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Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

Chem. Soc. Rev., 2024, 53,10450-10490
DOI: 10.1039/D4CS00527A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Denis Leybo, Ubong J. Etim, Matteo Monai, Simon R. Bare, Ziyi Zhong, Charlotte Vogt
Metal–support interactions (MSI) impact catalyst activity, stability, and selectivity. This review critically evaluates recent findings, theoretical advances, and MSI tuning strategies, offering new perspectives for future research in the field.
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Contribution of an instructional module, incorporating PhET simulations, to Rwanda students’ knowledge of chemical reactions and acids and bases through Social Interaction.

Chem. Educ. Res. Pract., 2025, Accepted Manuscript
DOI: 10.1039/D4RP00105B, Paper
Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode MUKAMA, Olivier Habimana, Paulin Manirakiza , Jean Claude Dushimimana , Jean Pierre Alpha Munyaruhengeri , Samia Khan, Elizabeth Lakin
The current study ascertained the influence an instructional module had on enhancing students’ understanding of chemical reactions and acid-base topics. The sample size for this study consisted of 197 students,...
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“It is not just the shape, there is more”: students’ learning of enzyme–substrate interactions with immersive Virtual Reality

Chem. Educ. Res. Pract., 2025, Advance Article
DOI: 10.1039/D4RP00210E, Paper
Henry Matovu, Mihye Won, Roy Tasker, Mauro Mocerino, David Franklin Treagust, Dewi Ayu Kencana Ungu, Chin-Chung Tsai
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Advancing Lithium-Sulfur Battery Efficiency: Utilizing a 2D/2D g-C3N4@MXene Heterostructure to Enhance Sulfur Evolution Reactions and Regulate Polysulfides in Lean Electrolyte Conditions

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D4MH00200H, Communication
Vijay Kumar, Otavio Augusto Titton Dias, Abdelaziz Gouda, Ritu Malik, Mohini M. Sain
Lithium–sulfur batteries (LSBs) show promise for achieving a high energy density of 500 Wh/kg, despite challenges such as poor cycle life and low energy efficiency due to sluggish redox kinetics...
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Hierarchical surface-modification of nano-Cu toward one pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions

Mater. Horiz., 2024, 11,1957-1963
DOI: 10.1039/D3MH01921G, Communication
Zhi-Qiang Wang, ChengHua Deng, Bo Li, Hai-Qiang Luo, Peng Hao, Xiao Liu, Jian-Gong Ma, Peng Cheng
One pot H-transfer-coupling–cyclization–CO2 fixation tandem reactions to synthesize high value-added dihydrobenzofurans are realized through the hierarchically constructed Cu–Ag nanoalloy with a MOF cover as an efficient catalyst.
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actions

Urban Interactions [electronic journal].




actions

Superstar Exporters: An Empirical Investigation of Strategic Interactions in Danish Export Markets [electronic journal].




actions

Social Interactions in Pandemics : Fear, Altruism, and Reciprocity [electronic journal].

National Bureau of Economic Research




actions

Skin-in-the-Game in ABS Transactions: A Critical Review of Policy Options [electronic journal].




actions

Rebating Antitrust Fines to Encourage Private Damages Actions [electronic journal].




actions

Professional Interactions and Hiring Decisions: Evidence from the Federal Judiciary [electronic journal].

National Bureau of Economic Research




actions

Market Reactions to Quest for Decentralization and Independence: Evidence from Catalonia [electronic journal].




actions

Informative Social Interactions [electronic journal].




actions

IEEE Transactions on Artificial Intelligence [electronic journal].




actions

Feverish Stock Price Reactions to COVID-19 [electronic journal].




actions

Factions in Nondemocracies: Theory and Evidence from the Chinese Communist Party [electronic journal].

National Bureau of Economic Research




actions

Dynamic Social Interactions and Health Risk Behavior [electronic journal].

National Bureau of Economic Research




actions

Demand and Welfare Analysis in Discrete Choice Models with Social Interactions [electronic journal].

National Bureau of Economic Research




actions

Dancing with the Stars: Innovation Through Interactions [electronic journal].

National Bureau of Economic Research




actions

Cryptocurrency market reactions to regulatory news [electronic journal].




actions

Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D3QI02507A, Research Article
Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The change of counter anions significantly affects the environment around Co(II) ions, leading to two zero-field single-ion magnets possessing different uniaxial anisotropies and dynamic magnetic properties.
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00511B, Research Article
Open Access
Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
A cyanido-bridged Co–W assembly with π–π interactions showed a thermal phase transition and a photo–induced metamagnetism based on a charge transfer–induced spin transition.
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Dynamic satellite–parent liposome networks for quantitative microreactions

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04925J, Edge Article
Open Access
Jia-Qi Tian, Nan-Nan Deng
A dynamic satellite–parent liposome network was developed to explore molecular transfer and quantitative microreactions through environmental stimuli, offering a platform to mimic multicellular systems in vitro.
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Differentiating carrier protein interactions in biosynthetic pathways using dapoxyl solvatochromism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05499G, Edge Article
Open Access
Matthew G. Miyada, Yuran Choi, Kyle Rich, James J. La Clair, Michael D. Burkart
A highly sensitive solvatochromic system was developed to monitor the loading and interactivity of carrier proteins associated with fatty acid, polyketide and non-ribosomal peptide biosynthesis.
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ModaXL 200 mg Review - Dosage, Interactions, Side Effects (Full Guide)

Want to order ModaXL 200 mg in 2024? Read this guide and learn more about the smart drug ModaXL. Safety, correct dosages, possible side effects, best places to buy the nootropic and much more in this helpful review.




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Split decision: On the rivalry between the two NCP factions

The ECI and the office of the Speaker have not played fair in cases of defection




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Network interactions simultaneously enhance stiffness and lubricity of triple-network hydrogels

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00969J, Paper
Nabila Ali, Connor J. Demott, Olivia F. Dingus, Melissa A. Grunlan, Alison C. Dunn
Tough hydrogels with a charge-variable third network were assessed for biomimicking lubricity in both water and FBS solution.
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Controlling wall–particle interactions with activity

Soft Matter, 2024, 20,8395-8406
DOI: 10.1039/D4SM00634H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Luke Neville, Jens Eggers, Tanniemola B. Liverpool
The interaction between a disk and wall in an active nematic depends on a combination of activity and anchoring, with contractile nematics repelling disks with planar anchoring.
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Rolling and ordering of micro rods in shear flow induced by rod wall interactions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00999A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Martin Wittmann, Igor M. Kulić, Antonio Stocco, Juliane Simmchen
We use experiments and theoretical models to investigate the rolling and translational motion of rod-shaped micro particles close to a solid wall in the presence or absence of shear flow.
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Scale-dependent interactions enable emergent microrheological stress response of actin–vimentin composites

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00988F, Paper
Julie Pinchiaroli, Renita Saldanha, Alison E. Patteson, Rae M. Robertson-Anderson, Bekele J. Gurmessa
The unique mechanical behaviors of actin–vimentin composites in both linear and nonlinear regimes are shaped by the complex interactions among actin entanglements, vimentin crosslinking, and poroelastic properties.
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Self-consistent electrostatic formalism of bulk electrolytes based on the asymmetric treatment of the short- and long-range ion interactions

Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM01174K, Paper
Sahin Buyukdagli
Internal energy of monovalent electrolytes (left) and dimensionless screening parameter of multivalent electrolytes (right).
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UPI transactions could double to 1 billion per day in the next few months: RBI Guv Das

RBI is in no great hurry to immediately announce a nationwide rollout of the central bank digital currency (CBDC)



  • Money & Banking

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UPI sets new record, transactions rise to 16.58 billion in October

Festival season spending aided the 45 per cent y-o-y rise in October UPI transactions



  • Money & Banking

actions

Pilikula zoo gets new attractions in the form of Asiatic Lion, other animals and birds




actions

Real estate transactions drop 71% in Q3 2024, private equity dominates

Despite the overall fall, the number of deals rose 5% quarter-on-quarter and 54% year-on-year, with a potential revival in Q4. 




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Pune’s home sales value surges 19% in Q3 2024 despite a slight dip in transactions

Based on data from the Inspector General of Registration (IGR), the city’s home sales value jumped 19 per cent year-on-year (YoY), reaching ₹13,865 crore




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Synthesis of C-glycosides enabled by palladium-catalyzed glycosylation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01619J, Review Article
Wenli Tong, Jie-Ping Wan, Jianchao Liu
This review highlights the recent progress in palladium-catalyzed C-glycosylation reactions for the synthesis of C-glycosides.
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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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HSAB theory guiding electrophilic substitution reactions of o-carborane

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01546K, Research Article
Yan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian Chen
Herein, we systematically compared the reactivity of o-carborane and benzene toward different electrophiles and explained the results with the HSAB principle.
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The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01703J, Review Article
Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
Recent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.
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Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives

Org. Chem. Front., 2024, 11,6418-6425
DOI: 10.1039/D4QO01298D, Research Article
Wei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun Yao
A phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.
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Transition-metal-catalyzed C–Ge coupling reactions

Org. Chem. Front., 2024, 11,6558-6572
DOI: 10.1039/D4QO01637H, Review Article
Jie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan He
This review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.
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Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01794C, Research Article
Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
The mechanism of selenium-catalyzed allylic amination reactions with different ligands has been explored using density functional theory calculations.
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Carbonate weakens the interactions between potassium and calcareous soil

RSC Adv., 2024, 14,35275-35285
DOI: 10.1039/D4RA05988C, Paper
Open Access
Wei Du, Shifeng Wang, Yizhe Yang, Chenyang Xu, Feinan Hu, Wuquan Ding, Jialong Lv
Adsorption energies of K+ in carbonate-removed (CREM) and carbonate-reserved (CRES) calcareous soil.
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Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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Construction of efficient Pb(II) carboxylate catalysts for Oxygen and Hydrogen Evolution Reactions

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02958E, Paper
Janak ., Vijay Sarjerao Sapner, Bhaskar Ramchandra Sathe, Sadhika Khullar
The development of cost-effective and efficient electrocatalysts can solve the problem in the production of energy via water splitting reactions. In this work, we focused on two lead-based coordination polymers...
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Syntheses and structures of dimesitylphosphinite complexes of alkali metals and their catalytic activity in hydrophosphorylation reactions

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02721C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Benjamin E. Fener, Philipp Schüler, Phil Liebing, Helmar Görls, Matthias Westerhausen
The diarylphosphinite complexes of the alkali metals exhibit a broad structural variety. Especially for potassium dimesitylphosphinite, the heterocubane cage can be broken down into dimeric K2O2 units by adding oligodentate ether molecules.
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Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02514H, Paper
Khalil Youssef, Antoine Vacher, Thanaphon Khrueawatthanawet, Thierry Roisnel, Frédéric Barrière, Dominique Lorcy
Multinuclear complexes involving two or three redox active Pt(dithiolene) moieties were synthesized and electronic interactions were analysed through a combination of experimental and theoretical investigations.
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Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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