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Guanidine modification improves functions of natural RNA-targeting alkaloids

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05833F, Communication
Open Access
Tamaki Endoh, Sagar Satpathi, Yutong Chen, Saki Matsumoto, Tatsuya Ohyama, Peter Podbevšek, Janez Plavec, Kazumitsu Onizuka, Fumi Nagatsugi, Naoki Sugimoto
Guanidine modification on berberine improved RNA binding affinity and enhanced suppression of protein expression.
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Effect of Functionalized Multiwalled Carbon Nanotubes on Mechanical, Swelling and Viscoelastic Properties on Gum ghatti-cl-poly(NIPAm) Hydrogels

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01677G, Paper
Pragnesh N Dave, Pradip Macwan
The present work involves the Gum ghatti-cl-poly(NIPAm)/-o-MWCNT (GGNIPACNT) hydrogels via free radical polymerization technique. The synthesized hydrogels were characterized by FTIR analysis which suggested the successful binding of -o-MWCNT in...
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Compare Mode in Google AI Studio: Your Companion for Choosing the Right Gemini Model

Compare Mode is a powerful new feature designed to help you make informed decisions about which Gemini model best suits your needs.




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Mentalist Suhani Shah is all set to mesmerise Bangaloreans

Suhani Shah, said to be India’s first female mentalist, will be performing in Bengaluru this weekend as part of her silver jubilee celebrations in the field of magic




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Magnetically recyclable nanophotocatalysts in photocatalysis-involving processes for organic pollutant removal from wastewater: current status and perspectives

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00906H, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zexiao Zheng, Juhua He, Zuyao Zhang, Ashutosh Kumar, Musharib Khan, Cheuk Wai Lung, Irene M. C. Lo
The critical review covers the applications, associated mechanisms, challenges, and prospects of magnetically recyclable nanophotocatalysts in photocatalysis-related processes.
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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Integrated microfluidic-based ultrafine water condensation particle counter (UWCPC) for monitoring of airborne nanoparticle generation and growth mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00686G, Paper
Seong-Jae Yoo, Yong-Jun Kim
This study reports a newly developed condensation particle counter for nanoparticle source tracking, growth mechanism analysis, and wide area nanoparticle monitoring.
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Regulating water decontamination and food safety by a reusable, nano-sized MOF@cotton@chitosan composite through nanomolar detection of the drug nitroxinil and organoarsenic feed additive p-arsanilic acid

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00066H, Paper
Subhrajyoti Ghosh, Debjit Mal, Shyam Biswas
MOF@cotton@chitosan composite for nanomolar fluorescence sensing of nitroxinil drug and p-arsanilic acid in real samples is presented.
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The pulmonary effects of nickel-containing nanoparticles: cytotoxicity, genotoxicity, carcinogenicity, and their underlying mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00929G, Critical Review
Yiqun Mo, Yue Zhang, Qunwei Zhang
This review summarized the cytotoxic, genotoxic, and carcinogenic effects of Ni-containing NPs on humans, lung cells in vitro, and rodent lungs in vivo, and the underlying mechanisms. Their extra-pulmonary effects were also briefly mentioned.
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Purification of As(III) through oxidation of siderite and As(III) by dissolved oxygen: behavior and mechanism

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00974B, Paper
Wenting Yu, Zhipeng Gao, Huaming Guo
Siderite oxidation can be achieved with dissolved oxygen (DO), which would control the oxidation and the fate of As(III), but the interaction mechanism between siderite and As(III) with the presence of DO needs more investigation.
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Mechanistic approaches for crosstalk between nanomaterials and plants: plant immunomodulation, defense, stress resilience, toxicity, and perspectives

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00053F, Paper
Ragini Singh, Pinky Choudhary, Santosh Kumar, Hemant Kumar Daima
Plants are confronted with unexpected and diverse environmental pressures in the era of climate change. Plant development and metabolism are significantly hindered by both abiotic and biotic stress, which leads...
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Interfacial catalytic degradation mechanism of n-hexane over polyhedral Co3O4 nanocatalysts derived from topotactic condensation of ZIF-67

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00101J, Paper
Yunlong Guo, Meicheng Wen, Guiying Li, Jiejing Kong, Shengnan Song, Qiuxia Liu, Taicheng An
A progressive transition from the L–H model to MvK model is observed, where a polyhedral Co3O4 nanocatalyst enabled by topotactic condensation of ZIF-67 is synthesized for catalytic degradation of n-hexane.
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Interaction of disposable face mask (nano)microplastics with antibiotics: performance and mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00775H, Paper
Ting Zhang, Xi Chen, Angrui Jiang, Jingfan Qi, Zhaoyang You, Kinjal J. Shah
The adsorption of ciprofloxacin (CIP), sulfamethoxazole (SMX) and tetracycline (TC) on disposable face mask (nano-)microplastics occurs in the order SMX > CIP > TC, which correlates with the octanol–water partition coefficient of antibiotics.
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High-efficiency removal of Cd(II) and As(III) from irrigation water using a S–Fe–C composite: performance and mechanisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00863K, Paper
Zihao Liang, Yanpeng Liang, Hua Lin, Yuxi Lu, Huawei Li, Jie Zhang, Honghu Zeng, Gongning Chen
SFC showcased exceptional Cd(II) and As(III) removal capacities of 405 mg g−1 and 349 mg g−1, respectively, while preserving magnetic recovery properties after repeated adsorption cycles, making it an environmentally sustainable functional material.
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Mycogenic silver nanoparticles from Penicillium citrinum IB-CLP11 – their antimicrobial activity and potential toxicity effects on freshwater organisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper
Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Mechanistic description of lead sorption onto nanoplastics

Environ. Sci.: Nano, 2024, 11,1671-1681
DOI: 10.1039/D3EN00677H, Paper
Florent Blancho, Mélanie Davranche, Adrien Léon, Rémi Marsac, Stéphanie Reynauld, Bruno Grassl, Julien Gigault
Although it is currently recognized that nanoplastics (NPs) are present in the environment, their ability to carry metals or other contaminants and the processes involved are still poorly investigated.
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Mixing mechanisms of lead nanoparticles with mineral particles: implication of atmospheric transportation of lead

Environ. Sci.: Nano, 2024, 11,1452-1461
DOI: 10.1039/D3EN00805C, Paper
Yongpeng Ji, Qiuju Shi, Baocong Zhao, Ziqi Wu, Jiaxin Wang, Weina Zhang, Jiangyao Chen, Yuemeng Ji, Taicheng An
Lead nanoparticles rapidly mix with sand and dust (SD) particles to form mixed particles during SD storms period and have significant potential to be transported by SD particles in atmosphere.
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Co-transport of ferrihydrite–organic matter colloids with Sb(V) in saturated porous media: implications for antimony mobility

Environ. Sci.: Nano, 2024, 11,1462-1476
DOI: 10.1039/D3EN00701D, Paper
Wenjian Mao, Dengjun Wang, Pan Wu, Jian Zhu, Peng Liao, Kaidi Lai, Zihan Ding, Yuqin Zhang, Zhongxu He, Ruyi Zheng, Yonglin Chen
Schematic diagram of the mechanism of Fe–NOM–Sb(V) colloids formation and transport in the natural environment.
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Molecular mechanisms of dimethylarsinic acid adsorption onto aluminum substituted ferrihydrite surfaces

Environ. Sci.: Nano, 2024, 11,1713-1723
DOI: 10.1039/D3EN00664F, Paper
Yiting Ge, Jiaqi Wang, Fayang Guo, Meng Yuan, Wentao Wang, Jiangshan Li, Jing Zhang, Xionghan Feng, Wenfeng Tan, Yupeng Wu, Hui Yin
Aluminum substitution in ferrihydrite promotes the formation of monodentate mononuclear and outer-sphere complexes of dimethylarsinic acid on the mineral surfaces at the expense of bidentate binuclear complexes at pH 6.
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Composite materials based on halloysite clay nanotubes and cellulose from Posidonia oceanica sea balls: from films to geopolymers

Environ. Sci.: Nano, 2024, 11,1508-1520
DOI: 10.1039/D3EN00879G, Paper
Martina Maria Calvino, Giuseppe Cavallaro, Stefana Milioto, Giuseppe Lazzara
The combination of natural halloysite nanotubes and cellulose recovered from egagropili is effective to fabricate composite films and geopolymers promising for packaging and building applications, respectively.
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Crystallinity regulation induced organics degradation on Ultra-thin 2D Co3O4/SiO2 Nanosheets: the critical trigger of oxygen vacancy

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00134F, Paper
Wenhui Bai, Hongze Lu, Yang Liu, Xue Yuan, Yuejie Ai, Lidong Wang, Zhe Chen
As an antibiotic drug, sulfamethoxazole (SMX) is a nitrogen-containing and sulfur-containing heterocyclic compound, which is an endocrine disruptor and difficult to be biodegraded. Not only can it exist stably in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Macro- and micro-structural manifestation and engineering of large-size polycrystalline ZnSe

CrystEngComm, 2024, 26,1986-1993
DOI: 10.1039/D3CE01243C, Paper
Xiaobo Zhao, Cong Zhang, Zhengping Wang, Dazhi Lu, Haohai Yu, Huaijin Zhang
Polycrystalline ZnSe materials with sizes of 100 mm were grown by the CVD method, and their constitution structures and defects were investigated to analyze the influence of the preparation conditions on the optical transmission properties of the materials.
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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Crystallization behaviour and growth mechanisms of spinel crystals in vanadium slag with high MgO content

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00189C, Paper
Jiang Diao, Haoran Tao, Zhiqiu Lai, Yiyu Qiu, Lian Chen, Hongyi Li, Bing Xie
In this study, MgO content and FeO/SiO2 ratio were found to significantly increase the integrated crystallization rate of spinel phase in vanadium slag.
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Pure organic TPB single crystal for direct X-ray detection

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00200H, Paper
Kai Jiang, Lingyan Xu, Rongjin Shang, Lu Liang, Yingming Wang, Zhentao Qin, Wanqi Jie
High-quality TPB single crystals were obtained without obvious step-like growth morphology. The TPB devices could present α-particle and γ-ray spectral responses with high energy resolution, showing potential for direct radiation detection.
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Solvent-polarity-controlled assembly of polynuclear titanium-calixarene complexes: constructing isolated {Ti7}, {Ti13}, {Ti24} and {Tb2Ti13} clusters

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01275A, Paper
Yanyan Wang, Ying Xiong, Wuping Liao
The assembly of polynuclear titanium-calixarene complexes is based on Ti4–C8A SBUs.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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A highly stable hydrogen-bonded organic framework for hydrogen storage

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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Twitter applies temporary limit to address data scraping, system manipulation: Elon Musk

That comes after Twitter had announced that it will require users to have an account on the social media platform to view tweets.




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Musk sets tweet-viewing limits to combat data scraping from large AI companies

Temporary limits to address “extreme levels of data scraping and system manipulation”




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Dharavi set to get a ₹5,000-crore makeover from Adani group

Adani group pips DLF to bag Asia’s biggest slum redevelopment project




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Operating profit margin of 625 listed companies hits multi-year low

This, even as earnings jumped 27 per cent y-on-y, finds an ICRA study




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More than 5.57 lakh cos struck off due to non-compliance with companies law provisions

A special task force has recommended the use of certain red flag indicators as alerts to identify shell companies




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Paddy procurement to be expedited soon: G.R. Anil




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Munambam issue animates politics in the waning hours of bypoll campaign

Opposition is mindful that a rightward drift in traditionally pro-UDF Christian votes catalysed BJP’s win in the Thrissur Lok Sabha constituency. CPI(M) reckons that splitting minority votes on religious lines may benefit BJP




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Sexual harassment in public spaces and police patrols [electronic resource] : experimental evidence from urban India / Sofia Amaral, Girija Borker, Nathan Fiala, Anjani Kumar, Nishith Prakash, Maria Micaela Sviatschi

Cambridge, MA. : National Bureau of Economic Research, 2023




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How costs limit contraceptive use among low-income women in the U.S [electronic resource] .: a randomized control trial / Martha J. Bailey, Vanessa Wanner Lang, Alexa Prettyman, Iris Vrioni, Lea J. Bart, Daniel Eisenberg, Paula Fomby, Jennifer Barber, Van

Cambridge, MA. : National Bureau of Economic Research, 2023




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Elgar companion to Herbert Simon [electronic resource]/ edited by Gerd Gigerenzer (Herbert Simon Society; Max Planck Institute for Human Development, Berlin, Germany), Shabnam Mousavi (Center for Artificial Intelligence (CENTAI), Turin, Italy) and Riccar

Cheltenham, UK ; Northampton, Massachusetts : Edward Elgar Publishing, [2024]




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Maharashtra Assembly elections 2024: Ajit Pawar’s NCP releases poll manifesto, promises to raise Ladki Bahin scheme amount

For farmers, the Nationalist Congress Party promised to raise the Shetkari Sanman Nidhi scheme amount from ₹12,000 to ₹15,000 per year.




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Maharashtra Assembly elections 2024: Uddhav's Sena (UBT) releases manifesto; promises to scrap Dharavi project, provide free education

The party leader unveils Maharashtra Assembly polls manifesto with promises of free education, stable prices for essential items, and scrapping Dharavi project




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Shiv Sena (UBT)’s manifesto promises to scrap reservation cap, Adani’s Dharavi project

Uddhav Thackeray moots new housing policy, vows to scrap cluster development of Koliwadas till the consent of the fishing community is obtained; says joint MVA manifesto to be released by the weekend