ea Neutral mononuclear indium(III) photosensitizers for CO2 photoreduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17772-17776DOI: 10.1039/D4DT02595D, CommunicationZaichao Zhang, Li-Zhi Fu, Piao He, Xiao-Yi YiNeutral mononuclear indium(III) complexes (In-1–In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligands are employed as photosensitizers in photocatalytic CO2 reduction.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18013-18020DOI: 10.1039/D4DT02533D, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. NolanDespite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17789-17793DOI: 10.1039/D4DT02791D, CommunicationGargi Kundu, Debjit Pramanik, Soumya Ranjan Dash, Ravi Kumar, Mayur Sangole, Srinu Tothadi, Aryya Ghosh, Kumar Vanka, Kirandeep Singh, Sakya S. SenThe reduction of octafluoronapthalene by cobaltocene in preence of NHC led to a distinct Co(I) species with the cleavage of the C–F bond and the formation of Co–C bond.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea A mechanistic study of chiral manganese porphyrin-catalyzed enantioselective C–H hydroxylation reaction By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02452D, PaperJing-Kun Gao, Wandong Chen, Junjie Tai, Zhengwei Chen, Hang Liu, Yuxin Du, Yiting Jiang, Yuanbin She, Yun-Fang YangThis study uses DFT to explain the enantioselectivity of C–H hydroxylation by a chiral manganese porphyrin. A two-point hydrogen bonding favors pro-(S) C–H bond abstraction by 1.9 kcal mol−1, leading to (S)-hydroxylated products.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02589J, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef HolubThe objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02838D, PaperYiwen Guan, Xian Xu, Xin XuAn FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02420F, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yohei Kametani, Yoshihito ShiotaMechanistic analysis of nitrite (NO2−) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02508C, PaperJustin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van StipdonkA series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02652G, CommunicationYue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng ChengIsomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ea Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit By Published On :: Wednesday, March 30, 2022, 13:23 +0530 The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam. Full Article
ea Virtual reality By www.thehindubusinessline.com Published On :: Wed, 05 Jun 2013 12:22:22 +0530 Full Article S Madhavan
ea Virtual to real By www.thehindubusinessline.com Published On :: Fri, 02 Aug 2013 17:25:20 +0530 Full Article S Madhavan
ea Achieving gender parity is still a dream By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:03:00 +0530 Antiquated stereotypes about the roles and responsibilities of women are a pain Full Article Open Page
ea Learning languages By www.thehindu.com Published On :: Sun, 22 Sep 2024 02:10:00 +0530 Are our practices and actions pushing children away from languages? Full Article Open Page
ea The heart of the matter By www.thehindu.com Published On :: Sun, 29 Sep 2024 03:25:00 +0530 On World Heart Day, September 29, random thoughts on keeping the ticker ticking Full Article Open Page
ea An ode to teachers By www.thehindu.com Published On :: Sun, 06 Oct 2024 01:39:06 +0530 Teachers must strike the right balance to foster inclusivity and bridge the cultural, linguistic and learning gaps Full Article Open Page
ea Making sense of death By www.thehindu.com Published On :: Sun, 06 Oct 2024 03:05:12 +0530 Untimely death is scary because it may shatter the lives of the living Full Article Open Page
ea Self-care is the best healing By www.thehindu.com Published On :: Sun, 20 Oct 2024 02:35:00 +0530 Work on building your network, wear a smile and genuinely thank those who assist in your daily work Full Article Open Page
ea Permeating partiarchy By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:05:00 +0530 It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family Full Article Open Page
ea Real is rational and rational is real By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:55:00 +0530 They may seem inextricably intertwined, but their relationship is a complex interplay of a myriad forces Full Article Open Page
ea Learning it the hard way By www.thehindu.com Published On :: Sun, 27 Oct 2024 01:48:00 +0530 How a simple fix was given the go-by and how it led to worries Full Article Open Page
ea Book of the Year 2017 By physicsworld.com Published On :: 2017-12-13T14:42:08Z Physics World book experts Matin Durrani and Tushna Commissariat discuss the themes and trends that surround some of the best popular-physics books of 2017, before announcing the winner of our annual book award Full Article
ea D’Cunha report on COVID ‘scam’ adds more heat to bypoll campaign By www.thehindu.com Published On :: Sat, 09 Nov 2024 23:45:20 +0530 While Yediyurappa denied the allegation and called it ‘politically motivated’, Chief Minister Siddaramaiah, quoting The Hindu report, said it vindicated their earlier stand Full Article Karnataka
ea Heavy fog affects 21 flights at Kempegowda International Airport in Devanahalli in Bengaluru By www.thehindu.com Published On :: Sun, 10 Nov 2024 09:46:15 +0530 There were more than 15 delays, and six flights diverted Full Article Bengaluru
ea Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 17:22:47 +0530 Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy Full Article Karnataka
ea Karnataka makes online applications mandatory for private aided school teacher recruitment By www.thehindu.com Published On :: Sun, 10 Nov 2024 18:03:16 +0530 DSEL has developed a separate app to conduct aided schools teachers’ recruitment transparently Full Article Karnataka
ea BJP made money from heaps of dead bodies during COVID-19, claims Dinesh Gundu Rao By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ea Woman and her associates booked for cheating homemakers in Bengaluru By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:56:42 +0530 Full Article Karnataka
ea Tunga Aarati held in Shivamogga as part of campaign to clean river Tungabhadra By www.thehindu.com Published On :: Mon, 11 Nov 2024 13:23:18 +0530 Shivamogga MLA S.N. Channabasappa appreciated the efforts of people and students involved in the padayatra from Sringeri to Harihar as part of a campaign to keep the river clean Full Article Karnataka
ea Activists demand that govt. grant land to landless, instead of encroachers on contract By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:02:51 +0530 They also urged the State government to recover the hundreds of acres of land encroached upon by private company estates in the Malnad region Full Article Karnataka
ea All roads lead to Channapatna on last day of public campaign By www.thehindu.com Published On :: Mon, 11 Nov 2024 22:29:29 +0530 Full Article Karnataka
ea Karnataka High Court directs Chief Secretary to form panel to examine plea for declaring Allama Prabhu Swamy temple as ancient monument By www.thehindu.com Published On :: Mon, 11 Nov 2024 22:47:38 +0530 The temple is submerged in the backwaters of Hidkal dam in Belagavi district for nearly six months in a year Full Article Karnataka
ea Karnataka School Examination and Assessment Board directs students from unauthorised schools not to register for SSLC exam this year By www.thehindu.com Published On :: Mon, 11 Nov 2024 23:28:30 +0530 Full Article Karnataka
ea Music is a great unifying and connecting factor even today, says Nagaraj Rao Havaldar By www.thehindu.com Published On :: Tue, 12 Nov 2024 09:00:00 +0530 Bengaluru-based musician Dr. Nagaraj Rao Havaldar recently presented a lecture-demonstration highlighting Karnataka’s unique status as a state that has nurtured stalwarts in both Hindustani and Carnatic traditions Full Article Karnataka
ea Kalaburagi: Man sentenced to 20 years of imprisonment for sexually assaulting minor girl By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:17:32 +0530 Full Article Karnataka
ea Sandur bypolls: Ballari Deputy Commissioner appeals to voters to exercise franchise By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:36:30 +0530 Full Article Karnataka
ea Farmers in Yadgir district sow groundnut as major crop for rabi season By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:50:22 +0530 Full Article Karnataka
ea Hearing impaired get free BTE aids at AIISH By www.thehindu.com Published On :: Tue, 12 Nov 2024 20:57:18 +0530 The premier speech and hearing institute in Mysuru collaborates with a Telangana-based NGO to provide hearing aids to the needy among the BPL families Full Article Karnataka
ea D’Cunha report revealed ₹918 crore misappropriated in COVID equipment procurement: Sharan Prakash Patil By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:01:16 +0530 Full Article Karnataka
ea PIX: United log first Europa League win By www.rediff.com Published On :: The win leaves United in 15th place in the Europa League standings on six points from four games. Full Article
ea Vinicius 'tricks' Real Madrid to win! By www.rediff.com Published On :: Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions. Full Article
ea PIX: Real Sociedad shock Barcelona By www.rediff.com Published On :: Barcelona suffered a shock 1-0 LaLiga defeat at Real Sociedad on Sunday that ended their seven-match winning streak in all competitions. Full Article
ea Fringe of the fringe : queering punk media history / edited by Kathrin Dreckmann, Elfi Vomberg, Linnea Semmerling. By darius.uleth.ca Published On :: Berlin : Hatje Cantz, [2023] Full Article
ea Circuit breaking [electronic resource] : using neuroscience-informed psychotherapy to treat psychoactive substance abuse / Robert Youdin. By darius.uleth.ca Published On :: New York, NY : Oxford University Press , 2024. Full Article
ea The effects of COVID-19 on early childhood education [electronic resource] : research and implications / by Raquel Plotka and Ruth Guirguis. By darius.uleth.ca Published On :: [Bradford/] : Ethics International Press Ltd, 2024. Full Article
ea The neuroscience of psychotherapy [electronic resource] : healing the social brain / Louis J. Cozolino By darius.uleth.ca Published On :: [New York] : W. W. Norton & Company, Incorporated, 2024. Full Article
ea Sacred cow, mad cow : a history of food fears / Madeleine Ferrières ; translated by Jody Gladding By darius.uleth.ca Published On :: New York : Columbia University Press, c2006 Full Article
ea Pandemonium : bird flu, mad cow disease, and other biological plagues of the 21st century / Andrew Nikiforuk By darius.uleth.ca Published On :: Toronto : Viking Canada ; New York, NY : Penguin Group (USA), 2006 Full Article
ea Why people smoke [electronic resource] : an innovative approach to treating tobacco dependence / Frank T. Leone and Sarah Evers-Casey ; with illustrations by Joey Leone. By darius.uleth.ca Published On :: Philadelphia : University of Pennsylvania Press, [2023] Full Article
