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The effect of second coordination sphere interactions on the magnetic anisotropy of transition metals

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02873B, Paper
Sofie S. Leiszner, Mauro Perfetti, Emil Damgaard-Møller, Yu-Sheng Chen, Bo B. Iversen
By investigating second coordination sphere effects on the magnetic anisotropy of a Co(II) single molecule magnet (SMM), we aim to clarify their role in magneto-structural correlations to enhance the performance of transition metal SMMs.
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Reactions of a geminal Sc/P Lewis pair with pyridotetrazole and beyond

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02838D, Paper
Yiwen Guan, Xian Xu, Xin Xu
An FLP pyridyl nitrene adduct was isolated from the denitrogenative reaction of the Sc/P complex with pyridotetrazole. FLP reactivity of the Sc/P complex with many small molecules were investigated with the generation of metallacyclic complexes.
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Mechanistic studies of NOx reduction reactions involving copper complexes: encouragement of DFT calculations

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02420F, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yohei Kametani, Yoshihito Shiota
Mechanistic analysis of nitrite (NO2) and nitric oxide (NO) reduction reactions promoted by copper complexes provides a reliable view of electron transfer and atom movement.
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Synthesis of organo-uranium(II) species in the gas-phase using reactions between [UH]+ and nitriles

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02508C, Paper
Justin G. Terhorst, Theodore A. Corcovilos, Samuel J. Lenze, Michael J. van Stipdonk
A series of gas-phase, σ-bonded [U–R]+ species (R = CH3, C2H3, C2H5, C3H7, or C5H6) can be generated by using preparative tandem mass spectrometry (PTMSn) via ion-molecule reactions between [UH]+ and neutral nitriles.
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Three-step thermodynamic vs. two-step kinetics-limited sulfur reactions in all-solid-state sodium batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03160A, Paper
Tongtai Ji, Qingsong Tu, Yang Zhao, Dominik Wierzbicki, Vincent Plisson, Ying Wang, Jiwei Wang, Kenneth S. Burch, Yong Yang, Hongli Zhu
This study unveils the intrinsic three-step thermodynamic and the two-step kinetics-limited pathways in all-solid-state sodium–sulfur batteries, providing crucial insights into sulfur reaction mechanisms for high-performance energy storage solutions.
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Digital Pareto-front mapping of homogeneous catalytic reactions

React. Chem. Eng., 2024, 9,787-794
DOI: 10.1039/D3RE00673E, Communication
Open Access
Negin Orouji, Jeffrey A. Bennett, Sina Sadeghi, Milad Abolhasani
We present a digital framework for rapid multi-objective reaction space exploration and optimization of homogeneous catalytic reactions through autonomous experimentation and Bayesian optimization.
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Thermokinetic analyses of metal-sensitive reactions in a ceramic flow calorimeter

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00014E, Paper
Open Access
Soritz S., Sommitsch A., Irndorfer S., Brouczek D., Schwentenwein M., Priestley I. J. G., Iosub A. V., Krieger J. P., Gruber-Woelfler H.
A ceramic flow calorimeter for metal-sensitive reactions is characterized and used to obtain thermokinetic data on highly exothermic reactions.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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Metagenomic and transcriptomic profiling of the hypoglycemic and hypotriglyceridemic actions of Tremella fuciformis-derived polysaccharides in high-fat-diet- and streptozotocin-treated mice

Food Funct., 2024, 15,11096-11114
DOI: 10.1039/D4FO01870B, Paper
Xiaofei Xu, Xiaofei Liu, Liyan Liu, Jin Chen, Jingjing Guan, Donghui Luo
Tremella fuciformis polysaccharides exhibit hypoglycemic and hypotriglyceridemic activities through altering the taxonomic and functional attributes of the gut microbiota and modulating gene expression in the liver.
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Human milk oligosaccharides and milk fat globule membrane reduce allergic reactions in mice through the modulation of gut microbiota and metabolic functions

Food Funct., 2024, 15,11252-11265
DOI: 10.1039/D4FO03851G, Paper
Xinzhang Chen, Shengjun Yang, Zhengtao Guo, Bailiang Li, Zhongjiang Wang, Lianzhou Jiang
Human milk oligosaccharides (HMOs) and the milk fat globule membrane (MFGM) represent novel treatments for cow's milk allergy (CMA).
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Tangled in a web of distractions?

The power to enter and exit lies in your hands.




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Exploring anodic oxidation reactions in hybrid water electrolysis: special emphasis on substrate choice

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00907J, Review Article
Baghendra Singh, Neetu Verma
Anodic oxidation reactions have been assessed focusing on essential parameters for the substrate choice.
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Ultrasmall RuO2/CoFe2O4 nanoparticles with robust interfacial interactions for the enhanced acidic oxygen evolution reaction

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00719K, Paper
Open Access
Ming Wei, Liuhua Mu, Zhiwei Liu, Feng Gao, Guangjian Song, Qiankang Si, Mao Zhang, Fangfang Dai, Min Zhang, Rui Ding, Li Yang, Zhonggui Gao, Sanzhao Song
Ultrasmall RuO2/CoFe2O4 nanoparticles with strong interfacial interactions exhibit enhanced oxygen evolution reaction (OER) performance, driven by efficient charge transfer between RuO2 and CoFe2O4.
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Theoretical insights into Pt–Rh alloy nanoparticles: stability, elemental distribution, and catalytic mechanisms for NO + CO reactions

Catal. Sci. Technol., 2024, 14,6286-6297
DOI: 10.1039/D4CY00755G, Paper
Yuzheng Li, Xianbao Duan, Zhang Liu, Caoran Li, Fangwen Ye, Zhihong Zhang, Liuqing Chen, Chun Du, Qingbo Wang, Bin Shan
Pt–Rh alloy nanoparticles featuring surfaces with both Pt and Rh atoms are poised to demonstrate bifunctional catalytic prowess in the NO + CO reaction.
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Enhancing light-driven photocatalytic reactions through solid solutions of bismuth oxyhalide/bismuth rich photocatalysts: a systematic review

Catal. Sci. Technol., 2024, 14,6466-6495
DOI: 10.1039/D4CY00820K, Review Article
Open Access
Robert O. Gembo, Rudzani Ratshiedana, Lawrence M. Madikizela, Ilunga Kamika, Cecil K. King'ondu, Alex T. Kuvarega, Titus A. M. Msagati
The pursuit of sustainable environmental remediation strategies has led to intensive research in photocatalysis.
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Electrostatic interactions and structural transformations in viral shells

Nanoscale, 2024, 16,20182-20193
DOI: 10.1039/D4NR02612H, Paper
Open Access
Ivan Yu. Golushko, Daria S. Roshal, Olga V. Konevtsova, Sergei B. Rochal, Rudolf Podgornik
Considering the simplest energy of electrostatic interactions between proteins together with the mechanical energy of the continuum shell, one can model various structural transformations possible in viral capsids.
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Improving Dynamic Control of Toehold-Mediated Strand Displacement Reactions through Phosphorothioate Modifications

Nanoscale, 2024, Accepted Manuscript
DOI: 10.1039/D4NR04201H, Paper
Ruyi Liang, Yiyang Shen, Tanqing Long, Peilin Yang, Chuanrui Xu, Tongbo Wu, Mingxia Zhang
The toehold-mediated strand displacement reaction plays a crucial role in the functionality of DNA nanodevices. However, the reaction's velocity is heavily reliant on the length of the toehold region. A...
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Agency areas in ASR district beckon tourists with new attractions this season

Paramotor rides and tethered hot air balloon rides are being launched in the Araku Valley, where most of the tourists prefer to stay, say officials




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Take recovery from ‘avoidance transactions’ seriously, IBBI tells creditors. 

Recovery for creditors could go up at least 10 per cent on such approach, says IBBI Chief Mital; Till Sep 2024, total clawback on avoidance transactions applications stood at ₹7,516 crore




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Dyslexia in many languages [electronic resource] : insights, interactions, and interventions / edited by Gad Elbeheri, Gavin Reid and Angela Fawcett.

Abingdon, Oxon ; New York, NY : Routledge , 2025.




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Simple guidelines could make designing catalysts for electrochemical reactions easy

Theoretical model uses readily available data to predict catalysts for tackling energy challenges




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ACS Board actions from the June executive meeting




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Single atoms catalyze Suzuki reactions

Flow chemistry process takes place on carbon nitride surface




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Engineering high-valence nickel sites in Ni3S2/Ni3Se2 architectures enabling urea-assisted hydrogen evolution reactions

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04318A, Paper
Taotao Ai, Miaomiao Bai, Weiwei Bao, Jie Han, Xueling Wei, Xiangyu Zou, Jungang Hou, Lizhai Zhang, Zhifeng Deng, Yuxin Zhang
Bifunctional Ni3S2@Ni3Se2 electrocatalysts were constructed for urea-assisted hydrogen evolution. In the HER/UOR two-electrode system, the heterogeneous interface modulates the electronic structure and thus improves the catalytic performance.
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Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
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Donald Trump’s victory sparks mixed reactions; experts urge intensified action for climate crisis




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[ Politics ] Open Question : Should Gregory and Travis McMichael be freed and given a medal of honor for their heroic actions of taking a dangerous thug of the streets?




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Actions rather than words

A team mobilised by OM El Salvador walked for hours to show God’s love to the people of Cabañas. With actions rather than words.




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Our actions leave their mark on society

The Gospel is primarily about relationships that impact, influence and are relevant, states Pastor Hugo Echeverri, a representative of OM in Colombia.




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‘India well placed to deal with Fed, global central bank actions’

India is better placed to manage uncertainty arising from different monetary policy...




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Audit of Central Bank to include all its transactions: Nehme

The audit of Lebanon's central bank accounts announced last month will include every transaction at the bank, Economy Minister Raoul Nehme said in an interview published on Sunday.





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State and Metro Governments, Consumer Actions Drive Dramatic Shift in US Energy Landscape

The United States is experiencing a significant shift in its energy landscape. Last year, utility-scale wind and solar power combined for 47 percent of new generation capacity in the U.S. Based on this expansion, 11 states now generate more than 10 percent of their electricity from solar, wind, and geothermal power, with three of these states — Iowa, South Dakota, and Kansas — exceeding 20 percent. In 2014, California became the first state in the nation to garner 5 percent of its electricity from utility-scale solar. When including hydropower, four states —Idaho, Washington, Oregon, and South Dakota — now exceed 70 percent renewables generation.




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Value added tax and barter transactions

This VAT and Duties Tribunal decision, Riverside Sports & Leisure Limited, concerned the grant of a lease over sports facilities. It illustrates the point that value added tax (VAT) can be problematical in the most innocuous of transactions. In...




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FOOi: the tipping point in cashless transactions in Canada

Transitioning to the cashless society just got easier with FOOi, a digital wallet that enables Canadians to make instant peer-to-peer and peer-to-business payments. And it all began with a conversation about tipping.   “Climbing Mount Kilimanjaro together was easier in some respects than launching this app,” says David Morrison. “We’ve certainly experienced a steep learning…




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Audit of Lebanon's central bank to include all its transactions - economy minister




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Mixed reactions to Government’s new Covid-19 slogan

Britons are now set to be asked to ‘Stay alert, control the virus, save lives’.




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Science-industry knowledge exchange: A mapping of policy instruments and their interactions

Countries deploy a variety of policy instruments to promote science-industry knowledge exchange. While these instruments are often discussed in isolation, they are implemented collectively and may negatively affect each other or add excessive complexity. This paper develops a conceptual framework to map policy instruments for knowledge exchange and assess interactions.




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Countries should focus on labour market policies to help refugees and improve coordinated actions to tackle illegal immigration

Migration flows to OECD countries have dropped slightly for the first time since 2011, with around 5 million new permanent migrants in 2017, down from 5.3 million in 2016. This trend is mainly due to a significant decrease in new asylum applications, with 1.2 million applications in 2017 compared to 1.6 million in 2016, according to a new OECD report.




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Climate change and trade policy interactions: Implications of regionalism - Trade and Environment Working Paper

This report examines the implications of regional climate governance for international trade and conversely the implications of regional trade governance for climate change action. Regional approaches to climate change governance are discussed with a specific focus on the rise of “climate clubs” and their implications for international trade.