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One-dimensional ladder gallium coordination polymer

A one-dimensional ladder-type coordination polymer, poly[[(μ2-hydroxido)(μ2-1H-pyrazole-3,5-di­carboxyl­ato)gallium(III)] monohydrate], [Ga(C5H2N2O4)(OH)(H2O)]n or [Ga(HPDC)(OH)(H2O)]n, I, isotypic with a V3+ coordination polymer previously reported by Chen et al. [J. Coord. Chem. (2008). 61, 3556–3567] was prepared from Ga3+ and pyrazole-3,5-di­carb­oxy­lic acid monohydrate (H3PDC·H2O). Compound I was isolated using three distinct experimental methods: hydro­thermal (HT), microwave-assisted (MWAS) and one-pot (OP) and the crystallite size should be fine-tuned according to the method employed. The coordination polymeric structure is based on a dimeric Ga3+ moiety comprising two μ2-bridging hydroxide groups, which are inter­connected by HPDC2− anionic organic linkers. The close packing of individual polymers is strongly directed by the supra­molecular inter­actions, namely several O—H⋯O and N—H⋯O hydrogen-bonding inter­actions.




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The first coordination compound of deprotonated 2-bromo­nicotinic acid: crystal structure of a dinuclear paddle-wheel copper(II) complex

A copper(II) dimer with the deprotonated anion of 2-bromo­nicotinic acid (2-BrnicH), namely, tetrakis(μ-2-bromonicotinato-κ2O:O')bis[aquacopper(­II)](Cu—Cu), [Cu2(H2O)2(C6H3BrNO2)4] or [Cu2(H2O)2(2-Brnic)4], (1), was prepared by the reaction of copper(II) chloride dihydrate and 2-bromo­nicotinic acid in water. The copper(II) ion in 1 has a distorted square-pyramidal coordination environment, achieved by four carboxyl­ate O atoms in the basal plane and the water mol­ecule in the apical position. The pair of symmetry-related copper(II) ions are connected into a centrosymmetric paddle-wheel dinuclear cluster [Cu⋯Cu = 2.6470 (11) Å] via four O,O'-bridging 2-bromo­nicotinate ligands in the syn-syn coordination mode. In the extended structure of 1, the cluster mol­ecules are assembled into an infinite two-dimensional hydrogen-bonded network lying parallel to the (001) plane via strong O—H⋯O and O—H⋯N hydrogen bonds, leading to the formation of various hydrogen-bond ring motifs: dimeric R22(8) and R22(16) loops and a tetra­meric R44(16) loop. The Hirshfeld surface analysis was also performed in order to better illustrate the nature and abundance of the inter­molecular contacts in the structure of 1.




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A single-crystal diamond X-ray pixel detector with embedded graphitic electrodes

The first experimental results from a new transmissive diagnostic instrument for synchrotron X-ray beamlines are presented. The instrument utilizes a single-crystal chemical-vapour-deposition diamond plate as the detector material, with graphitic wires embedded within the bulk diamond acting as electrodes. The resulting instrument is an all-carbon transmissive X-ray imaging detector. Within the instrument's transmissive aperture there is no surface metallization that could absorb X-rays, and no surface structures that could be damaged by exposure to synchrotron X-ray beams. The graphitic electrodes are fabricated in situ within the bulk diamond using a laser-writing technique. Two separate arrays of parallel graphitic wires are fabricated, running parallel to the diamond surface and perpendicular to each other, at two different depths within the diamond. One array of wires has a modulated bias voltage applied; the perpendicular array is a series of readout electrodes. X-rays passing through the detector generate charge carriers within the bulk diamond through photoionization, and these charge carriers travel to the nearest readout electrode under the influence of the modulated electrical bias. Each of the crossing points between perpendicular wires acts as an individual pixel. The simultaneous read-out of all pixels is achieved using a lock-in technique. The parallel wires within each array are separated by 50 µm, determining the pixel pitch. Readout is obtained at 100 Hz, and the resolution of the X-ray beam position measurement is 600 nm for a 180 µm size beam.




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Enhancing the homogeneity of YBa2(Cu1−xFex)3O7−δ single crystals by using an Fe-added Y2O3 crucible via top-seeded solution growth

This paper reports an Fe-added Y2O3 crucible which is capable of balancing the solution spontaneously and is employed to effectively enhance the homogeneity of YBa2(Cu1−xFex)3O7−δ single crystals.




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EDDIDAT: a graphical user interface for the analysis of energy-dispersive diffraction data

EDDIDAT is a program that provides a graphical user interface (GUI) for the evaluation of energy-dispersive X-ray diffraction data with the focus on the depth-resolved residual stress analysis.




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Appalachian Trail survey aims hidden cameras at large predators

Describing his project of counting bears, bobcats and other predatory mammals along the Appalachian Trail, National Zoological Park wildlife ecologist William McShea looks to American literature for a comparison.

The post Appalachian Trail survey aims hidden cameras at large predators appeared first on Smithsonian Insider.




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Study aims to give endangered Shenandoah salamander better odds at survival

Each year thousands of vacationers enjoy the scenery along Virginia’s Skyline Drive, little knowing that for a few brief moments they are passing through the territory of an endangered […]

The post Study aims to give endangered Shenandoah salamander better odds at survival appeared first on Smithsonian Insider.




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John Marshall Ju/’hoan Bushman Film and Video Collection added to UNESCO register

The John Marshall Ju/'hoan Bushman Film and Video Collection, 1950-2000, was among 35 documentary heritage items of exceptional value added to UNESCO’s Memory of the World Register in 2009.

The post John Marshall Ju/’hoan Bushman Film and Video Collection added to UNESCO register appeared first on Smithsonian Insider.



  • Anthropology
  • Science & Nature
  • National Museum of Natural History

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Clay vessels by Native American potter Jeri Redcorn added to Smithsonian collections

The Caddo people of Arkansas, Louisiana, Texas and Oklahoma have maintained many of their traditional ways and actively work to preserve their unique tribal cultural today. One example is the pottery of Jeri Redcorn.

The post Clay vessels by Native American potter Jeri Redcorn added to Smithsonian collections appeared first on Smithsonian Insider.




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Rutgers glider added to the collections of the National Museum of Natural History

The Scarlet Knight, as the glider is called, made nautical history as the first submersible glider to successfully cross the Atlantic Ocean.

The post Rutgers glider added to the collections of the National Museum of Natural History appeared first on Smithsonian Insider.




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Smithsonian and MIT to launch online mystery game for middle-shool children

On April 4 the Smithsonian and the Massachusetts Institute of Technology will launch VANISHED, an 8-week online/offline environmental disaster mystery game for middle-school children, meant […]

The post Smithsonian and MIT to launch online mystery game for middle-shool children appeared first on Smithsonian Insider.




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Space shuttle Discovery to be added to National Air and Space Museum collection

Discovery, the longest-serving orbiter in the space shuttle fleet, will be accepted into the Smithsonian’s National Air and Space Museum collection. The space shuttle has been the icon for American spaceflight for a generation, and Discovery has flown every type of mission during its 27-year career.

The post Space shuttle Discovery to be added to National Air and Space Museum collection appeared first on Smithsonian Insider.




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Black hole came from a shredded galaxy

Astronomers using NASA's Hubble Space Telescope have found a cluster of young, blue stars encircling the first intermediate-mass black hole ever discovered. The presence of the star cluster suggests that the black hole was once at the core of a now-disintegrated dwarf galaxy.

The post Black hole came from a shredded galaxy appeared first on Smithsonian Insider.




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3-D imaging adds remarkable new understanding of North America’s mysterious Clovis people

The only explanation for such symmetry across these vast distances, explains Smithsonian anthropologist Dennis Stanford, is that the method of creating the points was handed down from person to person.

The post 3-D imaging adds remarkable new understanding of North America’s mysterious Clovis people appeared first on Smithsonian Insider.




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Split-personality elliptical galaxy holds a hidden spiral

Astronomers have discovered that one well-known elliptical galaxy has a split personality. Centaurus A is hiding a gassy spiral in its center.

The post Split-personality elliptical galaxy holds a hidden spiral appeared first on Smithsonian Insider.




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Galactic thief: “I would have gotten away with it but for those meddling astronomers!”

One of the closest galaxies to the Milky Way almost got away with theft....

The post Galactic thief: “I would have gotten away with it but for those meddling astronomers!” appeared first on Smithsonian Insider.




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HI-C adds big piece to the solar corona puzzle

But how can the solar atmosphere get hotter, rather than colder, the farther you go from the Sun's surface? A suborbital rocket launched in July provides the answer.

The post HI-C adds big piece to the solar corona puzzle appeared first on Smithsonian Insider.





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Gray whale specimen an important addition to Natural History Museum collections

Rope, golf balls, sweat pants, bottles and aluminum cans are a few of the discarded items biologist Matt Klope says he has found inside the […]

The post Gray whale specimen an important addition to Natural History Museum collections appeared first on Smithsonian Insider.




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Young star suggests our sun was a feisty toddler

If you had a time machine that could take you anywhere in the past, what time would you choose? Most people would probably pick the […]

The post Young star suggests our sun was a feisty toddler appeared first on Smithsonian Insider.




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Q&A: Plastics expert Odile Madden on plastic debris in Alaskan waters

In June, Odile Madden, materials scientist at the Smithsonian’s Museum Conservation Institute, was a participant on a 6-day interdisciplinary expedition to a number of beaches […]

The post Q&A: Plastics expert Odile Madden on plastic debris in Alaskan waters appeared first on Smithsonian Insider.




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Zoo scientists find sudden stream temperature changes boost hellbender immune systems

Hellbenders, aquatic salamanders from the eastern United States, are surprisingly good at dealing with unpredictable weather. In a recent study published in the Journal of […]

The post Zoo scientists find sudden stream temperature changes boost hellbender immune systems appeared first on Smithsonian Insider.




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In modern amphibian “ark,” new species added with due diligence

Bright orange with a distinctive call the Panamanian poison dart frog Andinobates geminisae lives in only a small area of the Caribbean Coast of Panama. […]

The post In modern amphibian “ark,” new species added with due diligence appeared first on Smithsonian Insider.




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What squirms inside a tiny bird? Odd new tapeworm species

Parasites such as nematodes, tapeworms, flukes, ticks and lice are normal in nature and can even be beneficial for animals, including humans, says Anna Phillips, […]

The post What squirms inside a tiny bird? Odd new tapeworm species appeared first on Smithsonian Insider.




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New App adds Virtual Flesh to Victorian-era Bone exhibit

Point your smartphone at the skeleton of a vampire bat mounted in a museum case, wait a minute and you will see it wiggle, jump […]

The post New App adds Virtual Flesh to Victorian-era Bone exhibit appeared first on Smithsonian Insider.




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CASSIOPEIA’S HIDDEN GEM: THE CLOSEST ROCKY, TRANSITING PLANET

Skygazers at northern latitudes are familiar with the W-shaped star pattern of Cassiopeia the Queen. This circumpolar constellation is visible year-round near the North Star. […]

The post CASSIOPEIA’S HIDDEN GEM: THE CLOSEST ROCKY, TRANSITING PLANET appeared first on Smithsonian Insider.




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RADIO TELESCOPES COULD SPOT STARS HIDDEN IN THE GALACTIC CENTER

The center of our Milky Way galaxy is a mysterious place. Not only is it thousands of light-years away, it’s also cloaked in so much […]

The post RADIO TELESCOPES COULD SPOT STARS HIDDEN IN THE GALACTIC CENTER appeared first on Smithsonian Insider.




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Odd anatomy: flexible joint between skull and spine allow dragonfish to open wide

Food is scarce in the deep, dark regions of the ocean where barbeled dragonfishes and their relatives dwell. Known as the Stomiidae, some of these […]

The post Odd anatomy: flexible joint between skull and spine allow dragonfish to open wide appeared first on Smithsonian Insider.




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Microplastics in our environment: A conversation with Odile Madden, Smithsonian plastics scientist

Odile Madden knows a lot about plastic. A materials scientist with the Smithsonian Museum Conservation Institute, she has spent the past eight years studying plastics […]

The post Microplastics in our environment: A conversation with Odile Madden, Smithsonian plastics scientist appeared first on Smithsonian Insider.




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Theoretical study of the properties of X-ray diffraction moiré fringes. I. Corrigenda and addenda

Seven corrections are made and several supplementary equations are added to the article by Yoshimura [Acta Cryst. (2015), A71, 368–381].




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Isotopy classes for 3-periodic net embeddings

Entangled embedded periodic nets and crystal frameworks are defined, along with their dimension type, homogeneity type, adjacency depth and periodic isotopy type. Periodic isotopy classifications are obtained for various families of embedded nets with small quotient graphs. The 25 periodic isotopy classes of depth-1 embedded nets with a single-vertex quotient graph are enumerated. Additionally, a classification is given of embeddings of n-fold copies of pcu with all connected components in a parallel orientation and n vertices in a repeat unit, as well as demonstrations of their maximal symmetry periodic isotopes. The methodology of linear graph knots on the flat 3-torus [0,1)3 is introduced. These graph knots, with linear edges, are spatial embeddings of the labelled quotient graphs of an embedded net which are associated with its periodicity bases.




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How To Email To Multiple Addresses At The Same Time




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How To Add An Attachment To An Email

in Outlook Express and Thunderbird




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Tom Crouch, Senior curator in the National Air and Space Museum’s Aeronautics Division, discusses Thaddeus Lowe and the birth of American aerial reconnaissance

Tom Crouch, Senior curator in the National Air and Space Museum's Aeronautics Division, discusses Thaddeus Lowe and the birth of American aerial reconnaissance during the Civil War. This presentation was recorded on May 11, 2011 on the National Mall.

The post Tom Crouch, Senior curator in the National Air and Space Museum’s Aeronautics Division, discusses Thaddeus Lowe and the birth of American aerial reconnaissance appeared first on Smithsonian Insider.




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Adding 750,000 dots to The Obliteration Room

Time-lapse captured at the Hirshhorn Museum of Yayoi Kusama’s The Obliteration Room, on view in “Yayoi Kusama: Infinity Mirrors.” In Yayoi Kusama’s “The Obliteration Room,” […]

The post Adding 750,000 dots to The Obliteration Room appeared first on Smithsonian Insider.



  • Art
  • History & Culture
  • Video
  • Hirshhorn Museum and Sculpture Garden

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Armenian Wedding Ceremony

At the 2018 Smithsonian Folklife Festival, Armenian participants Mariam Hovhannisyan and Stepan Toroyan—who were recently married—recreated a traditional ceremony on the National Mall, with contributions […]

The post Armenian Wedding Ceremony appeared first on Smithsonian Insider.



  • Art
  • History & Culture
  • Video
  • Smithsonian Folklife Festival

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Remarkable new tree species was “hidden in plain sight” in the Andes

Hidden in plain sight–that’s how researchers describe their discovery of a new genus of large forest tree commonly found, yet previously scientifically unknown, in the […]

The post Remarkable new tree species was “hidden in plain sight” in the Andes appeared first on Smithsonian Insider.




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How To Find Out Your Ip Address And Other Tcp/ip Settings In Windows




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How To Reset Your Computer's Gateway Ip Address




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There's many a good tune played on an old fiddle – a new colour for Alfred Werner's isomer counting




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Maroon 5 called out for faking 'Sugar' wedding crashing

A screenshot from Maroon 5's "Sugar" music video.; Credit: Maroon 5

Mike Roe

Maroon 5 has a new music video built around a simple, viral-bait premise: Adam Levine and the rest of the band trying to crash as many weddings around Los Angeles as they can in one day (Dec. 6 of last year). It's a lot of fun, directed by "Wedding Crashers" movie director David Dobkin, but it appears that some of those "crashed weddings" may have been staged.

Watch the video (warning: contains adult language):

Maroon 5: Sugar

Fans have noticed that several of the couples seen in the video appear to be actors. Actors Stephen and Barbara Woo posted on Facebook that they played the parents of one of the brides in the video and said that not only were the weddings staged, they didn't even take place on one day, claiming that all the weddings were shot in the same location over the course of three days.

Facebook post by actors

The groom from the wedding featured the most in the video has been named by observers as Nico Evers-Swindell, according to Cosmopolitan. Evers-Swindell was already married to actress Megan Ferguson since 2011 — and she's not the "bride" in the video.

Fans have fingered one of the models as "America's Next Top Model" runner-up Raina Hein, according to Cosmopolitan. Also, the man believed to be her long-term boyfriend isn't the groom in the Maroon 5 weddings.

Don't lose heart, though — at least one of the weddings in the video appears to be real, with wedding photographer Duke Khodaverdian telling E! that yes, it was the real deal.

"It was an incredible surprise and everyone at the wedding is going to cherish those memories," Khodaverdian told E! in December.

Instagram 1

Instagram 2

A representative for the band told "Entertainment Tonight" that only the grooms knew about the band in each case — but it looks like that means in the case of the real crashed weddings. The representative did concede that some shots "had to be shot separately from the real weddings due to time and space constraints that were given," and the article does note that the video was shot over three days.

Levine expressed his excitement about crashing the weddings in an interview with People magazine.

"I had no idea I would be affected by the overwhelming reactions we received from the couples and guests," Levine said. He told "Entertainment Tonight" that it was stressful to arrange, but that the surprise felt good. "[We were] happy that they liked our band, too – [that] would have been a total disaster."

They also solicited Twitter to find people lip-syncing "Sugar" to possibly put in their music video, but it doesn't look like those submissions got used.

Maroon 5 Sugar tweet

If you want to see Levine involved in a different dubious outfit, you can see him back hosting "The Voice" on Feb. 23. Open call auditions for the show begin Jan. 24 in New York, with Los Angeles auditions on Jan. 31 and Feb. 1.

Did you spot any more actors you recognize in this video? Do you have any more evidence of any of these weddings being either real or faked? Let me know on Twitter at @MikeRoe.

This content is from Southern California Public Radio. View the original story at SCPR.org.




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Isotopy classes for 3-periodic net embeddings

Entangled embedded periodic nets and crystal frameworks are defined, along with their dimension type, homogeneity type, adjacency depth and periodic isotopy type.




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My old phone without sim card shows same ip address as my active phone




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Powerline Adapters suddenly super slow