The dinuclear mol­ecule of the title compound, [Mo2(C9H13)2(CO)6] or [Mo(tBuCp)(CO)3]2 where tBu and Cp are tert-butyl and cyclo­penta­dienyl, is centrosymmetric and is characterized by an Mo—Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, the tBuCp and the carbonyl ligands are in a transoid arrangement to each other. In the crystal, inter­molecular C—H⋯O contacts lead to the formation of layers parallel to the bc plane.

The title complex, (1,4,7,10,13,16-hexa­oxa­cyclo­octa­decane-1κ6O)(μ-oxalato-1κ2O1,O2:2κ2O1',O2')triphenyl-2κ3C-potassium(I)tin(IV), [KSn(C6H5)3(C2O4)(C12H24O6)] or K[18-Crown-6][(C6H5)3SnO4C2], was synthesized. The complex consists of a potassium cation coordinated to the six oxygen atoms of a crown ether mol­ecule and the two oxygen atoms of the oxalatotri­phenyl­stannate anion. It crystallizes in the monoclinic crystal system within the space group P21. The tin atom is coordinated by one chelating oxalate ligand and three phenyl groups, forming a cis-trigonal–bipyramidal geometry around the tin atom. The cations and anions form ion pairs, linked through carbonyl coordination to the potassium atoms. The crystal structure features C—H⋯O hydrogen bonds between the oxygen atoms of the oxalate group and the hydrogen atoms of the phenyl groups, resulting in an infinite chain structure extending along a-axis direction. The primary inter-chain inter­actions are van der Waals forces.

This study presents the synthesis, characterization and Hirshfeld surface analysis of the title mononuclear complex, [PdCl2(C12H14N4)]·C3H7NO. The compound crystalizes in the P21/c space group of the monoclinic system. The asymmetric unit contains one neutral complex Pd(HLc-Pe)Cl2 [HLc-Pe is 2-(3-cyclo­pentyl-1,2,4-triazol-5-yl)pyridine] and one mol­ecule of DMF as a solvate. The Pd atom has a square-planar coordination. In the crystal, mol­ecules are linked by inter­molecular N—H⋯O and C—H⋯N hydrogen bonds, forming layers parallel to the bc plane. A Hirshfeld surface analysis showed that the H⋯H contacts dominate the crystal packing with a contribution of 41.4%. The contribution of the N⋯H/H⋯N and H⋯O/O⋯H inter­actions is somewhat smaller, amounting to 12.4% and 5%, respectively.

In the title compound, C33H29ClN2O2, the two piperidine rings of the di­aza­bicyclo moiety adopt distorted-chair conformations. Inter­molecular C—H⋯π inter­actions are mainly responsible for the crystal packing. The inter­molecular inter­actions were qu­anti­fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter­actions contribute most to the crystal packing (52.3%). The mol­ecular structure was further optimized by density functional theory (DFT) at the B3LYP/6–31 G(d,p) level and is compared with the experimentally determined mol­ecular structure in the solid state.

When reacted in dry, degassed toluene, [Ir(COD)Cl]2 (COD = cyclo­octa-1,5-diene) and 2 equivalents of 2-(di-tert-butyl­phosphinito)anthra­quinone (tBuPOAQH) were found to form a unique tri-iridium compound consisting of one monoanionic dinuclear tri-μ-chlorido complex bearing one bidentate tBuPOAQ ligand per iridium, which was charge-balanced by an outer sphere [Ir(toluene)(COD)]+ ion, the structure of which has not previously been reported. This product, which is a toluene solvate, namely, (η2:η2-cyclo­octa-1,5-diene)(η6-toluene)­iridium(I) tri-μ-chlorido-bis­({3-[(di-tert-butyl­phosphan­yl)­oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(III)) toluene monosolvate, [Ir(C7H8)(C8H12)][Ir2H2(C22H24O3P)2Cl3]·C7H8 or [Ir(toluene)(COD)][Ir(κ-P,C-tBuPOAQ)(H)]2(μ-Cl)3]·toluene, formed as small orange platelets at room temperature, crystallizing in the triclinic space group Poverline{1}. The cation and anion are linked via weak C—H⋯O inter­actions. The stronger inter­molecular attractions are likely the offset parallel π–π inter­actions, which occur between the toluene ligands of pairs of inverted cations and between pairs of inverted anthra­quinone moieties, the latter of which are capped by toluene solvate mol­ecules, making for π-stacks of four mol­ecules each. The related ligand, 2-(di-tert-butyl­phosphinometh­yl)-anthra­quinone (tBuPCAQH), did not form crystals suitable for X-ray diffraction under analogous reaction conditions. However, when the reaction was conducted in chloro­form, yellow needles readily formed following addition of 1 atm of carbon monoxide. Diffraction studies revealed a neutral, dinuclear, di-μ-chlorido complex, di-μ-chlorido-bis­(carbon­yl{3-[(di-tert-butyl­phosphan­yl)­oxy]-9,10-dioxoanthracen-2-yl}hydridoiridium(I)), [Ir2H2(C23H26O2P)2Cl2(CO)2] or [Ir(κ-P,C-tBuPCAQ)(H)(CO)(μ-Cl)]2, Ir2C48H54Cl2O6P2, again crystallizing in space group Poverline{1}. Offset parallel π–π inter­actions between anthra­quinone groups of adjacent mol­ecules link the mol­ecules in one dimension.

The reaction of Zn(ClO4)2·6H2O with Na3SbS4·9H2O in a water/aceto­nitrile mixture leads to the formation of the title compound, (μ-tetra­thio­anti­monato-κ2S:S')bis­[(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ4N)zinc(II)] perchlorate 0.8-hydrate, [Zn2(SbS4)(C10H24N4)2]ClO4·0.8H2O or [(Zn-cyclam)2(SbS4)]+[ClO4]−·0.8H2O. The asymmetric unit consists of two crystallographically independent [SbS4]3– anions, two independent perchlorate anions and two independent water mol­ecules as well as four crystallographically independent Zn(cyclam)2+ cations that are located in general positions. Both perchlorate anions and one cyclam ligand are disordered and were refined with a split mode using restraints. The water mol­ecules are partially occupied. Two Zn(cyclam)2+ cations are linked via the [SbS4]3– anions into [Zn2(cyclam)2SbS4]+ cations that are charged-balanced by the [ClO4]− anions. The water mol­ecules of crystallization are hydrogen bonded to the [SbS4]3– anions. The cations, anions and water mol­ecules are linked by N—H⋯O, N—H⋯S and O—H⋯S hydrogen bonds into a three-dimensional network. Powder X-ray diffraction proves that a pure sample had been obtained that was additionally investigated for its spectroscopic properties.

The crystal structure of the title compound, [Ni(C8H20N4)(NO3)]NO3, at room temperature, has monoclinic (P21/n) symmetry. The structure displays inter­molecular hydrogen bonding. The nickel displays a distorted bipyramidal geometry with the symmetric bidentate bonded nitrate occupying an equatorial site. The 1,4,7,10-tetra­aza­cyclo­dodecane (cyclen) backbone has the [4,8] configuration, with three nitro­gen-bound H atoms directed above the plane of the nitro­gen atoms towards the offset nickel atom with the fourth nitro­gen-bound hydrogen directed below from the plane of the nitro­gen atoms. The nitrate anion O atoms are seen to hydrogen bond to the H atoms bound to the N atoms of the ligand.

The title compound, C18H21N3O3, was prepared from 1,3,5-benzene­tricarbonyl trichloride and cyclo­propyl­amine. Its crystal structure was solved in the monoclinic space group P21/c. In the crystal, the three amide groups of the mol­ecule are inclined at angles of 26.5 (1), 36.9 (1) and 37.8 (1)° with respect to the plane of the benzene ring. The mol­ecules are linked by N—H⋯O hydrogen bonds, forming two-dimensional supra­molecular aggregates that extend parallel to the crystallographic ab plane and are further connected by C—H⋯O contacts. As a result of the supra­molecular inter­actions, a propeller-like conformation of the title mol­ecule can be observed.

Used cooking oil will be accepted only at the Blackburn Solidwaste Convenience Center at 3864 Rocky Ford Road, Newton, NC 28658. No business waste accepted. The Blackburn Solidwaste Convenience Center is open Monday through Saturday from 8 a.m. to 6 p.m.

The agreement would substantially increase the number of items collected for recycling across Catawba County, with further expansion of items collected as needed over time; begin �single stream� collection of recyclable commodities so recycled materials would no longer be required to be separated at curbside; increase Republic Services� investment in Catawba County by $13 million; and protect more than 150 local jobs.

A new County Solid Waste Franchise with Republic Services (formerly known as GDS), effective July 1, is bringing expanded recycling, new fee schedule, services.

Catawba County offers electronics and paint recycling, year round, at Blackburn Landfill during regular landfill operating hours, as of July 1.

Many Catawba County residents will be able to recycle more items beginning November 4.

The U.S. Global Change Research Program (USGCRP) asked the National Academies of Sciences, Engineering, and Medicine to review the draft Fourth National Climate Assessment (NCA4) – a congressionally mandated report that evaluates the state of climate science and the broad range of impacts of climate change in the United States every four years – and the draft Second State of the Carbon Cycle Report (SOCCR2) – a report that feeds into the overall assessment process developed by the USGCRP.

Life cycle assessments of low-carbon transportation fuels — such as electricity, biofuels, or hydrogen — are valuable tools for measuring environmental impacts, but uncertainties remain in the models that are currently used, and further research should be conducted to strengthen their reliability.

NASA's Aqua satellite passed over the U.S. Southwest and captured infrared data on the clouds associated with former Tropical Cyclone Newton.

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The brand's new multipack offerings will launch around Expo West.

To recycle, consumers simply insert or reattach the twist tie to a bread bag that is qualified for store drop-off before placing it in the bin.

The upcycled tortilla chips reportedly save 20 gallons of water per bag.

Five new ingredients accelerate nutritious, sustainable product development.

Upcycled Foods, Inc. has co-developed Upcycled Pizza Dough with DeIorio's Foods, Inc., a frozen dough manufacturer that's celebrating its 100th anniversary this year. 

Innovators collaborate to design upcycled ingredient solutions for food industry.

T. Hasegawa's newest trends report takes a look at foodservice, flavors, and generational trends.

To support consumers in making conscious decisions, Cabosse Naturals has deepened its collaboration with the Upcycled Food Association.

The companies are empowering consumers to "act" and make an impact with every bar.

 
 000
 WTNT83 KNHC 070848
 TCVAT3
 
 RAFAEL WATCH/WARNING ADVISORY NUMBER 15
 NWS NATIONAL HURRICANE CENTER MIAMI FL     AL182024
 348 AM EST THU NOV 7 2024
 
 .HURRICANE RAFAEL
 
 CAUTION...THIS PRODUCT ONLY APPROXIMATELY CONVEYS THE EXTENT OF
 TROPICAL CYCLONE WIND AND SURGE WATCHES AND WARNINGS. PLEASE SEE
 THE LATEST PUBLIC ADVISORY FROM THE NATIONAL HURRICANE CENTER FOR
 THE PRECISE LATERAL EXTENT OF WIND WATCHES AND WARNINGS ALONG THE
 COAST...AS WELL AS THE APPROXIMATE LATERAL EXTENT OF SURGE WATCHES
 AND WARNINGS. THE PRECISE EXTENT OF SURGE WATCHES AND WARNINGS
 CAN BE FOUND IN THE NWS NATIONAL DIGITAL FORECAST DATABASE HAZARD
 GRIDS.
 
 FLZ077-078-071000-
 /O.CAN.KNHC.TR.W.1018.000000T0000Z-000000T0000Z/
 348 AM EST THU NOV 7 2024
 
 $$
 
 ATTN...WFO...KEY...
 

 
 000
 WTPZ84 KNHC 210907
 TCVEP4
 
 HILARY WATCH/WARNING ADVISORY NUMBER 20
 NWS NATIONAL HURRICANE CENTER MIAMI FL     EP092023
 207 AM PDT MON AUG 21 2023
 
 .POST-TROPICAL CYCLONE HILARY
 
 CAUTION...THIS PRODUCT ONLY APPROXIMATELY CONVEYS THE EXTENT OF
 TROPICAL CYCLONE WIND AND SURGE WATCHES AND WARNINGS. PLEASE SEE
 THE LATEST PUBLIC ADVISORY FROM THE NATIONAL HURRICANE CENTER FOR
 THE PRECISE LATERAL EXTENT OF WIND WATCHES AND WARNINGS ALONG THE
 COAST...AS WELL AS THE APPROXIMATE LATERAL EXTENT OF SURGE WATCHES
 AND WARNINGS. THE PRECISE EXTENT OF SURGE WATCHES AND WARNINGS
 CAN BE FOUND IN THE NWS NATIONAL DIGITAL FORECAST DATABASE HAZARD
 GRIDS.
 
 CAZ043-048-050-055>058-060>062-065-087-088-358-362-366>383-548-552-
 554-211015-
 /O.CAN.KNHC.TR.W.2009.000000T0000Z-000000T0000Z/
 207 AM PDT MON AUG 21 2023
 
 $$
 
 ATTN...WFO...LOX...SGX...
 

Tool Tips—July 2019

000
WTPZ64 KNHC 231124
TCUEP4

Hurricane Roslyn Tropical Cyclone Update
NWS National Hurricane Center Miami FL EP192022
520 AM MDT Sun Oct 23 2022

...ROSLYN MAKES LANDFALL IN WEST-CENTRAL MEXICO...

Satellite imagery indicates that Roslyn has made landfall in
west-central mainland Mexico near Santa Cruz in northern Nayarit
around 520 AM MDT (1120 UTC). The maximum sustained winds are
estimated to be 120 mph (195 km/h), and the minimum central pressure
is estimated to be 960 mb (28.35 inches).

SUMMARY OF 520 AM MDT...1120 UTC...INFORMATION
---------------------------------------------------
LOCATION...22.0N 105.6W
ABOUT 55 MI...90 KM NW OF TEPIC MEXICO
MAXIMUM SUSTAINED WINDS...120 MPH...195 KM/H
PRESENT MOVEMENT...NNE OR 25 DEGREES AT 16 MPH...26 KM/H
MINIMUM CENTRAL PRESSURE...960 MB...28.35 INCHES

$$
Forecaster Bucci/Brown

Whereas requests for the designation are typically submitted by brand owners, Metsä Board is one of the few material suppliers to get their paperboard grades proactively pre-qualified.

000
WTNT64 KNHC 100756
TCUAT4

Hurricane Milton Tropical Cyclone Update
NWS National Hurricane Center Miami FL AL142024
400 AM EDT Thu Oct 10 2024

...STRONG WINDS SPREAD ALONG THE EAST COAST OF FLORIDA AS THE CENTER
OF MILTON NEARS CAPE CANAVERAL...
...400 AM EDT POSITION UPDATE...

A sustained wind of 83 mph (134 km/h) and a gust to 92 mph (148
km/h) was recently reported at a Weatherstem station in Marineland.
A sustained wind of 67 mph (108 km/h) and a gust to 73 mph (117
km/h) was recently reported at a Weatherstem station on South
Hutchinson Island. A sustained wind of 54 mph (87 km/h) and a gust
of 83 mph (133 km/h) was recently reported at buoy 41069 near Ponce
de Leon Inlet. A sustained wind of 54 mph (87 km/h) and a gust of 84
mph (135 km/h) was recently reported at Daytona Beach International
Airport.

This will be the final hourly position update for Milton since the
center of the hurricane is moving offshore of the east coast of
Florida. The next full forecast advisory for Milton will be at 500
AM EDT (0900 UTC).

SUMMARY OF 400 AM EDT...0800 UTC...INFORMATION
-----------------------------------------------
LOCATION...28.5N 80.7W
ABOUT 10 MI...20 KM NW OF CAPE CANAVERAL FLORIDA
ABOUT 35 MI...55 KM E OF ORLANDO FLORIDA
MAXIMUM SUSTAINED WINDS...85 MPH...135 KM/H
PRESENT MOVEMENT...NE OR 55 DEGREES AT 18 MPH...30 KM/H
MINIMUM CENTRAL PRESSURE...977 MB...28.85 INCHES

$$
Forecaster Reinhart/Mahoney

No tropical cyclones as of Wed, 13 Nov 2024 12:37:46 GMT

When it comes to recycling, studies show that consumers express concerns about recycling success in the United States, but companies are looking to change that through education, awareness and improved access.

REBBL, a brand of SYSTM Foods, announced the expansion of its Protein portfolio with the debut of REBBL Protein Shakes.

The eye-catching design of shrink and stretch labels make them desirable to beverage-makers, but experts add that sustainability is playing a greater role in the future of this market.

Experts say factors like environmental concerns, lifestyle preferences, visual marketing strategies, product quality considerations, craft beverage trends and the efficiency of aluminum recycling processes are causing brands to turn to aluminum packaging.

MIPS cycling helmets are expensive, high-end, and out of reach, but no longer! While all the brands sell MIPS cycling helmets for very expensive prices, we are, nearly recklessly, doing the complete opposite.

Launched on the global crowdfunding platform Kickstarter.

Launched on the global crowdfunding platform Kickstarter.

Launched on the global crowdfunding platform Kickstarter.

Experienced Bicycle Accident Attorneys Commit to Helping Injured Cyclists Navigate Legal Challenges

Fenix ultra-bright rechargeable bicycle light BC26R features 1600 lumens output.

Waste management brokers like Waste Sense specialise in helping businesses find the most cost-effective and efficient garbage solutions.

Cowl Vent Grille Reduces Landfill Waste, Carbon Emissions, Part Weight and Cost

Customers looking for recycling equipment can now browse through objective reviews before making a purchase.

In order to achieve the best dust and gas separation efficiency to ensure no loss of suction, Maircle conducted 30,000 experiments and developed a cyclone filtration system with a dust and gas separation rate of 99.97%.

OTOFLY today announced that passed the GRS certification toda. This certification is a major step in OTOFLY's drive for innovation to address quality issues in the use of recycled silicone materials.

Unistar Technologies recycles over 150,000 pounds of electronic scrap through R2V3 partners

• Collaboration will help to off-set the carbon equivalent of 26,000 cars* • Integrating repurposed balls into Laykold's latest court surface technology will drive environmental and player performance