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Synthesis, crystal structure and Hirshfeld surface analysis of N-(4-methoxyphenyl)picolinamide

The synthesis, crystal structure, and Hirshfeld surface analysis of N-(4-methoxyphenyl)picolinamide (MPPA), C13H12N2O2, are presented. MPPA crystallizes in the monoclinic space group P21/n, with a single molecule in the asymmetric unit. Structural analysis reveals that all non-hydrogen atoms are nearly coplanar, and the molecule exhibits two intramolecular hydrogen bonds that stabilize its conformation. Supramolecular features include significant intermolecular interactions, primarily C—H...π and various hydrogen bonds, contributing to the overall crystal cohesion, as confirmed by energy framework calculations yielding a total interaction energy of −138.3 kJ mol−1. Hirshfeld surface analysis indicates that H...H interactions dominate, followed by C...H and O...H interactions, highlighting the role of van der Waals forces and hydrogen bonding in crystal packing.




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Surface Hub 2, Microsoft lo ha vuelto a hacer




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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced catalytic activity and stability of SOFC electrodes through plasma-driven surface modification

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06111F, Paper
Open Access
Hyunduck Shin, Jongsu Seo, SungHyun Jeon, Seung Jin Jeong, Jinwook Kim, Siwon Lee, Jeong Jin Lee, WooChul Jung
Plasma-induced surface amorphization prevents Sr phase separation, boosting the catalytic activity and stability of SOFC cathode. This finding expands the application of amorphous features to practical electrodes, previously limited to model studies.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




surface

In situ analysis of the oxygen evolution reaction on the CuO film in alkaline solution by surface interrogation scanning electrochemical microscopy: investigating active sites (CuIII) and kinetics

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00628C, Paper
Seokjun Han, Jinoh Yoo, Won Tae Choi
Surface interrogation scanning electrochemical microscopy was employed to assess the electrocatalytic activity of CuO films for the oxygen evolution reaction in an alkaline solution.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




surface

Enhanced surface reconstruction of V-Doped Ni3N driven by strong OH adsorption to boost 5-hydroxymethylfurfural electrooxidation for energy-saving H2 production

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01543F, Paper
Qi Zhou, Juan Wang, Ga Jin, Huiling Liu, Cheng Wang
Coupling biomass electrooxidation with hydrogen evolution reaction (HER) provides an alternative approach for simultaneously increasing the energy efficiency of H2 production and producing high value-added chemicals. Here, a V-doped Ni3N...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Subsurface analysis and correlation of Mount Clark and lower Mount Cap formations (Cambrian), Northern Interior Plains, Northwest Territories

Sommers, M J; Gingras, M K; MacNaughton, R B; Fallas, K M; Morgan, C A. Bulletin of Canadian Petroleum Geology vol. 68, no. 1, 2020 p. 1-29, https://doi.org/10.35767/gscpgbull.68.1.1
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/20190098_329482.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/20190098_329482.jpg" title="Bulletin of Canadian Petroleum Geology vol. 68, no. 1, 2020 p. 1-29, https://doi.org/10.35767/gscpgbull.68.1.1" height="150" border="1" /></a>




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Surface Radars Market worth $22.49 billion by 2029 at a CAGR of 5.4%

(EMAILWIRE.COM, October 30, 2024 ) The Surface Radars Market will grow tremendously from 2020 through 2029, based on the increase in defense spending, escalations in geopolitical tensions, and needs for advanced border security and early warning systems. The surface radars market is projected to...




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2023 State Of Cyber Assets Report Reveals Nearly 600% Annual Growth In Vulnerable Cloud Attack Surface

JupiterOne, the leading cyber asset visibility and management company, today announced the release of its second annual State of Cyber Assets Report (SCAR). The report analyzed more than 291amp;nbsp;million assets, findings, and policies to establish the current state of enterprise cloud assets, including cloud and physical environments of devices, networks, apps, data,amp;nbsp;and users.amp;nbsp;




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Leaf-inspired graphene surfaces repel frost formation for a week

Ice wreaks havoc on surfaces, but we might have a new way to prevent it building up. Scientists at Northwestern University have shown that textured surfaces with thin layers of graphene oxide can stay completely frost-free for long periods.

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Only Surface Deep: Twenty-second Sunday after Pentecost &amp; Ninth Sunday of Luke

Looking at the heart of things clearly a principle of the Old Testament as well as the New. But in the NT, we learn also that God has concern for the material world and for the details of life, for in the Incarnation He took on all that it is to be human. We read our passages for Divine Liturgy in the light of other Old and New Testament readings that help us to see things in perspective. (Galatians 6:11-18; Luke 12:16-21; 1 Chronicles 28:9)




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Interlagos must improve “very bad” new track surface for 2025, say F1 drivers | Formula 1

Formula 1 drivers urged the operators of the Interlagos circuit to improve the new surface they laid ahead of this year's event.




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The Effect of Engagement and Perceived Course Value on Deep and Surface Learning Strategies




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What's going on? Developing reflexivity in the management classroom: From surface to deep learning and everything else in between.

'What's going on?' Within the context of our critically-informed teaching practice, we see moments of deep learning and reflexivity in classroom discussions and assessments. Yet, these moments of criticality are interspersed with surface learning and reflection. We draw on dichotomous, linear developmental, and messy explanations of learning processes to empirically explore the learning journeys of 20 international Chinese and 42 domestic New Zealand students. We find contradictions within our own data, and between our findings and the extant literature. We conclude that expressions of surface learning and reflection are considerably more complex than they first appear. Moreover, developing critical reflexivity is a far more subtle, messy, and emotional experience than previously understood. We present the theoretical and pedagogical significance of these findings when we consider the implications for the learning process and the practice of management education.




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Another case of police excesses surfaces

The report further showed that the additional SHO had been previously found guilty of framing a man in a fake case




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Surface Temperatures at the Continental Scale: Tracking Changes with Remote Sensing at Unprecedented Detail

Temperature is a main driver for most ecological processes, and temperature time series provide key environmental indicators for various applications and research fields. High spatial and temporal resolutions are crucial for detailed analyses in various fields of research. A disadvantage of temperature data obtained by satellites is the occurrence of gaps that must be reconstructed. Here, we present a new method to reconstruct high-resolution land surface temperature (LST) time series at the continental scale gaining 250-m spatial resolution and four daily values per pixel. Our method constitutes a unique new combination of weighted temporal averaging with statistical modeling and spatial interpolation. This newly developed reconstruction method has been applied to greater Europe, resulting in complete daily coverage for eleven years. To our knowledge, this new reconstructed LST time series exceeds the level of detail of comparable reconstructed LST datasets by several orders of magnitude. Studies on emerging diseases, parasite risk assessment and temperature anomalies can now be performed on the continental scale, maintaining high spatial and temporal detail. We illustrate a series of applications in this paper. Our dataset is available online for download as time aggregated derivatives for direct usage in GIS-based applications (Reconstructed MODIS Land Surface Temperature Dataset - http://gis.cri.fmach.it/eurolst/).

Source: Metz M, Rocchini D, Neteler M. (2014) Surface Temperatures at the Continental Scale: Tracking Changes with Remote Sensing at Unprecedented Detail.Remote Sensing 6(5): 3822-3840. doi: 10.3390/rs6053822

 





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Surface Temperatures at the Continental Scale: Tracking Changes with Remote Sensing at Unprecedented Detail




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Icon Protection Unites Four Pioneers in the Surface Protection Industry Under One Roof

With over 1,000 years of collective industry experience among them, Ram Board, Surface Shields, Trimaco and Antinox are united under one parent brand: Icon Protection.




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Protecting construction, surface mining workers from silica dust: CPWR publishes new resources

Silver Spring, MD — Three new resources from CPWR – The Center for Construction Research and Training are intended to help prevent silica exposure among construction and surface mining workers who operate mobile equipment in enclosed cabs.




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OSHA’s rule on walking/working surfaces under OMB review

Washington – After more than two decades in development, OSHA’s final rule on walking/working surfaces to address slips, trips and falls is under White House review.




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Walking/working surfaces rule will be finalized before January, David Michaels says

Anaheim, CA – OSHA’s final rule on walking/working surfaces to address slips, trips and falls in the workplace soon could be a reality, agency administrator David Michaels said Tuesday during a roundtable discussion at the 2016 NSC Congress & Expo.




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Environmentally Friendly Work Surfaces

An environmentally friendly work surface option for control room consoles, called Marmoleum from Winsted Corporation, is made of natural and sustainable raw materials, which emit no volatile organic compounds and are completely biodegradable.




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For surface coal miners, the ‘big hazard’ is silica, NIOSH expert says

Washington — Surface coal miners, especially those who work in drilling, may be exposed to higher concentrations of respirable dust or quartz. This puts them at elevated risk of coal workers’ pneumoconiosis – a deadly but preventable disease known as black lung, results of a recent NIOSH study show.




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Anti-slip surface tape

FLEXMASTER Safety Renovation Treads offer an easily applied anti-slip surface to interior or exterior stairs at workplaces, reducing the risk of slips and falls.




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OSHA proposes updates to handrail, stair rail requirements in Walking-Working Surfaces standard

Washington — OSHA is seeking to update the handrail and stair rail system requirements in its standard on walking-working surfaces for general industry.




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Notorious Botnet Has Resurfaced to Exploit End-of-Life Routers & IoT Devices

A recent report by Black Lotus Labs has revealed a multi-year campaign aimed at vulnerable small home/small office (SOHO) routers.




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Free White Paper: OSHA Walking-Working Surfaces Rules

In this new white paper, J. J. Keller’s safety and regulatory experts address common questions they’ve received about ladders, stairs, pits, and platforms to help readers clearly understand how to protect workers and stay in compliance.




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‘Big impact’: OSHA aims to issue final rule on walking/working surfaces in August

Washington – OSHA’s final rule on preventing slips, trips and falls is scheduled for publication in August, according to the spring regulatory agenda released May 18.




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Surface-mount LED lamps

Fusion GloLight Six-Inch Oval Multi-Function Surface-Mount LED Lamps not only employ GloLight optical technology, but also are available with a unique reflective safety bezel for commercial vehicles that need a higher level of conspicuity.




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The push for a 4-day workweek resurfaces in Congress

Washington — Two senators have reintroduced a bill to establish the 32-hour workweek as an American standard.




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Is the surface of your smartphone hosting allergens and asthma triggers?

If you have allergies or asthma, clean your smartphone more often to minimize reaction triggers that may be lurking on the surface, researchers recommend in a recent study.




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OSHA’s standard on walking-working surfaces

What is the OSHA standard on walking-working surfaces for general industry (1910 Subpart D) and why is it important to the safety of workers?




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White House reviewing MSHA rule on surface mobile equipment safety

Washington — A Mine Safety and Health Administration final rule that would require mine operators to have a written safety program for mobile and powered haulage equipment is a step closer to publication.




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ECOsurfaces Introduces New Sustainable Desert & River Flooring Line

The new ECOsurfaces Desert & River commercial flooring line from Ecore, a company that transforms reclaimed materials into high-performance products that make people’s lives better, offers the architect and design community an innovative solution that fuses aesthetics and sustainability with ergonomics, acoustics and safety.




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AHF Products: A One-Stop Shop for Hard Surface Commercial Flooring

At NeoCon 2024, Floor Trends & Installation met up with AHF Products Chief Commercial Officer Jennifer Zimmerman and Vice President of Commercial Fred Reitz to learn more about the company’s commercial channel strategy, incorporating AHF Contract, Armstrong Flooring, Crossville Tile and Parterre brands.




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The Dixie Group Names Mike Johnson VP Hard Surfaces

In this role, Johnson will lead hard surface product innovation, marketing, and strategic direction.




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Karastan Expands Hard and Soft Surface Collections for 2024

Karastan's updates include its BelleLuxe Waterproof and LuxeCraft hard surface lines, as well as new soft surface options across the brand’s wool, SmartStrand and XTRA collections.




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Transom Capital Group Launches Artivo Surfaces, Uniting Virginia Tile and Galleher Under New Brand

In a move to reshape flooring distribution, Transom Capital Group has announced the formation of Artivo Surfaces, a new parent company that brings together distributors Virginia Tile and Galleher. This strategic consolidation creates a multi-regional powerhouse with 48 locations across 18 states, offering an extensive range of flooring solutions from coast to coast. 




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Stiles Machinery to Showcase Line of Hardwood Surface Solutions at International Woodworking Fair

Stiles Machinery will showcase surface solutions, such as sanding, veneering, and finishing at the International Woodworking Fair (IWF) in booth 4835 in Hall B, located at the Georgia World Congress Center in Atlanta, Georgia, from August 6 – 9, 2024.




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Industry Veteran Paul Dominie Launches Onn Surfaces, Offering Tailored Hard Surface Flooring Solutions

Industry veteran Paul Dominie has launched a new brand, Onn Surfaces, which provides timeless hard surfaces, including engineered hardwood, laminate, luxury vinyl plank, and glue-down luxury vinyl flooring.




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Multifamily Supplier Urban Surfaces Celebrates 5 Years with i4F Drop-Lock Technology, Expands Commitment

Multifamily flooring supplier Urban Surfaces uses i4F technologies to ensure high-quality flooring installations. 




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Ecore EcoSurfaces Rx Line Introduces AssurGrip Rx Resilient Vinyl Flooring

AssurGrip Rx vinyl flooring provides support and safety for commercial surfaces. 




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Transom Capital-backed Artivo Surfaces Acquires Tom Duffy Company, Deal Expands Artivo’s Brand Portfolio and National Reach

Artivo Surfaces, the Transom Capital-backed parent company of Virginia Tile, Galleher, and Trinity Hardwood, is acquiring Tom Duffy Company, a strategic move that significantly strengthens Artivo’s position as a market leader in the tile and flooring industry.




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Why choose phones with antibacterial surfaces?

In recent times, there has been a greater focus on hygiene in the workplace, likely spurred on by the COVID pandemic. While some germs are completely harmless, others can cause unpleasant illnesses. The chances of a germ surviving largely depends on the type of species, the surface where it is present, and other factors such as ambient temperature or solar radiation.





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Morphological control for hollow rod crystals of a photochromic di­aryl­ethene on spherulites by surface properties of substrates

1,2-Bis(3,5-di­methyl-2-thienyl)perfluoro­cyclo­pentene formed its own spherulites by sublimation onto the hydro­philic surfaces of the (0001) planes of α-quartz and sapphire substrates. The formation of different morphologies of these spherulites was attributed to the surface properties of each substrate. Depending on the morphology of the spherulites, hollow rod crystals with cross sections of different sizes and shapes and branching structures were generated on the surfaces of the spherulites.




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Morphological control for hollow rod crystals of a photochromic diarylethene on spherulites by surface properties of substrates

Sublimation methods utilizing the surface properties of substrates can address the challenge of controlling hollow morphologies in rod crystals. Spherulites were formed on the hydrophilic surface of the (0001) planes of α-quartz and sapphire substrates by sublimation of 1,2-bis(3,5-dimethyl-2-thienyl)perfluorocyclopentene (1a). Various types of hollow morphologies, distinguished by the size and shape of their cross sections and by the presence or absence of branching structures, were formed separately on α-quartz and sapphire substrates. Such precise control of the hollow morphologies was attributed to the wettability of each substrate, leading to the formation of spherulites of 1a. In addition, it was indicated that the formation process of the surface morphologies of spherulites was associated with the hollow morphologies of rod crystals of 1a.




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Crystal structure and Hirshfeld surface analysis of bis­(benzoyl­acetonato)(ethanol)dioxidouranium(VI)

In the complex, the ligand binds to the metal through an oxygen atom. The geometry of the seven-coordinate U atom is penta­gonal bipyramidal, with the uranyl O atoms in apical positions.




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Crystal structure and Hirshfeld-surface analysis of an etoxazole metabolite designated R13

The crystal structure of a metabolite of the insecticide/acaricide etoxazole, designated R13 is presented along with a Hirshfeld surface analysis of inter­molecular inter­actions present in the crystal structure.