ea Liverpool goes top of Premier League as Man City’s 32-game unbeaten streak ends at Bournemouth By www.thehindu.com Published On :: Sun, 03 Nov 2024 04:51:00 +0530 Manchester City’s 32-game unbeaten streak in the Premier League has ended in a 2-1 loss at Bournemouth as Liverpool wrested back the lead in the title race Full Article Football
ea Man United makes its worst league start in almost 40 years after 1-1 draw with Chelsea By www.thehindu.com Published On :: Mon, 04 Nov 2024 08:38:12 +0530 Moises Caicedo’s stunning long-range volley has secured a 1-1 draw for Chelsea against Manchester United in the Premier League Full Article Football
ea Neymar picks up another injury in second game back from ACL tear By www.thehindu.com Published On :: Tue, 05 Nov 2024 05:33:00 +0530 Neymar has time to recover before his next game, however, as he is not registered for the team’s matches in the Saudi Pro League and the next fixture in the AFC competition is on Nov. 25. Full Article Football
ea Real Madrid, Manchester City humiliated in Champions League; Liverpool enjoys Alonso’s return By www.thehindu.com Published On :: Wed, 06 Nov 2024 09:50:52 +0530 Defending champion Madrid was humbled 3-1 at home by AC Milan; City lost 4-1 at Sporting Lisbon Full Article Football
ea Blasters keen to learn from negatives and move on By www.thehindu.com Published On :: Wed, 06 Nov 2024 17:16:52 +0530 Full Article Football
ea Barcelona, Inter and upstart Brest win again in Champions League; bizarre penalty dooms Aston Villa By www.thehindu.com Published On :: Thu, 07 Nov 2024 10:48:38 +0530 Barcelona and Inter Milan lead Champions League standings, with Brest as a surprising newcomer in contention Full Article Football
ea Ancelotti calls for Real Madrid’s positive reaction after consecutive losses By www.thehindu.com Published On :: Fri, 08 Nov 2024 19:00:36 +0530 Ancelotti's side sit second in the league standings with 24 points from 11 matches, nine points behind leaders Barcelona, who have played a game more Full Article Football
ea Bullion cues: Gold uptrend steady By www.thehindubusinessline.com Published On :: Sat, 30 Mar 2024 18:07:48 +0530 Silver expected to catch up Full Article Derivatives
ea Jewellery retailers fear a lacklustre Akshaya Tritiya this year due to soaring gold prices By www.thehindubusinessline.com Published On :: Fri, 12 Apr 2024 20:55:10 +0530 Akshaya Tritiya, which falls on May 10 this year, is considered auspicious to buy gold Full Article Gold & Silver
ea Dip in gold prices ahead of Akshaya Tritiya to boost demand By www.thehindubusinessline.com Published On :: Tue, 23 Apr 2024 19:10:45 +0530 Lingering global uncertainty may boost prices again Full Article Gold & Silver
ea RBI’s gold holding increases by 27.46 metric tonnes in FY24, reaching 822.10 metric tonnes mark By www.thehindubusinessline.com Published On :: Tue, 14 May 2024 08:07:57 +0530 The report noted that the ratio of short-term debt to reserves has decreased, and foreign exchange reserves covering imports have increased to 11 months Full Article Gold & Silver
ea Gold outperforms Nifty 50 over 2-year and 5-year periods By www.thehindubusinessline.com Published On :: Wed, 22 May 2024 19:08:16 +0530 Data from PMS Bazaar indicates that from FY22-24, MCX Gold returned 14.05%, outperforming the Nifty’s 13.1% Full Article Markets
ea Silver likely to rule at higher levels this year on supply deficit By www.thehindubusinessline.com Published On :: Thu, 23 May 2024 09:00:00 +0530 Supply shortage forecast to increase by 17% even as industrial demand is projected to rise 9% Full Article Gold & Silver
ea Investor interest surges as ₹27,000 crore of Sovereign Gold Bonds purchased in FY24, reveals RBI report By www.thehindubusinessline.com Published On :: Fri, 31 May 2024 09:18:45 +0530 The surge in investments can be attributed to the prospects of higher returns, tax benefits, and the bonds’ exemption from capital gains tax. Full Article Gold & Silver
ea Gold steadies after slide below key $2,300 level By www.thehindubusinessline.com Published On :: Mon, 10 Jun 2024 09:53:22 +0530 Spot gold was up 0.2% at $2,396.69 per ounce, as of 0146 GMT. U.S. gold futures fell 0.5% to $2,313.60 Full Article Gold & Silver
ea After dipping 5% from peak, gold likely to decline further By www.thehindubusinessline.com Published On :: Tue, 11 Jun 2024 18:45:11 +0530 The yellow metal set to lose its glitter on China pausing gold buys, US strong labour market Full Article Gold & Silver
ea Gold rush grips Asia despite near-record prices By www.thehindubusinessline.com Published On :: Wed, 12 Jun 2024 09:45:46 +0530 Gold demand has also been boosted due to lower confidence in other investment options, such as real estate and equities, analysts say Full Article Gold & Silver
ea Bonds, stocks and gold beat Bitcoin as doubts gather over crypto rebound By www.thehindubusinessline.com Published On :: Fri, 14 Jun 2024 13:09:20 +0530 Bitcoin lags behind bonds, stocks and gold, signaling a possible slowdown in the crypto market Full Article Crypto Currency
ea Tamil Nadu’s mineral exploration projects for gold, rare-earth elements approved By www.thehindubusinessline.com Published On :: Fri, 21 Jun 2024 18:57:39 +0530 The state has seen an increase in mineral revenue, with plans to explore new deposits through agencies like the Geological Survey of India. Full Article Gold & Silver
ea Gold eases, investors seek more cues on US Fed's rate path By www.thehindubusinessline.com Published On :: Mon, 15 Jul 2024 09:34:51 +0530 UIS dollar rose on safety bids after an attempted assassination of former US President Donald Trump, which raised his odds of winning Full Article Gold & Silver
ea Gold hits all-time high in August as import duties drop and USD weakens By www.thehindubusinessline.com Published On :: Sat, 07 Sep 2024 19:48:32 +0530 The rise was primarily driven by a drop in the US dollar and lower 10-year Treasury yields due to potential Federal Reserve rate cuts. Full Article Gold & Silver
ea Bullion Cues: Gold set to break out By www.thehindubusinessline.com Published On :: Sat, 21 Sep 2024 17:39:15 +0530 Silver probing a barrier Full Article Derivatives
ea Gold steadies after Iran strikes spark surge of haven buying By www.thehindubusinessline.com Published On :: Wed, 02 Oct 2024 09:24:12 +0530 Gold has rallied nearly 30 per cent this year, hitting a series of record highs. Full Article Gold & Silver
ea Bullion Cues: No threat for the bulls By www.thehindubusinessline.com Published On :: Sat, 05 Oct 2024 19:03:05 +0530 Traders can retain the longs Full Article Derivatives
ea Gold hits near record levels, silver follows suit amidst rising demand By www.thehindubusinessline.com Published On :: Fri, 11 Oct 2024 19:41:01 +0530 Gold prices surged by ₹1,150 to ₹78,500 per 10 grams, while silver prices rose by ₹1,500 to reach ₹93,000 per kg Full Article Gold & Silver
ea 65% of millennials prefer digital gold over traditional for its ease of access and convenience: Moneyview survey By www.thehindubusinessline.com Published On :: Wed, 16 Oct 2024 19:33:09 +0530 Digital gold can be easily converted to cash or physical gold, giving investors flexibility to trade without incurring heavy transaction costs or delays Full Article Gold & Silver
ea Gold prices hit record highs, affecting demand during festival season By www.thehindubusinessline.com Published On :: Sat, 19 Oct 2024 16:45:26 +0530 Gold jewellery demand this Dhanteras is expected to be subdued due to a 5% surge in bullion prices, now at ₹77,410 per 10 grams Full Article Gold & Silver
ea Bullion Cues: Breaks out afresh By www.thehindubusinessline.com Published On :: Sat, 19 Oct 2024 19:37:38 +0530 Retain the long positions Full Article Derivatives
ea RBI steadily building up gold reserves By www.thehindubusinessline.com Published On :: Tue, 29 Oct 2024 20:20:42 +0530 The RBI held about 60 per cent of its gold reserves in safe custody in India as at September-end 2024 against about 50 per cent as at March-end 2024 Full Article Economy
ea Bullion Cues: Roadblock ahead By www.thehindubusinessline.com Published On :: Sat, 02 Nov 2024 17:37:26 +0530 Traders wait for a breakout Full Article Derivatives
ea Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Rhenium(I) and technetium(I) complexes with megazol derivatives: towards the development of a theranostic platform for Chagas disease By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02714K, PaperAna Cristina Resende Gonçalves, Silvia Helena Libardi, Júlio Cesar Borges, Ronaldo Junio de Oliveira, Carla Gotzmann, Olivier Blacque, Sergio Albuquerque, Carla Duque Lopes, Roger Alberto, Pedro Ivo da Silva MaiaThe diagnosis and treatment of Chagas disease (CD) in the chronic phase remains a challenge. With that in mind, a potential theranostic device based on the trypanocidal agent known as...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02690J, CommunicationAlexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di SunFirst metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Triple-shelled Ni@MnO/C hollow spheres with enhanced performance for rechargeable zinc-ion capacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02303J, PaperTao Xiang, Zaiting Qu, Daohong Zhang, Chenglong Hu, Zhen Chen, Qiufan WangNi/MnO@C nanospheres with different core–shell structures are obtained by using Ni3Mn-MOFs as templates, exhibiting excellent electrochemical properties as cathodes in zinc-ion storage.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Heteroleptic mononuclear Cu(I) halide complexes containing carbazolyl substituted phenyl diphosphine and monophosphine: structures and photophysical and electroluminescent properties By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02469A, PaperZhun Chen, Wei Xu, Ruiqin Zhu, Li Liu, Xin-Xin Zhong, Fa-Bao Li, Guijiang Zhou, Hai-Mei QinHeteroleptic mononuclear Cu(I) halide complex 4 containing carbazolyl groups in diphosphine and monophosphine shows high PLQY (0.75) and a short decay lifetime (1.9 μs) with a high kr value of 3.95 × 105 s−1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02467B, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank VanhaeckeThis study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02734E, PaperHui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang TangA biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3 By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02606C, PaperIan DanceI describe how nitrogenase catalyses N2 → HNNH → HNNH2 → NH3 + NH and how the calculated dynamics explain recent kinetics data.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02958E, PaperJanak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika KhullarThe development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea The Bonding Situations in Ruthenium Chalcogenonitrosyl Compounds: A Physical Reasoning By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02680B, PaperRichard Fragnani Cardoso, Vinícius Acir Glitz, Renato Luis Tame Parreira, Giovanni Finoto Caramori, Luis Henrique Silveira LacerdaThis research presents, for the first time, a comprehensive and rigorous investigation of ruthenium(II) chalcogenonitrosyl bonding situations in two sets of coordination compounds: [Ru(NE)Cl2(L_{OEt})] (1a-4a) and [Ru(NE)Cl2(L_{OEt})]- (1b-4b), where E...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02721C, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias WesterhausenThe diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Accelerating the reaction kinetics of Ni1−xO/Ni(OH)2/NF by defect engineering for urea-assisted water splitting By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02871F, PaperYuan Rui, Zong Li, Miaohui Wang, Yunxia Liu, Haiping Lin, Peipei Huang, Qing LiThe reaction kinetics of Ni1-xO/Ni(OH)2/NF are accelerated through a defect engineering strategy by combining Zn doping and acid etching, leading to improved intrinsic activities for UOR.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02514H, PaperKhalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique LorcyMultinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Influence of weakly coordinating anions binding to the hexa-tert-butyl dysprosocenium cation By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02713B, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sophie C. Corner, Gemma K. Gransbury, David P. MillsWe present the synthesis and characterisation of two dysprosium metallocene complexes with bound weakly coordinating anions. Despite their similarity these complexes exhibit vastly different effective energy barriers to magnetic reversal.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea β-Cyclodextrin and cucurbit[7]uril as protective encapsulation agents of the CO-releasing molecule [CpMo(CO)3Me] By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT01863J, PaperRodrigo P. Monteiro, Isabel B. Calhau, Ana C. Gomes, André D. Lopes, José P. Da Silva, Isabel S. Gonçalves, Martyn PillingerFor inclusion compounds between the complex [CpMo(CO)3Me] (1) and β-cyclodextrin or cucurbit[7]uril, the macrocyclic hosts modulate to different degrees the UV light-mediated CO release from encapsulated 1.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17819-17828DOI: 10.1039/D4DT01625D, PaperSonghan Hu, Kai Wang, Xinxin Xu, Qiang WangTwo Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Effect of mono- and dinuclear thiosemicarbazone platinacycles in the proliferation of a colorectal carcinoma cell line By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17803-17818DOI: 10.1039/D4DT01490A, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Francisco Reigosa-Chamorro, Sandra Cordeiro, M. Teresa Pereira, Beatriz Filipe, Pedro V. Baptista, Alexandra R. Fernandes, José M. VilaThe study of the antiproliferative activity of thiosemicarbazone platinacycles puts forward their high selectivity and low IC50 values.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17756-17765DOI: 10.1039/D4DT01868K, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozary, Claude PiguetEfficient and easy lanthanide(III)-based luminescence reading of iron(II) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
