentencing Further Delayed

A federal judge has delayed the sentencing of former Nassau County Executive Edward Mangano and his wife for their corruption convictions.




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Stationery business on rise in Koramangala

The business of fine writing instruments is growing in tandem with other luxury segments in Koramangala and its surroundings.




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The Manganiyar Seduction

I came out of this concert wanting to reach for my mobile phone and text 'OMG' to everyone I knew. Not being a text fan or the kind of person to use the OMG (Oh My God) moniker, I was surprised by my own reaction! So what was it about the sight and sound of 43 turbanned musicians from northern India, sitting in velvet-lined, curtained boxes stacked up on the stage of Perth Concert Hall?



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Man buried under collapsed wall at Bootu Creek manganese mine in Northern Territory

Authorities are trying to find a 59-year-old man buried under soil and rock after a wall collapsed at a manganese mine in the central Northern Territory.




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Day 11 Nature walk through iSimangaliso Wetland Park

iSimangaliso Wetland Park In the afternoon the VESA African Unearth group headed of to the nearby iSimangaliso Wetland park for a nature walk with Johan one of our group leaders at the Crocodile Centre in St. Lucia. Johan is very k




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New manga subscription service launches with a quarantine-friendly 2-month free trial

Read "Attack on Titan," "Somali & the Forest Spirit," "Fire Force," "Arte" and more with Mangamo, a new mobile manga subscription service.




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Brain manganese and the balance between essential roles and neurotoxicity [Molecular Bases of Disease]

Manganese (Mn) is an essential micronutrient required for the normal development of many organs, including the brain. Although its roles as a cofactor in several enzymes and in maintaining optimal physiology are well-known, the overall biological functions of Mn are rather poorly understood. Alterations in body Mn status are associated with altered neuronal physiology and cognition in humans, and either overexposure or (more rarely) insufficiency can cause neurological dysfunction. The resultant balancing act can be viewed as a hormetic U-shaped relationship for biological Mn status and optimal brain health, with changes in the brain leading to physiological effects throughout the body and vice versa. This review discusses Mn homeostasis, biomarkers, molecular mechanisms of cellular transport, and neuropathological changes associated with disruptions of Mn homeostasis, especially in its excess, and identifies gaps in our understanding of the molecular and biochemical mechanisms underlying Mn homeostasis and neurotoxicity.