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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Twitter may face difficulties showing Meta stole trade secrets

Legal experts say while many companies have accused competitors that hired former employees and have a similar product of stealing trade secrets, the cases are difficult to prove




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WhatsApp unveils ‘Secret Code’ feature to enhance privacy

The new feature allows users to set a distinct password that is separate from their phone unlock code




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I&B Ministry issues advisory to media and social media platforms ahead of Ram temple consecration ceremony

This comes after the Ministry observed that certain fake and unverified messages are being spread, especially on social media.




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Outstanding power sector dues of States decline by ₹24,680 crore

It is expected that strict implementation of the LPS rules will bring back financial viability of the power sector in the country and would attract investment to ensure reliable 24x7 electricity to the consumers




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ONDC may cover mobility, hospitality and travel sectors

Plans come at a time when traditional transport, hotel and restaurant sectors are up in arms against monopolisation of some aggregators




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110 mt of coal stocks to be maintained at mine pitheads, power plants by March 2023: Coal Secretary

For the first time, power plants on the western coast would receive coal through the coastal shipping route, he said




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Public, private sectors need to leverage synergy and think out-of-the-box, says PM Modi

Modi meets economists seeking suggestions for the Budget




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Of secret gardens, music and garlic

Check out the places where people are partying across the globe this month




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Embrace modern science, AYUSH secretary urges Ayurveda docs




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Second entrance of Kottayam railway station opened




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Sack security agency: Press Club to Tatas




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Holdplay: police secure concert venue




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The long-term effects of income for at-risk infants [electronic resource] : evidence from supplemental security income / Amelia A. Hawkins, Christopher A. Hollrah, Sarah Miller, Laura R. Wherry, Gloria Aldana, Mitchell D. Wong

Cambridge, MA. : National Bureau of Economic Research, 2023




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Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance

Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance Indo-Pacific Lens on the Arctic: How US Partners in Asia View Arctic Security and Governance

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​​Vietnamese Perspective on the Significance of the US-Australia Alliance in Southeast Asian Security​

​​Vietnamese Perspective on the Significance of the US-Australia Alliance in Southeast Asian Security​ ​​Vietnamese Perspective on the Significance of the US-Australia Alliance in Southeast Asian Security​

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Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship Strategic Partners or Fickle Friends? Indonesia’s Perceptions of the US-Australia Defense and Security Relationship

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Shifting waste workers from the informal sector to the formal

A material recovery and segregation facility in Delhi shows that this is possible




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Insurance is the new buzzword in the renewable power sector

Insurers are eyeing the solar, wind and green power projects as the new growing market to tap




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Drone technology is expected to revolutionise India's marine fisheries sector




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Union Minister Kumaraswamy spotlights 'revolutionary changes' in India's health sector




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No longer one-sided beneficiary of alliance with US: South Korean National Security Advisor




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India's public sector banks clocks 11 pc growth at Rs 236 lakh crore in April-Sep FY25




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Telangana SPF takes over security of Secretariat from the TGSP




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Telugu-origin Usha Chilukuri set to become 'Second Lady' of US




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Andhra Pradesh eyes Rs 1,000 cr investment in drone sector




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PM Modi, Spanish President Sanchez hold productive discussions, review bilateral cooperation across various sectors




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Centre to unveil drone technology for fisheries sector in Kochi




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Sonata Software secures multi-year deal from Fortune 500 manufacturing company

The client is partnering with Sonata Software to modernise its operations and deliver a homogenous, unified user experience at scale




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Indian online gaming sector faces money laundering threat, warns report

The sector employs around one lakh people and has the potential to to create 2,50,000 jobs by 2025




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Revolutionising data security: IBM introduces Guardium Data Security Centre with GenAI capabilities

The centre incorporates GenAI features for generating risk summaries and improving productivity among security teams.




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IT sector records positive net hiring from top four firms for first time in two years

Despite this positive trend, industry experts caution that the current demand environment remains uncertain, and graduates have expressed frustrations over delayed joining dates 




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UST opens second delivery centre in Bengaluru 

The new facility is located in Helios Business Park, Kadabeesanahalli




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SaaS can help firms enhance their cybersecurity posture: CyberArk official

Contrary to common misconceptions, SaaS solutions will be helpful in managing complex IT environments, says Rohan Vaidya




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Cyient DLM secures 16-year aerospace contract with Honeywell 

The shares of Cyient DLM Limited were trading at ₹644.85 up by ₹11.80 or 1.86 per cent on the NSE today at 1.40 pm




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RRP Semiconductor secures ₹440 crore order from Telecrown Infratech for solar project

The order includes Silicon Solar Cells, melted Silicon Crystals, and Polycrystalline materials, aimed at supporting the setup of 106 MW solar power PV modules in various locations across Maharashtra




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SAP’s India lab fastest-growing and second-largest, says company CEO

The company deepened its investments in the country with the new campus, aiming to create 15,000 new jobs in Bengaluru




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Indian IT sector lags in global RPE standards, yet digital shift signals growth potential

The Indian IT sector, while traditionally emphasising cost-effective outsourcing, is gradually evolving to enhance RPE and profitability through investments in upskilling and digital innovation




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KPMG in India forms strategic alliance with SecurityBridge to enhance SAP security and compliance

KPMG in India, one of the country’s leading professional services firms, has announced a strategic alliance with SecurityBridge GmbH, a renowned provider of SAP-native cybersecurity solutions. This collaboration aims to enhance SAP security and compliance offerings for clients by integrating SecurityBridge’s cutting-edge technology into KPMG’s comprehensive service portfolio




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Synthesis of alkenylphosphine oxides via Tf2O promoted addition–elimination of ketones and secondary phosphine oxides

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00318G, Communication
Jiangkai Ma, Lianjie Wang, Anjiang Qiao, Zhongxian Li, Fengqian Zhao, Junliang Wu
An efficient method for the synthesis of alkenylphosphine oxides via the addition-elimination of SPOs to ketones has been developed. The reaction exhibits good yields and compatibility. Several conversions have also proven the value of this method.
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Visible light-driven photocatalytic sulfonative oxidation of benzyl secondary amines

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00348A, Paper
Yong-Xiang Lü, Xinqian Wang, Ying-Ming Pan, Keyume Ablajan
A method for the α-oxidation and sulfonation of benzyl secondary amines was developed utilizing Ir(III) or Eosin Y as the photocatalyst in the presence of O2 as a green oxidant....
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2022 holds promise for the airline sector

Omicron might dent growth, but the long-term outlook seems promising




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Evolution of security in aviation

Data and technology need to be adopted




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Hong Kong unveils responsible AI framework for financial sector

Hong Kong’s responsible AI framework comes amid increasing international competition and tensions affecting access to AI technology




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The Role of Artificial Intelligence in Enhancing Software Performance and Security

Sachin Samrat Medavarapu, a recognized leader in AI-enhanced security and performance optimization, has built an impressive career marked by a series of significant achievements.




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The secret of doing great work

Find that sweet spot between loving what you do and doing what you love




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As farm labour diminishes, mechanisation is key for India’s agri-sector growth, says Mahindra & Mahindra’s Sikka 

Hemant Sikka says the farm machinery industry is expected to grow from ₹9,200 crores in financial year 2022 to ₹15,000 crores in financial year 2026.




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High import duties; resisting pressure to open agricultural sector important to ensure India's food security: GTRI

Economic think tank GTRI (Global Trade Research Initiative) in its report said that India needs to cut its reliance on imported vegetable oils to promote better health outcomes and also reduce the import bill