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Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00185K, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lars J. C. van der Zee, Jelle Hofman, Joost M. van Gaalen, J. Chris Slootweg
Here, we discuss predicting thermal and photoinduced single-electron transfer (SET) in frustrated Lewis pairs (FLPs) and characterizing the resulting radical pair. We then extend these methods' application to main-group chemistry.
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ARCaDia: Single-round screening of a DNA-type targeted covalent binder possessing a latent warhead

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04594G, Communication
Open Access
Masumi Taki, Masayasu Kuwahara, Chaohui Li, Naoko Tomoda, Naoyuki Miyashita, Tetsuo Kan, Jay Yang
A covalent binder for a target protein was obtained by a direct single-round screening of a latent-warhead-modified DNA library via affinity/reactivity-based co-selection of aptameric deoxyribonucleic acid (ARCaDia), followed by a...
The content of this RSS Feed (c) The Royal Society of Chemistry




single

Ion induced ultra-tough single-network ionogel

Chem. Commun., 2024, 60,13388-13391
DOI: 10.1039/D4CC04732J, Communication
Zhenchuan Yu, Biaolong Ma, Jiqiang Wang
A strategy to fabricate ultra-tough ionogels by ionic induction is proposed, which provides a simple and general method for tuning ionogel properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04451G, Communication
Dopil Kim, Jun Yeong Kim, Haein Kim, Eunjin Jeong, Minhyuk Lee, Dongwook Kim, JunWoo Kim, Myung Hwan Park, Min Kim
We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation...
The content of this RSS Feed (c) The Royal Society of Chemistry




single

Study on growth technology and optical properties of large size and high quality methylamine lead bromide single crystals

CrystEngComm, 2024, 26,2003-2008
DOI: 10.1039/D4CE00028E, Paper
Yuanlong Sun, Yundong Ma, Xiangting Li, Ziyu Hu, Guozong Zheng
As a new generation of photoelectric materials, organic–inorganic halide perovskites have been widely used in photodetectors, solar cells and other fields, but most of the current mainstream applications are thin film materials.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pure organic TPB single crystal for direct X-ray detection

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00200H, Paper
Kai Jiang, Lingyan Xu, Rongjin Shang, Lu Liang, Yingming Wang, Zhentao Qin, Wanqi Jie
High-quality TPB single crystals were obtained without obvious step-like growth morphology. The TPB devices could present α-particle and γ-ray spectral responses with high energy resolution, showing potential for direct radiation detection.
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Enhanced photocatalytic activity of single-atom Au1/TiO2 catalysts prepared using cold plasma

CrystEngComm, 2024, 26,2103-2111
DOI: 10.1039/D4CE00171K, Paper
Zikun Yang, Jingxuan Zheng, Mengge Shi, Zhao Wang
Single-atom Au1/TiO2-DBD catalysts were synthesised using DBD plasma and glow plasma, and the synergistic effect of single-atom Au and oxygen vacancies improved the degradation performance.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemical solution deposition of a (GaAl)2O3 single layer with high thickness and silver-enhanced crystal quality

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00086B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao Tang, Wesam A. AlQanbar, Mohamed Ben Hassine, Yi Lu, Haicheng Cao, Chuanju Wang, Zixian Jiang, Tingang Liu, Na Xiao, Mingtao Nong, Vishal Khandelwal, Xiaohang Li
A new study presents a revolutionary CSD method to create thick (180 nm) single-layer (GaAl)2O3 films with enhanced crystal quality through silver doping.
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A novel one-dimensional Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructure fabricated by a single-nozzle electrospinning technique and its low color drift property at high temperature

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00149D, Paper
Shanshan Cong, Zhuang Tian, Hongquan Yu, Sai Xu, Lihong Cheng, Baojiu Chen, Tianshuo Liu
1D Y2(Zr0.6Ti0.4)2O7:Eu tube-in-tube nanostructures were fabricated by a simple single-nozzle electrospinning method. These materials exhibit excellent luminescent stability and lower color drift performance at high temperatures.
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The development of an approach for the precision determination of thermal strain tensor elements for single crystals using the example of t-Ag0.8Li0.2InSe2

CrystEngComm, 2024, 26,2207-2218
DOI: 10.1039/D3CE01186K, Paper
Polina S. Serebrennikova, Sergey I. Lobanov, Alexander S. Sukhikh, Lyudmila I. Isaenko, Sergey A. Gromilov
A new approach to the precision determination of single-crystal unit cell parameters is proposed and demonstrated using tetragonal Ag0.8Li0.2InSe2.
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Distribution of basal plane dislocations in 4-degree off-axis 4H-SiC single crystals

CrystEngComm, 2024, 26,2143-2154
DOI: 10.1039/D4CE00055B, Paper
Sheng'ou Lu, Binjie Xu, Yazhe Wang, Hongyu Chen, Wei Hang, Rong Wang, Julong Yuan, Xiaodong Pi, Deren Yang, Xuefeng Han
The basal plane slip model in 4H-SiC was developed to investigate the effects of off-axis angles on total resolved shear stress. The results showed that the TRSS changed from 6-fold to 4-fold symmetry with the increasing off-axis angles.
The content of this RSS Feed (c) The Royal Society of Chemistry




single

A single adverse weather event such as El Niño may not be a threat to macroeconomic stability, RBI Bulletin

There were years when, despite El Niño, rainfall was close to normal and inflation remained benign; the officials




single

Single and ready to mingle? Here comes ROFL

ROFL, a friends-of-friends network of singles, which started in Delhi about seven years ago, has now expanded to seven cities across India; finding like-minded people and creating happy spaces is their success mantra



  • Life & Style

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iOS18 Photos: Tab Bar to Single Scroll View

The most significant user interface change from iOS 17 to iOS 18 are the navigation differences in Apple's Photos app. The ubiquitous tab bar that's became the default navigation model in mobile apps is gone and in its place is one long scrolling page. So how does it work and why?

Most mobile applications have adopted a bottom bar for primary navigation controls. On Android it's called bottom navigation and on iOS, a tab bar, but the purpose is the same: make the top-level sections of an application visible and let people move between them.

And it works. Across multiple studies and experiments, companies found when critical parts of an application are made more visible, usage of them increases. For example, Facebook saw that not only did engagement go up when they moved from a “hamburger” menu to a bottom tab bar in their iOS app, but several other important metrics went up as well. Results like this made use of tab bars grow.

But in iOS 18, Apple removed the tab bar in their Photos app. Whereas the prior version had visible tabs for the top-level sections (Library, For You, Albums, Search), the redesign is just a single scroll view. The features previously found in each tab are now accessed by scrolling up and down vs. switching between tabs. One notable exception is Search which stays anchored at the top of the screen.

In addition to the persistent Search button, there's also a Select action and user profile image that opens a sheet with account settings. As you scroll up into your Photo library a persistent set of View controls appears at the bottom of the screen as well. The Close action scrolls you to the end of your Photo library and reveals a bit of the actions below making the location of features previously found in tabs more clear.

It's certainly a big change and given the effectiveness of tab bars, its also a change that has people questioning why? I have no inside information on Apple's decision-making process here but based on what I've learned about how people use Google Photos, Yahoo! Photos, and Flickr, I can speculate.

  1. By far the dominant use of a Photo gallery is scrolling to find an image whether to share, view, or just browse.
  2. Very few people organize their photo libraries and those that do, do it rarely.
  3. People continue to have poor experiences with searching images, despite lots of improvements, so they default to browsing when trying to find photos.
  4. Most automatic curation features like those found in For You just get ignored.

All that together can easily get you to the design answer of "the app should just be a scrolling list of all your Photos". Of course there's trade-offs. The top-level sections, and their features are much less visible, and thereby less obvious. The people who do make use of features like Albums and Memories now need to scroll to them vs. tapping once. But as iOS18 rolls out to everyone in the Fall, we'll see if these trade-offs were worth it.




single

From elementary to advanced: rational design of single component phosphorescence organogels for anti-counterfeiting applications

Mater. Chem. Front., 2024, 8,3577-3586
DOI: 10.1039/D4QM00498A, Research Article
Huamiao Lin, Yi Shi, Yan Li, Shuzhan Chen, Wei Wang, Peng Geng, Jiaying Yan, Shuzhang Xiao
In this work, we designed and synthesized two non-conventional organogels (DBF-dAc and DBF-dPh). DBF-dPh organogels emitted long-lasting room-temperature phosphorescence with a visible afterglow and multi-layered anti-counterfeiting capabilities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Porphyrin-linked graphdiyne as a substrate for constructing single-atom catalysts with transition metals towards oxygen reduction reactions and oxygen evolution reactions

Mater. Chem. Front., 2024, 8,3741-3746
DOI: 10.1039/D4QM00555D, Research Article
Jiejie Ping, Mei Wu, Manyu Liu, Yan Jiang, Wenhui Shang, Menggai Jiao, Jiahao Ruan, Nan Wang, Zhiyu Jia
Porphyrin-linked graphdiyne anchored with transition metals exhibits outstanding electrochemical performance, attributed to the modifications in the coordination environment.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Instantaneous growth of single monolayers as the origin of spontaneous core–shell InxGa1−xN nanowires with bright red photoluminescence

Nanoscale Horiz., 2024, Advance Article
DOI: 10.1039/D4NH00412D, Communication
Vladimir G. Dubrovskii, George E. Cirlin, Demid A. Kirilenko, Konstantin P. Kotlyar, Ivan S. Makhov, Rodion R. Reznik, Vladislav O. Gridchin
We demonstrate spontaneous core–shell InxGa1−xN nanowires exhibiting bright photoluminescence at 650 nm. The surprising effect of material separation is attributed to the periodically changing environment for single monolayer growth.
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Edge-doped substituents as an emerging atomic-level strategy for enhancingM-N4-C single-atom catalysts in electrocatalysis of ORR, OER, and HER

Nanoscale Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4NH00424H, Communication
Liang Xie, Wei Zhou, Zhibin Qu, Yuming Huang, Longhao Li, Chaowei Yang, Junfeng Li, Xiaoxiao Meng, Fei Sun, Jihui Gao, Guangbo Zhao
M-N4-C single-atom catalysts (MN4) have gained attention for their efficient use at the atomic level and adjustable properties in electrocatalytic reactions like ORR, OER, and HER. Yet, understanding MN4's activity...
The content of this RSS Feed (c) The Royal Society of Chemistry




single

In its 125th year, McDowell’s joins the single malt party with a wine-forward batch

Last week, when the world’s largest selling whisky brand, McDowell’s, launched a single malt, the colour purple — in all its hues — dominated the room. An apt colour to denote that the origin of the Batch Indian Single Malt was from a distillery in the wine capital Nashik




single

A single-column and efficient procedure for separating Fe and Mg from geological materials for isotopic analyses using MC-ICP-MS

J. Anal. At. Spectrom., 2024, 39,2783-2790
DOI: 10.1039/D4JA00272E, Paper
Guanhong Zhu, Zhenmin Ge, Le Zhang, Gangjian Wei, Jinlong Ma
We developed a single-column and efficient procedure for separating Fe and Mg from geological materials for isotope measurements.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Evaluation of miniaturized ultrasonic nebulization for high-efficiency sampling in characterization of silver nanoparticles by single particle inductively coupled plasma mass spectrometry

J. Anal. At. Spectrom., 2024, 39,2791-2798
DOI: 10.1039/D4JA00320A, Paper
Junhang Dong, Zhenli Zhu, Lujie Li, Pengju Xing, Shuyang Li, Lei Ouyang, Xing Liu, Wei Guo, Hongtao Zheng, Rong Qian
Miniaturized ultrasonic nebulization (MUN) provides high sampling efficiency for single particle inductive coupled plasma mass spectrometry (sp-ICPMS).
The content of this RSS Feed (c) The Royal Society of Chemistry




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A single-stage purification method for the precise determination of zirconium isotopic composition in geological samples by double spike MC-ICP-MS

J. Anal. At. Spectrom., 2024, Advance Article
DOI: 10.1039/D4JA00332B, Paper
Lanping Feng, Chen Wang, Yan Han, Wen Zhang, Jing-Liang Guo, Lian Zhou, Zhaochu Hu
A simple, fast and efficient column separation method for extracting Zr from geological sample matrices using DGA resin.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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SPCal - An open source, easy-to-use processing platform for ICP-TOFMS based single event data

J. Anal. At. Spectrom., 2024, Accepted Manuscript
DOI: 10.1039/D4JA00241E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Thomas Edward Lockwood, Lukas Schlatt, David Clases
Single particle inductively coupled plasma – mass spectrometry (SP ICP-MS) has evolved into one of the most powerful techniques for the bottom-up characterisation of nanoparticle suspensions. The latest generations of...
The content of this RSS Feed (c) The Royal Society of Chemistry




single

IISc receives its single largest private donation of Rs 425 crore

The unique school and the 800-bed multispeciality hospital on campus will create ‘physician-scientists’




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Catalytic kinetic growth of a half-metallic hexagonal boron nitride-graphene lateral heterostructure using transition metal single-atom catalysts on Rh(111)

J. Mater. Chem. A, 2024, 12,30498-30507
DOI: 10.1039/D4TA05741D, Paper
Yandi Zhu, Weihu Li, Xiaoyan Ren, Lili Zhang, Xingju Zhao, Shunfang Li
Transition metal single-atom catalysts (TM = Mn, Zr, Nb, Mo, Hf, Ta, and W) promote growth of a h-BN-G heterostructure on C-dimer-unpreferred Rh(111).
The content of this RSS Feed (c) The Royal Society of Chemistry




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A soft molecular single-source precursor approach to synthesize a nanostructured Co9S8 (pre)catalyst for efficient water oxidation and biomass valorization

J. Mater. Chem. A, 2024, 12,30522-30533
DOI: 10.1039/D4TA05436A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Basundhara Dasgupta, Suptish Ghosh, Carsten Walter, Markus S. Budde, Georg J. Marquardt, Han-Hsu Chen, Markus G. M. Breithaupt, Tolga Yilmaz, Christoph Garmatter, Tamanna Ahamad, Ingo Zebger, Matthias Driess, Prashanth W. Menezes
A nanocrystalline Co9S8 (pre)catalyst derived from a novel {CoIIS4} complex is reported for the oxygen evolution reaction (OER) and selective biomass valorization. During OER, Co9S8 reconstructs completely into a CoOOH active phase via S-leaching.
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Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped carbon nanotubes for stable Zn–air batteries with ultra-high power densities

J. Mater. Chem. A, 2024, 12,30798-30809
DOI: 10.1039/D4TA04194A, Paper
Manigandan Ramadoss, Hesheng Yu, Anand Rajkamal, Gun Jin Yun, Ziheng Zhang, Chengtao Yang, Fei Ma, Yu Wu, Chen Daiqian, Yuanfu Chen
Fe-single-atom-coupled Fe3C multifunctional catalysts on P-, F-, N-doped CNT deliver comparable OER behavior to RuO2, better ORR performance than Pt/C, and better ZAB performance than Pt/C–RuO2, due to the nanoarchitecture and abundant active sites.
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Achieving dynamic stability of single-crystal low-Co Ni-rich cathode material for high performance lithium batteries

J. Mater. Chem. A, 2024, 12,30831-30841
DOI: 10.1039/D4TA04698F, Paper
Adil Saleem, Leon L. Shaw, Mehwish Khalid Butt, Javed Rehman, Arshad Hussain, Zawar Hussain, Rashid Iqbal, Muhammad Kashif Majeed
The demand for high-energy-density lithium-ion batteries (LIBs) has driven intensive research into cathode materials that exhibit both superior performance and stability over multiple charge–discharge cycles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Lesbian Courting Site & App For Single Girls

In case you are not within the disposition for internet dating right now, don’t endure it. Discover a lot of carefree and delightful lesbian singles to play with. Plus, the sign-up process is easy sufficient and you’ll have your profile Seattle hookup culture up and working very quickly. Best hookup sites (including 20 runner-ups) to […]




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This website Where Females Are Looking for Guys & You Can Meet Single Girls

Content Best “Mail Order Bride” Sites to look for Love In foreign countries When http://aevawedding.com/bosnian-brides you become a member of our online dating community, bored and lonely housewives from your location become visible to you. So , feel free to inform us your preferences and we will then assist you to meet the real matches. […]




single

Single-screen theatres in Telangana to shut shop for 10 days

With summer drawing a blank, theatres want to save money by stopping screenings 




single

Puma India and dating site Bumble announce ‘singles-only’ running event in Bengaluru

The 3km run aimed at singes aged between 21 and 35 years will start at Bengaluru’s Nexus Koramangala Mall on November 10




single

Cuprous-based layered single-crystalline scintillators for X-ray detection and imaging

J. Mater. Chem. C, 2024, 12,17587-17594
DOI: 10.1039/D4TC03080J, Paper
Yuke Zhao, Danping Chen, Haitao Tang, Hailin Liu, Yong Liu, Yangyang Dang, Qianqian Lin
A new metal halide single crystal (C6H10N2)2Cu2I3(PO2)3 was demonstrated. The optical and X-ray properties of (C6H10N2)2Cu2I3(PO2)3 were fully characterized and evaluated, which demonstrated great potential for X-ray detection and imaging.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Light-induced magnetic switching in a coumarin-based Tb Single Molecule Magnet

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03152K, Paper
Open Access
Elena Bartolomé, Ana Arauzo, Javier Luzón, Laura Gasque
We present the intriguing magneto-optical properties of the lanthanide complex [Tb(coum)3(batho)]·0.7EtOH], named Tb-batho, based on coum = 3-acetyl-4-hydroxylato-coumarin and batho = bathophenanthroline ligands. Tb-batho displays visible-range luminescence with a notable...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A metal–organic framework enhanced single network organohydrogel with superior low-temperature adaptability and UV-blocking capability towards human-motion sensing

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03148B, Paper
Ying Li, Zhongquan Yu, Jialuo Zhang, Enke Feng, Xiaoqin Li, Linan Cao, Zhiming Yang, Zhiqiang Wu
A UiO-66-NH2 nanoparticle reinforced organohydrogel with anti-freezing and UV-blocking properties was synthesized for sensing complex human movements and transmitting different messages even at subzero temperature.
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Oxide Lu2TeO6 single crystal for X-ray detection with ultralow detection limit.

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04341C, Paper
Tingting Cao, Feifei Guo, Fuai Hu, Xutang Tao, Zeliang Gao
Semiconductor-based X-ray detectors become critical in medical diagnosis, industrial inspections, and scientific research. The recently reported metal oxide single crystal materials have demonstrated low detection limits and outstanding stability. Herein,...
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Large magnetic anisotropy and rotating cryomagnetocaloric effect in single-crystalline paramagnetic lanthanide calcium oxyborates LnCa4O(BO3)3 with Ln = Pr, Nd, Gd, Tm, Er

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC03249G, Paper
Fatiha Azrour, Romain Viennois, Jérôme Long, Corine Reibel, Jérome Debray, Fapeng Yu, Shujun Zhang, Mickaël Beaudhuin, Jerome Rouquette
The lanthanide calcium oxyborates LnCa4O(BO3)3 compounds form a family of multifunctional materials with promising nonlinear and linear optical properties and piezoelectrical properties because of their polar crystal structure. In the...
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New single-dose treatment shows promise in anti-malaria battle



  • Policy & Issues

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Progress and challenges in structural, in situ and operando characterization of single-atom catalysts by X-ray based synchrotron radiation techniques

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00967J, Review Article
Yuhang Liu, Xiaozhi Su, Jie Ding, Jing Zhou, Zhen Liu, Xiangjun Wei, Hong Bin Yang, Bin Liu
Single-atom catalysts (SACs) represent the ultimate size limit of nanoscale catalysts, combining the advantages of homogeneous and heterogeneous catalysts.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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single

Shrivalli makes progress in singles and doubles




single

The Tyranny of the Single Minded: Guns, Environment, and Abortion [electronic journal].




single

Single mothers and their children: Evaluating a work-encouraging welfare reform [electronic journal].




single

Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02507A, Research Article
Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00500G, Research Article
Qingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang Tao
Recently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Bulk single crystal growth and optoelectronic properties of the quasi-two-dimensional perovskites (CH3NH3)3Bi2X9 (X− = Br− and I−)

Inorg. Chem. Front., 2024, 11,2442-2456
DOI: 10.1039/D3QI02687F, Research Article
Zhiyuan Li, Xiangjun Wang, Peng Zhao, Jingquan Liu, Xiangxin Tian
Single crystals of MA3Bi2X9 (X = Br, I) with quasi-two-dimensional structures were successfully grown and the relationship between the compositions, dimensionality, and properties were discussed.
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Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00691G, Research Article
Cai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu Wang
Four pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...
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Chelating Coordination Modulation Method for the Synthesis of Ti-MOF Single Crystals

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00436A, Research Article
Hui-Zi Li, Shangda Li, Fei Wang, Jian Zhang
Despite titanium-based metal-organic frameworks (Ti-MOFs) are promising as efficient photocatalysts, the high reactivity of titanium ions makes the synthesis and structure determination of new Ti-MOFs quite challenging. In this study,...
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single

Reservoirs with less than 50% storage down to single digit

Key dams’ water level unchanged at 87% of capacity this week




single

‘Jacquemus’: Viral sensation Tesher’s latest single nods to Brazil, Bollywood and summertime

Infused with influences from Brazilian Baile Funk, Bollywood and hints of other regional Indian musical influences, Tesher says he wanted to create a song that would sound familiar to people across cultures 




single

Spotting d-band centers of single-atom catalysts by oxygen intermediate-boosted electrochemiluminescence

Chem. Sci., 2024, 15,18085-18092
DOI: 10.1039/D4SC03763D, Edge Article
Open Access
Ruyu Xie, Kaitao Li, Rui Tian, Chao Lu
We have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.
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