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Diverse quantum interference regimes in intramolecular singlet fission chromophores with thiophene-based linkers

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, 15,17823-17830
DOI: 10.1039/D4SC03546A, Edge Article
Open Access
Jonghwan Lee, Sungsik Eom, Hyungjun Kim
This work explores intramolecular singlet fission chromophores having diverse thiophene-based linkers and highlights the relation between quantum interference and nonadiabatic coupling in the multiexciton formation step of singlet fission.
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Correction: Second-shell modulation on porphyrin-like Pt single atom catalysts for boosting oxygen reduction reaction

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC90219J, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tayyaba Najam, Syed Shoaib Ahmad Shah, Hanqing Yin, Xin Xiao, Shamraiz Talib, Qianqian Ji, Yonggui Deng, Muhammad Sufyan Javed, Jie Hu, Ruo Zhao, Aijun Du, Xingke Cai, Qiang Xu
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Real-time impedance-activated dielectrophoretic actuation for reconfigurable manipulation of single flowing particles

By pubs.rsc.org
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Lab Chip, 2024, 24,5145-5154
DOI: 10.1039/D4LC00622D, Paper
Alexis Lefevre, Cristian Brandi, Adele De Ninno, Filippo Ruggiero, Enrico Verona, Michaël Gauthier, Paolo Bisegna, Aude Bolopion, Federica Caselli
We present an original all-electrical platform that combines MIC-sensing and DEP-actuation for precise and selective trajectory control of single flowing particles.
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Quantifying platinum binding on protein-functionalized magnetic microparticles using single particle-ICP-TOF-MS

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Anal. Methods, 2024, Advance Article
DOI: 10.1039/D4AY00268G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Veronica C. Bradley, Benjamin T. Manard, Lyndsey Hendriks, Daniel R. Dunlap, Amber N. Bible, Ada Sedova, Patricia Saint-Vincent, Brian C. Sanders, Hunter B. Andrews
This work describes an analytical procedure, single particle-inductively coupled plasma-time-of-flight-mass spectrometry (SP-ICP-TOF-MS), that was developed to determine the platinum binding efficiency of protein-coated magnetic microparticles.
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Hydrogel-based 3D fabrication of multiple replicas with varying sizes and materials from a single template via iterative shrinking

By pubs.rsc.org
Published On ::

Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00835A, Paper
Eunseok Heo, Hye Been Koo, Jun Chang Yang, In Cho, Hyun-Hee Lee, Yong-Jin Yoon, Steve Park, Jae-Byum Chang
3D printing technologies have been widely used for the rapid prototyping of 3D structures, but their application in a broader context has been hampered by their low printing throughput. For...
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Magnetic colloidal single particles and dumbbells on a tilted washboard moir'e pattern in a precessing external field

By pubs.rsc.org
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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM01183J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Farzaneh Farrokhzad, Nico C. X. Stuhlmüller, Piotr Kuswik, Maciej Urbaniak, Feliks Stobiecki, Sapida Akhundzada, Arno Ehresmann, Daniel de las Heras, Thomas M. Fischer
We measure the dynamical behavior of colloidal singlets and dumbbells on an inclined magnetic moir'e pattern, subject to a precessing external homogeneous magnetic field. At low external field strength single...
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Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01600A, Research Article
Yongfeng Wang, Ruijun Chu, Yanxiao Wang, Mengyuan Zhou, Yuan Chen, Cheng Xu, Jingyu Sun, Guodong Yin
A novel class of heterocyclic AIEgens has been synthesized via a multicomponent reaction of isatins, 2,3-diaryl cyclopropenones, and alkyl bromides.
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Recent advances in carbon atom addition for ring-expanding single-atom skeletal editing

By pubs.rsc.org
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01806K, Review Article
Ting Yuan, Lei Shi
This review focuses on recent advances in carbon atom addition for ring-expanding single-atom skeletal editing.
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Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01714E, Research Article
Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
Transition-metal-free ring expansion of benzoisothiazol-3-ones has been established to construct various 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion.
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Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02467B, Paper
Open Access
Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank Vanhaecke
This study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.
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Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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Single-ion magnetism in novel Btp-based cobalt complexes of different charge

By pubs.rsc.org
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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02338B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gustavo Rama-Martínez, Marcelo Osorio-Celis, Yolanda Sabater-Algarra, Diego Sánchez-Brunete, Antonio L. Llamas-Saiz, Eugenia P. Quirós-Díez, M. Eugenio Vázquez, Miguel Vázquez López, María del Carmen Giménez López
By deprotonating Btp-derived ligands, precise control over counterions in the outer-coordination sphere is achieved in both neutral and charged anisotropic CoII complexes exhibiting field-induced single-ion magnetism.
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A comprehensive study on the physicochemical characteristics of faecal sludge from septic tank and single pit latrine facilities in a typical semi-urban Indian town: a case study of Rajasthan, India

By pubs.rsc.org
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Environ. Sci.: Water Res. Technol., 2024, 10,2906-2928
DOI: 10.1039/D4EW00127C, Paper
Open Access
Harishvar Jothinathan, Ajit Pratap Singh
Faecal sludge (FS) samples were analysed to assess their characteristics. FS has high chemical oxygen demand, ranging from 4406 to 160 000 mg l−1, influenced by sludge age, sanitation type, and inflow/outflow to onsite sanitation contaminants.
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Air India tweaks policy; ultra long haul flights’ cabin crew to get single rooms during layovers

By www.thehindu.com
Published On :: Sat, 26 Oct 2024 20:20:03 +0530

However, cabin crew members of ultra-long haul flights will get single rooms during layovers as well as during unscheduled layovers in the event of a flight diversion, as per the internal communication


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'As Long As There Is Single BJP MP or MLA..': Amit Shah Vows No Religion-Based Reservation For Muslims

By
Published On :: Sunday, November 10, 2024, 15:55 +0530

Maha Polls: Union Home Minister Shah said that a recent memorandum submitted by the Ulema Association to the Congress sought a 10 per cent reservation in jobs and education for the Muslim community but the BJP is against religion-based reservation.


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India's logistics cost will reduce to single-digit in 5 years: Gadkari

By www.thehindu.com
Published On :: Thu, 19 Sep 2024 19:51:14 +0530


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India’s logistics cost will come down to single-digit percentage in two years: Gadkari

By www.thehindu.com
Published On :: Thu, 17 Oct 2024 14:49:00 +0530

According to quick estimates of the economic think tank National Council of Applied Economic Research (NCAER), logistics costs in India ranged between 7.8% to 8.9% of GDP for the fiscal 2021-22


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Singles' Day shopping festival loses its shine under China's lagging economy

By www.thehindu.com
Published On :: Mon, 11 Nov 2024 12:03:08 +0530

The annual event named by the numeric form of its Nov. 11 date was started by e-commerce platform Alibaba, which offered attractive discounts to entice shoppers to spend big.


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IIT Madras gets largest single donation of ₹228 crore from Alumnus Krishna Chivukula

By www.thehindubusinessline.com
Published On :: Tue, 06 Aug 2024 19:09:17 +0530

Chivukula graduated with a M. Tech (Aerospace Engineering), majoring in Jet Propulsion in 1970 from IIT Madras. In addition, he received an MBA from The Harvard Business School in 1980


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Coordination environment-tailored electronic structure of single atomic copper sites for efficient electrochemical nitrate reduction toward ammonia

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, 17,8360-8367
DOI: 10.1039/D4EE02746A, Paper
Tianchi Huang, Taiyu Liang, Jiao You, Qihua Huo, Shuai Qi, Jingwen Zhao, Na Meng, Jinglian Liao, Chunyan Shang, Hengpan Yang, Qi Hu, Chuanxin He
A robust strategy is developed to finely tune the electronic structure of Cu by employing single atomic Cu–N–C via both first and second coordination shell engineering, thereby boosting the performance for the nitrate reduction reaction.
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Theoretical calculations-driven rational screening of d-block single-atom electrocatalysts based on d-p orbital hybridization for durable aqueous zinc-iodine batteries

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04119D, Paper
Jin Yang, Yuanhong Kang, Fanxiang Meng, weiwei meng, guanhong Chen, Minghao Zhang, Zeheng Lv, Zhipeng Wen, Chengchao Li, Jinbao Zhao, Yang Yang
Aqueous Zn−iodine (Zn-I2) batteries, featuring intrinsically high-safety aqueous electrolytes and eco-friendly cathode/anode materials, however are restricted by the shuttling of polyiodide and sluggish redox kinetics of iodine redox. Although various...
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Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage

By pubs.rsc.org
Published On ::

Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
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New research shows most space rocks crashing into earth come from a single source

By www.thehindu.com
Published On :: Tue, 22 Oct 2024 16:19:20 +0530

Scientists know that while some of these meteorites come from the Moon and Mars, the majority come from asteroid.


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South Africa petrochem unit world’s single largest greenhouse gas source

By www.thehindu.com
Published On :: Fri, 25 Oct 2024 10:57:15 +0530

The Sasol facility places the country at a crossroads because its coal-based technology emits much more carbon dioxide emitted per tonne of product


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Thanks to two special genes, a single atom can change the colour of a bird

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 14:56:57 +0530

New studies advance our understanding of how birds produce their colourful displays – and how these traits have evolved.


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Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

By pubs.rsc.org
Published On ::

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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First-principles investigation of an efficient non-noble single-atom catalyst Fe1/Ti2CO2 for formaldehyde oxidation

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper
Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe1/Ti2CO2 is an efficient catalyst that can remove indoor formaldehyde.
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Single-step in situ synthesis of bimetallic catalysts via a gas-phase route: the case of PdZn–ZnO

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6321-6330
DOI: 10.1039/D4CY00807C, Paper
Andrija Kokanović, Dunja Pupavac, Stéphane Chenot, Stéphane Guilet, Igor M. Opsenica, Slavica Stankic
In this study, we explore the catalytic activity of highly pure PdZn–ZnO nanopowder, synthesized via an innovative metal–organic chemical vapor synthesis (MOCVS) method.
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Synergistic promotion of oxygen vacancy and Lewis acidity of Nb2O5 on the preferential hydroxymethyl hydrogenolysis of 5-hydroxymethylfurfural catalyzed by single atom Pt

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6550-6560
DOI: 10.1039/D4CY00559G, Paper
Ting-Hao Liu, Shuai Fu, Jin-Tao Gou, Yin-Sheng Zhang, Chang-Wei Hu, Hua-Qing Yang
Over Pt1/Nb2O5, oxygen vacancy increases the catalytic activity, while the strong Lewis acidity of Nb2O5 selectively promotes the hydrogenolysis of the –CH2OH group rather than the hydrogenation of the –CHO group.
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Effect of graphene electrode functionalization on machine learning-aided single nucleotide classification

By pubs.rsc.org
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Nanoscale, 2024, 16,20202-20215
DOI: 10.1039/D4NR02274B, Paper
Mohd Rashid, Milan Kumar Jena, Sneha Mittal, Biswarup Pathak
In this study, we explored the role of functionalized entities (C, H, N, and OH) in graphene electrodes using a machine learning (ML) framework integrated with the quantum transport method to achieve precise single DNA nucleotide identification.
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Nucleic acid detection with single-base specificity integrating isothermal amplification and light-up aptamer probes

By pubs.rsc.org
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Nanoscale, 2024, 16,20067-20072
DOI: 10.1039/D4NR01638F, Communication
Jaekyun Baek, Jihyun Park, Youngeun Kim
CLASSIC is a label-free DNA detection platform with single-nucleotide specificity and attomolar sensitivity. This assay offers rapid and sequence-specific DNA analysis through single-strand conversion and split light-up aptamer probes.
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Ultra-low noise measurements of ionic transport within individual single-walled carbon nanotubes

By pubs.rsc.org
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Nanoscale, 2024, Advance Article
DOI: 10.1039/D4NR02941K, Paper
Laure Bsawmaii, Clément Delacou, Valerii Kotok, Sébastien Méance, Koutayba Saada, M. Amine Kribeche, Saïd Tahir, Christophe Roblin, Antonin Louiset, Hanako Okuno, Manoel Manghi, John Palmeri, François Henn, Adrien Noury, Vincent Jourdain
Nanofluidic devices incorporating an individual single-walled carbon nanotube, which achieve a 1–3 orders of magnitude noise reduction over conventional devices, were fabricated using high dielectric constant materials.
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GVMC to implement strict ban on single-use plastic in Visakhapatnam from January 1

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 23:12:14 +0530

The corporation will be taking up awareness campaigns on a massive scale for a period of 45 days and fines will be imposed on those violating norms, say officials


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Ind vs NZ: The joys and sorrows of the high-risk game in a single frame

By www.thehindu.com
Published On :: Wed, 23 Oct 2024 02:30:00 +0530

The high-risk style is set to continue, and whenever the Bengaluru Test situation arises again, there will be wistful talk of Cheteshwar Pujara, and even Sunil Gavaskar.


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The house hunt: The tale of every single woman with a career

By www.thehindubusinessline.com
Published On :: Wed, 26 Feb 2020 13:03:11 +0530


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Rafael Nadal not sure he’ll play singles after winning in doubles with Alcaraz at Paris Olympics

By www.thehindubusinessline.com
Published On :: Sun, 28 Jul 2024 09:01:47 +0530

Rafael Nadal's first match in singles, against Hungary's Marton Fucsovics, is scheduled for Sunday


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Can single-cell genomics lead to a new wave of drug targets? Celsius Therapeutics thinks so

By cen.acs.org
Published On :: 15 May 2018 10:30:00 +0000

The start-up, based on the work of Broad Institute scientist Aviv Regev, has raised $65 million to develop therapies for cancer and autoimmune disease


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Celsius Therapeutics launches to tap single-cell genomics for drug discovery

By cen.acs.org
Published On :: 21 May 2018 05:00:03 +0000


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Europe to ban some single-use plastics

By cen.acs.org
Published On :: 01 Jun 2018 00:07:11 +0000

New obligations for industry as the region and other areas target the causes of marine litter


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Sensing molecules released from single cells without labels

By cen.acs.org
Published On :: 05 Jun 2018 21:38:50 +0000

Combination of microfluidics and a nanosensor achieves label-free detection of cytokines from individual cells


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Sensing molecules released from single cells without using labels

By cen.acs.org
Published On :: 11 Jun 2018 05:00:03 +0000

Combination of microfluidics and a nanosensor achieves label-free detection of cytokines from individual cells


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Single atoms catalyze Suzuki reactions

By cen.acs.org
Published On :: 08 Jul 2018 13:08:02 +0000

Flow chemistry process takes place on carbon nitride surface


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Characterizing compounds released from single-use plastic bags

By cen.acs.org
Published On :: 12 Jul 2018 22:23:31 +0000

The biomanufacturing alternatives to metal vats release different molecules depending on age and type of material


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Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
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Single cobalt atom catalysis for the construction of quinazolines and quinazolinones via the aerobic dehydrocyclization of ethanol

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04928D, Paper
Xueping Zhang, Kai Xu, Yi Zhuang, Shihao Yuan, Yamei Lin, Guo-Ping Lu
It is still a significant and challenging for the synthesis of N-heterocycles through the aerobic dehydrocyclization of ethanol since ethanol is the largest renewable small molecule feedstock but with high...
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Pune airport records 100 metric tons of cargo movement on single day

By indianexpress.com
Published On :: Sat, 26 Oct 2024 11:50:16 +0000


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Covid-19: Karnataka sees biggest single-day jump of 54

By www.thehindubusinessline.com
Published On :: Sun, 10 May 2020 20:48:56 +0530

With 54 new cases, Karnataka witnessed the highest single-day jump in number of new positive cases. The largest number of patients tested positive to


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Special event helps children of single mom's show their appreciation

By edmonton.ctvnews.ca
Published On :: Sat, 9 May 2020 18:23:00 -0600

Some kids took advantage of the opportunity to show their appreciation for their moms on Saturday afternoon at the Love You Mama event.


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Polar vortex shatters single-day records in Barrie

By barrie.ctvnews.ca
Published On :: Sat, 9 May 2020 19:45:38 -0400

Many in the region had to dust off their snow shovels for at least one more dig out on Saturday morning after a polar vortex blasted parts of the province, catching many off guard.


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[ Singles & Dating ] Open Question : Is bring a girl home ok?

By answers.yahoo.com
Published On :: Sun, 10 May 2020 09:06:02 +0000

So once I went on a night out and I kissed a drunk girl and she was hinting she wanted to come home with me but I didn't let it happen. If this happens again will it be weird if I bring a girl home at like 3 in the morning and I live with my parents. Do I have to hide her? What if we have sex? In the morning my mum just come in and opens the door to get my washing. What if she does this and there is a girl in the bed? Will I get in trouble? I don't know anything about this stuff. I'm 21 do people this age even do this or is it only people in there 30s? It will be nice to spend the night with a girl. Is it a bad idea. I have no brothers or friends so I don't know what people do. I want to know for the next time?


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